The influence of dynamic load changes on temporary impedance in hydrogen fuel cells, selection and validation of the electrical equivalent circuit
Abstrakt
To achieve optimal performance of a fuel cell, a reliable monitoring and diagnostic method is required. The currently utilized methods give limited information or they are impossible to use under dynamic working conditions. To obtain comprehensive information about the fuel cell operation we utilized novel dynamic electrochemical impedance spectroscopy. Impedance measurements in dynamic mode were performed on a hydrogen fuel cell, working under various conditions. By utilizing this new methodology, optimum parameters for cell operation were determined. An electrical equivalent circuit for cathodic processes was determined. Presence of an interlayer, between the membrane and the catalytic layer, was postulated. The instantaneous impedance spectra were analysed under the function of current load. The complete character of the impedance spectra was revealed, and the electrical equivalent circuit was validated. The presence of the interlayer was established by impedance analysis and by a profile of platinum content changes in the membrane electrode assembly. The proposed investigation methodology provides monitoring and diagnostics of fuel cell components, which gives the possibility of streamlined management of the fuel cell operation.
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APPLIED ENERGY
nr 251,
ISSN: 0306-2619 - Język:
- angielski
- Rok wydania:
- 2019
- Opis bibliograficzny:
- Darowicki K., Janicka E., Mielniczek M., Zieliński A., Gaweł Ł., Mitzel J., Hunger J.: The influence of dynamic load changes on temporary impedance in hydrogen fuel cells, selection and validation of the electrical equivalent circuit// APPLIED ENERGY -Vol. 251,iss. 113396 (2019),
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.apenergy.2019.113396
- Bibliografia: test
-
- Mai T, Cole W, Reimers A. Setting cost targets for zero-emission electricity generation technologies. Applied Energy 2019;250:582-92. doi:10.1016/j.apenergy.2019.05.001. otwiera się w nowej karcie
- Conte M. ENERGY | Hydrogen Economy. Encyclopedia of Electrochemical Power Sources, Elsevier; 2009, p. 232-54. doi:10.1016/B978-044452745-5.00084-8. otwiera się w nowej karcie
- Zhang T, Wang P, Chen H, Pei P. A review of automotive proton exchange membrane fuel cell degradation under start-stop operating condition. Applied Energy 2018;223:249-62. doi:10.1016/j.apenergy.2018.04.049. otwiera się w nowej karcie
- Löbberding L, Madlener R. Techno-economic analysis of micro fuel cell cogeneration and storage in Germany. Applied Energy 2019;235:1603-13. doi:10.1016/j.apenergy.2018.11.023. otwiera się w nowej karcie
- Sulaiman N, Hannan MA, Mohamed A, Ker PJ, Majlan EH, Wan Daud WR. Optimization of energy management system for fuel-cell hybrid electric vehicles: Issues and recommendations. Applied Energy 2018;228:2061-79. doi:10.1016/j.apenergy.2018.07.087. otwiera się w nowej karcie
- Antolini E, Giorgi L, Pozio A, Passalacqua E. Influence of Nafion loading in the catalyst layer of gas-diffusion electrodes for PEFC. Journal of Power Sources 1999;77:136-42. doi:10.1016/S0378-7753(98)00186-4. otwiera się w nowej karcie
- Shi Z, Wang X, Draper O. Effect of Porosity Distribution of Gas Diffusion Layer on Performance of Proton Exchange Membrane Fuel Cells. vol. 11, ECS; 2007, p. 637-46. doi:10.1149/1.2780977. otwiera się w nowej karcie
- Kumbur EC, Mench MM. FUEL CELLS -PROTON-EXCHANGE MEMBRANE FUEL CELLS | Water Management. Encyclopedia of Electrochemical Power Sources, Elsevier; 2009, p. 828-47. doi:10.1016/B978-044452745-5.00862-5. otwiera się w nowej karcie
- Niu Z, Bao Z, Wu J, Wang Y, Jiao K. Two-phase flow in the mixed-wettability gas diffusion layer of proton exchange membrane fuel cells. Applied Energy 2018;232:443-50. doi:10.1016/j.apenergy.2018.09.209. otwiera się w nowej karcie
- Li Y, Yang J, Song J. Structure models and nano energy system design for proton exchange membrane fuel cells in electric energy vehicles. Renewable and Sustainable Energy Reviews 2017;67:160-72. doi:10.1016/j.rser.2016.09.030. otwiera się w nowej karcie
- El-kharouf A, Mason TJ, Brett DJL, Pollet BG. Ex-situ characterisation of gas diffusion layers for proton exchange membrane fuel cells. Journal of Power Sources 2012;218:393-404. doi:10.1016/j.jpowsour.2012.06.099. otwiera się w nowej karcie
- Slepski P, Janicka E, Darowicki K, Pierozynski B. Impedance monitoring of fuel cell stacks. Journal of Solid State Electrochemistry 2015;19:929-33. doi:10.1007/s10008-014-2676-8. otwiera się w nowej karcie
- Darowicki K, Janicka E, Slepski P. Study of Direct Methanol Fuel Cell Process Dynamics Using Dynamic Electrochemical Impedance Spectroscopy. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE 2012;7:12090-7.
- Darowicki K, Gawel L. Impedance Measurement and Selection of Electrochemical Equivalent Circuit of a Working PEM Fuel Cell Cathode. Electrocatalysis 2017;8:235-44. doi:10.1007/s12678-017-0363-0. otwiera się w nowej karcie
- Slepski P, Darowicki K, Janicka E, Lentka G. A complete impedance analysis of electrochemical cells used as energy sources. Journal of Solid State Electrochemistry 2012;16:3539-49. doi:10.1007/s10008-012-1825-1. otwiera się w nowej karcie
- Wysocka J, Krakowiak S, Ryl J, Darowicki K. Investigation of the electrochemical behaviour of AA1050 aluminium alloy in aqueous alkaline solutions using Dynamic Electrochemical Impedance Spectroscopy. Journal of Electroanalytical Chemistry 2016;778:126-36. doi:10.1016/j.jelechem.2016.08.028. otwiera się w nowej karcie
- Darowicki K, Ślepski P, Szociński M. Application of the dynamic EIS to investigation of transport within organic coatings. Progress in Organic Coatings 2005;52:306-10. doi:10.1016/j.porgcoat.2004.06.007. otwiera się w nowej karcie
- Darowicki K. Theoretical description of the measuring method of instantaneous impedance spectra. Journal of Electroanalytical Chemistry 2000;486:101-5. doi:10.1016/S0022- 0728(00)00110-8. otwiera się w nowej karcie
- Darowicki K, Orlikowski J, Lentka G. Instantaneous impedance spectra of a non-stationary model electrical system. Journal of Electroanalytical Chemistry 2000;486:106-10. doi:10.1016/S0022-0728(00)00111-X. otwiera się w nowej karcie
- Cahan BD. AC Impedance Investigations of Proton Conduction in Nafion TM . Journal of The Electrochemical Society 1993;140:L185. doi:10.1149/1.2221160. otwiera się w nowej karcie
- Wintersgill MC, Fontanella JJ. Complex impedance measurements on Nafion. Electrochimica Acta 1998;43:1533-8. doi:10.1016/S0013-4686(97)10049-4. otwiera się w nowej karcie
- Makharia R, Mathias MF, Baker DR. Measurement of Catalyst Layer Electrolyte Resistance in PEFCs Using Electrochemical Impedance Spectroscopy. Journal of The Electrochemical Society 2005;152:A970. doi:10.1149/1.1888367. otwiera się w nowej karcie
- Reshetenko T, Kulikovsky A. Impedance Spectroscopy Study of the PEM Fuel Cell Cathode with Nonuniform Nafion Loading. Journal of The Electrochemical Society 2017;164:E3016-21. doi:10.1149/2.0041711jes. otwiera się w nowej karcie
- Song C, Tang Y, Zhang JL, Zhang J, Wang H, Shen J, et al. PEM fuel cell reaction kinetics in the temperature range of 23-120°C. Electrochimica Acta 2007;52:2552-61. doi:10.1016/j.electacta.2006.09.008. otwiera się w nowej karcie
- Singh RK, Devivaraprasad R, Kar T, Chakraborty A, Neergat M. Electrochemical Impedance Spectroscopy of Oxygen Reduction Reaction (ORR) in a Rotating Disk Electrode Configuration: Effect of Ionomer Content and Carbon-Support. Journal of the Electrochemical Society 2015;162:F489-98. doi:10.1149/2.0141506jes. otwiera się w nowej karcie
- Paulus UA, Schmidt TJ, Gasteiger HA, Behm RJ. Oxygen reduction on a high-surface area Pt/Vulcan carbon catalyst: a thin-film rotating ring-disk electrode study. Journal of Electroanalytical Chemistry 2001;495:134-45. doi:10.1016/S0022-0728(00)00407-1. otwiera się w nowej karcie
- Wagner N, Friedrich KA. FUEL CELLS -PROTON-EXCHANGE MEMBRANE FUEL CELLS | Dynamic Operational Conditions. Encyclopedia of Electrochemical Power Sources, Elsevier; 2009, p. 912- 30. doi:10.1016/B978-044452745-5.00239-2. otwiera się w nowej karcie
- Darowicki K, Janicka E, Mielniczek M, Zielinski A, Gawel L, Mitzel J, et al. Implementation of DEIS for reliable fault monitoring and detection in PEMFC single cells and stacks. Electrochimica Acta 2018. doi:10.1016/j.electacta.2018.09.105. otwiera się w nowej karcie
- Kulikovsky AA, Eikerling M. Analytical solutions for impedance of the cathode catalyst layer in PEM fuel cell: Layer parameters from impedance spectrum without fitting. Journal of Electroanalytical Chemistry 2013;691:13-7. doi:10.1016/j.jelechem.2012.12.002. otwiera się w nowej karcie
- Paik CH, Jarvi TD, O'Grady WE. Extent of PEMFC Cathode Surface Oxidation by Oxygen and Water Measured by CV. Electrochemical and Solid-State Letters 2004;7:A82. doi:10.1149/1.1649698. otwiera się w nowej karcie
- Boukamp B. A Nonlinear Least Squares Fit procedure for analysis of immittance data of electrochemical systems. Solid State Ionics 1986;20:31-44. doi:10.1016/0167-2738(86)90031-7. otwiera się w nowej karcie
- Pearson K. X. On the criterion that a given system of deviations from the probable in the case of a correlated system of variables is such that it can be reasonably supposed to have arisen from random sampling. The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science 1900;50:157-75. doi:10.1080/14786440009463897. otwiera się w nowej karcie
- Źródła finansowania:
- Weryfikacja:
- Politechnika Gdańska
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