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Search results for: THERMODYNAMIC%20STATE
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Duhem and Natanson: Two Mathematical Approaches to Thermodynamics
PublicationIn this article, the previously unrecognized contributions of Pierre Duhem and Ladislavus Natanson in thermodynamics are shown. The mathematical remodelling of a few of their principal ideas is taken into consideration, despite being neglected in the literature. To emphasize these ideas in an appropriate epistemological order, it would be crucial to first revalue and reconstruct some underrepresented parts of the proceedings process...
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1.21 Computation of Structure, Dynamics, and Thermodynamics of Proteins
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Singular Surface Curves in the Resultant Thermodynamics of Shells
PublicationWithin six-parameter shells theory we discuss the governing equations of shells with material or non-material singular curves. By singular curve we mean a surface curve where are discontinuities in some surface fields. As an example we consider shells with junctions and shells undergoing stress-induced phase transitions.
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Chapter 7: Engineering Thermodynamics and the Carnot Cycle
PublicationThe chapter presents information about thermodynamics and thermodynamic cycles, especially the history and meaning of Carnot Cycle as well as P-v and T-s Diagrams
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Thermodynamic and electromagnetic properties of hard-core charged bosons on a lattice
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Thermodynamic modeling of combustion process of the internal combustion engines – an overview
PublicationThe mathematical description of combustion process in the internal combustion engines is a very difficult task, due to the variety of phenomena that occurring in the engine from the moment when the fuel-air mixture ignites up to the moment when intake and exhaust valves beginning open. Modeling of the combustion process plays an important role in the engine simulation, which allows to predict incylinder pressure during the combustion,...
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Heat capacities and thermodynamic properties of antimony substituted lanthanum orthoniobates
PublicationThe results of heat capacity measurements for the lanthanum orthoniobate substituted with 10, 20 and 30 mol% of antimony (LaNb0.9Sb0.1O4, LaNb0.8Sb0.2O4 and LaNb0.7Sb0.3O4) are presented and discussed. Temperature dependence of low temperature heat capacity was analyzed within the Debye and Einstein models. The Debye temperature decreased, whereas the Einstein temperature increased with antimony content. The decrease of the Debye...
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The laws of termodynamics and Homo sapiens the engineer
PublicationRozdział przedstawia główne zasady termodynamiki i ich wykorzystanie przez człowieka. Zasady termodynamiki odniesiono do biologii oraz organizmów żywych.
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Thermodynamical approach to quantifying quantum correlations
PublicationWe consider the amount of work which can be extracted from a heat bath using a bipartite state ρ shared by two parties. In general it is less then the amount of work extractable when one party is in possession of the entire state. We derive bounds for this “work deficit” and calculate it explicitly for a number of different cases. In particuar, for pure states the work deficit is exactly equal to the distillable entanglement of...
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On coertia and inertia in aspects of Natanson’s nonlinear extended thermodynamics
PublicationIn this article, the previously underrepresented contributions of Natanson to the field of thermodynamics have been presented. In order to identify a source of irreversibility at Nature, Natanson introduced the concept of Coertia, which is similar to inertia. Natanson’s Coertia is a fundamental property of space that is responsible for every irreversible phenomena in matter, as well as in the electromagnetic and gravitational fields....
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Conductivity, structure, and thermodynamics of Y2Ti2O7–Y3NbO7 solid solutions
PublicationThe defect fluorite yttrium niobate Y3NbO7 and pyrochlore yttrium titanate Y2Ti2O7 solid solutions have been synthesized via a solid state synthesis route. The resulting stoichiometry of the oxides is Y2+xTi2−2xNbxO7, where x = 0 to x = 1. All of the samples were single-phase; however, for those with a predominant fluorite phase, a small amount of additional pyrochlore phase was detected. The volume of the solid solution unit cells...
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New Insights into Thermodynamics of Solutes in Neat and Complex Solvents
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The laws of thermodynamics: entropy, free energy, information and complexity
PublicationW rozdziale przedstawiono podstawowe Zasady Termodynamiki. Omówiono zagadnienia związane z pojęciem entropii, energii Gibbsa, egzergii oraz systemami złożonymi.
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Thermodynamics of micellization of imidazolium ionic liquids in aqueous solutions
PublicationPodobieństwo pomiędzy strukturami niektórych cieczy jonowych, a surfaktamtami jonowymi wskazuje na możliwość wykazywania, przez te związki, tendencji do agregacji i adsorpcji na powierzchniach międzyfazowych. Mierząc w różnych temperaturach przewodnictwo elektryczne w funkcji stężenia oznaczono temperaturę Kraffta i zależność temperaturową krytycznego stężenia micelizacji (CMC) dla czterech, różniących się długościami łańcucha,...
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Thermodynamics aspects of interactions between acridine derivatives and DNA
PublicationDNA is a molecular target for many anticancer and antiviral drugs. Therefore, a clear understanding of the interaction of small molecules with DNA is important in the rational design of ligands that can bind to DNA with high affinity and selectivity. There are several methods to investigate interactions between drug and DNA. Some of them measure changing into DNA structures, such as lengthening and untwisting of helix of DNA. Other...
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Thermodynamics of solid phases containing rare earth oxides
PublicationRare earth elements (RE) are incorporated into a large variety of complex oxide phases to provide tailored mechanical, electrical, optical, and magnetic properties. Thermodynamics control phase stability, materials compatibility in use, corrosion, and transformation. This review presents, in one compilation, the thermodynamic properties of a large number of such materials and discusses systematic trends in energetics and the factors...
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Thermodynamic and electrostatic properties of ternary Oxytricha nova TEBP-DNA complex
PublicationZa pomocą metod chemi obliczeniowej badano właściwości molekularne kompleksu telomerowego białka TEBP z Oxytricha nova w kompleksie trójskkładnikowym z DNA o sekwencji telomerowej. Wyliczone wartości energii kompleksowania wskazują specyficznie na jedną z dróg tworzenia kompleksu, gdzie wpierw podjednostka alfa łaczy się z DNA a następnie podjednostka beta dołącza się do takiego dwuskładnikowego kompleksu. Policzone rozkłady molekularnego...
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Influence of Antimony Substitution on Spontaneous Strain and Thermodynamic Stability of Lanthanum Orthoniobate
PublicationThe analysis of the antimony substitution influence on temperature dependence of unit cell distortion has been done. The values of spontaneous strain and Landau order parameter for three different antimony contents varied had been calculated. The phase transition occurring for antimony substituted lanthanum orthoniobate was found to be second order. The high temperature solution calorimetry method has been used to investigate...
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THERMODYNAMIC ANALYSIS OF A GENERATION IV SCWR NUCLEAR POWER PLANT CYCLE
PublicationThis article presents a flow and thermodynamic analysis of a Generation IV nuclear cycle. An SCWR (Supercritical water reactor) is a high temperature and high pressure reactor that uses water at a temperature above its thermodynamic critical point as the working fluid. The cycle used for the calculations consists of one interstage superheater and 7 regenerative heat exchangers. Division pressure was optimized in view of the cycle efficiency,...
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Thermodynamic Cycles of Air Microturbine Power Plants Working on Biomass Fuels
PublicationThe gas turbine engine is modified to work as an air turbine set which consists, in the simplest arrangement, of a compressor, a heat exchanger and a turbine. Air is a working medium for both: the compressor and the turbine. This kind of air turbine set can be applied in power plants working on biomass fuels. In this solution we can burn fuels of varying parameters in the external combustion chamber without any harmful effects...