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Year 2025
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Laser melting synthesis of Mg and Si3N4-doped soda-lime glass: structure and thermal analysis
PublicationThree series of soda-lime glasses doped with varying contents of Mg, Si3N4, or a combination of both were synthesizedusing laser melting in less than 3 min. The addition of these dopants resulted in notable changes in the structural and ther-mal properties of the glass. Both IR and Raman spectra indicated that the silicate network primarily consisted of Q3 units,with significant amounts of Q2 and Q4 units present in most samples....
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Machine Learning Enhanced Optical Fiber Sensor For Detection Of Glucose Low Concentration In Samples Mimicking Tissue
PublicationThis study presents anoptical fiber sensor for detecting low glucose concentrations in a sample mimicking urine. Our research focused on designing a sensor capable of detecting 0.5% glucose concentrations in artificial urine. Algorithms were applied to analyze and accurately classify the data andidentify the principal components of the collected data. The Random Forest and XGBoostmodel achieved the highest...
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Net-zero policy and forward default risk in the energy sector:Evidence of corporate environmentalism using (a)symmetricmodels
PublicationThis study aims to examine the impact of the net-zero policy on forward default risk atthe firm level within the energy sector of the US, spanning over the period 2007–2021.The research employs Panel Vector Autoregression (PVAR) modeling, as well as linearand non-linear Autoregressive Distributed Lag (ARDL) models to investigate this rela-tionship. The findings suggest that the implementation of net-zero policy measures canhave...
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Novel nonsteroidal steroid sulfatase inhibitors containing glutamic acid unit
PublicationIn the present work, we designed and successfully synthesized novel steroid sulfatase (STS) inhibitors based on coumarin, tyramine, triazole, and flavone cores with an additional glutamic acid residue in the structure. The molecular modeling studies revealed that designed derivatives have potential to bind to the molecular target active site, at least theoretically. The biological activity of synthesized compounds was evaluated...
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Observation of quantum oscillations, linear magnetoresistance, and crystalline electric field effect in quasi-two-dimensional PrAgBi2
PublicationWe report the magnetic and magnetotransport properties with electronic band-structure calculation of the Bi square net system PrAgBi2. The magnetization and heat capacity data confirm the presence of a crystalline electric field (CEF) effect in PrAgBi2. Analysis of the CEF effect using a multilevel energy scheme reveals that the ground state of PrAgBi2 consists of five singlets and two doublets. The de Haas-van Alphen (dHvA) quantum...
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Opposite effect of the Cu photodeposition on the ∙OH generation and diclofenac degradation depends on the exposed anatase facet
PublicationExposition of a specific crystal facets and modification with co-catalysts are often used in order to improve photocatalytic activity of a material. However, considering complexity of these interactions, it is still challenging to fully understand and predict activity of a specific system. Here, we report combination of the {0 0 1} and {1 0 1} crystal facets of anatase TiO2 with CuXO co-catalyst, applied for diclofenac degradation,...
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Optimizing conductivity in Na-V-Te-O glass through controlled heat treatment
PublicationSemiconducting Na2O-V2O5-TeO2 glasses with various Na2O contents were melted and subjected to controlled heating to improve conductivity. Topography analysis were performed using confocal microscopy and scanning electron microscopy on both as-quenched and heat-treated samples. X-ray diffraction confirmed the amorphous nature of the samples post-melting, with subsequent heating resulting in the formation of nanocrystallites primarily...
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Phages as potential life-saving therapeutic option in the treatment of multidrug-resistant urinary tract infections
PublicationUrinary tract infections (UTIs) are among the most common bacterial infections worldwide and increasing antimicrobial resistance (AMR) challenges conventional antibiotic treatments. Phage therapy (PT) has emerged as a promising alternative due to its specificity, safety and efficacy against multidrug-resistant (MDR) pathogens causing infectious diseases. PT demonstrates significant potential in treating chronic and recurrent UTIs,...
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Photocatalytic membranes based on Cu–NH2-MIL-125(Ti) protected by poly(vinylidene fluoride) for high and stable hydrogen production
PublicationA porous, photocatalytically active, and water-stable composite membrane has been developed based on Cu–NH2-MIL-125(Ti), a titanium-based metal–organic framework (MOF) and PVDF polymeric matrix. To tune the structural and functional properties of the PVDF/MOF composites, the loading degree of the MOF within the polymer was systematically varied. The most effective performance of the composite material was achieved with a 10% wt/wt...
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Physicochemical properties of La0.5Ba0.5Co1-xFexO3-δ (0≤x≤1) as positrode for proton ceramic electrochemical cells
PublicationWe report on essential properties of materials in the series La0.5Ba0.5Co1-xFexO3-δ as positrodes for proton ceramic electrochemical cells (PCECs). The unit cell and thermochemical expansion coefficient (TCEC) of these cubic perovskites decrease with iron content x, the TCEC of La0.5Ba0.5FeO3-δ going as low as 11·10-6 1/K. The materials behave as LaMO3 perovskites with small band gaps and Ba acting as acceptors compensated by electron...
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Polymer Materials for U-Shaped Optic Fiber Sensors: A Review
PublicationFiber optic sensors have gained popularity over the last few decades. This is due to their numerous advantages, such as good metrological parameters, biocompatibility and resistance to magnetic and electric fields and environmental pollution. However, those built from glass fiber have one main disadvantage—they are fragile, meaning they can be easily damaged, even by the presence of vibration. Due to the great progress made by...
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Probiotic potential of Bacillus Isolates from Polish Bee Pollen and Bee Bread
PublicationThe main goal of this study was the evaluation of the probiotic potential of 10 Bacillus spp. strains isolated from 5 bee bread and 3 bee pollen samples. The antagonistic interaction with Staphylococcus aureus and Escherichia coli was a primary criterion for the preliminary selection of the isolates. Three out of ten strains—PY2.3 (isolated from pollen), BP20.15 and BB10.1 (both isolated from bee bread)—were found to be possible...
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Rapid methods for microorganism quantification in human milk: Possibilities and evaluation
PublicationThis study evaluates the potential of rapid microbiological methods, traditionally used for food and environmental samples, to assess human milk (HM) quality in Human Milk Banks. Several methods, including a bioluminescence, the Micro Biological Survey (MBS) colorimetric method, triphenyltetrazolium chloride (TTC) reductase test, and flow cytometry (BacSomatic™️), were compared to the PN-EN ISO 4833–1:2013-12 reference method....
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Recent Research Progress in the Abrasive Machining and Finishing of Additively Manufactured Metal Parts
PublicationAdditive manufacturing (AM) has revolutionized the production of complex geometrical parts with metals; however, the usual layer-by-layer deposition results in poor surface quality and unpredictable surface integrity. Abrasive machining and finishing techniques play vital roles in counteracting these challenges and qualifying AM parts for practical applications. This review aims to present recent research developments concerning...
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Recycling organic waste to biochar amended soils stabilizes Miscanthus x giganteus growth
PublicationSix treatments including straw biochar and its blends with organic waste (a mixture of anaerobically digested model kitchen waste, stillage and its enhancement with the fish waste digestate, both solid and liquid fractions) were tested via greenhouse experiment using fast-growing and pollution-resilient Miscanthus × giganteus. The four months long tests under spring/summer conditions in northern Poland with six fertiliser loads...
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Role of Cu and Ni in dual sites layered electrocatalysts for ammonia electrooxidation
PublicationSingle metal layered α-Ni(OH)2, β-Ni(OH)2 or dual metal layered NiCu hydroxides were hydrothermally deposited on nickel foam (NF) and investigated for electrochemical oxidation of ammonia. Copper induced conversion of hydrotalcite (α-Ni(OH)2) phase into the mixed hydrotalcite/brucite (α/β-NiCu) structure, which is distinguished by smaller stacks and larger interplanar distances, demonstrated the highest catalytic performance. Copper...
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Silver and Silver/Sodium Bisphosphonate Salts: Rare Examples of Molecular Solid Solutions and Their Biological Activity as Dual-Action Compounds
PublicationBisphosphonates (BPs) are an important treatment for osteoporosis and bone metastases due to their low toxicity, high thermostability, and the ability to inhibit bone resorption. Notably, BPs like alendronate, which contain a primary amine group, exhibit potent antiresorptive and antiangiogenic properties. Recent studies have focused on enhancing the BP properties by incorporating bioactive metals to increase their therapeutic...
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Simulation of energy management system using model predictive control in AC/DC microgrid
PublicationThis research seeks to enhance energy management systems (EMS) within a microgrid by focusing on the importance of accurate renewable energy prediction and its strong correlation with load curtailment. Analyzing the precision of disturbance predictions, reveals that predicting one hour in advance is more effective than immediate predictions or those made several hours beforehand. Furthermore, the study investigates scheduling load...
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Solvent Selection as a Key Factor in the Performance of Semitransparent Heterojunctions Composed of Hydrogenated Nanotubes and Bismuth Sulfides
PublicationResearch on titanium nanotubes modified with metal sulfides, particularly bismuth sulfide (Bi2S3), aims to create heterostructures that efficiently absorb sunlight and then separate photogenerated charge carriers, thereby enhancing the energy conversion efficiency. This study shows a key role of solvent used for sulfide and bismuth salt solutions used during successive ionic layer adsorption and reaction (SILAR) onto the morphology,...
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Structural insights into fungal and human topoisomerase II with implications for in silico antifungal drug design
PublicationTopoisomerases are essential enzymes regulating DNA supercoiling and disentanglement, critical for genomic integrity. While topoisomerase inhibitors are well-established in anticancer and antibacterial chemotherapy, their potential as antifungal agents remains underexplored or even not proofed. This study investigates structural distinctions between Saccharomyces cerevisiae topoisomerase II (ScTopoII) and human topoisomerase IIα...
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Structural patterns and cytotoxic activity of dinuclear Cu(II), Ni(II) and Cd(II) complexes with pyridine-based malonic acid dihydrazone
PublicationA dinuclear Cu(II) complex, [Cu2(L)(H2L)](ClO4)2·4H2O (Cu-1), with a condensation derivative of 2-acetylpyridine and malonic acid dihydrazide (H2L), was obtained through a direct synthesis. After recrystallization, the single-crystalline product was characterized by single crystal X-ray diffraction analysis, EPR, UV/Vis and IR spectroscopy. In the resulting dimeric Cu(II) complex, one ligand molecule is coordinated in its dianionic...
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Sub‐Nanometer‐Scale Cu9S5 Enables Efficiently Electrochemical Nitrate Reduction to Ammonia
PublicationThe sub-nanometer is a key feature size in materials science. Unlike single-atom and nanomaterials, size effects and inter-component cooperative actions in sub-nanomaterials will effective on its performance is more significant. Here, 0.95 nm ordered arrangement Cu9S5 sub-nanowires (Cu9S5 SNWs) are synthesized through the co-assembly effect of inorganic nuclei (Cu9S5) and clusters (phosphotungstic acid-PTA), achieving a significant...
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Superconductivity in Ternary Mg4Pd7As6
PublicationThe synthesis and characterization of a new compound Mg4Pd7As6, which is found to be a superconductor with Tc = 5.45 K is reported. Powder X-ray diffraction confirms the U4Re7Si6 structure (space group Im-3m, no. 229) with the lattice parameter a = 8.2572(1) Å. Magnetization, specific heat, and electrical resistivity measurements indicate that it is a moderate-coupling ( = 0.72) type-II superconductor. The electronic and phonon...
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Surface Charge Density Spectra: Complex Analysis of the Electrical Double Layer Developed from Measurements of Hexanol Adsorption Kinetics
PublicationA procedure for deriving surface charge density spectra from differential capacitance data is presented in this study, providing a deeper analysis of the generated charge. A set of simulated differential capacitance spectra was determined for three types of adsorption process control: diffusion control, adsorption control, and mixed control. Based on the differential capacitance curves and spectra, surface charge density spectra...
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Tailoring oxide nanoparticle exsolution in La0.5Ba0.5-yCo1-xFexO3-δ
PublicationWe show that oxide nanoparticles (NPs) exsolve on La0.5Ba0.5-yCo1-xFexO3-δ (x = 0-1, y = 0 or 0.01) in oxidizing conditions. The phenomenon occurs only in Co-containing materials and depends on pO2 and pH2O pressures. Under dry conditions, the smallest NPs average about 30 nm, with 200-300 NPs/µm2 at pO2=5×10-5 atm. For pO2=1 atm, NP size increases to 100-200 nm, and population drops to a few to about 20 NPs/µm2 depending on A-site...
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Technological content of export diversification—Evolution along the economic growth process
PublicationExports from high-income countries are three times more diversified than those from low-income economies. We provide a new tech-based interpretation of the stages of diversification accompanying the economic growth paths of countries. Using the decomposition properties of the relative Theil index in a sample of 160 countries (1996–2018), we reveal that export diversification is driven mainly by changes in the variety of non-tech...
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The effect of hydrothermal carbonization (HTC) on entrained flow steam gasification of sewage sludge. Experimental validation of various gasification models
PublicationProper sewage sludge management is challenging due to legal requirements, environmental concerns, and logistical complexities. Steam gasification offers a promising solution by producing high-quality syngas. While research has largely focused on fixed bed gasifiers, their scalability limitations restrict their economic viability. Entrained flow gasifiers, scalable to hundreds of megawatts as demonstrated in coal gasification, present...
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The impact of China’s One-Belt One-Road initiative on international trade and global value chains
PublicationThis study examines the potential effects of China’s ‘One-Belt One-Road’initiative (OBOR) on trade flows and global value chain (GVC) connections.The empirical analysis is based on the augmented trade gravity model, which comprises 186 economies and 199 of their partners from 2000 to 2018. We also estimate the gravity model for involvement in GVC (domestic value added in intermediate exports, foreign value added in exports, and...
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The Impact of Hybrid Flame Retardant Compositions on the Performance of Foamed Flexible Polyurethane/Ground Tire Rubber Composites
PublicationCurrent sustainability-oriented trends affect polyurethane (PU) materials and stimulate the incorporation of recycled or waste-based materials as fillers. Ground tire rubber (GTR) poses as an auspicious candidate due to the excellent performance of car tires. Despite the benefits related to the mechanical performance, it contributes to the increasing flammability of the resulting composites. Herein, presented work assessed the...
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The influence of selected metal oxides and laser modification on the surfaces of titanium alloys – Bibliometric and systematic review
PublicationManufacturing of oxide coatings (ZnO, ZrO2 , CuO) and laser processing are methods for modifying the surface of titanium and its alloys. It is particularly useful in implantology, where these techniques allow for proper connection of the implant to human tissue. The article consists of two complementary parts: a bibliographic review and a literature survey. The results of a bibliographic analysis conducted for a set of 429 publications...
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The interactions of Pu22 G-quadruplex, derived from c-MYC promoter sequence, with antitumor acridine derivatives – an NMR/MD combined study
PublicationUnsymmetrical bisacridines (UAs) represent a novel class of anticancer agents that exhibit significant antitumor activity against a wide range of cancer cell lines and solid tumors in vivo. UAs consist of two different acridine-based ring systems, which are connected by an aminoalkyl linker. Recent studies have demonstrated that UAs can suppress the c-MYC protooncogene, which is overexpressed in many tumor types. As a proposed...
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Thermal pathways for sustainable waste management: Leveraging leather tannery waste as a renewable energy source
PublicationThe growing production of consumer goods increases waste generation, challenging disposal systems. The aim of the work was to use real data to propose a closed loop leather production process, so as to eliminate storage and use the potential of thermal processes for energy recovery. Such actions allow for improving the company's economic balance, but above all for a positive environmental impact. The tanning industry generates...
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Towards developing fully sustainable elastomers: the role of chemistry
PublicationThe development of sustainable polymer materials is no longer just an option but a necessity. Elastomers are indispensable members of the polymer family due to their high tensile strength, durability, energy absorption capabilities, and excellent resistance to fatigue and environmental degradation. Elastomers have found a unique role in diverse industries, like transportation, automotive, aerospace, construction, and sports. However,...
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Transforming organic waste: Cabbage-derived carbon containing copper for electrochemical sensing of ascorbic acid
PublicationThis study presents a sustainable approach for transforming food waste into functional electrochemical materials by utilizing copper-enriched cabbage leaves as a precursor for carbon-based sensors. Chinese cabbage was soaked in aqueous solutions of Cu(NO₃)₂, CuSO₄, and Cu(CH₃COO)₂, followed by pyrolysis, which resulted in carbona- ceous materials with distinct structural and electrochemical characteristics. Raman spectroscopy and...
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Trimethyl Lock Based Tools for Drug Delivery and Cell Imaging – Synthesis and Properties
PublicationTrimethyl lock (TML) systems have become increasingly important in medicinal and bioorganic chemistry, particularly for their roles in the targeted delivery of therapeutic agents and as integral components in fluorogenic probes for cellular imaging. The simplicity and efficiency of their synthesis have established TML systems as versatile platforms for the controlled release of active molecules under particular physiological conditions....
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Tuning the Adhesive Strength of Functionalized Polyolefin-Based Hot Melt Adhesives: Unexpected Results Leading to New Opportunities
PublicationThe development of lightweight, often multi-component products requires adaptable and robust bondingsolutions. Hot melt adhesives increasingly attract industrial interestas they combine good adhesive strength, facile processability, andcost-efficiency. Recently, our group has reported on the remarkableadhesive performance of hydroxyl-functionalized propylene-basedcopolymers in bonding both polar and nonpolar surfaces. Theobtained...
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Uncovering the electrochemical processes and understanding the causes of the degradation via EIS-DRT in large-scale solid oxide fuel cell
PublicationInducing changes in performance and observation of electrochemical processes is quite easy to do using ‘button cells’, which are the favorite objects in most research studies. Unfortunately, those cells may sometimes provide misleading outcomes or lead to promising results, applicable only on small scale, belittling their technological value. In this study, a large-scale SOFC with a 100 cm2 cathode active surface area was subjected...
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Unlocking the electrochemical performance of glassy carbon electrodes by surface engineered, sustainable chitosan membranes
PublicationChitosan coatings, derived from crustacean shell waste, possess inherent biocompatibility and biodegradability, rendering them suitable for various biomedical and environmental applications, including electrochemical biosensing. Its amine and hydroxyl functional groups offer abundant sites for chemical modifications to boost the charge transfer kinetics and provide excellent adhesion, enabling the construction of robust electrode-coating...
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Unlocking the Secrets of Human Milk: Isolation and Characterization of Extracellular Vesicles
PublicationExtracellular vesicles from human milk (HMEVs) are crucial for neonatal development, immune modulation, and protection against pathogens. However, the lack of standardized isolation and characterization protocols poses significant challenges. This review aims to evaluate and compare various methods for the isolation and characterization of HMEVs, highlighting their effectiveness and potential applications. Preliminary purification...
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User Well-Being as a Paramount Challenge in Contemporary Built Environment Design: The Architecture of Psychiatric Hospitals and Its Influence on Treatment Processes and the Health, Safety, and Comfort of Patients and Medical Staff—A Systematic Literature Review and Insights from the New European Bauhaus Initiative
PublicationThe natural environment, urban systems, and the buildings in which we live, study, work, or undergo treatment affect our mental health. The aim of this literature review was to verify the state of knowledge on the impact of the forms of psychiatric hospital buildings and the architectural solutions used inside these facilities on their comfort and safety of use, more effective forms of therapy, and the health of patients, as well...
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Waste tire rubber with low and high devulcanization level prepared in the planetary extruder
PublicationWaste tires management is serious and global environmental problem. Therefore, searching for new andindustrially applicable solutions to convert waste tire rubber into high-value added products is gaining more andmore attention. Rubber devulcanization is step forward for further developing rubber recycling and upcyclingtechnologies. Thermo-mechanical treatment of ground tire rubber (GTR) performed in twin screw extruders iscurrently...
Year 2024
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3D-Breast System for Determining the Volume of Tissue Needed for Breast Reconstruction
Publication3D imaging systems can be used to effectively determine breast volumes for surgical applications. This article presents methods for surface reconstruction and volume determination based on the point cloud created by 3D imaging. Such a system would be used to accurately estimate breast volume in patients classified for breast reconstruction surgery at plastic surgery centers. To develop such a system, various methods of determining...
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A comparative analysis of methods and tools for low impact development (LID) site selection
PublicationThe site selection for Low Impact Development (LID) practices is a significant process. It affects the effectiveness of LID in controlling stormwater surface runoff, volume, flow rate, and infiltration. This research paper presents a comprehensive review of various methods used for LID site selection. It starts by introducing different methods and tools. Three main methods: index-based methods, GIS-based multi-criteria decision...
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A Comprehensive Review: Applications of the Kozeny–Carman Model in Engineering with Permeability Dynamics
PublicationIn this review article, we investigate the dynamic nature of the Kozeny–Carman Model concerning permeability and its application in engineering contexts. Providing insights into the changing dynamics of permeability within mining, petroleum, and geotechnical engineering, among other engineering applications. While some are complex and require additional modifcations to be applicable, others are simple and still function in specifc...
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A comprehensive review on economic, environmental impacts and future challenges for photovoltaic-based electric vehicle charging infrastructures
PublicationIn this paper, a comprehensive review of the impacts and imminent design challenges concerning such EV charging stations that are based on solar photovoltaic infrastructures is presented, which is based on state-of-the-art frameworks for PV-powered charging stations and the latest case studies. The main factors that are targeted in this review are the management of an EV charging system that is a composite of PV and public grid,...
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A green route for high-performance bio-based polyurethanes synthesized from modified bio-based isocyanates
PublicationThe need for sustainability and a circular economy leads to the development of innovative greener materials and technologies. This paper is focused on a novel class of bio-based polyurethanes (PUs) synthesized with the use of bio-monomers including bio-based isocyanates. The novelty of this work is related to the usage of bio-based modified isocyanate via a two-step solvent-free synthesis of novel cast bio-based poly(ester-urethanes)...
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A New Approach of Solidification Analysis in Modular Latent Thermal Energy Storage Unit Based on Image Processing
PublicationThe solidification process of RT18HC in a cylindrical shell and tube storage unit has been studied using a new methodology based on image processing. The main idea of the algorithm is to label the region of solidification and use statistical functions to calculate the dimensions of the solidification front over time. Said analysis includes two methods. The first method is to measure the solid fraction changes during solidification....
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A new strategy for PET depolymerization: Application of bimetallic MOF-74 as a selective catalyst
PublicationLarge-volume production of poly(ethylene terephthalate) (PET), especially in the form of bottles and food packaging containers, causes problems with polymer waste management. Waste PET could be recycled thermally, mechanically or chemically and the last method allows to obtain individual monomers, but most often it is carried out in the presence of homogeneous catalysts, that are difficult to separate and reuse. In view of this,...
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A Review of Recent Advances in Human-Motion Energy Harvesting Nanogenerators, Self-Powering Smart Sensors and Self-Charging Electronics
PublicationIn recent years, portable and wearable personal electronic devices have rapidly developed with increasing mass production and rising energy consumption, creating an energy crisis. Using batteries and supercapacitors with limited lifespans and environmental hazards drives the need to find new, environmentally friendly, and renewable sources. One idea is to harness the energy of human motion and convert it into electrical energy...
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A stochastic approach for the solution of single and multi – objective optimisation problems of biological processes in sequencing batch reactor
PublicationThis paper investigates the impact of implementing single and multi-optimisation solutions on the biological treatment process in a sequencing batch reactor (SBR). The research is based on a case study of the water resource recovery facility (WRRF) in Swarzewo, Northern Poland. The paper introduces the adaptive extremum seeking control (ESC) method for dissolved oxygen (DO) concentration control and places it in a layered control structure....