Wyszukiwarka
In-situ Cu-doped MnCo-spinel coatings for solid oxide cell interconnects processed by electrophoretic deposition
Abstrakt
The Cu doping of the Mn–Co spinel is obtained “in-situ” by electrophoretic co-deposition of CuO and Mn1.5Co1.5O4 powders and subsequent two-step reactive sintering. Cu-doped Mn1.5Co1.5O4 coatings on Crofer22APU processed by electrophoretic co-deposition method are tested in terms of long term oxidation resistance and area specific resistance tests up to 3600 h. The introduction of Cu in the spinel lead to higher level of densification of coatings for all the considered aging periods at 800 °C and stabilizes the cubic phase of the Mn1.5Co1.5O4 spinel. Corrosion rate of the Cu-doped Mn1.5Co1.5O4 coated Crofer22APU is ∼10x lower than for the uncoated Crofer22APU. The stabilization of the cubic phase due to Cu doping, which reduces the extent of the tetragonal-cubic phase transition and limits possible thermal stresses due to mismatch of coefficients of thermal expansion or volume changes, is reviewed and discussed by means of electrical conductivity measurements together with diffraction patterns and elemental analyses. These novel electrophoretic co-deposited Cu-doped MnCo spinel coatings represent an innovative approach to obtain coatings with higher density and have future applications in the view of reaching lower rates of Cr evaporation form the steel.
Cytowania
-
4 5
CrossRef
-
0
Web of Science
-
4 8
Scopus
Autorzy (6)
-
A Sabato
- Politecnico di Torino Department of Applied Science and Technology
-
H. Javed
- Politecnico di Torino Department of Applied Science and Technology
-
E Zanchi
- Politecnico di Torino Department of Applied Science and Technology
-
A Boccaccini
- University of Erlangen-Nuremberg Department of Materials Science and Engineering
-
F Smeacetto
- Politecnico di Torino Department of Energy
Cytuj jako
Pełna treść
pełna treść publikacji nie jest dostępna w portalu
Słowa kluczowe
Informacje szczegółowe
- Kategoria:
- Publikacja w czasopiśmie
- Typ:
- artykuły w czasopismach
- Opublikowano w:
-
CERAMICS INTERNATIONAL
nr 45,
strony 19148 - 19157,
ISSN: 0272-8842 - Język:
- angielski
- Rok wydania:
- 2019
- Opis bibliograficzny:
- Sabato A., Molin S., Javed H., Zanchi E., Boccaccini A., Smeacetto F.: In-situ Cu-doped MnCo-spinel coatings for solid oxide cell interconnects processed by electrophoretic deposition// CERAMICS INTERNATIONAL -Vol. 45,iss. 15 (2019), s.19148-19157
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.ceramint.2019.06.161
- Weryfikacja:
- Politechnika Gdańska
wyświetlono 149 razy
Publikacje, które mogą cię zainteresować
Electrophoretic co-deposition of Mn1.5Co1.5O4, Fe2O3 and CuO: Unravelling the effect of simultaneous addition of Cu and Fe on the microstructural, thermo-mechanical and corrosion properties of in-situ modified spinel coatings for solid oxide cell interconnects
- E. Zanchi,
- J. Ignaczak,
- S. Molin
- + 3 autorów
Electrophoretic co-deposition of Fe2O3 and Mn1,5Co1,5O4: Processing and oxidation performance of Fe-doped Mn-Co coatings for solid oxide cell interconnects
- E. Zanchi,
- B. Talic,
- A. Sabato
- + 3 autorów
Mn-Co spinel coatings on Crofer 22 APU by electrophoretic deposition: Up scaling, performance in SOFC stack at 850 °C and compositional modifications
- A. Sabato,
- E. Zanchi,
- S. Molin
- + 6 autorów