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Wyniki wyszukiwania dla: CHEMICAL ENGINEERING
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Synergistic effects of low-/medium-vacuum carbonization on physico-chemical properties and stability characteristics of biochars
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Noble metal-modified octahedral anatase titania particles with enhanced activity for decomposition of chemical and microbiological pollutants
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In silico study on the effects of carbonyl groups on chemical equilibrium of reactions with a polar product occurring under confinement in pores of activated carbons
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Enzyme-conjugated MXene nanocomposites for biosensing and biocatalysis acuities
PublikacjaEngineered two-dimensional (2-D) MXenes-based materials with tunable characteristics and multi-functionalities have brought up new paradigms in the biosensing and catalysis of chemical compounds. The profusion of electroactive functional moieties on the surface of few/multi-layer MXenes facilitates their ability to retain biomolecules such as enzymes resulting in unique dimensions for bioanalytical and biosensing applications....
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Green engineered biomaterials for bone repair and regeneration: Printing technologies and fracture analysis
PublikacjaDespite the exceptional self-regeneration properties of bone, severe injuries often require additional surgical intervention such as using artificial bone constructs. These structures need to meet a number of criteria regarding their structure, performance, alongside the rate and the mechanism of erosion and fracture when implanted, for stimulating the regeneration of defected bone and, more critically providing support in the...
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Spinning Fluids Reactor: A new design of a gas – liquid contactor
PublikacjaCurrent trends in chemical reactor design are based on adapting these to the requirements of a particular chemical process. Processes involving reactions between the gas and liquid phase in particular require precise adjustment of all parameters. The common denominator for most modern design solutions is enhancement of the mass transfer area and the overall volumetric mass transfer coefficient. Gas – liquid contactors evolved from...
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Mitigating metal-organic framework (MOF) toxicity for biomedical applications
PublikacjaMetal-organic frameworks (MOFs) are a novel class of crystalline porous materials, consisting of metal ions and organic linkers. These hybrid materials are highly porous and have a large specific surface area, making them of great interest for applications in gas separation, energy storage, biomedical imaging, and drug delivery. As MOFs are being explored for biomedical applications, it is essential to comprehensively assess their...
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Highly crystalline colloidal nickel oxide hole transport layer for low-temperature processable perovskite solar cell
PublikacjaHighly crystalline NiOX usually requires high annealing temperature (>300 °C) which is incompatible with flexible substrate and might consume high amount of energy. Herein, we demonstrate a facile emulsion process to synthesize highly crystalline, low temperature deposition (<150 °C) and solution processable NiOx nanoparticles (NPs) as a hole transport layer for the perovskite solar cells (PVSCs). A novel surfactant of tetramethylammonium...
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Advanced oxidation processes (AOPs) based wastewater treatment - unexpected nitration side reactions - a serious environmental issue: A review
PublikacjaChemical compounds containing nitro group (nitro-products) are a one of toxic by-products, that can be formed during wastewater treatment processes. In case of presence of nitrite or nitrate ions, the formation of nitro-products during advanced oxidation processes (AOPs) is very common. It is caused by the reactive nitrogen species (RNs) such as nitrate radical (NO3•), nitrite radical (NO2•), nitrogen oxide radical (NO•) and peroxynirite...
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Synergistic effects of hybrid advanced oxidation processes (AOPs) based on hydrodynamic cavitation phenomenon – A review
PublikacjaHigh-performance water treatment systems based on cavitational processes have received an increasing interest of scientific community in the past few decades. Numerous studies indicated the advantageous application of hydrodynamic cavitation as an alternative, reagent-free treatment method of various pollutants in water. Both approaches were proved as an effective method to achieve mineralization of many organic contaminants as...
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Metal-organic frameworks (MOF) based heat transfer: A comprehensive review
PublikacjaHigher than a standard level, the humidity provides a suitable environment for the pathogenic microorganisms to grow and increases energy consumption for cooling, increasing greenhouse gas emissions. Desiccant air-conditioning (DAC) is an effective method to reduce humidity and energy simultaneously. Conventional desiccants are not suitable for use as a desiccant in building air conditioners, mainly because of high regeneration...
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Numerical investigation on distribution characteristics of oxidation air in a lime slurry desulfurization system with rotary jet agitators
PublikacjaRotary jet agitator is an effective device for mixing, dispersing, dissolving, and suspending dispersed phases in liquid, and is particularly advantageous to the homogenization of oxygen-enriched air within the lime slurry desulfurization system. The distribution of oxygen-enriched air in agitators is vital for the process of gypsum crystallization and the homogeneous and sufficient oxygen-enriched air can promote the formation...
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Desulfurization of raw naphtha cuts using hybrid systems based on acoustic cavitation and advanced oxidation processes (AOPs)
PublikacjaA combination of dual-frequency acoustic cavitation (acoustic cavitation) and UV assisted advanced oxidation processes (AOPs) reaction system was developed for desulfurization of raw naphtha used to produce aviation fuels. Various types of oxidants in hybrid systems including hydrogen peroxide, acetic acid, acetone, air and ozone were compared. At optimum oxidant to sulfur compounds molar ratio (rox) of 5.0, the hybrid process...
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Characterization of diatomaceous earth coated with nitrated asphaltenes as superior adsorbent for removal of VOCs from gas phase in fixed bed column
PublikacjaAsphaltenes isolated from bitumen possess unusual adsorption characteristics that can be further enhanced by chemical modifications to promote interactions with VOCs’. Herein, nitrated asphaltenes are used as an active layer coated on a surface of a diatomaceous earth, in order to prepare an efficient adsorbent (AsfNitro). Breakthrough experiments with benzene, pyridine, and 1-nitropropane revealed significant increase in adsorption...
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Enhanced photocatalytic activity of accordion-like layered Ti3C2 (MXene) coupled with Fe-modified decahedral anatase particles exposing {1 0 1} and {0 0 1} facets
PublikacjaNew composites consisting of decahedral anatase particles exposing {001} and {101} facets coupled with accordion-like layered Ti3C2 with boosted photocatalytic activity towards phenol and carbamazepine degradation were investigated. The photocatalysts were characterized with X-ray diffraction (XRD), diffuse reflectance spectroscopy (DR/UV–Vis), Brunauer-Emmett-Teller (BET) specific surface area, Raman spectroscopy, scanning electron...
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Highly crystalline colloidal nickel oxide hole transport layer for low-temperature processable perovskite solar cell
PublikacjaHighly crystalline NiOX usually requires high annealing temperature (>300 °C) which is incompatible with flexible substrate and might consume high amount of energy. Herein, we demonstrate a facile emulsion process to synthesize highly crystalline, low temperature deposition (<150 °C) and solution processable NiOx nanoparticles (NPs) as a hole transport layer for the perovskite solar cells (PVSCs)....
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Activated biochars reduce the exposure of polycyclic aromatic hydrocarbons in industrially contaminated soils
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Decolorization of Congo red via hydrodynamic cavitation in combination with Fenton’s reagent
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Hydrodynamic studies in magnetically assisted external-loop airlift reactor
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Effects of a rotating magnetic field on gas-liquid mass transfer coefficient
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Gas to liquid mass transfer in mixing system with application of rotating magnetic field
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The study of influence of a rotating magnetic field on mixing efficiency
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Fluidic low-frequency oscillator with vortex spin-up time delay
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Promotion of borophene/NiO-based electrocatalyst for oxygen evolution reaction
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Photodegradation of single and mixture of parabens – Kinetic, by-products identification and cost-efficiency analysis
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Kinetics of the photosensitized degradation of benzyl 4-hydroxybenzoate in homogeneous aqueous solution under visible-light irradiation
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Photochemical decomposition of endocrine disrupting compounds – A review
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Coupling of electrocoagulation and ozone treatment for textile wastewater reuse
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Photosensitive chitosan for visible-light water pollutant degradation
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Comparison between industrial and simulated textile wastewater treatment by AOPs – Biodegradability, toxicity and cost assessment
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Photocatalytic water disinfection under the artificial solar light by fructose-modified TiO2
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Effect of preparation conditions and promoters on the structure and activity of the ammonia decomposition reaction catalyst based on nanocrystalline cobalt
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Effective green ammonia synthesis from gaseous nitrogen and CO2 saturated-water vapour utilizing a novel photocatalytic reactor
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The ultrafiltration ceramic membrane used for broth separation in membrane bioreactor
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A new submerged photocatalytic membrane reactor based on membrane distillation for ketoprofen removal from various aqueous matrices
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Antimicrobial properties of pristine and Pt-modified titania P25 in rotating magnetic field conditions
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Membrane cleaning and pretreatments in membrane distillation – a review
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Preparation, characterization and charge transfer studies of nickel – modified and nickel, nitrogen co-modified rutile titanium dioxide for photocatalytic application
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Hydrophobic PVDF hollow fiber membranes with narrow pore size distribution and ultra-thin skin for the fresh water production through membrane distillation
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Continuous and catalyst free synthesis of graphene sheets in thermal plasma jet
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Bulk processing of ZnO nanostructures via microwave assisted oxidation of mechanically seeded Zn dust for functional paints and coatings
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Low temperature removal of SO2 traces from air by MgO-loaded porous carbons
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On the metric dimension of corona product graphs
PublikacjaWe give several results on the metric dimension of corona product graphs.
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Selective preparation of biomass-derived porous carbon with controllable pore sizes toward highly efficient CO2 capture
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Insight into the microbial and genetic response of anammox biomass to broad range concentrations of different antibiotics: Linking performance and mechanism
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Catalytic carbonization of polypropylene into cup-stacked carbon nanotubes with high performances in adsorption of heavy metallic ions and organic dyes
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Catalytic conversion of linear low density polyethylene into carbon nanomaterials under the combined catalysis of Ni2O3 and poly(vinyl chloride)
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Application of hollow mesoporous carbon nanospheres as an high effective adsorbent for the fast removal of acid dyes from aqueous solutions
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Effect of the added amount of organically-modified montmorillonite on the catalytic carbonization of polypropylene into cup-stacked carbon nanotubes
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Mechanistic insights into the reactive radicals-assisted degradation of sulfamethoxazole via calcium peroxide activation by manganese-incorporated iron oxide–graphene nanocomposite: Formation of radicals and degradation pathway
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