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Search results for: oxygen reduction reaction
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Glutathione-mediated conjugation of anticancer drugs: an overview of reaction mechanisms and biological significance for drug detoxification and bioactivation.
PublicationThe effectiveness of many anticancer drugs depends on the creation of specific metabolites that may alter their therapeutic or toxic properties. One significant route of biotransformation is a conjugation of electrophilic compounds with reduced glutathione, which can be non-enzymatic and/or catalyzed by glutathione-dependent enzymes. Glutathione usually combines with anticancer drugs and/or their metabolites to form more polar...
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Effect of preparation conditions and promoters on the structure and activity of the ammonia decomposition reaction catalyst based on nanocrystalline cobalt
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The effect of the iron oxidation degree on distribution of promotors in the fused catalyst precursors and their activity in the ammonia synthesis reaction
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Toward an Understanding of the Chemiluminescence Accompanying the Reaction of 9-Carboxy-10-methylacridinium Phenyl Ester with Hydrogen Peroxide
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Raman investigation of minor component reaction during polymer synthesisprocess. IV Workshop on Atomic and Molecular Physics.
PublicationWykonano badania ramanowskie reakcji zachodzących podczas procesu wytwarzania polimerów hybrydowych w ich części organicznej. Optyczne monitorowanie przebiegu reakcji w czasie rzeczywistym umożliwiło zbadanie ich efektywności oraz czasu trwania. Wyjaśniono też rolę katalizatorów.
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EM-Driven Size Reduction and Multi-Criterial Optimization of Broadband Circularly-Polarized Antennas Using Pareto Front Traversing and Design Extrapolation
PublicationMaintaining small size has become an important consideration in the design of contemporary antenna structures. In the case of broadband circularly polarized (CP) antennas, miniaturization is a challenging process due to the necessity of simultaneous handling of electrical and field properties (reflection, axial ratio, gain), as well as ensuring sufficient frequency range of operation, especially at the lower edge of the antenna...
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Techniques of interference reduction in probe system for wafer level noise measurements of submicron semiconductor devices.
PublicationPrzedstawiono skrótowo system do ostrzowych pomiarów szumów struktur submikronowych. Znaczny wpływ na pomiary ostrzowe mają zakłócenia i szumy własne systemu, zwłaszcza zakłócenia o wysokim poziomie wpraowadzane przez ostrza (fluktuacje rezystancji styków ostrza do struktury powodowane przez wibracje i udary mechaniczne w środowisku pomiarowym)i środowisko elektromagnetyczne. Zakłócenia okresowe powodowane przez wibracje i pola...
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Fast multi-objective optimization of antenna structures by means of data-driven surrogates and dimensionality reduction
PublicationDesign of contemporary antenna structures needs to account for several and often conflicting objectives. These are pertinent to both electrical and field properties of the antenna but also its geometry (e.g., footprint minimization). For practical reasons, especially to facilitate efficient optimization, single-objective formulations are most often employed, through either a priori preference articulation, objective aggregation,...
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Design-oriented modeling of antenna structures by means of two-level kriging with explicit dimensionality reduction
PublicationThe employment of full-wave electromagnetic (EM) analysis is a practical necessity in the design of contemporary antenna structures. This is because simpler models are generally not available or of limited accuracy. At the same time, EM-based design is computationally expensive. Consequently, the ways of accelerating tasks such as parametric optimization or uncertainty quantification have to be sought. A possible workaround that...
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Reduction of Conducted Emissions Generated by WPT Systems with Multilevel Inverters using Spread Spectrum Approach
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The Optimal Spindle Speed Map for Reduction of Chatter Vibration During Milling of Bow Thruster Blade
PublicationW artykule przedstwiono przykład wykorzystania procedury tworzenia mapy optymalnych prędkosci obrotowych w celu ograniczenia drgań samowzbudnych podczas frezowania płata śruby okrętowego steru strumieniowego.
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Impact of TiO2 Reduction and Cu Doping on Bacteria Inactivation under Artificial Solar Light Irradiation
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One-Step Combustion Synthesis of Novel Nanocarbons via Magnesiothermic Reduction of Carbon-Containing Oxidants
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Application of agent-based simulated annealing and tabu search procedures to solving the data reduction problem
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Quantitative structure–activity relationships in enzymatic single-electron reduction of nitroaromatic explosives: implications for their cytotoxicity
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Enzymatic assays confirm the toxicity reduction after manure treatment of heavy metals contaminated soil
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Fischer–Tropsch synthesis: Studies effect of reduction variables on the performance of Fe–Ni–Co catalyst
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Surface morphology of PrBa2Cu3O7-ë single crystals after the long lasting high temperature reduction. .
PublicationZaprezentowano wyniki szczegółowej analizy powierzchni kryształów poddanych długotrwałej redukcji wysokotemperaturowej. Badania za pomocą skaningowej mikroskopii (SEM) wykazały obecność niestabilnych strukturalnie krystalitów powstałych w wyniku rozpadu powierzchni kryształów. Zanikanie zaindukowanego przy pomocy obróbki wysokotemperaturowej nadprzewodnictwa może być spowodowane migracją defektów podsieci Pr-Ba z wnętrza...
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Reduction of vibration level by the spindle speed optimisation during ball end milling of flexible details
PublicationPraca dotyczy nadzorowania drgań podczas skrawania przedmiotów podatnych frezem kulistym. Przedsatwiono wspomaganą komputerowo procedurę nadzorowania z optymalizacją prędkości obrotowej narzędzia. Przy modelowaniu wykorzystano niestacjonarny model obliczeniowy. Rezultatem modelowania jest układ hybrydowy, w którym oddzielono podukłady: modalny, łączący i strukturalny. Metoda wymaga identyfikacji częstości własnych co może być wykonane...
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Vitiligo pathogenesis: autoimmune disease, genetic defect, excessive reactive oxygen species, calcium imbalance, or what else?
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Nickel Nanoparticles Encapsulated in Nitrogen‐Doped Carbon Nanofibers as Excellent Bifunctional Catalyst for Hydrogen and Oxygen Evolution Processes
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Correction: New insights into the role of lattice oxygen in the catalytic carbonization of polypropylene into high value-added carbon nanomaterials
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Reactive oxygen species (ROS) production in human peripheral blood neutrophils exposedin vitroto static magnetic field
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Genes regulating biochemical pathways of oxygen metabolism in porcine oviductal epithelial cells during long-term IVC
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Nitrogen/Oxygen Enriched Hierarchical Porous Carbons Derived from Waste Peanut Shells Boosting Performance of Supercapacitors
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Benthic fluxes of oxygen and nutrients under the influence of macrobenthic fauna on the periphery of the intermittently hypoxic zone in the Baltic Sea
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Structure and characterization of physicochemical and magnetic properties of new complex containing monobridged oxygen copper(II) dinuclear cation
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Oxygen release from BaLnMn2O6 (Ln: Pr, Nd, Y) under reducing conditions as studied by neutron diffraction
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Crystal structure and proton conductivity in highly oxygen-deficient Ba1−xLax(In,Zr,Sn)O3−δ perovskites
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Advantages of continuous Fenton reaction over the traditional batch process in wastewater treatment in a single and two-step mode
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Enhanced hydrogen evolution reaction on highly stable titania-supported PdO and Eu2O3 nanocomposites in a strong alkaline solution
PublicationIn this work, PdO/TiO2 and Eu2O3/TiO2 nanocomposites (NCs), were synthesized using a new facile, template-free and one-step solvothermal approach, and characterized by several instrumentation techniques. X-ray photoelectron spectroscopy (XPS) studies revealed the presence of oxidised form of the Pd and Eu nanoparticles within the nanocomposite materials (PdO and Eu2O3). The two catalysts exhibited remarkable activity for the HER...
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Visible light-induced photocatalytic reaction of gold-modified titanium(IV) oxide particles: action spectrum analysis
PublicationAnalizy spektrum działania wykazały, ze wzbudzenie powierzchniowego plazmonu złota inicjuje utlenianie 2-propanolu w świetle widzialnym w napowietrzonej zawiesinie tlenku(IV) tytanu zmodyfikowanego zlotem. Badania przeprowadzone z użyciem światła polichromatycznego wykazały, ze szybkość reakcji foto-utleniania zależy od właściwości tlenku(IV) tytanu, takich jak rozmiar ziaren, pola powierzchni właściwej, formy krystalicznej (anataz...
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The Studies on α-Pinene Oxidation over the TS-1. The Influence of the Temperature, Reaction Time, Titanium and Catalyst Content
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Reaction Model Taking into Account the Catalyst Morphology and Its Active Specific Surface in the Process of Catalytic Ammonia Decomposition
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Reaction of methanol ligated manganese(II) silanethiolate with pyridine related ligands - different structures of complexes with MnNO2S2 kernel
PublicationReakcja silanotiolanu manganu(II) z pirydyną i jej metylowymi pochodnymi prowadzi do uzyskania heteroleptycznych kompleksów o tym samym rdzeniu MnNO2S2, ale o różnym typie strukturalnym. W przypadku posłużenia się pirydyną i 2-metylopirydyną uzyskano układy zawierające dwie cząsteczki alkoholu przykoordynowane do centrum metalicznego. Z kolei w przypadku 3- i 4-metylopirydyny funkcję S,O-donorów spełniają reszty silanotiolanowe.
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Reaction of bis[bis(tri-tert-butoxysilanethiolato)cadmium(II)] with 3,5-dimethylpyridine - 113Cd NMR Solution study
PublicationAnaliza 113Cd NMR dla reakcji bis[bis(tri-tert-butoksysilanotiolanu)kadmu(II)] z 3,5-dimetylopirydyną została przeprowadzona w roztworze benzenu-d6 i toluenu-d8. Otrzymane wyniki wskazują, że w roztworze istnieje równowaga pomiędzy powstającymi mieszanymi kompleksami kadmu z ligandami siarkowymi i azotowymi.
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Analysis of volatile fraction of hybrid fruit pulp using Proton Transfer Reaction - Time-Of-Flight Mass Spectrometry
PublicationFruits and vegetables are important ingredients in human diet. Because of this, it is very important to know their exact composition and to control their quality. Based on the aroma of food products, it is possible to pre-evaluate their quality and freshness. The aim of this work was to characterize the volatile fraction of the hybrid fruit ‘sweetie’ using the modern analytical device PTR-TOFMS. Hybrid fruit samples are human-made...
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H2O˙+ and OH+ reactivity versus furan: experimental low energy absolute cross sections for modeling radiation damage
PublicationRadiotherapy is one of the most widespread and efficient strategies to fight malignant tumors. Despite its broad application, the mechanisms of radiation-DNA interaction are still under investigation. Theoretical models to predict the effects of a particular delivered dose are still in their infancy due to the difficulty of simulating a real cell environment, as well as the inclusion of a large variety of secondary processes. This...
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Novel therapeutic compound acridine–retrotuftsin action on biological forms of melanoma and neuroblastoma
PublicationPURPOSE: As a continuation of our search for anticancer agents, we have synthesized a new acridine-retrotuftsin analog HClx9-[Arg(NO2)-Pro-Lys-Thr-OCH3]-1-nitroacridine (named ART) and have evaluated its activity against melanoma and neuroblastoma lines. Both tumors develop from cells (melanocytes, neurons) of neuroectodermal origin, and both are tumors with high heterogeneity and unsatisfactory susceptibility to chemotherapies....
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Prime-Boost Vaccination with Toxoplasma Lysate Antigen, but Not with a Mixture of Recombinant Protein Antigens, Leads to Reduction of Brain Cyst Formation in BALB/c Mice
PublicationIntroduction Infection with the ubiquitous parasite Toxoplasma gondii is a threat for immunocompro- mised patients and pregnant women and effective immune-prophylaxis is still lacking. Methods Here we tested a mixture of recombinant T . gondii antigens expressed in different develop- mental stages, i.e., SAG1, MAG1 and GRA7 (SMG), and a lysate derived from T . gondii tachyzoites (TLA) for prophylactic vaccination against cyst formation....
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Phosphorus, nitrogen and oxygen co-doped polymer-based core-shell carbon sphere for high-performance hybrid supercapacitors
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How to guide photocatalytic applications of titanium dioxide co-doped with nitrogen and carbon by modulating the production of reactive oxygen species
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Oznaczanie tlenu – od metody Winklera do czujników enzymatycznych (Determination of oxygen – from Winkler Method to enzymatic sensor)
PublicationMonitoring of dioxygen levels is of utmost importance from the view-point of life processes, medical diagnostics, nutrition and chemical industries. In all these measurements both low and high levels of this element are important. The common methods for the determination of dioxygen are the Winkler method, Clark electrode and pulsoxymeters. A new, already strong field of research can be now recognized – the development of miniaturized...
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Improved Efficacy Behavioral Modeling of Microwave Circuits through Dimensionality Reduction and Fast Global Sensitivity Analysis
PublicationBehavioral models have garnered significant interest in the realm of high-frequency electronics. Their primary function is to substitute costly computational tools, notably electromagnetic (EM) analysis, for repetitive evaluations of the structure under consideration. These evaluations are often necessary for tasks like parameter tuning, statistical analysis, or multi-criterial design. However, constructing reliable surrogate models...
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Fast Multi-Objective Optimization of Narrow-Band Antennas Using RSA Models and Design Space Reduction
PublicationComputationally efficient technique for multi-objective design optimization of narrow-band antennas is presented. In our approach, the corrected low-fidelity antenna model (obtained through coarse-discretization EM simulations) is enhanced using frequency scaling and response correction, sampled, and utilized to obtain a fast response surface approximation (RSA) antenna surrogate. The RSA model is constructed in the reduced design space....
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Mutual Coupling Reduction in Antenna Arrays Using Artificial Intelligence Approach and Inverse Neural Network Surrogates
PublicationThis paper presents a novel approach to reduce undesirable coupling in antenna arrays using custom-designed resonators and inverse surrogate modeling. To illustrate the concept, two stand-ard patch antenna cells with 0.07λ edge-to-edge distance are designed and fabricated to operate at 2.45 GHz. A stepped-impedance resonator is applied between the antennas to suppress their mutual coupling. For the first time, the optimum values...
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Selection of Methods of Surface Texture Characterisation for Reduction of the Frequency-Based Errors in the Measurement and Data Analysis Processes
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Instrumented end notched flexure - Crack propagation and process zonemonitoring Part II: Data reduction and experimental
PublicationA mode II instrumented end notched flexure three point bending (ENF) adhesion test is described. The adhesive joint consists of two aluminium alloy (AW7075-T6) plates bonded with a structural epoxy adhesive (Hysol EA 9395™). Strain gauges are attached to the outer surface (backface) of the substrates in the lengthwise direction to measure local surface strain during crack propagation. Simultaneously, load/displacement measurements...
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Sustained Sympathetic and Blood Pressure Reduction 1 Year After Renal Denervation in Patients With Resistant Hypertension
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Antiplasmodial Activity of Nitroaromatic Compounds: Correlation with Their Reduction Potential and Inhibitory Action on Plasmodium falciparum Glutathione Reductase
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