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Search results for: RARE-EARTH METAL
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Enhancement of the Magnetoresistance in the Mobility‐Engineered Compensated Metal Pt 5 P 2
PublicationThe magnetoresistance (MR) in nonmagnetic materials continues to be a fertile research area in materials science. The search for giant, positive MR has been limited to a rather small window of materials such as high-mobility semimetals in single-crystalline form. Here, the observation of a very large positive MR in metallic Pt5P2 in polycrystalline form is reported. The observations reveal that improvement of the crystallinity...
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Use of clinoptilolite for the immobilization of heavy metal ions and preparation of autoclaved building composites
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Bottom up approach of metal assisted electrochemical exfoliation of boron towards borophene
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Tuning Carbon Nanotubes Through Poor Metal Addition to Iron Catalysts in CVD
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Hollow carbon sphere/metal oxide nanocomposites anodes for lithium-ion batteries
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Left-handed propagation characteristics of a dielectric and metal-loaded periodic circular waveguide
PublicationIn this paper, a periodic dielectric/metallic rod is located in a circular waveguide to obtain left-handed operation. Two geometries of the dielectric/metallic rod are proposed and examined. The dispersion characteristics of the investigated waveguides are obtained using a surface impedance model. Moreover, equivalent circuit models are proposed allowing for calculation of the dispersion characteristics and scattering parameters...
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Transition-Metal-Promoted Oxidative Cyclization To Give 1,2,4-Trisubstituted Carbazole Scaffolds
PublicationHerein, we describe the synthesis of a 1,2,4-trisubstituted carbazole core from 5-(1H-indol-3-yl)-3-oxopentanoic acid esters or amides. For oxidative cyclization, we tested two different approaches. First, we used manganese triacetate as a conventional moderate oxidizer to ensure the radical course of the reaction. Second, we examined the use of a more complex oxidizing agent I2/Me(OTf)3. In both cases, formation of a fused-ring...
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Dynamic FE simulations of buckling process in thin-walled cylindrical metal silos
PublicationW artykule przedstawiono wyniki dynamicznej analizy wyboczeniowej cienkościennych silosów metalowych o przekroju kołowym. Analizy MES wykonano dla wstępnych imperfekcji geometrycznych o różnym kształcie i amplitudzie. Wyniki analizy dynamicznej porównano z analizami statycznymi.
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Carpathian Journal of Earth and Environmental Sciences
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Journal of Advances in Modeling Earth Systems
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Journal of the Korean Earth Science Society
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JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH
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JOURNAL OF GEOPHYSICAL RESEARCH-EARTH SURFACE
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Journal of Earth Science & Climatic Change
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Journal of Astronomy and Earth Sciences Education
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JOURNAL OF SOUTH AMERICAN EARTH SCIENCES
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Jordan Journal of Earth and Environmental Sciences
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Journal of Asian Earth Sciences: X
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Annual Review of Earth and Planetary Sciences
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NATURAL HAZARDS AND EARTH SYSTEM SCIENCES
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Defected Ag/Cu-MOF as a modifier of polyethersulfone membranes for enhancing permeability, antifouling properties and heavy metal and dye pollutant removal
PublicationIn this study, a novel bimetallic metal-organic framework (MOF) i.e. Ag/Cu-MOF was synthesized using a solvothermal method and later incorporated at different concentrations (0.1–2 wt%) using a phase inversion method for modification and antifouling property improvement of polyethersulfone (PES) membranes. The resulting Ag/Cu-MOF characteristics were investigated using different techniques, such as FTIR, XRD, FE-SEM and EDX. The...
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Reactions of lithiated diphosphanes R2P-P(SiMe3)LiTHF (R = tBu, iPr) with [(PNP)TiCl2]. Two different coordination types of phosphanylphosphido ligand to the metal center.
Publication[(PNP)TiCl2] (PNP = N[2-PiPr2-4-methylphenyl]2) reacts with one equivalent of lithium derivative of diphosphane R2P-P(SiMe3)LinTHF (R = tBu, iPr) in toluene and forms the first complex with g1-coordination [(PNP)Ti(Cl){g1-P(SiMe3)-PtBu2}] (1) and complex with g2-coordination [(PNP)Ti(Cl){g2-P(SiMe3)-PiPr2}] (2) of phosphanylphosphido ligands to the titanium center. The similar reaction with two equivalents of tBu2P-P(SiMe3)LinTHF...
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Damian Rosiak dr inż.
PeopleEducation 2010–2014: Gdansk University of Technology, Chemical Faculty (Eng.) field of study: biotechnology specialty: drug biotechnology 2014–2015: Gdansk University of Technology, Chemical Faculty (M.Sc.) field of study: biotechnology specialty: drug biotechnology 2015–2020: Gdansk University of Technology, Department of Inorganic Chemistry (Ph.D.) discipline: chemical sciences specialty: inorganic chemistry Scientific...
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Evaluation of a novel method based on amplification of DNA fragments surrounding rare restriction sites (ADSRRS-figerprinting) for typing strains of vancomycin resistant Enterococcus faecium.
PublicationBadania objęły wankomycyno oporne szczepy Enterococcus faecium izolowane od pacjentów oddziału Hematologii Szpitala Klinicznego w Gdańsku. Wykazano, że ADSRRS-fingerprinting jest metodą szybką o dużym potencjale różnicującym i dużej powtarzalności w badaniach epidemiologicznych.
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Lower Rim Substituted p-tert-Butyl-Calix[4]arene. Part 16. Synthesis of 25, 26, 27, 28-tetrakis(piperidinethiocarbonylmethylene)-p-tert-butylcalix[4]arene and its interaction with metal ions
PublicationThe synthesis, characterisation and X-ray crystal structures of p-tert-butyl-calix[4]arenethioamide L and its complex with lead L-Pb2+ is reported. The cation-binding properties in solution have been assessed by liquid-liquid extraction of the metal picrates from water into dichloromethane and by stability constants determination in acetonitrile using UV-absorption spectrophotometry or potentiometry. The compound was used as active...
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Earth and Space Science
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Titania nanotubes modified by a pyrolyzed metal-organic framework with zero valent iron centers as a photoanode with enhanced photoelectrochemical, photocatalytical activity and high capacitance
PublicationThe paper discusses the synthesis, photoelectrochemical and electrochemical behaviour of titania nanotube arrays modified by a pyrolyzed metal-organic framework (MOF). A poly(3,4–ethylenedioxyphene) (PEDOT) matrix with an embedded inorganic network of iron hexacyanoferrate (BP) covering TiO2 nanotubes (TNT) is used as a MOF for the further sintering procedure, resulting in a novel, thin film of carbonaceous wrap supported Fe catalytic...
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Modifications of the heat source model in numerical analyses of the metal-cored arc welding process
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Synthesis and characterization of metal polycarboxylates constructed from lanthanides(iii) and 1,2,4,5-benzenetetracarboxylic acid
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Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad
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Porphyrazines Peripherally Functionalized with Hybrid Ligands as Molecular Scaffolds for Bimetallic Metal-Ion Coordination
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Application of electrochemical impedance spectroscopy to monitoring discharging process of nickel/metal hydride battery.
PublicationThis paper presents the possibility of applying impedance analysis to cell diagnostics. In order to obtain characteristic curves of both electrodes of a NiMH battery simultaneously, a reference electrode was added into the circuit. The authors analysed the cell under three cases, i.e. when its properties are determined only by the state of the positive electrode, only by the state of the negative electrode, or when both electrodes...
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Application of electrochemical impedance spectroscopy to monitoring discharging process of nickel/metal hydride battery
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Adiabatic Compressibilities of Divalent Transition-Metal Perchlorates and Chlorides in N,N-Dimethylacetamide and Dimethylsulfoxide
PublicationZmierzono prędkości rozchodzenia się dźwięku roztworów nadchloranów i chlorków manganu(II), kobaltu(II), niklu(II), miedzi(II) i cynku(II) w N,N-dimetyloacetamidzie i dimetylosulfotlenku w temperaturze 298.15 K. Obliczono ściśliwości adiabatyczne i pozorne ściśliwości adiabatyczne badanych roztworów. Przedyskutowano wpływ anionu i rodzaju rozpuszczalnika na uzyskane graniczne wartości pozornych ściśliwości adiabatycznych soli.
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High-Entropy Perovskites as Multifunctional Metal Oxide Semiconductors: Synthesis and Characterization of (Gd0.2Nd0.2La0.2Sm0.2Y0.2)CoO3
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Influence of H2S on degradation of 9Cr-1Mo steel in advanced stage of metal dusting process
PublicationPrzedstawiono wyniki badań stali 9Cr-1Mo w zaawansowanym stadium procesu pylenia metalu po 10 latach eksploatacji w piecu rafineryjnej instalacji platformingu CCR, przeprowadzonych w celu podjęcia decyzji o dozowaniu związków siarki do wsadu instalacji. Na podstawie długotrwałej ekspozycji próbek stali w 600C w mieszaninie wodoru i siarkowodoru wykazano, że siarka może być powodem procesów wpływających niekorzystnie na stan materiału...
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Three dimensional graphene/carbonized metal-organic frameworks based high-performance supercapacitor
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Metal tolerance and Cd phytoremoval ability in Pisum sativum grown in spiked nutrient solution
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Complexation studies of 3-substituted β-diketones with selected d- and f-metal ions
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Influence of Filler Metal on Electrochemical Characteristics of a Laser-Welded CoCrMoW Alloy Used in Prosthodontics
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Bactericidal Properties of Plasmonic Photocatalysts Composed of Noble Metal Nanoparticles on Faceted Anatase Titania
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Apparent molar volumes of divalent transition metal chlorides and perchlorates in dimethyl sulfoxide solutions.
PublicationZmierzono gęstości roztworów nadchloranów i chlorków dwuwartościowych metali szeregu Mn(II)-Zn(II) w dimetylosulfotenku. Wyznaczone na drodze ekstrapolacji cząstkowe objętości molowe nadchloranów rozdzielono na udziały jonowe. Przeanalizowano wpływ pola ligandów na cząstkowe objętości molowe kationów. Przedstawiono związek między wartościami pozornych objętości molowych a stanami koordynacyjnymi soli w DMSO.
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Fatigue ''safe-life'' criterion for metal elements under multiaxial constant and periodic loads.
PublicationRozpatrywane jest okresowe naprężenie którego kartezjańskie składowe są zadane w postaci szeregów Fouriera. Dla uwzględnienia naprężenia średniego wykorzystano uogólnioną formułę Soderberga dla materiałów ciągliwych. Zdefiniowano naprężenie równoważne o synchronicznych składowych i sformułowano kryterium zmęczenia, które obejmuje warunki zarówno wytrzymałości statycznej jak i bezpieczeństwa zmęczeniowego. Kryterium to zawiera stałe...
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Apparent molar volumes of divalent transition metal perchlorates and chlorides in N,N-dimethylacetamide.
PublicationZmierzono gęstości roztworów nadchloranów i chlorków manganu(II), kobaltu(II), niklu(II), miedzi(II) i cynku(II) w temperaturach 10, 20,25, 30, 40, 50 i 60(o)C. Obliczono pozorne objętości molowe. Wyznaczono graniczne wartości cząstkowych molowych objętości tych soli oraz odpowiednie rozszerzalności. Przeanalizowano i wyjaśniono różnice we właściwościach wolumetrycznych roztworów nadchloranów i chlorków.
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Using impedance spectroscopy to characterize and monitor protection aspects of organic coating systems on metal
PublicationOrganiczne powłoki ochronne stosowane są powszechnie do ochrony konstrukcji metalowych przed korozją i zużyciem mechanicznym. W pracy zaproponowano nowy typ sensora impedancyjnego, który może być zastosowany do ciągłej oceny właściwości barierowych i adhezyjnych systemów powłokowych w warunkach terenowych w sposób nieniszczący, bez konieczności stosowania naczyń z elektrolitem. Przedstawiono koncepcję czujnika oraz przykładowe...
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Simulation of buckling process of cylindrical metal silos with flat sheets containing bulk solids.
PublicationW artykule symulowano proces wyboczenia w cylindrycznych metalowych silosach z płaskich blach wypełnionych materiałem sypkim. Wykonano analizy nieliniowe stosując MES dla silosów pustych i napełnionych. Zbadano wpływ wstępnych imperfekcji geometrycznych na nośność wyboczeniowo. Wyniki porównano z wynikami doświadczalnymi w Uniwersytecie Karlsruhe.
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A magnetic stir bar sorbent of metal organic frameworks, carbon foam decorated zinc oxide and cryogel to enrich and extract parabens and bisphenols from food samples
PublicationA porous composite magnetic stir bar adsorbent was fabricated for the extraction and enrichment of parabens and bisphenols from selected beverage samples. The adsorbent comprised a metal organic framework, carbon foam decorated zinc oxide and magnetic nanoparticles embedded in polyvinyl alcohol cryogel. The porous composite stir bar adsorbent could adsorb parabens and bisphenols via hydrogen bonding, π-π and hydrophobic interactions....
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Chromium‑based metal organic framework for pipette tip micro‑solid phase extraction: an effective approach for determination of methyl and propyl parabens in wastewater and shampoo samples
PublicationAbstract Background A chromium-based metal organic framework was synthesized and employed as an efficient sorbent for pipette tip micro-solid phase extraction and preconcentration of parabens from wastewater and shampoo samples up to sub-ppb level before their spectrophotometric analysis. Results Factors affecting preconcentration including volume and type of solvent, amount of sorbent, number of extraction, and volume and pH of...
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AlP compound and P-doping for promotion of electrocatalytic activity of N-doped carbon derived from metal-organic framework
PublicationWater splitting plays a key role in future fuels, where two processes occur - the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). Nitrogen-doped carbon derived from...
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Group-9 Transition-Metal Suboxides Adopting the Filled-Ti2Ni Structure: A Class of Superconductors Exhibiting Exceptionally High Upper Critical Fields
PublicationTi2Ni and the related η-carbide structure are known to exhibit various intriguing physical properties. The Ti2Ni structure with the cubic space group Fd3̅m is surprisingly complex, consisting of a unit cell with 96 metal atoms. The related η-carbide compounds correspond to a filled version of the Ti2Ni structure. Here, we report on the structure and superconductivity in the η-carbide-type suboxides Ti4M2O with M = Co, Rh, and Ir....