Search results for: TRIPLETY GUANINOWE
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Triplet Formation and Triplet‐Triplet Annihilation Upconversion in Iodine Substituted Non‐Orthogonal BODIPY‐Perylene Dyads
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Triplet Formation and Triplet‐Triplet Annihilation Upconversion in Iodine Substituted Non‐Orthogonal BODIPY‐Perylene Dyads
PublicationBODIPY-perylene dyads have emerged as useful metal free sensitizers for triplet-triplet annihilation upconversion (TTAUC), these dyads are capable of efficient triplet generation via spinorbit charge transfer intersystem crossing (SOCT-ISC). This important route to triplet formation requires dyads in which two moieties are oriented perpendicular to each other. In this contribution, we give a deeper insight on the behavior of recently...
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BODIPY‐Perylene Charge Transfer Compounds; Sensitizers for Triplet‐Triplet Annihilation Up‐conversion
PublicationBODIPY heterochromophores, asymmetrically substituted with perylene and/or iodine at the 2 and 6 positions were prepared and investigated as sensitizers for triplet-triplet annihilation up conversion (TTA-UC). Single-crystal X-ray crystallographic analyses show that the torsion angle between BODIPY and perylene units lie between 73.54 and 74.51, though they are not orthogonal. Both compounds show intense, charge transfer absorption...
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Electron Binding Capabilities of Some Silylenes Having Small Singlet−Triplet Splittings or Triplet Ground States
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Triplet–Triplet Annihilation Upconverting Liposomes: Mechanistic Insights into the Role of Membranes in Two-Dimensional TTA-UC
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Triplet–Triplet Annihilation Upconverting Liposomes: Mechanistic Insights into the Role of Membranes in Two-Dimensional TTA-UC
PublicationTriplet−triplet annihilation upconversion (TTA-UC) implemented in nanoparticle assemblies is of emerging interest in biomedical applications, including in drug delivery and imaging. As it is a bimolecular process, ensuring sufficient mobility of the sensitizer and annihilator to facilitate effective collision in the nanoparticle is key. Liposomes can provide the benefits of two-dimensional confinement and condensed concentration...
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Triple Helix
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Tkaninowe tarcze polerskie do operacji ręcznych i zautomatyzowanych
PublicationNa podstawie własnego doświadczenia w produkcji narzędzi, kontaktów z użytkownikami oraz analizy ofert producentów przedstawiono narzędzia do ścierno-polerskich obróbek wykończeniowych, w których elementem roboczym jest tkanina. Zwrócono uwagę na ich konstrukcję, stosowane materiały włókiennicze oraz warunki i optymalne obszary ich zastosowań.
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Possible singlet-to-triplet pairing transition inNaxCoO2·yH2O
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Possible singlet-to-triplet pairing transition in Na_xCoO_2 * yH_2O
PublicationW pracy przedstawiono dokładne pomiary górnego pola krytycznego (H_c2) w niedawno odkrytym nadprzewodniku Na_xCoO_2 * yH_2O. Zauważono niezwykłe zachowanie pola krytycznego w funkcji temperatury. W celu wyjaśnienie zjawiska rozwiązano równania Gorkova dla sieci trójkątnej. Eksperymentalny wynik może być interpretowany jako przejście singlet - tryplet wywołane polem magnetycznym.
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Alkylation of 9-substituted guanine derivatives with α,ω-dihaloalkanes
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A Triplet-Learnt Coarse-to-Fine Reranking for Vehicle Re-identification
PublicationVehicle re-identification refers to the task of matching the same query vehicle across non-overlapping cameras and diverse viewpoints. Research interest on the field emerged with intelligent transportation systems and the necessity for public security maintenance. Compared to person, vehicle re-identification is more intricate, facing the challenges of lower intra-class and higher inter-class similarities. Motivated by deep...
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A Triplet-learnt Coarse-to-Fine Reranking for Vehicle Re-identification
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TRIPLEC-Communication Capitalism & Critique
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Organic electroluminescence from singlet and triplet exciplexes: Exciplex electrophosphorescent diode
PublicationW pracy zaobserwowano po raz pierwszy elektroluminescencję z trypletowych stanów ekscypleksowych w układzie dwuamina TPD (donor) -organiczny kompleks gadolinu (akceptor). Opsano konstrukcję elektrofosforescencyjnej diody ekscypleksowej.
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Triplet exciton interactions in solid films of an elektrophosphorescent Pt(II) porphyrin
PublicationW pracy pokazano, że fosforescencja porfiryny platynowej (PtOEP) jest wygaszana na skutek oddziaływania między monomerowymi i dimerowymi ekscytonami trypletowymi. Stała oddziaływania dla monomerowych ekscytonów trypletowych wynosi 8x10-12 cm3/s a dla ekscytonów dimerowych 8x10-15 cm3/s.
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Telomere uncapping by common oxidative guanine lesions: Insights from atomistic models
PublicationOxidative damage to DNA is widely known to contribute to aging and disease. This relationship has been extensively studied for telomeres – structures that cap chromosome ends – due to their role in cell proliferation and senescence, and exceptional susceptibility to oxidation. Indeed, the repetitive telomeric DNA sequence contains the 5′-GGG-3′ motif that has the lowest ionization potential of all trinucleotides. Accordingly, experiments...
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Melamine-modified boron-doped diamond towards enhanced detection of adenine, guanine and caffeine
PublicationThis work describes the electrochemical method of boron-doped diamond (BDD) modification by poly-melamine to obtain organic film. The detection of adenine, guanine and caffeine were carried out by differential pulse wave voltammetry. The poly-melamine modified B-NCD electrodes exhibit excellent activity towards the electrochemical oxidation of all examined analytes. The poly-melamine modified BDD electrodes in all measurements...
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Triplet energy exchange between fluorescent and phosphorescent organic molecules in a solid state matrix.
PublicationW pracy przedstawiono model wymiany energii trypletów na podstawie mechanizmu Dextera i zweryfikowano go w układzie dwuamina TPD : organiczny komleks Ir(ppy)3: matryca poliwęglanowa, mierząc czasy życia emisji Ir(ppy)3 przy różnych koncentracjach molekuł TPD.
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Impacts in case of triple unilaterally constrained system
PublicationThe this paper focus on the behaviour of a “rigid” body biting into another “rigid” body, with some nonzero relative velocity. In the presently considered case, the introduced collision appears between a selected element of a multibody structure and its reference body being interpreted as the motionless ground. Instead of the classic case, described in a number of dissertations, where a single impacting contact is considered, three...
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Triple Combination of Ascorbate, Menadione and the Inhibition of Peroxiredoxin-1 Produces Synergistic Cytotoxic Effects in Triple-Negative Breast Cancer Cells
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Singlet and triplet excited states of a series of BODIPY dyes as calculated by TDDFT and DLPNO-STEOM-CCSD methods
PublicationThe singlet and triplet excited states of three iodine substituted BODIPY dyes differing by their substituent (-phenyl, -phenylOH and -phenylNO2) at the meso position of the BODIPY core (BOD) are investigated by (TDA)-TDDFT and DLPNO-STEOM-CCSD calculations. An assessment of hybrid (B3LYP and MN15) and double hybrid (SOS-PBE-QIDH and SOS-ωPBEPP86) exchange-correlation functionals is performed with respect to the DLPNO-STEOM-CCSD...
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Stark effect of atomic helium second triplet series in electric fields up to 1600 kV cm−1
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Meta-Design and the Triple Learning Organization in Architectural Design Process
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Conjugated control of triple active bridge converter with common HFT
PublicationPaper presents synthetic analyses of single input, dual output DC/AC/DC converter with common high frequency transformer. Rise the problem of cross-coupling power flows between secondary terminals, under asymmetrical control operating condition. It also proposes a new approach to converter control, based on conjugated phase shift modulation and defines its limitations. Finally, the developed control technique was verified by simulation...
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Triple correlation states between in-situ tested soil parameters
PublicationWhen testing soil parameters, the measured parameter values are only approximations of the true values. The measurand is determined based on metrological uncertainties or using statistical models for analysing data. Some parameters of the soil state present strong correlations, but others do not always provide simple correspondences. Multiple correlations between geotechnical parameters can provide a new perspective regarding the...
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Molecular dynamics simulations reveal the balance of forces governing the formation of a guanine tetrad—a common structural unit of G-quadruplex DNA
PublicationG-quadruplexes (G4) are nucleic acid conformations of guanine-rich sequences, in which guanines are arranged in the square-planar G-tetrads, stacked on one another. G4 motifs form in vivo and are implicated in regulation of such processes as gene expression and chromosome maintenance. The structure and stability of various G4 topologies were determined experimentally; however, the driving forces for their formation are not fully...
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Induction of unique structural changes in guanine-rich DNA regions by the triazoloacridone C-1305, a topoisomerase II inhibitor with antitumor activities.
PublicationCelem pracy było scharakteryzowanie odziaływania związku C-1305 z DNA w porównaniu do innych inhibitorów topoizomerazy II. Badania pokazują, że C-1305 odziaływuje preferencyjnie z parami CG, interkaluje do DNA i zaburza sąsiednie otoczenie w bardzo charakterystyczny sposób, który nie został zaobserwowany u pozostałych 22 badanych związków.
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Triple dermoid sinus in sacro-caudal region in Rhodesian Ridgeback dog.
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Triple-objective models for portfolio optimisation with symmetric and percentile risk measures
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Triple helical collagen-like peptide interactions with selected polyphenolic compounds
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Weak antilocalization effect and triply degenerate state in Cu-doped CaAuAs
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MCSA with Normalized Triple Covariance as a bearings diagnostic indicator in an induction motor
PublicationStatistics of bearing failures in induction motors indicate, that they constitute more than 40% of IM damage, therefore bearing diagnosis is very important. Vibration methods for bearing diagnostics have one major disadvantage - they require the availability of the machine for sensors installation. This is the reason for seeking new methods based on motor supply current analysis. Diagnosis of induction motors, conducted remotely...
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Miniaturized uniplanar triple-band slot dipole antenna with folded radiator
PublicationA miniaturized uniplanar slot dipole for triple-frequency operation is presented. The antenna consists of a folded slot radiator with an increased number of degrees of freedom that allow for efficient size reduction. Rigorous electromagnetic (EM)-driven design optimization is applied in order to achieve the smallest possible size while maintaining acceptable levels of antenna reflection at the required operating frequencies. The...
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A single and triple-objective mathematical programming models for assignment of services in a healthcare institution
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A Reference Point Method to Triple-Objective Assignment of Supporting Services in a Healthcare Institution
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The triple-sorbents solid-phase extraction for pharmaceuticals and estrogens determination in wastewater samples
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Structure and transport properties of triple-conducting BaxSr1−xTi1−yFeyO3−δ oxides
PublicationIn this work, BaxSr1−xTi1−yFeyO3−δ perovskite-based mixed conducting ceramics (for x = 0, 0.2, 0.5 and y = 0.1, 0.8) were synthesized and studied. The structural analysis based on the X-ray diffraction results showed significant changes in the unit cell volume and Fe(Ti)–O distance as a function of Ba content. The morphology of the synthesized samples studied by means of scanning electron microscopy has shown different microstructures...
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Current based Normalized Triple Covariance as a bearings diagnostic feature in induction motor
PublicationDiagnosis of induction motors, conducted remotely by measuring and analyzing the supply current is attractive with the lack of access to the engine. So far there is no solution, based on analysis of current, the credibility of which allow use in industry. Statistics of IM bearing failures of induction motors indicate, that they constitute more than 40% of IM damage, therefore bearing diagnosis is so important. The article provides...
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Rapid dimension scaling of triple-band antennas by means of inverse surrogate modeling
PublicationGeometry scaling of antennas, i.e., finding optimum dimensions of the structure for given operating conditions and material parameters is an important yet challenging problem. In this paper, we discuss fast dimension scaling of triple-band antennas with respect to operating frequencies. We adopt the inverse surrogate modeling approach where the surrogate model is a function of the three operating frequencies of the antenna and...
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Induction motor bearings diagnostic indicators based on MCSA and normalized triple covariance
PublicationInduction motors are one of the most widely used electrical machines. Statistics of bearing failures of induction motors indicate, that they constitute more than 40% of induction motor damage. Therefore, bearing diagnosis is so important for trouble-free work of induction motors. The most common methods of bearing diagnosis are based on vibration signal analysis. The main disadvantage of those methods is the need for physical access...
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Study on population dynamics for triple-linked food chain using a simulation-based approach
PublicationThe procedures based on simulation have become a feasible testing method that does not require investing valuable resources to create a concrete prototype, especially with the increasing computational power of computers. Thus, design changes can be adopted and design errors can be fixed before it is too late. Simulation turns to be a cheap, safe and often more acceptable from an ethical perspective. In our work we summarize the...
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Miniaturized Inline Bandpass Filters Based on Triple-Mode Integrated Coaxial-Waveguide Resonators
PublicationThis work presents a design technique to implement miniaturized cross-coupled bandpass filters in inline physical configurations based on triple-mode resonators. Triple-mode resonances are obtained by using integrated coaxial-waveguide cavity resonators. They consist of two coaxial conducting posts placed in the sidewalls of a rectangular waveguide cavity. In the proposed triplet, a transmission zero (TZ) can be positioned at any...
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In Vitro Cytotoxicity Assessment of Betulinic Acid Organic Salts on Triple-Negative Breast Cancer Cells
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Design of a SiC based triple active bridge ceil for a multi-megawatt DC-DC converter
PublicationThe paper describes the design methodology of a novel Triple Active Bridge cell used as the building block for modular DC-DC converters. The intended application is for Medium Voltage Direct Current grids, such as the DC collector for offshore wind farms. The latest generation of SiC MOSFET semiconductors is utilized to operate in the medium frequency range while optimizing the efficiency. The dimensioning of the main cell components,...
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Thermoelectric and electrical properties of triple-conducting multicomponent oxides based on substituted barium cerate-zirconate
PublicationMulticomponent oxides often have exceptional thermal stability and interesting electronic properties. The present work presents the thermoelectric and electrical properties of the Ba(Zr0.2Hf0.2Sn0.2Ti0.2Fe0.2)O3−δ and Ba(Zr0.1Hf0.1Sn0.1Ti0.1Co0.1Ce0.1Bi0.1Fe0.1Y0.1Zn0.1)O3−δ multicomponent perovskites. Single-phase cubic perovskites were synthesized using the solid-state reaction method. They were characterized using X-ray...
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Rola parków naukowo-technologicznych w modelu triple helix na przykładzie parków Polski Wschodniej
PublicationCelem artykułu jest omówienie roli parków naukowo-technologicznych w modelu triple helix, zarówno w aspekcie teoretycznym, jak i w oparciu o przeprowadzone badania empiryczne. Autorki zaprezentowały wyniki badańdotyczących powiązań wybranych parkówz pozostałymi grupami aktorów wyróżnionymi w modelu triple helix, ze szczególnym uwzględnieniem instytucji B+R, władz publicznych oraz innych instytucji pośredniczących. Badania przeprowadzono...
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Influence of iron content on water uptake and charge transport in BaCe0.6Zr0.2Y0.2−xFexO3−δ triple-conducting oxides
PublicationIn this work, we studied the BaCe0.6Zr0.2Y0.2−xFexO3−δ system which belongs to the triple-conducting oxides (TCOs) group. The electrochemical properties of BaCe0.6Zr0.2Y0.2−xFexO3−δ were investigated using electrochemical impedance spectroscopy (EIS) and the water uptake was analyzed using thermogravimetry (TG). All investigated materials exhibited water uptake, with proton concentration increasing with decreasing iron content....
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Comparing the Effects of Duo-Functional Triple-Layer Films Enriched with Different Sources of Curcumin on the Shelf-Life of Fish
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Co-free triple perovskite La1.5Ba1.5Cu3O7±δ as a promising air electrode material for solid oxide fuel cells
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