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Effect of Surface Treatment of Halloysite Nanotubes (HNTs) on the Kinetics of Epoxy Resin Cure with Amines
Abstrakt
The epoxy/clay nanocomposites have been extensively considered over years because of their low cost and excellent performance. Halloysite nanotubes (HNTs) are unique 1D natural nanofillers with a hollow tubular shape and high aspect ratio. To tackle poor dispersion of the pristine halloysite (P-HNT) in the epoxy matrix, alkali surface-treated HNT (A-HNT) and epoxy silane functionalized HNT (F-HNT) were developed and cured with epoxy resin. Nonisothermal differential scanning calorimetry (DSC) analyses were performed on epoxy nanocomposites containing 0.1 wt.% of P-HNT, A-HNT, and F-HNT. Quantitative analysis of the cure kinetics of epoxy/amine system made by isoconversional Kissinger–Akahira–Sunose (KAS) and Friedman methods made possible calculation of the activation energy (Eα) as a function of conversion (α). The activation energy gradually increased by increasing α due to the diffusion-control mechanism. However, the average value of Eα for nanocomposites was lower comparably, suggesting autocatalytic curing mechanism. Detailed assessment revealed that autocatalytic reaction degree, m increased at low heating rate from 0.107 for neat epoxy/amine system to 0.908 and 0.24 for epoxy/P-HNT and epoxy/A-HNT nanocomposites, respectively, whereas epoxy/F-HNT system had m value of 0.072 as a signature of dominance of non-catalytic reactions. At high heating rates, a similar behavior but not that significant was observed due to the accelerated gelation in the system. In fact, by the introduction of nanotubes the mobility of curing moieties decreased resulting in some deviation of experimental cure rate values from the predicted values obtained using KAS and Friedman methods.
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Autorzy (12)
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Vahideh Akbari
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Maryam Jouyandeh
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Seyed Paran
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Mohammad Ganjali
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Hossein Abdollahi Dr
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Henri Vahabi
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Zahed Ahmadi
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Amin Esmaeili
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Ahmad Mohaddespour
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Sajjad Habibzadeh
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Mohammad Saeb
Cytuj jako
Pełna treść
- Wersja publikacji
- Accepted albo Published Version
- Licencja
-
otwiera się w nowej karcie
Słowa kluczowe
Informacje szczegółowe
- Kategoria:
- Publikacja w czasopiśmie
- Typ:
- artykuły w czasopismach
- Opublikowano w:
-
Polymers
nr 12,
ISSN: 2073-4360 - Język:
- angielski
- Rok wydania:
- 2020
- Opis bibliograficzny:
- Akbari V., Jouyandeh M., Paran S., Ganjali M., Abdollahi H., Vahabi H., Ahmadi Z., Formela K., Esmaeili A., Mohaddespour A., Habibzadeh S., Saeb M.: Effect of Surface Treatment of Halloysite Nanotubes (HNTs) on the Kinetics of Epoxy Resin Cure with Amines// Polymers -Vol. 12,iss. 4 (2020), s.930-
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.3390/polym12040930
- Weryfikacja:
- Politechnika Gdańska
wyświetlono 135 razy
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