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Search results for: metal carbide
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Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review
PublicationDry reforming of hydrocarbons (DRH) is a pro-environmental method for syngas production. It owes its pro-environmental character to the use of carbon dioxide, which is one of the main greenhouse gases. Currently used nickel catalysts on oxide supports suffer from rapid deactivation due to sintering of active metal particles or the deposition of carbon deposits blocking the flow of gases through the reaction tube. In this view,...
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Studies of the mechanism of metal metal dusting of 10CrMo9-10 steel after 10 years of operation in trhe semi-regenerative catalytic reformer
PublicationThe study showed that metal dusting mechanism of 10CrMo9-10 steel operated in industrial environment differs from models developed in laboratories. Significant differences lie in the fact that the models developed in laboratories only assume the formation of metastable carbide M3C, while studies have shown that the formation of M3C carbides is associated with the transformation of primary carbides and in the next stage is preceded...
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Group-9 Transition-Metal Suboxides Adopting the Filled-Ti2Ni Structure: A Class of Superconductors Exhibiting Exceptionally High Upper Critical Fields
PublicationTi2Ni and the related η-carbide structure are known to exhibit various intriguing physical properties. The Ti2Ni structure with the cubic space group Fd3̅m is surprisingly complex, consisting of a unit cell with 96 metal atoms. The related η-carbide compounds correspond to a filled version of the Ti2Ni structure. Here, we report on the structure and superconductivity in the η-carbide-type suboxides Ti4M2O with M = Co, Rh, and Ir....
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Wear Resistance Enhancement of Al6061 Alloy Surface Layer by Laser Dispersed Carbide Powders
PublicationIn this paper, results of the experimental study on improving wear resistance in sliding friction of Al-based alloy are presented. The technique used involves the formation of a metal matrix composite (MMC) in the alloy surface layer by laser dispersion of carbide powders such as WC, TiC and SiC. For WC and TiC MMC surface coatings fabricated under conditions typical for most of the technologically relevant solid-state lasers (wavelength...
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The Effect of Cryogenic Treatment on Microstructure and Mechanical Response of AISI D3 Tool Steel Punches
PublicationRecently, deep cryogenic treatment is performed to improve the mechanical responses (wear, hardness, fatigue, and thermal conductivity) of various steel components. Researchers have tried to evaluate the eco-friendly and nontoxic process to optimize the parameters. Cold-shearing punches used to manufacture various holes that undergo severe impact loading and wear in the metal forming process. This study concerns the effect of soaking...
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Microstructure and Mechanical Properties of Combined GTAW and SMAW Dissimilar Welded Joints between Inconel 718 and 304L Austenitic Stainless Steel
PublicationA dissimilar welded joint of Inconel 718 and 304L austenitic stainless steel was prepared using a combined procedure with the gas tungsten arc welding and shielded metal arc welding processes by employing the Ni-based fillers: ERNiCr-3 and ENiCrFe-3. The welded joints were investigated for metallographic testing and mechanical properties, and a relationship was established between the microstructure and the resultant mechanical...
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Catalytic activity of Ni-MgAl2O4 modified with transition metal (Ti, Mo, W) carbides as potential catalysts for resource recovery via dry reforming of waste plastics
PublicationThe growing amounts of plastic waste and CO2 emissions are two environmental threats that require urgent attention. Pyrolysis combined with dry reforming (PCDR) is a technology that allows both CO2 utilization and resource recovery from waste plastic. New catalysts for PCDR are crucial for developing efficient and stable processes that can be widely implemented in the industry. In this study, Ni/MgAl2O4 catalysts modified using different...
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Analytical Estimation of Power Losses in a Dual Active Bridge Converter Controlled with a Single-Phase Shift Switching Scheme
PublicationMicro-grid solutions around the world rely on the operation of DC/DC power conver- sion systems. The most commonly used solution for these topologies is the use of a dual active bridge (DAB) converter. Increasing the efficiency and reliability of this system contributes to the improvement in the stability of the entire microgrid. This paper discussed an analytical method of energy efficiency and power loss estimation in a single...
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Impact of laser beam welding on mechanical behaviour of 2.25Cr–1Mo (P22) steel
PublicationThe use of welding processes in the manufacturing and repair of structures intended for the energy industry plays a key role in the guarantee of a continuous supply of fossil fuels, which is the basic condition for ensuring energy security. A square butt joint of 10 mm thick plate of 2.25Cr–1Mo (P22) steel was fabricated by autogenous laser beam welding process and then post-weld heat treatment (PWHT) for two sets of process parameters...
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MXenes Antibacterial Properties and Applications: A Review and Perspective
PublicationThe mutations of bacteria due to the excessive use of antibiotics, and generation of antibiotic-resistant bacteria have made the development of new antibacterial compounds a necessity. MXenes have emerged as biocompatible transition metal carbide structures with extensive biomedical applications. This is related to the MXenes’ unique combination of properties, including multifarious elemental compositions, 2D-layered structure,...
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Projektowanie, synteza i charakterystyka fotokatalizatorów nowej generacji na bazie związku Ti3C2Tx do usuwania aktywnych substancji farmaceutycznych
PublicationCelem niniejszej pracy było zastosowanie materiałów nowej generacji na bazie związku Ti3C2Tx w procesach fotokatalitycznej degradacji aktywnych substancji farmaceutycznych: karbamazepiny, acetaminofenu i ibuprofenu. Zakres prac badawczych obejmował syntezę fotokatalizatorów, charakterystykę ich właściwości fizykochemicznych, oraz ocenę aktywności fotokatalitycznej. Przedstawiono możliwość zastosowania węglika tytanu jako kokatalizatora...
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Ni-WC/Al2O3 and Ni-WC/MgWO4/MgAl2O4 catalysts for resource recovery via pyrolysis combined with the dry reforming of plastics (PCDR)
PublicationPlastic waste (PW) is currently one of an environmental threat. Despite the increasing share of recycled plastics, their disposal remains high. Therefore, there is a high demand for new PW management systems. Among them, pyrolysis combined with dry reforming (PCDR) is an advantageous solution because it allows for resource recovery in the form of gas and liquid fuels, with simultaneous utilization of CO2. To date, catalysts based...
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Experimental analysis of wear resistance of compacts of fine-dispersed iron powder and tungsten monocarbide nanopowder produced by impulse pressing
PublicationThe paper presents the results of studying the structure and wear resistance of compacts produced from fine dispersed reduced iron powder (average particle size 3–mu m) with the addition of tungsten carbide (WC) nanopowder with the average particle size of 25–30 nm. The mass fraction of tungsten carbide (wolfram carbide) in the powder composition was 5% and 10% of the total mass. Impulse pressing was conducted using the modified...
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High-density polyethylene/EPDM rubber blend composites of boron compounds for neutron shielding application
PublicationNovel materials with neutron shielding property were fabricated by incorporating boron compounds into highdensity polyethylene (HDPE)/Ethylene propylene diene monomer rubber (EPDM) blends. A detailed investigation on the morphological, thermal, mechanical, and neutron attenuation properties of suitable proportion of HDPE/EPDM blend with boric acid (BA), boron carbide (BC), and nano boron carbide (NBC) were performed. Morphology...
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Silicon carbide application issues
PublicationThe main goals of Task 3 and Task 4 of the ordered project ''New technologies based on silicon carbide and their application in HF, high power and high temperature electronics'' are presented
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Nickel phase deposition on V2CTx/V2AlC as catalyst precursors for a dry methane reforming: The effect of the deposition method on the morphology and catalytic activity
PublicationDry reforming of methane (DRM) is a promising alternative technology for the production of syngas with simultaneous utilization of two main greenhouse gases (CH4, CO2). However, DRM technology is still an industrially immature process due to the lack of stable and active catalyst. Therefore, the search for new catalytic materials is of great research interest. Recently, MAX and MXenes materials are increasingly being tested as...
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Improvement of microstructure and mechanical properties of high dense sic ceramics manufactured by high-speed hot pressing
PublicationNon-oxide ceramics possess high physical-mechanical properties, corrosion and radiation resistance, which can be used as a protective materials for radioactive wastes disposal. The aim of the present study was the manufacturing of high density SiC ceramics with advanced physical and mechanical parameters. The high performance on the properties of produced ceramics was determined by the dense and monolithic structure. The densified...
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Application of multisine nanoscale impedance microscopy to heterogeneous alloy surface investigations
PublicationIn the recent years atomic force microscopy is recognized as valuable tool for investigation of surficial features of construction materials. It concerns, among other things, studies of changes caused by such phenomena as galvanic corrosion, passivation associated with the growth of oxide layers, or sensitization of austenitic steels with the formation of carbide phases. In addition, atomic forcemicroscopy allows easy coupling...
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Investigation of RTS Noise in Reverse Polarized Silicon Carbide Schottky Diodes
PublicationOne of the method of electronic device quality and reliability evaluation is observation of its inherent noise. The RTS phenomena usually indicates the presence of large defects in the structure of the material of the device, therefore it can be treated as an indicator of technology quality. In the paper authors present results of RTS investigations in reverse polarized Silicon Carbide Schottky diodes. Devices being studied are...
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Time-frequency analysis of acoustic signals using concentrated spectrogram
PublicationThe paper presents improved method of time-frequency (TF) analysis of discrete-time signals. The method involves signal's local group delay (LGD) and channelized instantaneous frequency (CIF) to purposely redistribute all Short-time Fourier transform (STFT) lines. Additionally, the energy concentration index (ECI) and some histogram-like statistics are used to evaluate readability of estimated TF distributions of the energy. Recorded...
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A Multi Rig Screening Test for Thin Ceramic Coatings in Bio - Tribological Applications
PublicationA method is presented for the comparative testing of wear resistance of ceramic coatings made from materials potentially feasible in tribo - medical applications, mainly orthopaedic implants made from ceramics coated metals for low cost, long life and low wear particle emission into the body. The method was devised as the main tool for use in research and is comprised of flat on flat and ball on flat surface (sliding) tests. Seven...
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Advances in CSI-fed induction motor drives
PublicationThe application of current source inverters (CSI)in induction motor (IM) drives offers a number of advantages,including: voltage boosting capability, natural shoot-throughshort-circuit protection and generation of sinusoidal voltages.The exact generation of sinusoidal voltages is possible thanks tothanks to the effect of the output ac filter capacitors and mayimprove the accuracy of sensorless IM control. The eliminationof high...
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Carburization Behavior of High-Grade Pellets After Direct Reduction in Pure Hydrogen
PublicationCarburization is a critical aspect in the iron and steel industry as it significantly affects the mechanical and chemical properties of the final product. This study provides a comprehensive analysis of the carburization potential of high-grade quality iron ore pellets after direct reduction in pure hydrogen. The results show that the porosity of the pellets has a significant impact on the efficiency and success of the direct reduction...
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Crack propoagation in MgO-PSZ ceramic materials
PublicationThe properties of ceramic materials such as elevated hardness, high temperature capability, low coefficient of thermal expansion are of interest for rolling element materials. Widely used ceramic materials in engineering applications are silicon nitride, zirconia and alumina. The paper presents an experimental study of the fatigue life of MgO-PSZ ceramic material in lubricated contact with defined types of cracks. A ceramic angular...
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Failure analysis of a high-speed induction machine driven by a SiC-inverter and operating on a common shaft with a high-speed generator
PublicationDue to ongoing research work, a prototype test rig for testing high-speed motors/generators has been developed. Its design is quite unique as the two high- speed machines share a single shaft with no support bearings between them. A very high maximum operating speed, up to 80,000 rpm, was required. Because of the need to minimise vibration during operation at very high rotational speeds, rolling bearings were used. To eliminate...
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Regeneration of marine engine valves using laser surfacing
PublicationThis article presents an analysis of the applicability of laser surfacing of the exhaust valve face of a marine diesel engine using cobalt-based powder. After preparation by machining, the selected valves were subjected to laser surfacing using a high-power ROFIN DL020 laser. The EuTroLoy 16012 powder was used in the surfacing process. One of the valves was cut and subjected to metallographic examination and hardness measurements,...
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Comparison of Surface Quality and Tool-Life of Glulam Window Elements after Planing
PublicationThe quality of the surface of wooden elements, that have been planed, has a crucial importance in the whole production process, since the obtained effects affect the quality of wooden surface after fi nishing (painting). The occurrence of defects is usually the reason for qualifying a workpiece as scrap or for requiring additional work. This paper presents the selected results of research of the effect of the cutting tool wear...
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The influence oil additives on spread cracks in silicon nitride
PublicationThe paper presents an experimental study of the influence of oil additives (Cl, S, P, cerium dioxide (CeO2)) on spread cracks in silicon nitride. The additives Cl, S, P are bound in molecules in liquid form soluble in the base oil. The CeO2 is purely in powder form in suspension. The use of CeO2 powder was made based on the good results of polishing of silicon nitride. A ceramic angular contact ball bearing was modelled using a...
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Novel sugar-based nickel-tungsten carbide catalysts for dry reforming of hydrocarbons
PublicationThe search for new materials for dry reforming of hydrocarbons with high activity, stability, and ease of synthesis is still one of the main directions of research in the field of heterogeneous catalysis. Traditional methods of carbide synthesis require the use of combustible gases of petrochemical origin. The search for new catalysts based on renewable and safe carbon sources is highly demanded. Therefore, we report WC and Ni-WC...
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SiC-Based Power Electronic Traction Transformer (PETT) for 3 kV DC Rail Traction
PublicationThe design of rolling stock plays a key role in the attractiveness of the rail transport. Train design must strictly meet the requirements of rail operators to ensure high quality and cost-eective services. Semiconductor power devices made from silicon carbide (SiC) have reached a level of technology enabling their widespread use in traction power converters. SiC transistors oering energy savings, quieter operation, improved reliability...
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Fabrication and characterization of composite TiO2 nanotubes/ boron-doped diamond electrodes towards enhanced supercapacitors
PublicationThe composite TiO2 nanotubes / boron-doped diamond electrodes were deposited using Microwave Plasma Enhanced Chemical Vapor Deposition resulting in the improved electrochemical performance. This composite electrode can deliver high specific capacitance of 7.46 mF cm‐− 2 comparing to boron-doped diamond (BDD) deposited onto flat Ti plate (0.11 mF cm‐− 2).The morphology and composition of composite electrode were characterized...
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Dual Active Bridge (DAB) DC-DC converter for multilevel propulsion converters for electrical multiple units (EMU)
PublicationSemiconductor power devices made from silicon carbide (SiC) reached a level of technology enabling their widespread use in power converters. Two different approaches to implementation of modern traction converters in electric multiple units (EMU) have been presented in recent years: (i) 3.3-kV SiC MOSFET-based three-level PWM inverter with regenerative braking and (ii) 6.5-kV IGBT-based four-quadrant power electronic traction transformer...
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Silicon Oxycarbide (SiOC) Ceramic Materials as Anodes for Lithium Ion Batteries
PublicationPolymer derived ceramics (PDCs) have attracted attention as alternative anode material for Li-ion batteries. It has been found that ternary SiOC and SiCN ceramics obtained through pyrolysis of various preceramic polymers display high reversible capacities of 500 – 650 mAh/g. In this work we try to correlate the electrochemical performance of polymer derived silicon oxycarbide with its chemical composition and microstructural features....
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Aspects of intergranular corrosion of AISI 321 stainless steel in high-carbon-containing environments
PublicationPurpose – The purpose of this paper is to present a case study of unexpected sensitization to intergranular corrosion of highly resistant AISI 321 steel in petrochemical conditions, where it was subjected to the simultaneous influence of elevated temperature of 250°C and vapors from the asphalt production process. Design/methodology/approach – Corrosion coupons were exposed in an installation carrying asphalt vapors. To identify...
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Research on Tool Temperature Dependence on Lapping Grains Size
PublicationCommonly used as a finishing operation, lapping has been used for achieving ultra-high finishes and close tolerances between mating pieces. Its carried out by applying loose abrasive grains between work and lap surfaces, and causing a relative motion between them resulting in a finish of multi-directional lay. The grains activity (sliding and rolling) in the working gap causes not only the material removal but also the temperature...
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Modelling and analysis of medium frequency transformers for power converters
PublicationThe evolutions in power systems and electric vehicles, related to the economic opportunities and the environmental issues, bring the need of high power galvanically isolated DC-DC converter. The medium frequency transformer (MFT) is one of its key components, enabled by the increasing switching frequency of modern power semiconductors like silicon carbide transistors or diodes. The increased operating frequency offers small...