Filtry
wszystkich: 76
Wyniki wyszukiwania dla: PHOTOCHEMISTRY
-
Mechanism of phenol decomposition on FeCTiO2 and FeTiO2 photocatalysts via photo-Fenton process
Publikacja -
Photocatalytic decomposition of benzo-[a]-pyrene on the surface of acrylic, latex and mineral paints. Influence of paint composition
Publikacja -
Investigation of OH radicals formation on the surface of TiO2/N photocatalyst at the presence of terephthalic acid solution. Estimation of optimal conditions
Publikacja -
Hybridization of adsorptivity with photocatalytic activity—carbon-coated anatase
Publikacja -
Salicylaldimine-based receptor as a material for iron(III) selective optical sensing
Publikacjaα,α-Bis(salicylimino)-m-xylene (L) was prepared using both conventional and microwave-assisted procedure. The compound exhibits ability to colorimetric recognition of iron(III) ions in aqueous environment, what is shown by significant color change from yellow to purple. In DMSO : water (9:1 v/v) solvent system receptor creates with iron(III) cations complexes of 2:1 stoichiometry (L:Fe3+) with stability constant (log K) 7.54±0.21....
-
Photocatalytic activity of solvothermal prepared BiOClBr with imidazolium ionic liquids as a halogen sources in cytostatic drugs removal
PublikacjaIn this work, the BiOClBr, as a new family of bismuth based semiconductors, was successfully applied to remove of cytostatic drugs from water under UV-Vis light irradiation. BiOCl, BiOBr and BiOClBr were synthesized using two steps solvothermal method in glycerol. The inorganic salts (KCl and KBr) and 1-butyl-3-metylimidazolium chloride (BmimCl) and 1-butyl-3-metylimidazolium bromide (BmimBr) ionic liquids (ILs) were used as the...
-
Excited-state proton transfer and geminate recombination in the molecular cage of β-cyclodextrin
PublikacjaExcited-state proton transfer and geminate recombination in aqueous heptakis(2,6-di-O-methyl)-β-cyclodextrin have been compared with those in water by monitoring the photoinduced prototropic tautomerization of 6-hydroxyquinoline, which occurs via forming anionic intermediate. Enol deprotonation decelerates by 18 times whereas its reverse process accelerates slightly with encapsulation. The imine protonation of the intermediate...
-
TiO2-C nanocomposite synthesized via facile surfactant-assisted method as a part of less energy-consuming LED-based photocatalytic system for environmental applications
PublikacjaA novel facile method was used to incorporate carbon into the titania structure. An alternative synthesis method of carbon-doped TiO2 has been proposed by using a widely used and cheap surfactant. During the process, cetyltrimethylammonium bromide plays a dual role, as a morphology modifier and as a carbon source. The presented approach allows obtained TiO2-C nanostructures to be anatase nanocrystals with carbon being deposited...
-
Shape-dependent enhanced photocatalytic effect under visible light of Ag3PO4 particles
PublikacjaSilver phosphate (Ag3PO4) could be considered as visible light induced photocatalyst for pollutants degradation, due to its narrow band gap (∼2.4 eV). However, Ag3PO4 photoactivity depends on surface properties and synthesis route. In this study, differently shaped Ag3PO4 photocatalysts have been synthesized through the precipitation, ion exchange, soft-chemical or hydrothermal method. To correlate surface properties with photoactivity all...
-
Potential degradation of norfloxacin using UV-C/Fe2+/peroxides-based oxidative pathways
PublikacjaThe removal of norfloxacin (NOR), a widely used pharmaceutical and emerging water pollutant, was studied using UV-C and Fe2+ catalyzed peroxides-based oxidative processes (e.g., UV-C/Fe2+/H2O2, UV-C/Fe2+/S2O82− and UV-C/Fe2+/HSO5−) and compared with UV-C and UV-C/Fe2+. The UV-C and UV-C/Fe2+ degraded NOR to 38 and 55 %. However, use of peroxides, i.e., H2O2, S2O82−, HSO5− with UV-C and UV-C/Fe2+ promoted NOR %degradation to 75,...
-
Photoresponsive, amide-based derivative of embonic acid for anion recognition
PublikacjaThe synthesis and ion-binding properties of amide-based derivative of embonic acid andp-aminoazobenzenewere described. The new compound was characterized by X-ray structural analysis and spectroscopic methods.Ligand interacts in acetonitrile with Y-shaped anions (benzoates and acetates) and dihydrogen phosphatesforming complexes of 1:1 stoichiometry. In more polar DMSO the complexes stoichiometry changes to 2:1(L:anion). Light-inducedtranstocisisomerization...
-
A novel green one-step synthesis of gold nanoparticles using crocin and their anti-cancer activities
Publikacja -
The chitosan – Porphyrazine hybrid materials and their photochemical properties
Publikacja -
Photodynamic inactivation of Enterococcus faecalis by non-peripherally substituted magnesium phthalocyanines entrapped in lipid vesicles
Publikacja -
Tribenzoporphyrazines with dendrimeric peripheral substituents and their promising photocytotoxic activity against Staphylococcus aureus
Publikacja -
In vitro photodynamic activity of lipid vesicles with zinc phthalocyanine derivative against Enterococcus faecalis
Publikacja -
Forster energy transfer from nonexponentially decaying donors
PublikacjaPrzedyskutowano niezbędne modyfikacje stałej szybkości transferu foersterowskiego w sytuacji, kiedy zanik fluorescencji donora w nieobecności akceptora jest nieeksponencjalny. Stwierdzono, że najbardziej przydatna modyfikacja wynika założenia jednakowej wartości stałej zaniku radiacyjego dla wszystkich molekuł donora.
-
Light emitting diodes optimisation for secondary metabolites production by Droseraceae plants
Publikacja -
The effect of anatase and rutile crystallites isolated from titania P25 photocatalyst on growth of selected mould fungi
Publikacja -
Bactericidal effect of photodynamic inactivation against methicillin-resistant and methicillin-susceptible Staphylococcus aureus is strain-dependent
Publikacja -
The agr function and polymorphism: Impact on Staphylococcus aureus susceptibility to photoinactivation
Publikacja -
Preparation and characterization of new zinc(II) phthalocyanine — Containing poly(l-lactide)-b-poly(ethylene glycol) copolymer micelles for photodynamic therapy
Publikacja -
Effect of xanthophyll pigments on fluorescence of chlorophyll a in LHC II embedded to liposomes
Publikacja -
Protochlorophyll complexes with similar steady-state fluorescence characteristics can differ in fluorescence lifetimes. A model study in Triton X-100
Publikacja -
Effect of thienyl units in cyanoacrylic acid derivatives toward dye-sensitized solar cells
Publikacja -
Valorization of waste cabbage leaves by postharvest photochemical treatments monitored with a non-destructive fluorescence-based sensor
PublikacjaThe biosynthesis of polyphenolic compounds in cabbage waste, outer green leaves of white head cabbage (Brassica oleracea L. var. capitata subvar. alba), was stimulated by postharvest irradiation with UVB lamps or sunlight. Both treatments boosted the content of kaempferol and quercetin glycosides, especially in the basal leaf zone, as determined by the HPLC analysis of leaf extracts and by a non-destructive optical sensor. The...