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Development of novel optoelectronic sensory structures utilising colour centres in nanodiamonds and their interactions with analytes
PublikacjaThe goal of this dissertation was to develop and assess surface modifications of fluorescent nanodiamonds (NDs) for optical sensing. Three modification routes were tested, each aimed at a different application. Modification with poly-L-lysine (pLys) was verified for optical sensing of pH via an interrelationship between electrically negative (NV¯) and neutral (NV0) nitrogen-vacancy centres. Immobilisation of Ochratoxin A (OTA),...
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Cu-HKUST-1 and Hydroxyapatite–The Interface of Two Worlds toward the Design of Functional Materials Dedicated to Bone Tissue Regeneration
PublikacjaA novel composite based on biocompatible hydroxyapatite (HA) nanoparticles and Cu-HKUST-1 (Cu-HKUST-1@HA) has been prepared following a layer-by-layer strategy. Cu-HKUST-1 was carefully selected from a group of four Cu-based metal−organic frameworks as the material with the most promising antimicrobial activity. The formation of a colloidal Cu- HKUST-1 layer on HA nanoparticles was confirmed by various techniques, e.g., infrared...
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Nitrogen transformation during fermentation in agricultural biogas plants
PublikacjaThe aim of the present study was to determine changes in the organic nitrogen fraction in the liquid fraction of the digestate during laboratory tests of mono- and co-digestion. Three agricultural wastes were tested: distillery residue, cattle slurry and corn silage. In the mono-fermentation tests, the initial total nitrogen concentration depended on the feedstock used. As a result of the hydrolysis and ammonification of the organic...
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Modeling organic nitrogen conversions in activated sludge bioreactors
PublikacjaFor biological nutrient removal (BNR) systems designed to maximize nitrogen removal, the effluent total nitrogen (TN) concentration may range from 2.0 to 4.0 g N/m3 with about 25-50% in the form of organic nitrogen (ON). In this study, current approaches to modeling organic N conversions (separate processes vs. constant contents of organic fractions) were compared. A new conceptual model of ON conversions was developed and combined...
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Enzymatic cross-linking of β-lactoglobulin in solution and at air–water interface: Structural constraints
PublikacjaEffective and controlled use of cross-linking enzymes in structure engineering of food systems depends on characterization of the favorable conditions for enzyme-substrate complex and the limiting factors for the desired modification. In this respect, we analyzed the susceptibility of bovine β-lactoglobulin (BLG) to enzymatic cross-linking by Trichoderma reesei tyrosinase (TrTyr) and transglutaminase (TG). Changes in BLG molecular...
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The application of magnetic fluids in sealing nodes designed for operation in difficult conditions and in machines used in sea environment
PublikacjaPresented in article MF seals are being researched for sea technology purposes due to their excellenttightness and low resistance of motion. These features are most valuable for ring propellers and ship'smain propeller shaft. There are more reasons why technologists payf significant attention for various MFseals applications in their difficult operating conditions. For instance, an advanced pumping systemsare designed with contactless...
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The application of magnetic fluids in sealing nodes designed for operation in difficult conditions and in machines used in sea environment
PublikacjaPresented in article MF seals are being researched for sea technology purposes due to their excellent tightness and low resistance of motion. These features are most valuable for ring propellers and ship's main propeller shaft. There are more reasons why technologists payf significant attention for various MFseals applications in their difficult operating conditions. For instance, an advanced pumping systems are designed with contactless...