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Superconductivity in the niobium-rich compound Nb5Se4

Abstract

The niobium rich selenide compound Nb5Se4 was synthesized at ambient pressure by high-temperature solid–state reaction in a sealed Ta tube. Resistivity and heat capacity measurements reveal that this compound is superconducting, with a Tc = 1.85K. The electronic contribution to the specific heat γ and the Debye temperature are found to be 18.1 mJmol−1K−2 and 298 K respectively. The calculated electron-phonon coupling constant λep = 0.5 and the ΔCp/γTc = 1.42 ratio imply that Nb5Se4 is a weak coupling BCS superconductor. The upper critical field and coherence length are found to be 1.44 T and 15.1 nm, respectively.

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Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
JOURNAL OF ALLOYS AND COMPOUNDS no. 649, pages 906 - 909,
ISSN: 0925-8388
Language:
English
Publication year:
2015
Bibliographic description:
Klimczuk T., Baroudi K., Krizan J., Kozub A., Cava R.: Superconductivity in the niobium-rich compound Nb5Se4// JOURNAL OF ALLOYS AND COMPOUNDS. -Vol. 649, (2015), s.906-909
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.jallcom.2015.06.281
Verified by:
Gdańsk University of Technology

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