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Remarks on use of the term “deep eutectic solvent” in analytical chemistry
PublicationAbout 20 years ago, Abbott and co-workers researched new solvents that were based on mixtures of choline chloride with urea and carboxylic acids and that were liquid at ambient temperature. The term “deep eutectic solvent” (DES) was later adopted for similar mixtures. As DESs have a number of interesting features, they quickly attracted the attention of researchers and found application in various branches of chemical and materials...
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Polypropylene structure alterations after 5 years of natural degradation in a waste landfill
PublicationUp to 25% of plastic waste in Europe is still disposed of in landfills, despite recycling efforts. The plastic waste in the landfill plot may be exposed both to abiotic and biotic degradation processes, although it is thought that most of the plastic materials tend to be resistant to biodegradation or biodeterioration even after a long time. To verify if polypropylene (PP) can undergo the process of short-term biodegradation and...
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POSSIBILITIES OF ELECTRICAL ENERGY GENERATION IN PHOTOVOLTAIC SYSTEMS INSTALLED IN CENTRAL EUROPE
PublicationNowadays, fossil fuels are the main sources of energy from which electricity is obtained. But these sources will not last forever, so in due course renewable energies will have to replace them in this role. One of these new sources is solar energy. To generate electricity from sunlight, solar (photovoltaic - PV) cells and modules are used. The increasing interest in PV cells and modules worldwide is due mainly to the fact that...
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5-Thiocyanato-2′-deoxyuridine as a possible radiosensitizer: electron-induced formation of uracil-C5-thiyl radical and its dimerization
PublicationIn this work, we have synthesized 5-thiocyanato-2′-deoxyuridine (SCNdU) along with the C6-deuterated nucleobase 5-thiocyanatouracil (6-D-SCNU) and studied their reactions with radiation-produced electrons. ESR spectra in γ-irradiated nitrogen-saturated frozen homogeneous solutions (7.5 M LiCl in H2O or D2O) of these compounds show that electron-induced S–CN bond cleavage occurs to form a thiyl radical (dU-5-S˙ or 6-D-U-5-S˙) and...
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Minimization of a ship's magnetic signature under external field conditions using a multi-dipole model
PublicationThe paper addresses the innovative issue of minimizing the ship's magnetic signature under any external field conditions, i.e., for arbitrary values of ambient field modulus and magnetic inclination. Varying values of the external field, depending on the current geographical location, affect only the induced part of ship's magnetization. A practical problem in minimizing the ship signature is separating permanent magnetization...
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Survey on opportunities and barriers in lighting controls
PublicationThis report summarizes a survey performed in eight countries on the status quo of daylight and electric lighting control systems. Feedback from more than 100 international experts (building / facility managers and planers) was evaluated. The aim of the survey was to identify the perception of the different possibilities of the current lighting control solutions and the expectations about the control systems. The survey aims to...
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A concept of zero-dimensional and three-dimensional thermodynamic modelling of steam storage in a steam cycle
PublicationThis work presents the thermodynamic model of steam storage in a steam cycle. The innovative steam storage is an integral part of the unit and thus responds quickly to changes in load. This enhances the primary control reserve while maintaining high efficiency of energy conversion. With regard to power plants, it improves the operational safety of generation units, as it prevents boiler and turbines overload in the case of steep...
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Journey towards light – evolutionary adaptations of humans, flora and fauna. Guidelines for safe and healthy illumination
PublicationThe paper examines using relatively recent discoveries on how evolution has embedded within all living organisms a natural sensitivity towards their native environment, in particular luminance levels and specific wavelengths of light. The studies conducted so far indicate that lighting installations that are visible after dark impact on humans, flora and fauna and influence our evolutionary dispositions, possibly with negative...
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The dependence of linear viscoelasticity limits of cold-recycled mixtures on time of curing and compaction method
PublicationCold-recycled mixtures are currently among the most widely used and investigated methods that enable recycling of old pavement structures in an environmentally friendly manner. Upon milling, the old pavement structure – whose gradation can be improved with addition of virgin aggregate – is mixed and compacted at ambient temperature. The main binding agents are bituminous emulsion and cement. Due to their dual binding behaviour,...
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Measurement of benzene concentration in urban air using passive sampling
PublicationAbstract The concentration of benzene in urban air in theTri-City area of Poland (Gdańsk-Sopot-Gdynia, andTczew) was assessed using diffusive passive samplers (Rad-iello). Samples were collected during a four-year monitoringcampaign (2007-2010) at selected monitoring stations man-aged by the Agency of Regional Air Quality Monitoring inthe Gdańsk Metropolitan Area (ARMAAG) Foundation.The performance of the passive samplers was investigatedin...