Wyszukiwarka
Polymer derived SiOC/Sn nanocomposites from a low-cost single source precursor as anode materials for lithium storage applications
Abstrakt
Metal- based materials capable of lithium (Li) alloy formation are key to realization of the next generation of high-energy density anodes for Li-ion batteries, owing to their high storage capacity. Designing a good sup- porting matrix is essential for homogeneously nesting these metallic nanodomains, to effectively utilize their high capacity while tackling the volume expansion issues. Silicon oxycarbides (SiOC), obtained via a polymer derived approach, have recently gained interest as efficient host matrices. However, the high price and limited availability of the precursors for these ceramics present a challenge for their use at a commercial level. Sn nanoparticles, measuring less than 100 nm in size, are formed in-situ within the amorphous SiOC matrix using an economical single-source precursor. The polymeric precursor was indigenously developed from a novel, low cost vinyl functionalized polysiloxane and tin dioleate as the Sn source. Tin dioleate at different wt%, viz. 33–56 %, was uniformly crosslinked with the Q-T polysiloxane and was pyrolysed at 1000 ◦C in an argon atmosphere to obtain the SiOC/Sn nanocomposites. The electrochemical characterization of SiOC/Sn ceramic nanocomposite anodes exhibit outstanding specific capacities of 650 and 750 mAh g 1 at 372 and 18.6 mA g 1, respectively after 400 charge/discharge cycles.
Cytowania
-
0
CrossRef
-
0
Web of Science
-
0
Scopus
Autorzy (12)
-
Gurdial Blugan
-
Natalia Kovalska
-
Pradeep V.W. Sasikumar
-
Wim J. Malfait
-
Silvia Paz
-
Piotr Madajski
-
Mirosław Sawczak dr hab. inż.
-
Matthias M. Koebel
Cytuj jako
Pełna treść
- Wersja publikacji
- Accepted albo Published Version
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.est.2024.111676
- Licencja
-
otwiera się w nowej karcie
Słowa kluczowe
Informacje szczegółowe
- Kategoria:
- Publikacja w czasopiśmie
- Typ:
- artykuły w czasopismach
- Opublikowano w:
-
Journal of Energy Storage
nr 89,
ISSN: 2352-152X - Język:
- angielski
- Rok wydania:
- 2024
- Opis bibliograficzny:
- Blugan G., Kovalska N., Knozowski D., Sasikumar P. V., Malfait W. J., Paz S., Madajski P., Leśniewski M., Sawczak M., Santhosh B., Wilamowska-Zawłocka M., Koebel M. M.: Polymer derived SiOC/Sn nanocomposites from a low-cost single source precursor as anode materials for lithium storage applications// Journal of Energy Storage -Vol. 89, (2024), s.111676-
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.est.2024.111676
- Źródła finansowania:
-
- Publikacja bezkosztowa
- Weryfikacja:
- Politechnika Gdańska
wyświetlono 39 razy
Publikacje, które mogą cię zainteresować
Silicon oxycarbide-tin nanocomposite derived from a UV crosslinked single source preceramic precursor as high-performance anode materials for Li-ion batteries
- D. Knozowski,
- P. Vallachira Warriam Sasikumar,
- R. Dubey
- + 7 autorów
Material Design and Optimisation of Electrochemical Li-Ion Storage Properties of Ternary Silicon Oxycarbide/Graphite/Tin Nanocomposites
- D. Knozowski,
- P. Vallachira Warriam Sasikumar,
- P. Madajski
- + 4 autorów
Silicon Oxycarbide (SiOC) Ceramic Materials as Anodes for Lithium Ion Batteries
- M. Wilamowska-Zawłocka,
- V. Pradeep,
- M. Graczyk-Zajac
- + 2 autorów
Mechanisms of Li deposition on graphite anodes: surface coverage and cluster growth
- A. Bhandari,
- J. Dziedzic,
- J. R. Owen
- + 2 autorów