Physicochemical and Mechanical Performance of Freestanding Boron-Doped Diamond Nanosheets Coated with C:H:N:O Plasma Polymer - Publikacja - MOST Wiedzy

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Physicochemical and Mechanical Performance of Freestanding Boron-Doped Diamond Nanosheets Coated with C:H:N:O Plasma Polymer

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The physicochemical and mechanical properties of thin and freestanding heavy boron-doped diamond (BDD) nanosheets coated with a thin C:H:N:O plasma polymer were studied. First, diamond nanosheets were grown and doped with boron on a Ta substrate using the microwave plasma-enhanced chemical vapor deposition technique (MPECVD). Next, the BDD/Ta samples were covered with nylon 6.6 to improve their stability in harsh environments and flexibility during elastic deformations. Plasma polymer films with a thickness of the 500–1000 nm were obtained by magnetron sputtering of a bulk target of nylon 6.6. Hydrophilic nitrogen-rich C:H:N:O was prepared by the sputtering of nylon 6.6. C:H:N:O as a film with high surface energy improves adhesion in ambient conditions. The nylon–diamond interface was perfectly formed, and hence, the adhesion behavior could be attributed to the dissipation of viscoelastic energy originating from irreversible energy loss in soft polymer structure. Diamond surface heterogeneities have been shown to pin the contact edge, indicating that the retraction process causes instantaneous fluctuations on the surface in specified microscale regions. The observed Raman bands at 390, 275, and 220 cm−1 were weak; therefore, the obtained films exhibited a low level of nylon 6 polymerization and short-distance arrangement, indicating crystal symmetry and interchain interactions. The mechanical properties of the nylon-on-diamond were determined by a nanoindentation test in multiload mode. Increasing the maximum load during the nanoindentation test resulted in a decreased hardness of the fabricated structure. The integration of freestanding diamond nanosheets will make it possible to design flexible chemical multielectrode sensors.

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Wersja publikacji
Accepted albo Published Version
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.3390/ma13081861
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Creative Commons: CC-BY otwiera się w nowej karcie

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Kategoria:
Publikacja w czasopiśmie
Typ:
artykuły w czasopismach
Opublikowano w:
Materials nr 13,
ISSN: 1996-1944
Język:
angielski
Rok wydania:
2020
Opis bibliograficzny:
Rycewicz M., Macewicz Ł., Kratochvil J., Stanisławska A., Ficek M., Sawczak M., Stranak V., Szkodo M., Bogdanowicz R.: Physicochemical and Mechanical Performance of Freestanding Boron-Doped Diamond Nanosheets Coated with C:H:N:O Plasma Polymer// Materials -Vol. 13,iss. 8 (2020), s.1861-
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.3390/ma13081861
Weryfikacja:
Politechnika Gdańska

wyświetlono 140 razy

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