Wyniki wyszukiwania dla: CO- AND FE-BASED CATALYSTS

• Evaluation of electrosynthesized reduced graphene oxide–Ni/Fe/Co-based (oxy)hydroxide catalysts towards the oxygen evolution reaction

  Publikacja

  • K. Cysewska
  • M. S. Łapiński
  • M. Zając
  • J. Karczewski
  • P. Jasiński
  • S. Molin

  - Beilstein Journal of Nanotechnology - Rok 2023

  In this work, the specific role of the addition of graphene oxide (GO) to state-of-the-art nickel–iron (NiFe) and cobalt–nickel–iron (CoNiFe) mixed oxides/hydroxides towards the oxygen evolution reaction (OER) is investigated. Morphology, structure, and OER catalytic activity of the catalysts with and without GO were studied. The catalysts were fabricated via a two-step electrodeposition. The first step included the deposition...

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• M-BDC (M = Co and/ or Fe) MOFs as effective catalysts for hydrogen generation via hydrolysis of sodium borohydride

  Publikacja

  • M. Alaide de Oliveira
  • E. Silva Souza
  • J. de Jesus Santana
  • N. Łukasik
  • B. Stefany Lima da Silva
  • B. Silva Barros
  • J. Kulesza

  - APPLIED SURFACE SCIENCE - Rok 2023

  Mono- (Co-BDC, Fe-BDC) and bimetallic FeCo-BDC Metal-Organic Frameworks are successfully synthesized by the solvothermal method in DMF at 150 °C within 15 h and tested as catalysts for sodium borohydride hydrolysis. The materials are characterized by FTIR, PXRD, TGA, ICP-OES, H2-TPR, BET model, and SEM-EDS. The catalytic activity of these materials is studied for dehydrogenation of sodium borohydride in water at various temperatures...

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• Forming Ni-Fe and Co-Fe Bimetallic Structures on SrTiO3-Based SOFC Anode Candidates

  Publikacja

  • K. Kujawska
  • W. Koliński
  • B. Bochentyn

  - Fuels - Rok 2024

  The aim of this work was to verify the possibility of forming Ni-Fe and Co-Fe alloys via topotactic ion exchange exsolution in Fe-infiltrated (La,Sr,Ce)0.9(Ni,Ti)O3-δ or (La,Sr,Ce)0.9(Co,Ti)O3-δ ceramics. For this purpose, samples were synthesized using the Pechini method and then infiltrated with an iron nitrate solution. The reduction process in dry H2 forced the topotactic ion exchange exsolution, leading to the formation of...

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• Enhancing CO2 Conversion to CO over Plasma-Deposited Composites Based on Mixed Co and Fe Oxides

  Publikacja

  • H. Kierzkowska-Pawlak
  • M. Ryba
  • M. Fronczak
  • R. Kapica
  • J. Sielski
  • M. Sitarz
  • P. Zając
  • K. Łyszczarz
  • J. Tyczkowski

  - Catalysts - Rok 2021

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• Fe local structure in Pt-free nitrogen-modified carbon based electrocatalysts: XAFS study

  Publikacja

  • A. Witkowska
  • G. Giuli
  • M. Renzi
  • F. Nobili
  • M. Longhi

  - Journal of Physics : Conference Series - Rok 2016

  The paper presents a new results on the bonding environment (coordination number and geometry) and on oxidation states of Fe in nitrogen-modified Fe/C composites used as Pt-free catalysts for oxygen reduction in Direct Hydrogen Fuel Cells. Starting from glucose or fructose, two catalysts displaying different electrochemical performance were prepared and studied in the form of pristine powder and thin catalytic layer of electrode...

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• XPS measurements of the Fe-Bi based glass

  Dane Badawcze

  open access

  • M. Łapiński

  Fe-Si-O and Fe-Si-Pb-O glass was measured by XPS method. The influence of Pb dopand on the glass structure, including the valence of iron, was investigated. The influence of the annealing temperature on the behavior of iron in glass was also investigated. Studies have confirmed the mixed valence of iron in glasses and a high proportion of metallic Fe.

• Pendant Proton-Relays Systematically Tune the Rate and Selectivity of Electrocatalytic Ammonia Generation in a Fe-Porphyrin Based Metal-Organic Framework

  Publikacja

  • A. Ghatak
  • S. S. Golla
  • S. Sappati
  • L. Itamar
  • R. Shimoni
  • I. Hod

  - ANGEWANDTE CHEMIE-INTERNATIONAL EDITION - Rok 2024

  Electrocatalytic nitrite reduction (eNO2RR) is a promising alternative route to produce ammonia (NH3). Until now, several molecular catalysts have shown capability to homogeneously reduce nitrite to NH3, while taking advantage of added secondary-sphere functionalities to direct catalytic performance. Yet, realizing such control over heterogeneous electrocatalytic surfaces remains a challenge. Herein, we demonstrate that heterogenization...

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• XPS measurement of the Fe-Ti based materials

  Dane Badawcze

  open access

  • M. Łapiński

  The mono‐ and bimetal‐modified (Pd, Cu) titanium(IV) oxide and iron oxide (III) photocatalysts were prepared by chemical reduction method and characterized using XPS method. The composition of elements incorporated in the surface layer of mono- and bimetallic photocatalysts was determined by XPS analysis, as well as the valence state of elements. Measurements...

• XPS measurements of the Fe-Pb-Si based glass

  Dane Badawcze

  open access

  • M. Łapiński

  Glass samples with nominal compositions of xFe2O3-(50-x)PbO–50SiO2, where x = 12.5, 15, 17.5 (mol%) were prepared. Analytical grade substrates were used: Fe2O3, SiO2, and PbO. The appropriate amounts of reagents were mixed in an agate mortar. The powders obtained were melted in porcelain un-enamelled crucibles in an electric furnace at a temperature...

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