Mg2+ Doping Effects on the Structural and Dielectric Properties of CaCu3Ti4O12 Ceramics Obtained by Mechanochemical Synthesis - Publikacja - MOST Wiedzy

Twoje konto

zaloguj

Wyszukiwarka

Mg2+ Doping Effects on the Structural and Dielectric Properties of CaCu3Ti4O12 Ceramics Obtained by Mechanochemical Synthesis

Abstrakt

In this study, ceramic CaCu3Ti4O12 (CCTO) and CaCu3−xMgxTi4O12 solid solutions in which 0.1 ≤ x ≤ 0.5 were prepared by the mechanochemical method, realized by a high‐energy ball milling technique. The effects of the Mg2+ ion concentration and sintering time on the dielectric response in the prepared ceramics were investigated and discussed. It was demonstrated that, by the use of a sufficiently high energy of mechanochemical treatment, it is possible to produce a crystalline product after only 2 h of milling the mixture of the oxide substrates. Both the addition of magnesium ions and the longer sintering time of the mechanochemically‐produced ceramics cause excessive grain growth and significantly affect the dielectric properties of the materials. The X‐ray diffraction (XRD) analysis showed that all of the as‐prepared solid solutions, CaCu3−xMgxTi4O12 (0.0 ≤ x ≤ 0.5), regardless of the sintering time, exhibit a cubic perovskite single phase. The dielectric study showed two major contributions associated with the grains and the grain boundaries. The analysis of the electric modules of these ceramics confirmed the occurrence of Maxwell–Wagner type relaxation, which is dependent on the temperature.

Cytowania

  • 3

    CrossRef

  • 0

    Web of Science

  • 3

    Scopus

Autorzy (8)

Cytuj jako

Pełna treść

pobierz publikację
pobrano 58 razy
Wersja publikacji
Accepted albo Published Version
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.3390/ma14051187
Licencja
Creative Commons: CC-BY otwiera się w nowej karcie

Słowa kluczowe

Informacje szczegółowe

Kategoria:
Publikacja w czasopiśmie
Typ:
artykuły w czasopismach
Opublikowano w:
Materials nr 14,
ISSN: 1996-1944
Język:
angielski
Rok wydania:
2021
Opis bibliograficzny:
Dulian P., Bąk W., Piz M., Garbarz-Glos B., Sachuk O., Wieczorek-Ciurowa K., Lisińska-Czekaj A., Czekaj D.: Mg2+ Doping Effects on the Structural and Dielectric Properties of CaCu3Ti4O12 Ceramics Obtained by Mechanochemical Synthesis// Materials -Vol. 14,iss. 5 (2021), s.1187-
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.3390/ma14051187
Weryfikacja:
Politechnika Gdańska

wyświetlono 134 razy

Publikacje, które mogą cię zainteresować

THE APPLICATION OF THE MECHANOCHEMICAL SYNTHESIS FOR THE PREPARATION OF ADVANCED CERAMICS BASED ON BARIUM TITANATE

  • B. Garbarz-Glos,
  • W. Bąk,
  • A. Budziak
  • + 3 autorów
2020

ALTERNATIVE, DIRECT SYNTHESIS METHOD OF THE CERAMIC SOLID SOLUTIONS BASED ON BaTiO3 THROUGH A HIGH ENERGY BALL MILLING

  • W. Bąk,
  • P. Dulian,
  • B. Garbarz-Glos
  • + 2 autorów
2020

Effects of V2O5 Additive on Structure and Dielectric Properties of BiNbO4 Ceramics

2013

Dissolution of Nb-doped hydroxyapatite prepared via low-temperature mechanochemical method: Spectroscopy studies

2023
Meta Tagi