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Search results for: boron doped diamond
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Monometallic nanoparticles decorated and rare earth ions doped KTaO3/K2Ta2O6 photocatalysts with enhanced pollutant decomposition and improved H2 generation
PublicationNew, monometallic nanoparticles (MNPs) decorated surface and rare earth (RE) ions doped lattice of perovskite-type (KTaO3)/pyrochlore-type (K2Ta2O6) photocatalysts were successfully prepared by facile hydrothermal incorporation of RE ions into KTaO3/K2Ta2O6 lattices followed by photodeposition of MNPs. The impact of noble metal type (MNPs = Au, Pt, Rh) and rare earth dopant type (RE = Er, Pr) on the physicochemical properties correlated...
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Rare earth ions doped K 2 Ta 2 O 6 photocatalysts with enhanced UV–vis light activity
PublicationNew rare earth-doped K2Ta2O6 photocatalysts were successfully synthesized by hydrothermal method. The effect of dopant type (Y,Yb,Ho,Pr,Er) and amount of rare earth precursor (2,4,8 and 10 mol%) on the physicochemical and photocatalytic properties of RE-K2Ta2O6 have been investigated. All as-prepared materials were characterized by UV–vis diffuse reflectance spectroscopy, Brunauer-Emmett-Teller specific surface area measurement,...
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Long-working-distance Raman system for monitoring of uPA ECR CVD process of thin diamond/DLC layers growth
PublicationW artykule przedstawiono konstrucję systemu optoelektronicznego do monitoringu ramanowskiego in-situ procesu μPA ECR CVD (ang.: Microwave Plasma Assisted Electron Cyclotron Resonance Chemical Vapour Deposition), stosowanego do osadzania cienkich warstw diamentowych i diamentopodobnych DLC. System ma budowę modułową i wyposażony jest w dedykowane sondy optyczne. Przedstawiono wyniki pomiarów testowych, potwierdzjące, że system posiada...
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Stress-driven nonlocal elasticity for nonlinear vibration characteristics of carbon/boron-nitride hetero-nanotube subject to magneto-thermal environment
PublicationStress-driven nonlocal theory of elasticity, in its differential form, is applied to investigate the nonlinear vibrational characteristics of a hetero-nanotube in magneto-thermal environment with the help of finite element method. In order to more precisely deal with the dynamic behavior of size-dependent nanotubes, a two-node beam element with six degrees-of freedom including the nodal values of the deflection, slope and curvature...
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Effect of nano-boron spraying on the concentration of some nutrients in leaves and dry matter of two Vicia faba L. (Partim) cultivars
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Structural and catalytic properties of ceria layers doped with transition metals for SOFCs fueled by biogas
PublicationThe aim of this paper was to investigate an influence of the nanocrystalline Ce0.8A0.2O2-δ (A = Mn, Fe, Co, Ni, Cu) materials on the direct internal reforming of biogas in SOFC. Structural analysis of fabricated compounds has been done. An in-situ analysis of a composition of outlet gases from operating SOFC was performed using FTIR spectroscopy with simultaneous electrical tests. It was found out, that type of dopant strongly...
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Bismuth-Doped Nano Zerovalent Iron: A Novel Catalyst for Chloramphenicol Degradation and Hydrogen Production
PublicationIn this study, we showed that doping bismuth (Bi) at the surface of Fe0 (Bi/Fe0, bimetallic iron system)—synthesized by a simple borohydride reduction method—can considerably accelerate the reductive degradation of chloramphenicol (CHP). At a reaction time of 12 min, 62, 68, 74, 95, and 82% degradation of CHP was achieved with Fe0, Bi/Fe0-1 [1% (w/w) of Bi], Bi/Fe0-3 [3% (w/w) of Bi], Bi/Fe0-5 [5% (w/w) of Bi], and Bi/Fe0-8 [8%...
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Salt melt synthesis of curved nitrogen-doped carbon nanostructures: ORR kinetics boost
PublicationImplementing metal-free electrocatalysts for the oxygen reduction reaction (ORR) and revealing crucial chemical or topographical parameters driving their activity are vital for the development of power cells. The carbon-based catalysts are very often synthesized through carbonization of biopolymers, in particular, those one containing nitrogen groups such as chitosan. Unfortunately, the resulting carbonaceous materials usually...
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Influence of electropolymerization temperature on corrosion, morphological and electrical properties of PPy doped with salicylate on iron
PublicationIn this work, the influence of the electropolymerization temperature on corrosion, morphological and electrical properties of polypyrrole (PPy) film is studied. Polypyrrole is electrochemically synthesized on iron in the presence of sodium salicylate. The X-ray diffraction and scanning electron microscopy are performed in order to study the structure and morphology of electrodeposited PPy. The electroactive surface area, corrosion...
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Preparation of Ag/Cu-doped titanium (IV) oxide nanoparticles in W/O microemulsion
PublicationNanocząstki Cu-TiO2 oraz Ag/Cu-TiO2 otrzymano w mikroemulsji W/O. Właściwości fotokatalityczne zbadano w procesie degradacji fenolu (0,21mM) w zakresie światła widzialnego. Właściwości biobójcze zbadano poprzez wyznaczenie minimalnego stężenia zahamowania wzrostu (MIC) na szczepach bakterii E. coli, St. aureus oraz grzybów S. Cerevisiae i z rodziny Candida. Dla otrzymanych fotokatalizatorów określono wpływ stężenia domieszki metali...
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photocatalytic activity of silver doped tio2 in vis and uv light, prepared by microemulsion method
PublicationDitlenek tytanu otrzymany w wyniku hydrolizy izopropanolanu tytanu oraz komercyjny katalizator TiO-6 (Catalysis Society of Japan, rutyl, wielkość cząstek 15 nm) zmodyfikowano srebrem metodą mikroemulsyjną. Aktywność fotokatalityczna otrzymanych nanokompozytów Ag-TiO2 została zbadana dla fotodegradacji fenolu pod działaniem promieniowania ultrafioletowego oraz widzialnego. Zaobserwowano, że na efektywność fotorozkładu modelowego...
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The influence of charge compensation defects on the spectroscopic properties of europium doped Ca9Y(PO4)7
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Influence of Al3+co-doping on the spectral properties of europium doped Ca9Y(PO4)7
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Chromium(III)-Doped Fluoride Phosphors with Broadband Infrared Emission for Light-Emitting Diodes
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Evolution of the optical properties of chromium doped calcium tetraborate glass under high pressure
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High-pressure spectroscopy characterisation of LiSc(WO4)2 crystals doped with trivalent chromium
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Ultraviolet to near-infrared down-conversion in Bi3+–Yb3+ co-doped YAM phosphor
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Optical properties of pure and Ce3+ doped gadolinium gallium garnet crystals and epitaxial layers
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Nitrogen-doped porous carbon embedded with cobalt nanoparticles for excellent oxygen reduction reaction
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Facile synthesis N-doped hollow carbon spheres from spherical solid silica
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The anisotropic photorefractive effect in lithium sulfo-phosphate glass system doped with nickel ions
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The microstructure effect on the electrical and optical properties of undoped and Sr-doped SmCoO3 thin films.
PublicationW pracy przedstawiono elektryczne i optyczne właściwości niedomieszkowanego i domieszkowanego Sr SmCoO3 cienkich filmów. Gęste i przezroczyste filmy o grubościach 80-100nm były przygotowane na szafirze metodą nanoszenia wirowego ciekłych polimerów. Filmy były syntezowane w temperaturach od 500 do 800C co umożliwiło otrzymanie różnych mikrostruktur. Elektryczne właściwości filmów były mierzone w funkcji temperatury. Domieszkowanie...
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Organic electroluminescent devices containing phosphorescent molecules in molecularly doped hole transporting layer.
PublicationW pracy opisano mechanizm świecenia diody dwuwarstwowej diody elektroluminescencyjnej (EL) o zewnętrznej kwantowej wydajności świecenia osiągającej 9% fot./elektron. Warstwę transportującą elektrony tworzyła pochodna osadiazolu (PBD) otrzymana metodąnaparowania próżniowego. Warstwę transportującą dziury uzyskano przez wylanie roztworu poliwęglanu(PC), dendrymeru aminowego m-MTDATAoraz fosforyzującego kompleksu irydu Ir(ppy)3 i...
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Analysis of the grain boundary conductivity for nanocrystalline doped ceria using the brick layer model.
PublicationW pracy przedstawiono wyniki badań elektrycznych i mikrostrukturalnych ceru domieszkowanego itrem. Gęste i nanokrystaliczne filmy przygotowane zostały z użyciem prekursorów polimerowych na szafirze. Konduktancja elektryczna była badana w funkcji temperatury syntezy, która jest skorelowana z wielkością ziaren. Otrzymano mniejszą konduktancję nanokrystalicznego filmu ceru w porównaniu z próbkami ceramicznymi.
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N-doped carbon nanospheres as selective fluorescent probes for mercury detection in contaminated aqueous media: chemistry, fluorescence probing, cell line patterning, and liver tissue interaction
PublicationA precise nano-scale biosensor was developed here to detect Hg2+ in aqueous media. Nitrogen-doped carbon nanospheres (NCS) created from the pyrolysis of melamine–formaldehyde resin were characterized by FESEM, XRD, Raman spectra, EDS, PL, UV–vis spectra, and N2 adsorption–desorption, and were used as a highly selective and sensitive probe for detecting Hg2+ in aqueous media. The sensitivity of NCS to Hg2+ was evaluated by photoluminescence...
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Synthesis, thermal, structural and electrical properties of vanadium-doped lithium-manganese-borate glass and nanocomposites
PublicationA glassy sample with a nominal formula LiMn1−3x/2VxBO3 (where x = 0.05) was synthesised using the melt-quenching method. Material was characterised by differential thermal analysis (DTA), X-ray diffactometry (XRD) at room temperature and as a function of temperature (HT-XRD), X-ray photoelectron spectroscopy (XPS), impedance spectroscopy (IS) and scanning electron microscopy (SEM). Dependences of glass transition and crystallisation...
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Heat treatment effect on Eu3+ doped TeO2-BaO-Bi2O3 glass systems with Ag nanoparticles.
PublicationGlass systems of 73TeO2-4BaO-3Bi2O3-2Eu2O3-xAg ( in molar ratio where x= 0, 1, 2, 3) compositions have been successfully synthesized. Silver nanoparticles were obtained with the employment of heat treatment (HT) procedure executed at 350 °C. Glass transition temperatures of different compositions have been determined through DSC measurements. XRD measurement results presented characteristic amorphous halo indicating lack of long...
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Hetero-junction composed of poly(3,4-ethylenedioxythiophene) with poly(styrenesulphonate) and iodine doped titanium dioxide
PublicationPraca prezentuje nowe objętościowe heterozłacze typu p-n, gdzie domieszkowany jodem ditlenek tytanu (I-TiO2) pełni rolę elementu n, a poli(3,4-etylenodioksytiofen):poli(etylenosulfonian)(pEDOT:PSS)rolę elementu p. Heterozłącze zostało otrzymane na drodze potencjostatycznej polimeryzacji monomeru w obecnosci nanoproszku I-TiO2 zawieszonego w elektrolicie. Metoda pozwala na otrzymanie warstw hybrydowych, gdzie cząstki I-TiO2 są wbudowane...
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Dual-emission Eu-doped Ca2−xSrxPN3 nitridophosphate phosphors prepared by hot isostatic press
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Synthesis and luminescence characteristics of Dy3+ ions in silica xerogels doped with Ln2−xDyx(WO4)3
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Efficient removal of dyes and proteins by nitrogen-doped porous graphene blended polyethersulfone nanocomposite membranes
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Influence of attenuation on self-organized second-harmonic generation in a germanium-doped microstructured silica fiber
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Composite thermoluminescent detectors based on the Ce3+ doped LuAG/YAG and YAG/LuAG epitaxial structures
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The Superiority of TiO2 Supported on Nickel Foam over Ni-Doped TiO2 in the Photothermal Decomposition of Acetaldehyde
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Selectivity of Pb(II) transport across polymer inclusion membranes doped with imidazole azothiacrown ethers
PublicationMembrany wykonane z trioctanu celulozy zawierające jako jonofor 18 i 21-członowe azotiakorony z resztą imidazolu w makropierścieniu przebadano pod kątem transportu jonów Zn(II), Cd(II) i Pb(II) z wodnego roztworu soli (pH ~5.5, cMe = 0,001 M). W wyniku badań ustalono, że jon Pb(II) może być efektywnie wydzielony z roztworu mieszaniny jonów Pb(II), Zn(II), Co(II), Ni(II), Cu(II) i Cd(II).Sekwencja selektywności transportu dla 18-członowej...
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DC and AC Conductivity, Biosolubility and Thermal Properties of Mg-Doped Na2O–CaO–P2O5 Glasses
PublicationBioactive glasses have recently been extensively used to replace, regenerate, and repair hard tissues in the human body because of their ability to bond with living tissue. In this work, the effects of replacing Na2O with MgO on the electrical, biosolubility, and thermal properties of the target glass 10Na2O–60P2O5–30CaO (in mol%) were investigated. The electrical properties of the glasses were studied with the impedance spectroscopy...
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Superconductivity and appearance of negative magnetocaloric effect in Ba1–xKxBiO3 perovskites, doped by Y, La and Pr
PublicationRecently, substantial attention is given to the bismuth-based perovskites for variety of electronic applications. The perovskites are used for quantum dots displays (QLED), photovoltaic systems and superconducting (HTS) devices. In this paper comprehensive studies of Ba1–xKxBi1–yREyO3 bismuth perovskites (REBKBO, RE = Y , La or Pr) are reported. Apart from structural anomalous behavior at low temperatures, the electronic properties...
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From structure to luminescence investigation of oxyfluoride transparent glasses and glass-ceramics doped with Eu3+/Dy3+ ions
PublicationGlasses and glass-ceramics with nominal composition 73 TeO2– 4BaO– 3Bi2O3–18SrF2-2RE2O3 (where RE = Eu, Dy) have been synthesized by conventional melt-quenching technique and subsequent heat treatment at 370 °C for 24 h in air atmosphere. Various Eu3+ to Dy3+ molar ratio have been applied to investigate luminescence properties in both glass and glass-ceramic matrices. Especially, white light emission through simultaneous excitation...
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Effect of Different Radiation Sources and Noble Metal Doped onto TiO2 for Contaminants of Emerging Concern Removal
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Laser Thermal Oxidation by Ytterbium-Doped Fibre Laser of the Hot and Cold-Rolled Stainless Steel Surface
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Green Light-Excitable Ce-Doped Nitridomagnesoaluminate Sr[Mg2Al2N4] Phosphor for White Light-Emitting Diodes
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Nano-particle doped hydroxyapatite material evaluation using Spectroscopic Polarization Sensitive Optical Coherence Tomography
PublicationBio-ceramics such as hydroxyapatite (HAp) are widely used materials in medical applications, especially as an interface between implants and living tissues. There are many ways of creating structures from HAp like electrochemical assisted deposition, biomimetic, electrophoresis, pulsed laser deposition or sol-gel processing. Our research is based on analyzing the parameters of the sol-gel method for creating thin layers of HAp....
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Core-shell cobalt particles Co@CoO loaded on nitrogen-doped graphene for photocatalytic water-splitting
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A study of optical properties and annealing effect on the absorption edge of pristine- and iodine-doped polyazomethine thin films
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Tailoring the Stability of Ti-Doped Sr2Fe1.4TixMo0.6−xO6−δ Electrode Materials for Solid Oxide Fuel Cells
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Low-cost nitrogen-doped activated carbon prepared by polyethylenimine (PEI) with a convenient method for supercapacitor application
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Tribological Anti-Wear and Extreme-Pressure Performance of Multifunctional Metal and Nonmetal Doped C-based Nanodots
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The role of aluminium in metal–organic frameworks derived carbon doped with cobalt in electrocatalytic oxygen evolution reaction
PublicationWater electrolysis is one of the most crucial processes in the development of new energy sources, where ultra-clean fuel is produced - hydrogen. Oxygen evolution reaction (OER) is the sluggish process of overall water splitting. Therefore, this study presents the design, characterization and electrochemical study of cobalt-based electrocatalysts embedded into porous carbons derived from an Al-metal–organic...
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Experimental and theoretical analyses of the nonlinear optical effects in magnesium and copper co-doped zinc oxide nanorods
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Exsolution of Ni nanoparticles on the surface of cerium and nickel co-doped lanthanum strontium titanate as a new anodic layer for DIR-SOFC. Anti-coking potential and H2S poisoning resistance of the prepared material
PublicationThe aim of this study was to evaluate a new catalytic material for biogas fueled DIR-SOFC. This material was a perovskite-type SrTiO3 doped with La, Ce and Ni of a general formula La0.27Sr0.54Ce0.09Ni0.1Ti0.9O3-σ (LSCNT). Additional preparation steps were undertaken to promote a nickel exsolution process. Heat post-treatment of powders in a humidified H2 resulted in an intensive growth of nickel nanoparticles (NPs) while the temperature...