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Polyolefins Journal
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Functionalized polyolefins, synthesis application and industrial relevance
PublikacjaPolymers play a key role in our modern life full of technical advances and a continuous request for new materials with tailored properties for a low price. Their excellent mechanical properties, good processability, chemical stability and low price make polyolefins the polymers of choice for most commodity and some more specialized applications. As a result, polyolefins account for over 65% of the total world demand of plastic...
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Controlled grafting of vinylic monomers on polyolefins: a robust mathematical modeling approach
PublikacjaExperimental and mathematical modeling analyses were used for controlling melt free-radical grafting of vinylic monomers on polyolefins and, thereby, reducing the disturbance of undesired cross-linking of polyolefins. Response surface, desirability function, and artificial intelligence methodologies were blended to modeling/optimization of grafting reaction in terms of vinylic monomer content, peroxide initiator concentration,...
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Potential of Functionalized Polyolefins in a Sustainable Polymer Economy: Synthetic Strategies and Applications
PublikacjaPolymers play a crucial role in our modern life as no other material exists that is so versatile, moldable, and lightweight. Consequently, the demand for polymers will continue to grow with the human population, modernization, and technological developments. However, depleted fossil resources, increasing plastic waste production, ocean pollution, and related growing emission of greenhouse gases has led to a change in the way we...
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Structurally well-defined functionalized polyolefins and graft copolymers thereof as bitumen modifiers
PublikacjaHere we demonstrate the application of hydroxyl-functionalized propylene-based copolymers, poly(propylene-co-1-hexene-co-10-undecen-1-ol) (FPP) and poly(styrene-co-maleic anhydride) (SMA) graft copolymers derived thereof, poly(propylene-co-1- hexene-graft-styrene-co-maleic anhydride) (FPP-g-SMA) as bitumen modifiers. The FPP samples were synthesized via solution copolymerization, while FPP-g-SMA products were obtained via transesterification...
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Advancing sustainable hybrid bitumen systems: A compatibilization solution by functionalized polyolefins for enhanced crumb rubber content in bitumen
PublikacjaPolymer waste pollution has a profound effect on the environment and, consequently, on the lifestyle of hu- mankind. The massive production and disposal of cross-linked polymers clearly exemplify the challenges of recycling. Increasing efforts are being undertaken to introduce recycled polymers, especially crumb rubber (CR), into asphalt formulations. Due to the rather poor processability and phase separation associated with CR- modified...
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Characterization of fracture process in polyolefin fibre-reinforced concrete using ultrasonic waves and digital image correlation
PublikacjaThis study explores the monitoring of the fracture process in concrete beams and aims to characterize the evolution of damage in polyolefin fibre-reinforced concrete beams by utilizing the integrated application of two measurement techniques, digital image correlation and ultrasonic testing. The interpretation of registered wave time histories data was provided by the calculation of the magnitude-phase-composite metrics. An efficient...
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Nanosized Carbon Black Combined with Ni2O3 as “Universal” Catalysts for Synergistically Catalyzing Carbonization of Polyolefin Wastes to Synthesize Carbon Nanotubes and Application for Supercapacitors
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Microcrack monitoring and fracture evolution of polyolefin and steel fibre concrete beams using integrated acoustic emission and digital image correlation techniques
PublikacjaThe use of polymer and steel fibres in plain concrete appears to be an excellent solution for limiting crack propagation and improving the post-ductility performance of concrete structures. Based on this premise, this study investigated the fracture evolution of polyolefin fibre-reinforced concrete (PFRC) and steel fibre-reinforced concrete (SFRC) specimens through the integrated application of two diagnostic techniques, acoustic...
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iPP/HDPE blends compatibilized by a polyester: An unconventional concept to valuable products
PublikacjaPolyolefins are the most widely used plastics accounting for a large fraction of the polymer waste stream. Although reusing polyolefins seems to be a logical choice, their recycling level remains disappointingly low. This is mainly due to the lack of large-scale availability of efficient and inexpensive compatibilizers for mixed polyolefin waste, typically consisting of high-density polyethylene (HDPE) and isotactic polypropylene...
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Topological behavior mimicking ethylene–hexene copolymers using branched lactones and macrolactones
PublikacjaPolyolefins are of paramount importance in the world of polymers due to their technological and economic potential.1 However, their nonpolar character significantly restricts the compatibility and adhesion properties, which consequently limits their versatility. Moreover, an intensified demand for materials from renewable resources can also become a problematic venture for the current polyolefin industry.2 Although Braskem and...
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Acoustic emission signals in concrete beams under 3-point bending (polyolefin and steel fibre concrete)
Dane BadawczeThe DataSet contains the results of the mechanical behaviour of concrete beams with dimensions 40 x 40 x 160 cm3 under the 3-point bending. All specimens were manufactured based on the same concrete mixture composed of cement CEM I 42.5R (380 kg/m3), water (165 kg/m3), aggregate 0/2 mm (648 kg/m3), aggregate 2/8 mm (426 kg/m3), aggregate 8/16 mm (754...
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Polyolefins: from cradle to grave.
Kursy OnlineThe course will consist of lectures followed by discussions. Using the obtained knowledge, students will be asked to work out a plan selecting catalysts, production process and recycling process for a specific type of polyolefin for a selected application.
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Ultrasonic wave propagation and digital image correlation measurements of polyolefin fibre-reinforced concrete beams under 3-point bending (beam B-002)
Dane BadawczeThe DataSet contains the results of the mechanical behaviour of a concrete beam under a 3-point bending test. The beams had dimensions 15 x 15 x 70 cm3. The beam B-Con was made of concrete without fibres (as the reference beam), while beams B-002, B-004, and B-006 were manufactured from the concrete mix containing 2 kg/m3, 4 kg/m3 and 6 kg/m3 of fibres,...
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Ultrasonic wave propagation and digital image correlation measurements of polyolefin fibre-reinforced concrete beams under 3-point bending (beam B-Con)
Dane BadawczeThe DataSet contains the results of the mechanical behaviour of a concrete beam under a 3-point bending test. The beams had dimensions 15 x 15 x 70 cm3. The beam B-Con was made of concrete without fibres (as the reference beam), while beams B-002, B-004, and B-006 were manufactured from the concrete mix containing 2 kg/m3, 4 kg/m3 and 6 kg/m3 of fibres,...
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Ultrasonic wave propagation and digital image correlation measurements of polyolefin fibre-reinforced concrete beams under 3-point bending (beam B-004)
Dane BadawczeThe DataSet contains the results of the mechanical behaviour of a concrete beam under a 3-point bending test. The beams had dimensions 15 x 15 x 70 cm3. The beam B-Con was made of concrete without fibres (as the reference beam), while beams B-002, B-004, and B-006 were manufactured from the concrete mix containing 2 kg/m3, 4 kg/m3 and 6 kg/m3 of fibres,...
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Ultrasonic wave propagation and digital image correlation measurements of polyolefin fibre-reinforced concrete beams under 3-point bending (beam B-006)
Dane BadawczeThe DataSet contains the results of the mechanical behaviour of a concrete beam under a 3-point bending test. The beams had dimensions 15 x 15 x 70 cm3. The beam B-Con was made of concrete without fibres (as the reference beam), while beams B-002, B-004, and B-006 were manufactured from the concrete mix containing 2 kg/m3, 4 kg/m3 and 6 kg/m3 of fibres,...
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Polyolefins, commercial and alternative routes toward the world’s most important polymer
Kursy OnlineThe course will consist of lectures followed by discussions. Based on the gained knowledge the Students will be asked to prepare in teams a short essay how to economically produce a selected polyolefin and how to introduce the new product into the market.
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Randomly Functionalized Polyethylenes: In Quest of Avoiding Catalyst Deactivation
PublikacjaWell-defined randomly functionalized polyolefins produced by catalysis form an interesting class of polymers with great potential for various applications. One of the major challenges for the production of these materials forms the incompatibility of the commonly used electrophilic group 4 metal based catalysts and the desired nucleophilic, especially protic functionalities like hydroxyl and carboxylic acid groups. Although pacification...
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Recykling poliuretanów oraz poli(tereftalanu etylenu)
PublikacjaPoliuretany (PUR) oraz poli(tereftalan etylenu) (PET) stanowią zaraz obok poliolefin główne źródło odpadów z tworzyw sztucznych. Poliuretany są produkowane w formie elastomerów, elastycznych i sztywnych pianek oraz klejów i powłok. Szeroki wachlarz zastosowań poliuretanów, wynikający zarówno z ich unikalnych właściwości, jak i z możliwych form użytkowych, skutkuje rosnącym z roku na rok zapotrzebowaniem na te materiały. Poli(tereftalan...
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Self-Organization of Graft Copolymers and Retortable iPP-Based Nanoporous Films Thereof
PublikacjaPolyolefins might become inexpensive alternatives to the existing membranes based on polyethersulfone. Here we disclose the production of retortable, well-defined PP-based nanoporous membranes derived from amphiphilic graft copolymer precursors. The graft copolymers, containing a polypropylene backbone and polyester grafts, were obtained by grafting lactones, specifically δ-valerolactone and ε-caprolactone, from well-defined randomly...
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The Synergistic Microbiological Effects of Industrial Produced Packaging Polyethylene Films Incorporated with Zinc Nanoparticles
PublikacjaZinc compounds in polyolefin films regulate the transmission of UV-VIS radiation, affect mechanical properties and antimicrobial activity. According to hypothesis, the use of zinc- containing masterbatches in polyethylene films (PE) with different chemical nature—hydrophilic zinc oxide (ZO) and hydrophobic zinc stearate (ZS)—can cause a synergistic effect, especially due to their antimicrobial properties. PE films obtained on an...
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Zastosowania chromatografii wykluczania (SEC) w analityce technicznej i preparatyce – część I-sza.
PublikacjaW pracy scharakteryzowano założenia teoretyczne oraz mechanizm rozdzielania w warunkach chromatografii wykluczania (SEC). Przeanalizowano wady i zalety tej techniki rozdzielania. Przedstawiono przegląd zastosowań obejmujący wykorzystanie SEC w analityce technicznej oraz w preparatyce. SEC w warunkach liofilowych znajduje zastosowanie do rozdzielania mieszanin polimerów t.j. polistyren, polibutadien, poliizopren, poli(dimetylosiloksan),...
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Analysis of the Possibility of Using New Types of Protective Coatings and Abrasion-Resistant Linings under the Operating Conditions of the Spiral Classifier at KGHM Polska Miedź S.A. Ore Concentration Plant
PublikacjaA study was carried out to select the appropriate coatings for corrosion protection of the spiral classifier working at KGHM Polska Miedź S.A. Ore Concentration Plant. The abrasion resistance of selected protective coatings and wear-resistant linings was investigated using a DT-523 rotary abrasion tester with Taber CS-10 rubber abrasive discs. The average weight loss of the coatings after a cycle of 2000 revolutions was determined....