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Synthesis, structure and properties of poly(ether-urethane)s synthesized using a tri-functional oxypropylated glycerol as a polyol
Abstract
The main aim of this work was to obtain poly(ether-urethane)s using tri-functional polyoxyalkylene polyol (Rokopol G1000), which introducing the chemical cross-links into the structure of polyurethanes. Poly(ether-urethane)s were prepared using two-step method, called prepolymer method, which involves in the first step the reaction of 4,4'-diphenylmethane diisocyanate (MDI) and tri-functional polypropylene glycol glycerol triether polyol. In the second step, prepolymer chains were extended by using: 1,6-hexanediol, 1,4-butanediol in the mixture with poly(ethylene glycol), and poly(ethylene glycol). The prepolymer chains extending was realized at three different molar ratios of NCO groups (presented in prepolymer) to OH groups (presented in chain extender) i.e. 0.95, 1.00 or 1.05. The influence of chain extender type on the chemical structure, selected mechanical properties and termo-mechanical properties of the obtained poly(ether-urethane)s was investigated. The results showed that applying different types of chain extenders results in obtaining materials with diversified mechanical properties, but very similar thermal stability. The performance of obtained poly(ether-urethane)s is mostly affected by the chemical cross-links, which were introduced into soft segments by trifunctional polyetherol.
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- DOI:
- Digital Object Identifier (open in new tab) 10.1007/s10973-016-5928-2
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
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JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
no. 127,
edition 427,
pages 1 - 13,
ISSN: 1388-6150 - Language:
- English
- Publication year:
- 2016
- Bibliographic description:
- Datta J., Kosiorek P., Włoch M.: Synthesis, structure and properties of poly(ether-urethane)s synthesized using a tri-functional oxypropylated glycerol as a polyol// JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY. -Vol. 127, iss. 427 (2016), s.1-13
- DOI:
- Digital Object Identifier (open in new tab) 10.1007/s10973-016-5928-2
- Verified by:
- Gdańsk University of Technology
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