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Research on the separation properties of empty-column gas chromatography (EC-GC) and conditions for simulated distillation (SIMDIS)
Abstract
The paper presents the results of investigations on new procedures of determination of selected cleaning additives in diesel fuel. Two procedures: one-step analysis using gas chromatography with flame ionization detection (GC-FID) or mass spectrometry (GC-MS) and a two-step procedure in which normal-phase high-performance liquid chromatography (NP-HPLC) was used for preliminary separation of the additives, were compared. The additive fraction was collected using either simple elution or eluent backflush. Final determinations were performed by GC-FID and GC-MS. The studies revealed that it was impossible to determine the investigated analytes by one-step procedures, i.e. by using solely HPLC or GC. On the other hand, the use of a two-step procedure ensures reproducible results of determinations, and the limits of quantitation are, depending on the method of fraction collection by HPLC, from 1.4-2.2 ppm (GC-MS in SIM mode) to 9.6-24.0 ppm (GC-FID). Precision and accuracy of the developed procedures are compared, and possible determination errors and shortcomings discussed.
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- Publication version
- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.1007/s00216-013-7236-z
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Details
- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
no. 405,
edition 25,
pages 8377 - 8382,
ISSN: 1618-2642 - Language:
- English
- Publication year:
- 2013
- Bibliographic description:
- Boczkaj G., Kamiński M.: Research on the separation properties of empty-column gas chromatography (EC-GC) and conditions for simulated distillation (SIMDIS)// ANALYTICAL AND BIOANALYTICAL CHEMISTRY. -Vol. 405, iss. 25 (2013), s.8377-8382
- DOI:
- Digital Object Identifier (open in new tab) 10.1007/s00216-013-7236-z
- Verified by:
- Gdańsk University of Technology
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