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Wyniki wyszukiwania dla: hard carbons
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Carbon nanotubes chemically derivatized with rebox systems as mediators for biofuel cell applications
PublikacjaEnzymatyczne bioogniwa paliwowe to urządzenia wykorzystujące enzymy do przemiany energii chemicznej w elektryczną. Zyskana w ten sposób energia może służyć do zasilania wszczepialnych urządzeń (np. czujników glukozy, rozruszników serca).Przedstawiono sposób otrzymywania i właściwości bioelektrod, w których wykorzystano nanorurki węglowe modyfikowane mediatorami enzymatycznych reakcji redoks. Do nanorurek przyłączano zarówno mediatory...
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Derivatization of single-walled carbon nanotubes with redox mediator biocatalytic oxygen electrodes
PublikacjaSingle-walled carbon nanotubes were covalently modyfied with a redox mediator derived from 2,2'-azino-bis-(3-ethylbenzothiazole)-6-sulfonic acid.
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Advances in engineering of diameter and distribution of the number of walls of carbon nanotubes in alcohol CVD
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Influence of Hydrogenation on Morphology, Chemical Structure and Photocatalytic Efficiency of Graphitic Carbon Nitride
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Tuning Carbon Nanotubes Through Poor Metal Addition to Iron Catalysts in CVD
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Synthesis and Characterization of Nitrogen-doped Carbon Nanotubes Derived from g-C3N4
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Preparation and characterization of catalyst mix Fe-Co/MgO for carbon nanotubes growth
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Boosting of photocatalytic hydrogen evolution via chlorine doping of polymeric carbon nitride
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Advances in Pd Nanoparticle Size Decoration of Mesoporous Carbon Spheres for Energy Application
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Enhanced thermal properties of poly(lactic acid)/MoS2/carbon nanotubes composites
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Hollow carbon sphere/metal oxide nanocomposites anodes for lithium-ion batteries
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Negative carbon dioxide gas power plant integrated with gasification of sewage sludge
PublikacjaOne of the primary objectives of the negative carbon dioxide gas power plant (nCO2PP) is to develop an innovative technology confirming the possibility of the use of sewage sludge to produce electricity while having a positive impact on the environment. In this paper, a mathematical model is presented to estimate thermodynamic parameters of the system in relation to the gasification process and changes in such parameters in the...
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Diamondized carbon nanoarchitectures as electrocatalytic material for sulfate-based oxidizing species electrogeneration
PublikacjaThe introduction of nanotechnology seems to be an imperative factor to intensify the synergic effects of electrocatalytic materials to produce strong oxidant species or to increase the active sites on their surfaces as well as to enhance the conversion yield in a fuel cell, high-added value products, electrolytic treatment for environmental protection or the detection limit in electroanalysis. Recently, a new type of 3D-diamond...
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Thermo-Mechanical Simulation of Underwater Friction Stir Welding of Low Carbon Steel
PublikacjaThis article investigates the flow of materials and weld formation during underwater friction stir welding (UFSW) of low carbon steel. A thermo-mechanical model is used to understand the relation between frictional heat phenomena during the welding and weld properties. To better understand the effects of the water environment, the simulation and experimental results were compared with the sample prepared by the traditional friction...
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Towards Carbon Neutral Settlements. The Importance of Early-Stage Urban and Energetic Optimizations
PublikacjaThe aim of the research was to verify the essence of interdisciplinary energy optimizations in earlystage urban design process. A further aim was to the find most optimal design variant and scenario in terms of urban energy efficiency for the future development in Nowy Port, located in Gdansk, Poland - a place requiring complex revitalization. The research combined qualitative and quantitative approaches; an urban design layer...
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Diatoms Biomass as a Joint Source of Biosilica and Carbon for Lithium-Ion Battery Anodes
PublikacjaThe biomass of one type cultivated diatoms (Pseudostaurosira trainorii), being a source of 3D-stuctured biosilica and organic matter—the source of carbon, was thermally processed to become an electroactive material in a potential range adequate to become an anode in lithium ion batteries. Carbonized material was characterized by means of selected solid-state physics techniques (XRD, Raman, TGA). It was shown that the pyrolysis...
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Energy Neutrality Versus Carbon Footprint Minimization In Municipal Wastewater Treatment Plants
PublikacjaThe study presents analysis of the carbon footprint (CF) in six medium and large-size municipal wastewater treatment plants (WWTPs) located across Poland. The novelty of the presented study is searching the relationship between level of energy neutrality and CF in the case studies. Although energy and CF go hand-in-hand to some degree but moving towards energy neutrality in WWTPs might also lead to an increase in the total CF of...
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Energy neutrality versus carbon footprint minimization in municipal wastewater treatment plants
PublikacjaThis work aimed to compare the carbon footprint (CF) of six full-scale wastewater treatment plants (WWTPs). The CF was estimated in the range of 23–100 kg CO2e per population equivalent. In the total CF, the direct emissions held the highest share (62–74%) for the plants with energy recovery from biogas. In the plants depending entirely on the power grid, the indirect emissions due to energy consumption dominated the total CF (69–72%)....
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Structural, thermal and energetic characteristics of synthetic active carbons prepared on the basis of ion-exchange resin Amberlite IRC 84
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Biomass-based activated carbons produced by chemical activation with H3PO4 as catalysts for the transformation of α-pinene to high-added chemicals
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INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS
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Application of nonmetallic frustrated cations in the activation of small molecules
PublikacjaThe concept of nonmetallic frustrated cations has been used in small molecule activation. The in situ generated ambiphilic phosphinoborinium cation activated phenyl isocyanate, diisopropylcarbodiimide, and acetonitrile under very mild conditions without any catalyst, yielding single-, double-, or mixed-activation products. Furthermore, the mechanisms of the reactions of the phosphinoborinium cation with small molecules were elucidated...
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A prototype of electrochemical sensor for measurement of carbonyl compounds in air
PublikacjaThe paper presents the results of investigation on a prototype sensor for measurement of benzaldehyde and formaldehyde in air. Sensitivity, limit of quantification and coefficient of selectivity of the sensor have been determined as a function of membrane thickness and electrode type using square wave voltammetry (SWV) technique. The working and counter electrodes were made of platinum and gold. Ionic liquids 1-hexyl, 3-methylimidazolium...
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Electron attachment to representative cations composing ionic liquids
PublikacjaUsing ab initio electronic structure methods with flexible atomic orbital basis sets, we investigated the electronic structure and stability of reduction products of selected representative cations (C+) constituting ionic liquids. We found that an electron attachment to such cations leads to the neutral radicals, whereas a subsequent attachment of another (i.e., excess) electron leads to adiabatically stable anions only in two...
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Assessment of the structural evolution of polyimide-derived carbons obtained by phosphoric acid activation using Fourier transform infrared and Raman spectroscopy
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Salt melt synthesis of curved nitrogen-doped carbon nanostructures: ORR kinetics boost
PublikacjaImplementing metal-free electrocatalysts for the oxygen reduction reaction (ORR) and revealing crucial chemical or topographical parameters driving their activity are vital for the development of power cells. The carbon-based catalysts are very often synthesized through carbonization of biopolymers, in particular, those one containing nitrogen groups such as chitosan. Unfortunately, the resulting carbonaceous materials usually...
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Bis-phosphonated carbon nanotubes: one pot synthesis and their application as efficient adsorbent of mercury
PublikacjaEffective, one-pot method of CNTs phosphonylation is presented. Cheap and readily available reagents are used, so the process can be easily transferred to large-scale production. The product was analyzed using spectroscopic methods (FTIR, UV-vis, XPS). Thermal properties of the bis-phosphonated nanotubes are reported for the first time. Newly obtained material was tested as an adsorbent for mercury removal from water. The sorption...
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Induced-fit binding of laccase to gold and carbon electrodes for the biological fuel cell applications
PublikacjaAnalogues of laccase natural substrates (syringic, veratric, ferulic, vanillic, isovanillic, 3,5-dimethoxybenzoic aldehydes) were employed to bind and orient laccase molecules in a way which facilitates adsorption of the catalyst molecules and their electrical connection with the conductive support. Laccase was bound efficiently to these substrates both on gold and carbon electrodes forming, respectively, 2D and 3D films sensitive...
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Organic carbon fluxes of a glacier surface: a case study of Foxfonna, a small Arctic glacier
PublikacjaArctic glaciers are rapidly responding to global warming by releasing organic carbon (OC) to downstream ecosystems. The glacier surface is arguably the most biologically active and biodiverse glacial habitat and therefore the site of important OC transformation and storage, although rates and magnitudes are poorly constrained. In this paper, we present measurements of OC fluxes associated with atmospheric deposition, ice melt,...
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The influence of the carbon equivalent on the weldability of high-strength low-alloy steel in the water environment
PublikacjaFrom many years, the high strength low alloy steels are often used for offshore constructions. This constructions, due to the environment in which they work, require more frequent repairs than the constructions from the land. For economic reasons, repairs take place in the underwater conditions, however water significantly decreases the weldability of steel. The paper presents the results of the CTS weldability test for S460ML...
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Tailoring Electro/Optical Properties of Transparent Boron-Doped Carbon Nanowalls Grown on Quartz
PublikacjaCarbon nanowalls (CNWs) have attracted much attention for numerous applications in electrical devices because of their peculiar structural characteristics. However, it is possible to set synthesis parameters to vary the electrical and optical properties of such CNWs. In this paper, we demonstrate the direct growth of highly transparent boron-doped nanowalls (B-CNWs) on optical grade fused quartz. The effect of growth temperature...
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Electrochemical synthesis and characterization of nanocomposites based on poly(3,4-ethylenedioxythiophene) and functionalized carbon nanotubes
PublikacjaThis work is focused on new composite materials consisting of poly(3,4-ethylenedioxythiophene) (pEDOT) and functionalized multi-walled carbon nanotubes synthesized electrochemically. Three types of composites were synthesized: the first one containing carbon nanotubes with carboxyl groups (covalent functionalization), the second one containing oxidized carbon nanotubes ox-MWCNTs (with different oxygen-rich polar groups) (covalent...
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Novel Catalysts, Room Temperature, and the Importance of Oxygen for the Synthesis of Single-Walled Carbon Nanotubes
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Formation and electronic properties ofBC3single-wall nanotubes upon boron substitution of carbon nanotubes
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Machinability investigation in electric discharge machining of carbon fiber reinforced composites for aerospace applications
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Photocatalytic Carboxylation of Organic Substrates with Carbon Dioxide at Zinc Sulfide with Deposited Ruthenium Nanoparticles
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Influence of free carbon on the Young's modulus and hardness of polymer‐derived silicon oxycarbide glasses
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Nonequilibrium thermodynamic model of diffusion processes in the steel - carbon thin film tribological system
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The Role of Organic and Inorganic Amendments in Carbon Sequestration and Immobilization of Heavy Metals in Degraded Soils
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Reducing Carbon Footprint of Agriculture—Can Organic Farming Help to Mitigate Climate Change?
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Pd nanoparticles with tunable diameter deposited on carbon nanotubes with enhanced hydrogen storage capacity
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Synergistic effect of activated carbon and Ni2O3 in promoting the thermal stability and flame retardancy of polypropylene
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Nitrogen-doped porous carbon embedded with cobalt nanoparticles for excellent oxygen reduction reaction
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Hierarchical porous carbon sheets derived on a MgO template for high-performance supercapacitor applications
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Synthesis, Growth Mechanism, and Electrochemical Properties of Hollow Mesoporous Carbon Spheres with Controlled Diameter
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Biomass-derived robust three-dimensional porous carbon for high volumetric performance supercapacitors
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Sustainable polylysine conversion to nitrogen‐containing porous carbon flakes: Potential application in supercapacitors
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Novel strategy for preparation of highly porous carbon sheets derived from polystyrene for supercapacitors
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Sustainable recycling of waste polystyrene into hierarchical porous carbon nanosheets with potential applications in supercapacitors
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Ultrathin NiO confined within hollow carbon sphere for efficient electrochemical energy storage
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