Wyszukiwarka
Curing epoxy resin with anhydride in the presence of halloysite nanotubes: the contradictory effects of filler concentration
Abstrakt
Epoxy resins can be cured with a wide variety of curing agents such as amines and anhydrides, but anhydride curing would be more favorable for research purpose because of epoxy-anhydride curing taking place slowly at room temperature. Incorporation of natural nanosized minerals into epoxy is of environmental importance. Halloysite nanotubes (HNTs) display chemical properties similar to those of silica and alumina, and hydroxyl groups positioned somewhere in between or at the edge of HNTs layers give them potential to participate in epoxy ring-opening. Curing epoxy/anhydride systems containing HNTs at various concentrations (0.5, 1 and 2 wt.% based on 100 parts by weight of epoxy) via nonisothermal differential scanning calorimetry at three heating rates (5, 10 and 15 °C.min−1) is discussed here to study the effect of HNTs concentration on epoxy-anhydride curing reactions. The extent of crosslinking reaction was promoted at 0.5 and 1 wt.% of HNTs as a result of participation of hydroxyl groups of HNTs in epoxide ring-opening, while at 2 wt.% of HNTs a hindered curing was the case, which has been speculated on account of probable deactivation of anhydride curing agent by the internal surface of HNTs pursued by anhydride molecules diffusion into the lumen of HNTs.
Cytowania
-
7 2
CrossRef
-
0
Web of Science
-
7 1
Scopus
Autorzy (7)
-
Maryam Jouyandeh
- University of Isfahan, Faculty of Engineering Department of Chemical Engineering
-
Zohre Karami
- University of Isfahan, Faculty of Engineering Department of Chemical Engineering
-
Omid Moini
- University of Isfahan, Faculty of Engineering Department of Chemical Engineering
-
Seyed Paran
- ran Polymer and Petrochemical Institute, Tehran, Iran Department of Polymer Processing
-
Ali Jannesari
- Institute for Color Science and Technology, Tehran, Iran Department of Resin and Additives
-
Mohammad Saeb
- Institute for Color Science and Technology, Tehran, Iran Department of Resin and Additives
Cytuj jako
Pełna treść
pełna treść publikacji nie jest dostępna w portalu
Słowa kluczowe
Informacje szczegółowe
- Kategoria:
- Publikacja w czasopiśmie
- Typ:
- artykuł w czasopiśmie wyróżnionym w JCR
- Opublikowano w:
-
PROGRESS IN ORGANIC COATINGS
nr 126,
strony 129 - 135,
ISSN: 0300-9440 - Język:
- angielski
- Rok wydania:
- 2019
- Opis bibliograficzny:
- Jouyandeh M., Karami Z., Moini O., Formela K., Paran S., Jannesari A., Saeb M.: Curing epoxy resin with anhydride in the presence of halloysite nanotubes: the contradictory effects of filler concentration// PROGRESS IN ORGANIC COATINGS. -Vol. 126, (2019), s.129-135
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.porgcoat.2018.10.007
- Weryfikacja:
- Politechnika Gdańska
wyświetlono 177 razy
Publikacje, które mogą cię zainteresować
Effect of Surface Treatment of Halloysite Nanotubes (HNTs) on the Kinetics of Epoxy Resin Cure with Amines
- V. Akbari,
- M. Jouyandeh,
- S. Paran
- + 9 autorów
Acid-aided epoxy-amine curing reaction as reflected in epoxy/Fe3O4 nanocomposites: Chemistry, mechanism, and fracture behavior
- M. Jouyandeh,
- M. Shabanian,
- M. Khaleghi
- + 6 autorów
In-Out Surface Modification of Halloysite Nanotubes (HNTs) for Excellent Cure of Epoxy: Chemistry and Kinetics Modeling
- S. Moghari,
- S. H. Jafari,
- M. K. Yazdi
- + 4 autorów
Curing epoxy with ethylenediaminetetraacetic acid (EDTA) surface-functionalized Co Fe3-O4 magnetic nanoparticles
- M. Jouyandeh,
- M. Ganjali,
- J. A. Ali
- + 6 autorów