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Rok 2025
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Impact of Japanese Encephalitis in Adults: Risk Factors and Associated Challenges
PublikacjaJapanese encephalitis virus belongs to flavivirus and is the main cause of viral encephalitis in many countries of Southeast Asia with high fatality rate. JE directly affects the central nervous system and ultimately leads to neuronal cell death. JEV primarily affects the pediatric age group, but in the last few years, some reports have been published from different locations of the world reporting JE cases in adults. In this...
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Impact of postharvest processing on the health benefits of durian-derived products
PublikacjaDurian (Durio zibethinus Murr.) is a seasonal fruit with a short harvesting period, requiring postharvest processing such as cutting, peeling, freeze-drying, cooking, and frying to enhance its shelf life and nutritional quality. In this study, fresh Monthong durian (MTD), MTD Sticks, MTD Cake, and MTD Chips were analyzed for polyphenols, phenolic acids, tannins, flavonoids and thermal stability. Antioxidant activity was assessed...
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Improving compatibility between coffee or black tea ground wastes and polymer matrix via silane treatment for production sustainable biofillers
PublikacjaThe incorporation of bio-waste products into polymer materials as a fillers and colorants represents a highly significant approach for developing sustainable composites, aligning with the principles of a circular bioeconomy and contributing to reduced environmental impact. In this study, coffee grounds (CG) and black tea grounds (BTG), two mainstream food processing by-products, were employed as bio-fillers and pigments for ethylene-norbornene...
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Improving the Quality of Tyre Char as Part of a Closed-Loop Economy
PublikacjaThe escalating accumulation of waste tyres necessitates the formulation of robust and economically sustainable waste management strategies. In response to this pressing concern, pyrolysis has emerged as a pivotal technology for tyre recycling, affording valuable by-products including charcoal, pyrolysis oil, and pyrolysis gas, contingent upon specific process parameters. Of particular significance is the valorisation of the solid...
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In Silico Functional Annotation and Structural Characterization of Hypothetical Proteins in Bacillus paralicheniformis and Bacillus subtilis Isolated from Honey
PublikacjaBacillus species are ubiquitous and survive in competitive microbial communities under adverse environmental conditions. Bacillus paralicheniformis and Bacillus subtilis obtained from honey revealed a significant proportion of proteins within their genomes as uncharacterized hypothetical proteins (HPs). A total of 1007 HP sequences were evaluated, resulting in the successful annotation of 56 HPs by assigning specific functions...
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Influence of Alcohols on the Bending Rigidity and the Thickness of Phospholipid Membranes: The Role of Chain Length Mismatch
PublikacjaAlcohols influence the shape of the cells. To elucidate this phenomenon and understand the influence of alcohols on the mechanical properties of cell membranes such as bending rigidity, it is essential to investigate their effects on lipid bilayers. In this study, we explored the impact of short- and medium-chain alcohols on the bending rigidity and thickness of 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) bilayers in the...
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Insight into charge carrier dynamics and interface design of {0 0 1} TiO2 coupled with TiOF2 for photocatalytic degradation of contaminants of emerging concern
PublikacjaHerein, the role of titanium oxyfluoride (TiOF2) on the charge carriers generation and electron transport in the {0 0 1} TiO2/TiOF2 heterojunction photocatalysts was examined. Time-resolved microwave conductivity (TRMC), fluorescence lifetime spectroscopy, and DFT calculations were applied to investigate the charge carriers dynamics. These binary photocatalysts in a broad TiOF2 content were further studied in photocatalytic generation of...
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Investigation of bioprintable modified agar-based hydrogels with antimicrobial properties
PublikacjaDue to the numerous dangers arising from excessive use of antibiotics in treatments, researchers have been searching for natural alternatives to conventional antibiotics. Despite the popularity of plant extracts, essential oils, and their derivatives in herbal medicine, their applications in novel therapies are rather limited. This paper tries to open a new possibility for infection treatments by assessing the suitability of antimicrobial...
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Investigation on Swelling of Agar-Based Antibacterial Hydrogels for Hard-To-Heal Wound Dressings
PublikacjaDespite a wide range of available wound treatments, hard-to-heal wounds still pose a challenge. Hydrogels are often used as dressings for these wounds, because they sustain moisture in the wound environment, supporting the natural healing process. However, it is still not fully understood how physicochemical properties of hydrogel matrix affect the drug release process. Thus, detailed swelling kinetics examination coupled with...
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Mechanistic insights and atmospheric implications of the degradation reaction of 3-methoxy-1-propanol by reaction with hydroxyl radicals and identification of the end products in the presence of O2/NO
PublikacjaThe study investigated the degradation of 3-methoxy-1-propanol (3M1P) by OH using the M06-2X/6-311++G(d,p) level, with CCSD(T) single-point corrections. We focused on hydrogen atom abstraction from various alkyl groups within the molecule. The rate coefficient for 3M1P degradation was calculated from the sum of the rate coefficients corresponding to the removal of H-atoms from primary (-CH3), secondary (-CH2-), tertiary (-CH<),...
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Metal-organic frameworks (MOFs)-based hybrid structures in developing glucose sensors
PublikacjaAbstract The increasing number of diabetic individuals globally has highlighted the demand for nanostructured materials and devices for glucose detection, showcasing and demonstrating their importance in improving public health. Significant progress has correspondingly been made in the chemical modification of porous nanoparticles and nano-scale materials. Metal-organic frameworks (MOFs), due to their highly porous structure and...
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Methods and Instruments | Scanning Electrochemical Microscopy
PublikacjaScanning electrochemical microscopy is based on the recording of electrolysis currents (Faradaic currents) at a microelectrode (ME) probe that is scanned over the sample. Different working modes are available to couple the electrolysis at the ME to reactions at the sample. The article explains their principles and provides examples of their application. The feedback mode, the sample-generation/tip collection mode, the redox-competition...
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Mitochondrial exonuclease EXOG supports DNA integrity by the removal of single-stranded DNA flaps
PublikacjaSingle-stranded DNA (ssDNA) is an important intermediate generated during various cellular DNA transactions, primarily during long-patch base excision repair. When displaced by DNA polymerase during strand displacement DNA synthesis, ssDNA forms 5′ overhangs (flaps) that are either cleaved by DNA nucleases or protected from degradation upon binding of single-stranded DNA-binding proteins (SSB). Several nucleases are involved in...
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Monitoring of absorptive model biogas purification process using sensor matrices and gas chromatography
PublikacjaThis study examined the process of purifying model biogas using a new type of absorbent based on a Deep Eutectic Solvent (DES) and a commercially available absorbent (Genosorb) to remove acetone, toluene, and cyclohexane. The main aim of the research was to control the purification efficiency using gas chromatography (GC) and an alternative method based on sensor matrices (SM). As a result of comparing the multidimensional SM signals...
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Nanoparticle Skin Penetration: Depths and Routes Modeled In-Silico
PublikacjaNanoparticles (NPs) are increasingly explored for targeted skin penetration, particularly for pharmaceutical and cosmetic applications. However, the complex system between NP properties, skin structure, and experimental conditions poses significant challenges in predicting their penetration depth and pathways. To what depth do NPs penetrate the skin, and which pathways do they follow? These are the questions we tried to answer...
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Natural deep eutectic solvent mixed with powdered cork as a green approach for thin film SPME and determination of selected ultraviolet filters in lake waters
PublikacjaAn innovative and green determination method of ultraviolet filters, i.e. benzophenone-3 (BZ3), octocrylene (OCR), butyl methoxydibenzoylmethane (BDM) and ethylhexyl methoxycinnamate (EMC), in lake waters was proposed using thin film solid-phase microextraction (TF-SPME) and high-performance liquid chromatography with UV detection (HPLC-UV). A group of six solid natural deep eutectic solvents (NADESs) was tested along with compositions...
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Neutral pH, multioxidants Fenton oxidation of dimethyl sulfoxide and acetamidophenol as water pollutant models
PublikacjaOrganic water pollution is calling for advanced remediation methods such as the Fenton process, yet actual procedures involve transition metals at acidic pH, and generate only one oxidant, the hydroxyl radical. Here we used a solution of magnesium ions, bicarbonate ions, and hydrogen peroxide at pH 7.4 to generate reactive oxygen species for degrading dimethyl sulfoxide and acetamidophenol, as models of water pollutants. The performance...
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New insight into selective catalytic reduction of nitrogen oxides on zirconia decorated with vanadium oxide
PublikacjaSolvothermal synthesis of zirconia decorated with vanadium oxide is investigated with the aim of using it in the catalytic conversion of nitrogen oxides. The effect of the mass ratio of vanadium (1.9; 3.8 and 5.7 wt%) to pure zirconia on the physicochemical and catalytic properties of the fabricated materials is demonstrated. The physicochemical characterization of catalysts indicates a slight reduction in the size of particles...
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Novel nonsteroidal steroid sulfatase inhibitors containing glutamic acid unit
PublikacjaIn the present work, we designed and successfully synthesized novel steroid sulfatase (STS) inhibitors based on coumarin, tyramine, triazole, and flavone cores with an additional glutamic acid residue in the structure. The molecular modeling studies revealed that designed derivatives have potential to bind to the molecular target active site, at least theoretically. The biological activity of synthesized compounds was evaluated...
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On the use of black tea waste as a functional filler for manufacturing self-stabilizing polyethylene composites: In-depth thermal analysis
PublikacjaThermal and oxidative stabilization are critical aspects in the processing and exploitation of polyolefins. Black tea contains many natural antioxidants, the largest group of compounds in its composition. When used as a filler for composite manufacturing, the thermo-oxidation process of polyethylene can be slowed down. Black tea waste (BTW) generated during the process of packing tea into sachets was introduced into a bio-based...
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Opposite effect of the Cu photodeposition on the ∙OH generation and diclofenac degradation depends on the exposed anatase facet
PublikacjaExposition of a specific crystal facets and modification with co-catalysts are often used in order to improve photocatalytic activity of a material. However, considering complexity of these interactions, it is still challenging to fully understand and predict activity of a specific system. Here, we report combination of the {0 0 1} and {1 0 1} crystal facets of anatase TiO2 with CuXO co-catalyst, applied for diclofenac degradation,...
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Performance evaluation of green and conventional solvents in reversed-phase liquid chromatography based on the separation of non-polar and polar substances
PublikacjaThis study investigated the potential for replacing conventional solvents such as acetonitrile (ACN) and methanol (MeOH) with greener alternatives – ethanol (EtOH) and dimethyl carbonate (DMC) – in chromatographic separations. The aim was to assess whether these environmentally friendly solvents could achieve comparable separation performance while reducing the environmental impact of the analyses. Chromatographic separations were...
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Performances, mechanisms, and strategies for methane removal via gas biofiltration
PublikacjaControl of methane emissions has attracted widespread attention in the context of worldwide efforts to alleviate the greenhouse effect. Biofiltration, a green and cost-effective treatment process, has been widely used for the purification of methane. Currently, there is still a lack of comprehensive information on methane biofiltration. Herein, the state-of-the-art development trends of methane removal via biofiltration were comprehensively...
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Phages as potential life-saving therapeutic option in the treatment of multidrug-resistant urinary tract infections
PublikacjaUrinary tract infections (UTIs) are among the most common bacterial infections worldwide and increasing antimicrobial resistance (AMR) challenges conventional antibiotic treatments. Phage therapy (PT) has emerged as a promising alternative due to its specificity, safety and efficacy against multidrug-resistant (MDR) pathogens causing infectious diseases. PT demonstrates significant potential in treating chronic and recurrent UTIs,...
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Photocatalytic activity of zinc oxide nanorods incorporated graphitic carbon nitride catalyst
PublikacjaBackground Photocatalysts are user-friendly and serve as compatible materials for degrading industrial dye pollutants. This study utilizes zinc oxide/graphitic carbon nitride (ZnO/g-C3N4) nanocomposites against degrading methylene blue (MB). Methods The hydrothermal method assisted sonication technique was used to fabricate the ZnO/g-C3N4 composite with varying ratios of ZnO/g-C3N4 (1:0.25, 1:0.50, 1:1). The synthesized materials...
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Photocatalytic membranes based on Cu–NH2-MIL-125(Ti) protected by poly(vinylidene fluoride) for high and stable hydrogen production
PublikacjaA porous, photocatalytically active, and water-stable composite membrane has been developed based on Cu–NH2-MIL-125(Ti), a titanium-based metal–organic framework (MOF) and PVDF polymeric matrix. To tune the structural and functional properties of the PVDF/MOF composites, the loading degree of the MOF within the polymer was systematically varied. The most effective performance of the composite material was achieved with a 10% wt/wt...
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Photocatalytic selectivity oxidation of 2-phenoxy-1-phenylethanol coupled with Cd-MOF/S/Ni-NiO for hydrogen evolution performance and mechanism
PublikacjaIn this study, Cd-MOF/S/Ni–NiO (MOF = metal–organic framework) composite materials were prepared using a hydrothermal synthesis method and employed for the high-efficiency photocatalytic oxidation of the lignin β-O-4 model compound 2-phenoxy-1-phenylethanol, coupled with water splitting hydrogen evolution. The Cd-MOF/S/Ni–NiO composite material retained the petal-like morphology of Cd-MOF, with Ni-BTC acting as the precursor for...
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Porous Deep Eutectic Solvents–Unfulfilled Dream or the Next Breakthrough in Scientific Innovation?
PublikacjaPorous deep eutectic solvents (PDES) are capturing the imagination of scientists, promising a revolutionary leap in material science. These innovative materials, blending the versatility of deep eutectic solvents (DES) with the intricate architectures of porous structures, offer an exciting array of applications—from green chemistry and catalysis to energy storage and environmental remediation. However, the journey from laboratory...
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Probiotic potential of Bacillus Isolates from Polish Bee Pollen and Bee Bread
PublikacjaThe main goal of this study was the evaluation of the probiotic potential of 10 Bacillus spp. strains isolated from 5 bee bread and 3 bee pollen samples. The antagonistic interaction with Staphylococcus aureus and Escherichia coli was a primary criterion for the preliminary selection of the isolates. Three out of ten strains—PY2.3 (isolated from pollen), BP20.15 and BB10.1 (both isolated from bee bread)—were found to be possible...
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Progress in devulcanization of waste tire rubber: Upcycling towards a circular economy
PublikacjaAs a complex composite material, tire rubber has always presented significant environmental and waste management concerns due to its non-biodegradability and accumulation in landfills. The devulcanization of tire rubber has emerged as a historical challenge in the field of sustainable rubber engineering since Goodyear invented cross-linking in 1839. This review provides a comprehensive analysis of waste tire recycling processes,...
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Rapid methods for microorganism quantification in human milk: Possibilities and evaluation
PublikacjaThis study evaluates the potential of rapid microbiological methods, traditionally used for food and environmental samples, to assess human milk (HM) quality in Human Milk Banks. Several methods, including a bioluminescence, the Micro Biological Survey (MBS) colorimetric method, triphenyltetrazolium chloride (TTC) reductase test, and flow cytometry (BacSomatic™️), were compared to the PN-EN ISO 4833–1:2013-12 reference method....
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Red analytical performance index (RAPI) and software: the missing tool for assessing methods in terms of analytical performance
PublikacjaAlthough performing validation of an analytical method is a widely accepted standard, assessing and comparing the overall analytical potential covering all validation criteria is not straightforward. To answer the expectations of analytical chemists, we propose a new tool that solves this problem in a simple and user-friendly way. The Red Analytical Performance Index (RAPI) presented in this article is inspired by the Red-Green-Blue...
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Reusable Biosensor for Easy RNA Detection from Unfiltered Saliva
PublikacjaBiosensors are transforming point-of-care diagnostics by simplifying the detection process and enabling rapid, accurate testing. This study introduces a novel, reusable biosensor designed for direct viral RNA detection from unfiltered saliva, targeting SARS-CoV-2. Unlike conventional methods requiring filtration, our biosensor leverages a unique electrode design that prevents interference from saliva debris, allowing precise measurements....
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Ribes nigrum leaf extract downregulates proinflammatory gene expression and regulates redox balance in microglial cells
PublikacjaBackground: This study focuses on the investigation of the antioxidant and anti- inflammatory activities of alcohol extracts from Ribes nigrum leaves on murine BV-2 microglial Wt and Acyl-CoA oxidase 1 deficient (Acox1−/−) cell line models, useful for the investigation of some neurodegenerative disorders. Methods: The extract chemical composition was analyzed via LC-Q-Orbitrap HRMS. Various assays, including DPPH, MTT, and H2DCFDA,...
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Role of Cu and Ni in dual sites layered electrocatalysts for ammonia electrooxidation
PublikacjaSingle metal layered α-Ni(OH)2, β-Ni(OH)2 or dual metal layered NiCu hydroxides were hydrothermally deposited on nickel foam (NF) and investigated for electrochemical oxidation of ammonia. Copper induced conversion of hydrotalcite (α-Ni(OH)2) phase into the mixed hydrotalcite/brucite (α/β-NiCu) structure, which is distinguished by smaller stacks and larger interplanar distances, demonstrated the highest catalytic performance. Copper...
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Side-on phosphinoboryl platinum(ii) complexes
PublikacjaThe oxidative addition of bromo(phosphino)boranes to platinum(0) compounds enabled the formation of platinum(II) complexes with unprecedented side-on coordination of the boryl ligand. The resulting complex underwent a reaction with carbon dioxide, leading to the insertion of a CO2 molecule into the B–P bond of the phosphinoboryl ligand.
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Silver and Silver/Sodium Bisphosphonate Salts: Rare Examples of Molecular Solid Solutions and Their Biological Activity as Dual-Action Compounds
PublikacjaBisphosphonates (BPs) are an important treatment for osteoporosis and bone metastases due to their low toxicity, high thermostability, and the ability to inhibit bone resorption. Notably, BPs like alendronate, which contain a primary amine group, exhibit potent antiresorptive and antiangiogenic properties. Recent studies have focused on enhancing the BP properties by incorporating bioactive metals to increase their therapeutic...
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Structural insights into fungal and human topoisomerase II with implications for in silico antifungal drug design
PublikacjaTopoisomerases are essential enzymes regulating DNA supercoiling and disentanglement, critical for genomic integrity. While topoisomerase inhibitors are well-established in anticancer and antibacterial chemotherapy, their potential as antifungal agents remains underexplored or even not proofed. This study investigates structural distinctions between Saccharomyces cerevisiae topoisomerase II (ScTopoII) and human topoisomerase IIα...
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Structural patterns and cytotoxic activity of dinuclear Cu(II), Ni(II) and Cd(II) complexes with pyridine-based malonic acid dihydrazone
PublikacjaA dinuclear Cu(II) complex, [Cu2(L)(H2L)](ClO4)2·4H2O (Cu-1), with a condensation derivative of 2-acetylpyridine and malonic acid dihydrazide (H2L), was obtained through a direct synthesis. After recrystallization, the single-crystalline product was characterized by single crystal X-ray diffraction analysis, EPR, UV/Vis and IR spectroscopy. In the resulting dimeric Cu(II) complex, one ligand molecule is coordinated in its dianionic...
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Structure, performance, and photooxidative stability of Mater-Bi/brewers' spent grain composites as a function of filler thermomechanical and chemical modification
PublikacjaNowadays, to provide a step towards circularity, the development of sustainable polymer composites should include the application of waste-based materials that can act not only as simple fillers, reducing the use of polymers but also as functional additives, limiting or eliminating the use of synthetic components. Herein, in the presented study, the main by-product of the brewing industry, brewers' spent grain (BSG), was applied...
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Supramolecular deep eutectic solvents in extraction processes: a review
PublikacjaSolvent selection is essential for industrial and analytical extraction processes to ensure environmental safety and neutrality. Nevertheless, toxic and hazardous solvents are often used, due to their cost-effectiveness and ready availability. In green chemistry, alternative solvents such as supramolecular deep eutectic solvents are gaining attention due to their superior performance compared with traditional non-green solvents...
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Surface Charge Density Spectra: Complex Analysis of the Electrical Double Layer Developed from Measurements of Hexanol Adsorption Kinetics
PublikacjaA procedure for deriving surface charge density spectra from differential capacitance data is presented in this study, providing a deeper analysis of the generated charge. A set of simulated differential capacitance spectra was determined for three types of adsorption process control: diffusion control, adsorption control, and mixed control. Based on the differential capacitance curves and spectra, surface charge density spectra...
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Sustainable Management of Microplastic Pollutions from PET Bottles: Overview and Mitigation Strategies
PublikacjaThe widespread use of polyethylene terephthalate (PET) in bottled water packaging remains significant and is expected to increase further in the coming years. This trend raises concerns due to the generation of large amounts of waste. The degradation of PET leads to the release of low-molecular-weight substances and microplastic particles, which contaminate food products and the environment. This work highlights the significance...
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Synthesis, Structure, and Stability of Copper(II) Complexes Containing Imidazoline-Phthalazine Ligands with Potential Anticancer Activity
PublikacjaRecently, there has been great interest in metallopharmaceuticals as potential anticancer agents. In this context, presented studies aim to synthesize and evaluate of two copper(II) complexes derived from phthalazine- and imidazoline-based ligands against on three human cancer cell lines: cervix epithelial cell line (HeLa), breast epithelial-like adenocarcinoma (MCF-7), and triple–negative breast epithelial cancer cell line (MDA-MB-231),...
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The effect of substituents on the P–P and P=C bond properties in phosphanylphosphaalkenes
PublikacjaA new lithium salt of diphosphane, (iPr₂N)PhP-P(SiMe₃)Li (2), featuring two electronically differentiated substituents, is presented. Its reaction with benzophenone was then carried out, yielding a novel phosphanylphosphaalkene (3). The isolated compound was subsequently treated with nBuLi and PhLi to obtain stable activators (3a and 3b) of the potential polymerization of phosphorus-rich compounds.
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The Impact of Hybrid Flame Retardant Compositions on the Performance of Foamed Flexible Polyurethane/Ground Tire Rubber Composites
PublikacjaCurrent sustainability-oriented trends affect polyurethane (PU) materials and stimulate the incorporation of recycled or waste-based materials as fillers. Ground tire rubber (GTR) poses as an auspicious candidate due to the excellent performance of car tires. Despite the benefits related to the mechanical performance, it contributes to the increasing flammability of the resulting composites. Herein, presented work assessed the...
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The influence of chitosan's molecular weight, concentration, and dissolution method on the properties of electrophoretically deposited coatings on the Ti13Nb13Zr alloy surface
PublikacjaIn this study, the effects of molecular weight (high, medium, and low), concentration (0.1 and 0.5 %) and dissolution method (in a rarely used hydroxyacetic acid and utilizing a novel CO2 saturation) of chitosan on the microstructure, chemical composition, wettability, surface roughness, adhesion, corrosion resistance and antibacterial activity of chitosan coatings electrophoretically deposited (10 V, 1 min) on β titanium alloy...
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The interactions of Pu22 G-quadruplex, derived from c-MYC promoter sequence, with antitumor acridine derivatives – an NMR/MD combined study
PublikacjaUnsymmetrical bisacridines (UAs) represent a novel class of anticancer agents that exhibit significant antitumor activity against a wide range of cancer cell lines and solid tumors in vivo. UAs consist of two different acridine-based ring systems, which are connected by an aminoalkyl linker. Recent studies have demonstrated that UAs can suppress the c-MYC protooncogene, which is overexpressed in many tumor types. As a proposed...
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The solvent-assisted dispersive solid-phase extraction method revisited. Application for the determination of anionic surfactants
PublikacjaA new approach in solvent-assisted dispersive solid-phase extraction (SA-DSPE) procedure using a supercooled liquid was developed. It demonstrates the first use of a supercooled liquid in this technique, in particular, and in chemical analysis in general. Moreover, to the best of our knowledge, this is the first work devoted to the determination of the total concentration of anionic surfactants (as LAS, Linear alkylbenzene sulfonate)...
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Theoretical design of nanocatalysts based on (Fe2O3)n clusters for hydrogen production from ammonia
PublikacjaThe catalytic activities of high-spin small Fe(III) oxides have been investigated for efficient hydrogen production through ammonia decomposition, using the artificial force induced reaction method within the framework of density functional theory with the B3LYP hybrid exchange–correlation functional. Our results reveal that the adsorption free energy of NH3 on (Fe2O3 )n (n = 1–4) decreases with increasing cluster size up to n...