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Search results for: atmospheric refractions
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New type of repeated Si–C-podand catalysts for solid–liquid phase transfer reactions
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Proton transfer reactions from some diarylcyanomethanes to cis 1,2-bis(diethylaminomethyl)cyclohexane in acetonitrile
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Redox reactions of the FAD-containing apoptosis-inducing factor (AIF) with quinoidal xenobiotics: A mechanistic study
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Modelling of First- and Second-order Chemical Reactions on ARUZ – Massively-parallel FPGA-based Machine
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Influence of chloroform on crystalline products yielded in reactions of 5,10,15,20-tetraphenylporphyrin with HCl and copper(II) salts
PublicationStwierdzono, że chloroform wbudowuje się do sieci krystalicznej dichlorowodorku 5,10,15,20-tetrafenyloporfiryny, oraz że powoduje krystalizację nowej, jednoskośnej odmiany polimorficznej porfirynianu miedzi(II), CuTPP. W pracy opisano strukturę krystaliczną solwatu dichlorowodorku porfiryny z ośmioma cząsteczkami chloroformu, C44H32N42+·2Cl-·8CHCl3, i porównano ją...
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Reactions of solute species at an electrode modified with titanocene functionalized polypyrrole film: ferrocene and titanocene dichloride
PublicationPo raz pierwszy zbadano możliwość intermediacji ładunku poprzez centra tytanocenowe polimeru modyfikowanego chemicznie związanymi grupami dichloro tytanocenowymido polipirolu. Badano reakcje elektrodowe ferrocenu i dichlorotytanocenu. Wykazano aktywność elektrodową w zakresie potencjałów redoks pary Ti(IV/TiIII)w stosunku do reakcji redoks ferrocenu i reakcji dichlorotytanocenu. Wykazano, że centra TcCl2 polimeru są zadowalająco...
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Comparison of Absorbed and Intercepted Fractions of PAR for Individual Trees Based on Radiative Transfer Model Simulations
PublicationThe fraction of absorbed photosynthetically active radiation (fAPAR) is a key parameter for estimating the gross primary production (GPP) of trees. For continuous, dense forest canopies, fAPAR, is often equated with the intercepted fraction, fIPAR. This assumption is not valid for individual trees in urban environments or parkland settings where the canopy is sparse and there are well-defined tree crown boundaries. Here, the distinction...
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Stabilization of Eu3+ under a reductive atmosphere by the Al3+ co-doping of Sr2SiO4:Eu2+/Eu3+
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Current and future emissions of selected heavy metals to the atmosphere from anthropogenic cources in Europe
PublicationPrzedstawiono wyniki obliczeń emisji As, Cd, Cr, Ni i Pb do powietrza ze źródeł antropogennych w Europie. Obecnie spalanie paliw jest głównym źródłem emisji As, Cd, Cr i Ni (powyżej 50 % ogólnej emisji tych metali), natomiast spalanie benzyny jest głównym źródłem emisji Pb. Zaobserwowano ciągłą redukcje emisji tych metali w Europie w ciagu ostatnich 40 lat. Powiększający się stan wiedzy nt. źródeł, emisji oraz transportu i zachowania...
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Mercury emission to the atmosphere from anthropogenic sources in Europe in 2000 and their scenarios until 2020
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Current and future emissions of selected heavy metals to the atmosphere from anthropogenic cources in Europe
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Mercury emission to the atmosphere from anthropogenic sources in Europe in 2000 and their scenarios until 2020
PublicationPrzedstawiono obecny stan wiedzy na temat emisji rtęci ze źródeł antropogenicznych na terenie Europy w roku 2000. Zebrane dane stanowiły bazę wyjściową do opracowania scenariuszy emisji do roku 2020. Ponad połowa całkowitej emisji, szacowanej na 239 tony, pochodzi z energetyki przemysłowej oraz gospodarstw domowych i jest związana ze spalaniem stałych nośnikow energii. Istotnym źródłem emisji jest również produkcja cementu (ok....
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Remote Monitoring of Environmental Pollutants
PublicationAtmospheric air quality is one of the key factors influencing human health. Air quality evaluation is not an easy task as the atmosphere is a complex system subjected to continuous changes in time. Observed progress in the development of measurement devices and technologies is fundamental for acquisition of more reliable information about condition and quality of atmospheric air. Unfortunately, this process leads to an increase...
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High Temperature Corrosion Evaluation of Porous Hastelloy X Alloy in Air and Humidified Hydrogen Atmospheres
PublicationIn this work a commercially available porous Hastelloy X alloy is characterized in terms of high temperature corrosion resistance. The alloy was oxidized in the temperature range from 500C to 900C in air and humidified hydrogen for 100 hours. Corrosion rates and porosity changes were measured. Microstructural characterization was performed using X-ray diffractometry and scanning electron microscopy. Results show that porous alloys...
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On the coupling of hydride generation with atmospheric pressure glow discharge in contact with the flowing liquid cathode for the determination of arsenic, antimony and selenium with optical emission spectrometry
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Effect of the addition of non-ionic surfactants on the emission characteristic of direct current atmospheric pressure glow discharge generated in contact with a flowing liquid cathode
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Electrical signatures of Nimbostratus and Stratus clouds in ground-level vertical atmospheric electric field and current density at mid-latitude station Swider, Poland
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Application of Direct Current Atmospheric Pressure Glow Microdischarge Generated in Contact with a Flowing Liquid Solution for Synthesis of Au-Ag Core-Shell Nanoparticles
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Hydrogel-based nanocomposite catalyst containing uncoated gold nanoparticles synthesized using cold atmospheric pressure plasma for the catalytic decomposition of 4-nitrophenol
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Areas of Updraft Air Motion in an Idealised Weather Research and Forecasting Model Simulation of Atmospheric Boundary Layer Response to Different Floe Size Distributions
PublicationPresented dataset is part of a numerical modelling study focusing on the analysis of the influence of sea ice floe size distribution (FSD) on the horizontal and vertical structure of convection in the atmosphere. The total area and spatial arrangement of the up-drafts indicates that the FSD affects the total moisture content and the values of area averaged turbulent fluxes in the model domain. In fact, while convective updrafts...
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Diurnal variability of atmospheric water vapour, precipitation and cloud top temperature across the global tropics derived from satellite observations and GNSS technique
PublicationThe diurnal cycle of convection plays an important role in clouds and water vapour distribution across the global tropics. In this study, we utilize integrated moisture derived from the global navigation satellite system (GNSS), satellite precipitation estimates from TRMM and merged infrared dataset to investigate links between variability in tropospheric moisture, clouds development and precipitation at a diurnal time scale. Over...
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Reactions of the Lithiated DiphosphinetBu2P-P(SiMe3)Li with [(η6-C6H6)RuCl2]2in the Presence of Tertiary Phosphines
PublicationtBu2P–P(SiMe3)Li reacted with [(η6-C6H6)RuCl2]2at–40 °C in the presence of PR3(PR3=PEt3,PEt2Ph, PEtPh2) by the nucleophilic addition of the tBu2P–P(SiMe3) moiety to the benzene ring to yield solely the complexes [(R3P)2Ru(Cl)-{η5-C6H6(Me3SiP–PtBu2)}] (1). These products decomposed slowly at ambient temperature to yield benzene, Ru clusters, and small amounts of the dinuclear ruthenium complexes [{(R3P)2Ru}2(μ,η2:2-P2)2Ru(PR3)2](Ru–Ru)(6)....
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Anti-Microbiological, Anti-Hyperglycemic and Anti-Obesity Potency of Natural Antioxidants in Fruit Fractions of Saskatoon Berry
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Influence of milk, milk fractions and milk proteins on the growth and viability of mastitis-causing Staphylococcus aureus strain
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Soil organic carbon, macro- and micronutrient changes in soil fractions with different lability in response to crop intensification
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Catalytic activity and anion activation in SN2 reactions promoted by complexes of silicon polypodands. Comparison with traditional polyethers
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A TPC Detector for Studying Photo-nuclear Reactions at Astrophysical Energies with Gamma-ray Beams at ELI--NP
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Surfactant free fractions of metallic and semiconducting single-walled carbon nanotubes via optimised gel chromatography
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Spectroscopic studies of a ring opening process between epoxy- and aminosilanes and imine formation reactions in aqueous solutions
PublicationNMR and Raman spectroscopy studies were performed for different 3-aminopropyl(trimethoxy)- and 3-glycidoxypropyl (trimethoxy)silane based sol-gel systems containing different ketones. Exceptionally stable imine products were obtained depending on a reaction system at alkaline pH conditions and in the presence of water. These imine formation reactions were carried out without further catalyst. In addition, effect of water for the...
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Electrochemical simulation of metabolism for antitumor-active imidazoacridinone C-1311 and in silico prediction of drug metabolic reactions
PublicationThe metabolism of antitumor-active 5-diethylaminoethylamino-8-hydroxyimidazoacridinone (C-1311) has been investigated widely over the last decade but some aspects of molecular mechanisms of its metabolic transformation are still not explained. In the current work, we have reported a direct and rapid analytical tool for better prediction of C-1311 metabolism which is based on electrochemistry (EC) coupled on-line with electrospray...
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Medium-sized cyclic bis(anisylphosphonothioyl)- disulfanes and their corresponding cyclic sulfane-structures and most characteristic reactions
PublicationCyclic 8-, 9-, 10-, and 12-membered bis(anisylphosphonothioyl)disulfanes were synthesized. Next, structurally related 7 to 9-membered cis and trans sulfanes were isolated as a result of sulfur atom extrusion from the parent cyclic disulfanes. The results of the desulfurization of the disulfanes were compared to the results obtained for desulfurization of the respective bis(anisylphosphodithioates). Cyclic disulfanes predominantly...
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CO2 EMISSION TO THE ATMOSPHERE FROM CARBONATE WATERS: THE STUDY CASE OF THE LUBLIN UPLAND AND ROZTOCZE REGIONS
PublicationThe concentration of carbon dioxide dissolved in water (CO2(aq)) was measured in consecutive phases of the hydrological cycle. Its potentially possible degassing from groundwaters to the atmosphere was also assessed. The research was conducted in the area of occurrence of carbonate rocks of the Lublin Upland and Roztocze (SE Poland). The results of the measurements of CO2(aq) concentration varied as follows (min-max/mean): precipitation...
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Soft Tissue Retraction Maneuver in Cone Beam Computed Tomography Prior to Crown-Lengthening Procedure—A Technical Note
PublicationBackground: An accurate determination of the biological width and the relationship of the cemento-enamel junction with the border of the alveolar bone is crucial during a clinical crown-lengthening (CCL) procedure. The aim of this study was to present a technical note about the retraction techniques in cone beam computed tomography (CBCT) prior to CCL, highlighting the significant enhancement in procedural accuracy and predictability...
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Comparative field test for measurement of PM10 dust in atmospheric air using gravimetric (reference) method and b-absorption method (Eberline FH 62-1)
PublicationThe paper presents the results of a field test carried out in Gdansk region between 01-01-2010 and 31-12-2010 in order to demonstrate equivalence of the Eberline FH 62-1 sampler to the reference gravimetric method of suspended PM10 dust measurement. The differences in PM10 dust concentration provided by both methods have been discussed for different seasons of the year. A method of estimation of the correction factors/correction...
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Synthesizing of Sensitizing Glasses in Very Small Volumes and Strictly Controlled Atmospheres for Fiber and Integrated Optic Sensors
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Influence of meteorogical conditions om PM10 concentration in Gdańsk
PublicationThe paper presents the investigation of influence of meteorological conditions on the concentration of PM!) in Gdańsk in 2011 year. on the examples of episodes og high concentrations in this year. The results have shown the most crucial factors for high episodes of PM10: anticyclone atmospheric circulation, stable atmosphere conditions, low wind velocity and the occurence of inversion layer.
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Comparison of antioxidant and enzyme inhibition activities as well chemical composition of different extracts and fractions of Rubus caesius leaves
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Mobility and bioavailability of mercury in sediments of the southern Baltic sea in relation to the chemical fractions of iron: Spatial and temporal patterns
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Mobility and bioavailability of mercury in sediments of the southern Baltic sea in relation to the chemical fractions of iron: Spatial and temporal patterns
PublicationMarine sediments play a significant role as reservoirs for mercury (Hg), a bioaccumulative toxic pollutant that poses risks to human and ecosystem health. Iron (Fe) has been recognized as an influential factor in the complexation and bioavailability of Hg in sediments. However, limited studies have investigated the interactions between the chemical fractions of these elements in natural settings. This study aims to examine the...
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Migration of trace elements and radioisotopes to various fractions of solid wastes generated as a result of the sewage sludge incineration process
PublicationThe research was aimed at providing new knowledge in the field of chemical characteristics of solid waste generated in the process of combustion of sewage sludge in fluidized bed furnaces. The research material consisted of disposed fluidized beds (DFB), sewage sludge ash (SSA) and air pollution control residues (APC) from three Polish installations for the thermal treatment of sewage sludge. Natural radionuclides as well as anthropogenic...
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Electrochemical simulation of metabolic reduction and conjugation reactions of unsymmetrical bisacridine antitumor agents, C-2028 and C-2053
PublicationElectrochemistry (EC) coupled with analysis techniques such as liquid chromatography (LC) and mass spectrometry (MS) has been developed as a powerful tool for drug metabolism simulation. The application of EC in metabolic studies is particularly favourable due to the low matrix contribution compared to in vitro or in vivo biological models. In this paper, the EC(/LC)/MS system was applied to simulate phase I metabolism of the representative...
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Stock Markets’ Reactions to the Announcement of the Hosts. An Event Study in the Analysis of Large Sporting Events in the Years 1976–2032
PublicationThis study attempts to estimate the impact of the announcements of hosts of large sporting events on domestic stock markets. The research problem is to establish a connection between the uniqueness of a sporting event and investors’ beliefs through stock price behavior. Using appropriate estimation windows, 13 different sporting events classified as large, including mega and major events, were tested. The obtained results show...
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Effect of Thermal Treatment at Inert Atmosphere on Structural and Magnetic Properties of Non-stoichiometric Zinc Ferrite Nanoparticles
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Influence of pyrolysis atmosphere on the lithium storage properties of carbon-rich polymer derived SiOC ceramic anodes
PublicationPolymer derived carbon-rich SiOC ceramics are prepared from polysiloxane precursors through a pyrolysis process at 1000 °C using pure argon and argon/hydrogen mixture as pyrolysis atmosphere. The precursor is synthesized from a linear (Si–H)-containing polysiloxane cross-linked with divinylbenzene using hydrosilylation reaction in the presence of a platinum catalyst. Pyrolysis in Ar/H2 mixtures, compared to the treatment under...
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Waste disposal sites as sources of mercury in the atmosphere in the coastal zone of the Gulf of Gdańsk (southern Baltic Sea)
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Area-Averaged Surface Moisture Flux over Fragmented Sea Ice: Floe Size Distribution Effects and the Associated Convection Structure within the Atmospheric Boundary Layer
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Examination of the interactions occurring in the gas and liquid phases of atmospheric pressure glow discharge generated in contact with a liquid electrode leading to production of size-defined gold nanostructures
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Production of antimicrobial silver nanoparticles modified by alkanethiol self‐assembled monolayers by direct current atmospheric pressure glow discharge generated in contact with a flowing liquid anode
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Flowing Liquid Anode Atmospheric Pressure Glow Discharge as an Excitation Source for Optical Emission Spectrometry with the Improved Detectability of Ag, Cd, Hg, Pb, Tl, and Zn
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Comparison of the performance of direct current atmospheric pressure glow microdischarges operated between a small sized flowing liquid cathode and miniature argon or helium flow microjets
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