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Search results for: SORBENT
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Investigation of oleophilic nature of straw sorbent conditioned in water.
PublicationPrzedyskutowany został potencjał absorpcyjny słomy jęczmiennej kondycjonowanej w wodzie. W odniesieniu do właściwości powierzchni zewnętrznej oraz wewnętrznej łodygi i liści zostały zmierzone kąty zwilżania dla wody i dekanu zarówno dla słomy suchej, jak i mokrej.
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Solid Phase Microextraction: Apparatus, Sorbent Materials, and Application.
Publicationhe primary objective of this review article is to strategically screen and highlight the advancements in the area of solid phase microextraction (SPME). The plenty of review articles have been written on different aspects of SPME, this review is dedicated to provide the brief but clear overview of the research footprints so produced from SPME. Some of the key advancements in types and designs, coating materials, coating strategies,...
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OPTIMALIZATION OF SORBENT FEEDING IN THE DRY METHOD OF FLUE GAS DESULFURIZATION
PublicationThe swiftly developing sea transport contributes to a considerable increase of fuel usage in the international shipping, which results in the escalation of toxic compounds emitted into the atmosphere. It is followed by the constantly heightened requirements limiting those emissions. In the case of sulfur oxide emission, inside of SECA (Sulfur Emission Control Area), the maximum content of sulfur in the shipping fuels used on the...
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Modern trends in solid phase extraction: New sorbent media
PublicationBased on the recently published literature, this review provides an update of the most important features and application of formats and devices employed in solid phase extraction (SPE). Special attention was paid on new trapping media proposed in SPE prior the chromatography analysis, based on the use of nanostructured materials, including carbon nanomaterials, electrospun nanofibers, dendrimes and magnetic nanoparticles, molecular...
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Membrane Solid Phase Microextraction - a new concept of sorbent preparation
PublicationOpracowano nowy układ sorpcyjny do izolacji i/lub wzbogacania polarnych analitów organicznych z próbek wody z zastosowaniem techniki solid phase microextraction (SPME). Układ bazuje na oddzieleniu sorbentu polarnego od próbki za pomocą membrany hydrofobowej. Próbnik membrane-SPME (M-SPME) sporządzono z zastosowaniem polietylenoglikolu (PEG)o masie cząsteczkowej 20 kDa. Polimer ten jest rozpuszczalny w wodzie i w typowych warunkach...
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Exfoliated Graphite as a New Sorbent for Removal of Engine Oils from Wastewater
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The influence of magnetic particle incorporation on bisphenol A removal by β-cyclodextrin-derived sorbent
PublicationA novel, biomass-derived hybrid sorbent Ban-CD-EPI-Fe was successfully synthesized in a coprecipitation method, in which β-cyclodextrin copolymerized with banana peel extract and epichlorohydrin was grafted onto an iron oxide surface. The composition, presence of functional groups, morphology, thermal stability, and magnetic properties of the obtained material were characterized by Powder X-Ray Diffraction (XRD), X-Ray Photoelectron...
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Experimental and numerical investigation of mercury removal from flue gas by sorbent polymer composite
PublicationThis paper presents an experimental and numerical investigation of the performance of a sorbent polymer composite (SPC) material used for removing mercury from the flue gases in a full-scale industrial installation. The investigated material is an attractive alternative to activated carbon, which is commonly used for this purpose. While the application of the SPC is characterized by high capital expenditures, this technology offers...
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New sorbent materials for selective extraction of cocaine and benzoylecgonine from human urine samples
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Selective determination of cocaine and its metabolite benzoylecgonine in environmental samples by newly developed sorbent materials
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Determination of carbamazepine in urine and water samples using amino-functionalized metal–organic framework as sorbent
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Continuous Monitoring of Thermooxidative Degradation Products of Polystyrene by Membrane Extraction with Sorbent Interface and Gas Chromatography
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Porous material-based sorbent coatings in Solid-phase microextraction technique: Recent trends and future perspectives
PublicationThe use of porous materials as sorbents in sample preparation techniques has gained recent scientific attention in the context of developing novel fibers for the Solid-phase microextraction (SPME) technique. SPME requires the appropriate selection of a robust sorbent for successful utilization under variable conditions. A deeper understanding of the nature of newly developed porous SPME coatings and the impact of their structures...
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Construction of an innovative adsorbent bed configuration in the adsorption chiller - Selection criteria for effective sorbent-glue pair
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Characteristics of the Properties of Absodan Plus Sorbent and Its Ability to Remove Phosphates and Chromates from Aqueous Solutions
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Polymeric metal‐containing ionic liquid sorbent coating for the determination of amines using headspace solid‐phase microextraction
PublicationThis study describes the design, synthesis, and application of polymeric ionic liquid sorbent coatings featuring nickel metal centers for the determination of volatile and semivolatile amines from water samples using headspace solidphase microextraction. The examined polymeric ionic liquid sorbent coatings were composed of two ionic liquid monomers (tetra(3-vinylimidazolium)nickel bis[(trifluoromethyl)sulfonyl]imide [Ni2+(VIM)4]...
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Evaluation of polycaprolactone as a new sorbent coating for determination of polar organic compounds in water samples using membrane–SPME
PublicationCommercially available solid-phase microextraction fibers used for isolation of polar analytes are based on the adsorption phenomenon. In consequence, typical limitations bonded with analytes displacement and matrix effects are very frequent. In the present study, alternative solution is described. Polycaprolactone (PCL) was used for the first time as sorbent to isolate polar organic compounds from water samples using the membrane–solid-phase...
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Ionogel sorbent coatings for determining organophosphorus and pyrethroid insecticides in water and fresh juice samples by headspace-solid phase microextraction
PublicationThe sol–gel method yielded three different ionogel sorbent coatings that were obtained based on a silica material containing ionic liquids (ILs) immobilized in its pores. Two ILs, triethylsulfonium bis(trifluoromethylsulfonyl) imide [Set3][TFSI] and 1-butyl-1-methylpiperidinium bis(trifluoromethylsulfonyl)imide [C4C1Pip][TFSI], as well as their equimolar mixture [Set3/C4C1Pip], were used to obtain ionogel fibers. The developed...
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Membrane extraction with sorbent interface-gas chromatography as an effective and fast means for continuous monitoring of thermal degradation products of polyacrylonitrile
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Determination of selenium by X-ray fluorescence spectrometry using dispersive solid-phase microextraction with multiwalled carbon nanotubes as solid sorbent
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The possibility to use multi-walled carbon nanotubes as a sorbent for dispersive solid phase extraction of selected pharmaceuticals and their metabolites: Effect of extraction condition
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Synthesis, characterization and application of cross-linked functional terpolymer through epoxy group as sorbent for extraction of cadmium from waters and foods: Multivariate optimization
PublicationThe purpose of this study was to develop a selective sorbent for cadmium ions (Cd(II)) enrichment in orbital shaker assisted solid phase microextraction (OS-SPME) from different aqueous and food samples. A maleic anhydride-styrene-glycidyl methacrylate (MA-St-GMA) terpolymer was synthesized and characterized in detail. Experimental variables of sample preparation step were optimized using a central composite design (CCD). The final...
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Study on effectiveness of PVC/β-diketone sorbent in removing residue of Zn(II), Cr(III) and Ni(II) from post-galvanic wastewater
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Membrane in tandem with a helical sorbent trap as continuous sampling technique of the polyvinyl chloride thermo-oxidative degradation products for their on-line gas chromatographic monitoring
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Spectrofluorometrical Determination of Vitamin B 1 in Different Matrices Using Box‐Behnken Designed Pipette Tip Solid Phase Extraction by a Carbon Nanotube Sorbent
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Fast determination of bisphenol A in spiked juice and drinking water samples by pipette tip solid phase extraction using cobalt metal organic framework as sorbent
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A hierarchical porous composite magnetic sorbent of reduced graphene oxide embedded in polyvinyl alcohol cryogel for solvent‐assisted‐solid phase extraction of polycyclic aromatic hydrocarbons
PublicationA hierarchical porouscomposite magnetic sorbent was fabricated and applied tothe dispersive solvent-assisted solid-phase extraction of five polycyclic aromatichydrocarbons. A sorbent was first prepared by incorporating graphene oxide,calcium carbonate, and magnetite nanoparticles into a polyvinyl alcohol cryo-gel. The graphene oxide was converted to reduced graphene oxide using ascorbicacid and a hierarchical porous structure was...
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A magnetic stir bar sorbent of metal organic frameworks, carbon foam decorated zinc oxide and cryogel to enrich and extract parabens and bisphenols from food samples
PublicationA porous composite magnetic stir bar adsorbent was fabricated for the extraction and enrichment of parabens and bisphenols from selected beverage samples. The adsorbent comprised a metal organic framework, carbon foam decorated zinc oxide and magnetic nanoparticles embedded in polyvinyl alcohol cryogel. The porous composite stir bar adsorbent could adsorb parabens and bisphenols via hydrogen bonding, π-π and hydrophobic interactions....
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PCN-222 metal–organic framework: a selective and highly efficient sorbent for the extraction of aspartame from gum, juice, and diet soft drink before its spectrophotometric determination
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Box-Behnken design optimization of pipette tip solid phase extraction for methyl orange and acid red determination by spectrophotometry in seawater samples using graphite based magnetic NiFe2O4 decorated exfoliated as sorbent
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Badania osadu czynnego jako sorbentu oleju.
PublicationPrzeprowadzono badania właściwości sorpcyjnych wysuszonego osadu czynnego względem ciekłych węglowodorów. Zastosowano dwie techniki eksperymentalne:metodę wzniesienia kapilarnego i dynamiczną sorpcję oleju z dyspersji typu olej w wodzie. Sorbent uzyskany z osadu flokulowanego za pomocą polimeru organicznego był lepiej zwilżany niż sorbent otrzymany z osadu zagęszczanego bez dodatków chemicznych.
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Polimerowe ciecze jonowe - sorbenty nowej generacji w SPME
PublicationSposób przygotowywania próbek do analizy jest kluczowym etapem każdej procedury analitycznej. Od momentu wprowadzenia, technika mikroekstrakcji do fazy stacjonarnej (SPME), z uwagi na mnogość jej zalet cechuje duża popularność. W ostatnim czasie jej popularność rośnie, z uwagi na opracowywanie nowych sorbentów, które pozwoliłyby na rozszerzenie możliwości stosowania tej techniki. W artykule przedstawione są innowacyjne sorbenty...
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Sorbent, kolumna sorpcyjna lub chromatograficzna
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Sorbents modified by deep eutectic solvents in microextraction techniques
PublicationIn recent years, considerable attention has been directed towards the employment of green solvents, specifically deep eutectic solvents (DES), in liquid phase microextraction techniques. However, comprehensive and organized knowledge regarding the modification of sorbent surface structures with DES remains limited. Therefore, this paper reviews the application of DES in modifying and improving the properties of sorbents for microextraction...
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Możliwości usuwania fosforanów z wód opadowych z wykorzystaniem zmodyfikowanego sorbentu
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CaO-based high temperature CO2 sorbents – Literature review
PublicationThe use of CaO-based adsorbents has a high potential to capture CO2 from various systems due to its high reactivity with CO2, high capacity, and low cost of naturally derived CaO. The application of CaO-based sorbents to remove carbon dioxide is based on a reversible reaction between CaO and CO2. However, multiple carbonation/calcination cycles lead to a rapid reduction in the sorption capacity of natural CaO, and therefore efforts...
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Ion Capacity of Siliceous Sorbents with Surface Polymer Layers Composed of Different Dextran—Triethylenetetraamine Mixtures (Ion Capacity of Sorbents with Surface Polymer Layers)
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Progress in development of molecularly imprinted polymers as sorbents for sample preparation
PublicationSample preparation has been one of the most often investigated steps in analytical procedures.These investigations are focused on problems such as isolation of analytes from the sample matrix, matrix implification, analyte enrichment to the level above the detection limit of the instrumentation used, and the removal of interfering species to improve the final determination. Techniques based on solid (adsorption) and pseudo liquid...
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Retention behaviour of some high-intensity sweeteners on different SPE sorbents
PublicationThe objective of this paper is to provide information about application of solid phase extraction (SPE) for isolation of nine high-intensity sweeteners (acesulfame-K, alitame, aspartame, cyclamate, dulcin, neotame, saccharin, sucralose and neohesperidin dihydrochalcone) from aqueous solutions. The influence of several types of LC-MS compatible buffers (different pH values and compositions) on their recovery has been studied and...
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Treatment Wetland effluent quality improvement by usage sorbents of various origin
PublicationTWs are finding as low-cost and also effective system to treat domestic wastewater. The aim of this study is to find suitable adsorbing material for application in an additional treatment unit where treatment wetlands do not provide sufficient PO4 3- reduction level. Material M1 is a fine-grained by-product of thermal treatment of carbonate-siliceous rock (opoka) with high content of calcium carbonate CaCO3 in temperature 700°C....
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Computational modeling of molecularly imprinted polymers as a green approach to the development of novel analytical sorbents
PublicationThe development of novel molecularly imprinted polymers (MIP) sorbents for specific chemical compounds require a lot of tedious and time-consuming laboratory work. Significant quantities of solvents and reagents are consumed in the course of the verification of appropriate configurations of polymerization reagents. Implementation of molecular modeling in the MIP sorbent development process appears to provide a solution to this...
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The triple-sorbents solid-phase extraction for pharmaceuticals and estrogens determination in wastewater samples
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The Efficiency of P-Removal from Natural Waters with Sorbents Placed in Water Permeable Nonwovens
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Synthesis and Modification by Carbonization of Styrene–Ethylene Glycol Dimethacrylate–Lignin Sorbents and their Sorption of Acetylsalicylic Acid
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Physicochemical Properties and Application of Silica-Doped Biochar Composites as Efficient Sorbents of Copper from Tap Water
PublicationThis article concerns research on new sorption materials based on silica-doped activated carbon. A two-stage synthesis involved pyrolysis of plant material impregnated in a water glass solution , followed by hydrothermal activation of the pyrolysate in KOH solution. The resulting composite can be used as a sorbent in drinking water filters. The proposed method of synthesis enables the design of materials with a surface area...
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MEPS - MIKROEKSTRAKCJA NA ZŁOŻU SORBENTU – NOWE ROZWIĄZANIE W ZAKRESIE IZOLACJI I WZBOGACANIA ANALITÓW Z CIEKŁYCH PRÓBEK ŚRODOWISKOWYCH
PublicationSposób przygotowania próbek jest jednym z ważniejszych etapów każdej procedury analitycznej, a oznaczanie analitów na poziomie śladów, często w próbce o skomplikowanym składzie, wymaga szczególnie wyrafinowanego sposobu wydzielania i wzbogacania analitów. Jednym z ostatnich rozwiązań w tym zakresie jest zminiaturyzowany wariant ekstrakcji do fazy stałej czyli mikroekstrakcja na złożu sorbentu (MEPS). Wielką zaletą...
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Effective assessment of biopolymer-based multifunctional sorbents for the remediation of environmentally hazardous contaminants from aqueous solutions
PublicationPersistent contaminants in wastewater effluent pose a significant threat to aquatic life and are one of the most significant environmental concerns of our time. Although there are a variety of traditional methods available in wastewater treatment, including adsorption, coagulation, flocculation, ion exchange, membrane filtration, co-precipitation and solvent extraction, none of these have been found to be significantly cost-effective...
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Od odpadów rolniczych do wysokowydajnego sorbentu. Węgiel aktywny pochodzący z łupin orzechów laskowych do oczyszczania wody i ścieków
PublicationŁupiny orzechów laskowych, produkt uboczny przemysłu spożywczego, mają znaczny potencjał jako prekursor do produkcji węgla aktywnego ze względu na ich dużą dostępność i dużą zawartość węgla. Przedstawiono badania możliwości przekształcenia łupin orzechów laskowych w węgiel aktywny, wykorzystany do oczyszczania ścieków z zanieczyszczeń organicznych. Porównano procesy aktywacji fizycznej i chemicznej otrzymanego węgla. Otrzymano...
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Preparation and characterization of dummy-template molecularly imprinted polymers as potential sorbents for the recognition of selected polybrominated diphenyl ethers
PublicationThe main aim of this work was to conduct the preliminary/basic research concerning the preparation process of a new dummy molecularly imprinted polymer (DMIP) materials. Developed DMIPs were proposed as a sorption material in solid-phase extraction (SPE) technique for recognition of selected low mass polybrominated diphenyl ethers (PBDEs) e PBDE-47 and PBDE-99. Four new DMIPs were synthesized employing bulky polymerization technique...
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Możliwości wykorzystania w praktyce analitycznej sorbentów polimerowych z odciskiem molekularnym do wyodrębniania i/lub wzbogacania analitów z grupy trwałych zanieczyszczeń organicznych z próbek środowiskowych
PublicationPrzedstawiono przegląd informacji, które się pojawiły w ciągu ostatniego okresu czasu dotyczących wykorzystania w codziennej praktyce analitycznej różnego typu rozwiązań metodycznych wykorzystujących na etapie izolacji i/lub wzbogacania analitów z grupy trwałych zanieczyszczeń organicznych (TZO) sorbentów polimerowych z odciskiem molekularnym (MIP). Tego typu sorbenty znalazły szerokie zastosowanie przede wszystkim jako alternatywne...