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Wyniki wyszukiwania dla: COATING ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY
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The impact of air humidity on the operation of proton exchange membrane fuel cells determined using dynamic electrochemical impedance spectroscopy
PublikacjaThis paper describes the changes in the fuel cell impedance across a range of current loads and humidity changes. The changes of each equivalent circuit parameters representing specific processes occurring in fuel cells, as a function of humidity and current changes, were determined. Within the combined scope of current and humidity, the optimal working conditions of the cells were determined, corresponding to the lowest impedance...
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Dynamic electrochemical impedance spectroscopy and polarization studies to evaluate the inhibition effect of benzotriazole on copper-manganese-aluminium alloy in artificial seawater
PublikacjaPrzeprowadzono badania wpływu benzotriazolu (BTA) na korozję nowego typ mosiądzu (CMA) w środowisku syntetycznej wody morskiej przy użyciu dynamicznej elektrochemicznej spektroskopii impedancyjnej (DEIS), techniki polaryzacji rezystancyjnej i ekstrapolacji krzywych Tafela. Wyniki pomiarowe otrzymane przy użyciu tych metod wskazują spadek szybkości korozji wraz ze wzrostem stężenia BTA. Wskazuje to na inhibicyjne własności BTA w...
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In-situ odd random phase electrochemical impedance spectroscopy study on the electropolymerization of pyrrole on iron in the presence of sodium salicylate – The influence of the monomer concentration
PublikacjaIn this work, the potentiostatic electropolymerization of polypyrrole (PPy) on iron in aqueous solution of sodium salicylate and pyrrole is studied in situ by odd random phase electrochemical impedance spectroscopy (ORP-EIS). The influence of the pyrrole concentration on the electrosynthesis process is investigated. The ORP-EIS technique ensures a reliable analysis of the PPy electrosynthesis on iron by means of an advanced data...
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Biomolecular influenza virus detection based on the electrochemical impedance spectroscopy using the nanocrystalline boron-doped diamond electrodes with covalently bound antibodies
PublikacjaNew rapid pathogen detection methods with improved cost-effectiveness and efficiency are currently in the focus of the scientists from all over the world. Based on the experiences from the rapid spread of the influenza virus pandemic in 2009 it is clear that the development of the system for early diagnosis of this infection is essential. The crucial stage of the treatment is the detection of the viral infection during its initial...
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Corrosion behaviour of low carbon steel in artificial seawater using TP, LP, EIS, Harmonic Analysis (HA) and new method Dynamic Electrochemical Impedance Spectroscopy (DEIS)
PublikacjaZe względu na istotną rolę technik elektrochemicznych w badaniach procesów korozyjnych są one szeroko stosowane w monitorowaniu korozji. Celem niniejszej pracy jest zgromadzenie rezultatów wyników doświadczalnych uzyskanych różnymi technikami i znalezienie korelacji między nimi. Własności korozyjne stali stopowej (AISI 1026) w sztucznej wodzie morskiej zostały zbadane z wykorzystaniem ekstrapolacji tafelowskiej (TP), polaryzacji...
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Electrochemical Impedance Spectroscopy data of PDA-modified TiO2 nanotubes
Dane BadawczeThis dataset contains Electrochemical Impedance Spectroscopy data of the samples from TiO2 nanotubes modified with polydopamine. The studies were presented as a part of the research on "Band Gap Engineering toward Semimetallic Character of Quinone-Rich Polydopamine" (DOI: 10.1021/acs.jpcc.2c08804).
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The electrochemical impedance spectroscopy studies of cataphoretic-grown epoxy-based coatings
Dane BadawczeThe dataset contains electrochemical impedance spectroscopy spectra collected for epoxy-based cataphoretic coatings in order to determine the offered anti-corrosion protection. Particular spectra pertain to the coatings applied for the different magnitude of polarization potential imposed, namely 10V, 20V and 30V. The results were obtained within the...
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Model dynamic electrochemical impedance spectroscopy (DEIS) results obtained with various DC polarization rates
Dane BadawczeThe dataset contains results of model dynamic electrochemical impedance spectroscopy studies carried out on a setup of 10 diodes in series, which were connected in parallel with a condenser. The impedance data were acquired every 1 s (the analytic window length for Fourier Transform was 1 s). The model system was polarized between 0 and +8 V with DEIS...
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Electrochemical impedance spectroscopy measurements - conductivity vs. temperature and conductivity vs. oxygen partial pressure - BaCe0.6Zr0.2Y0.1Tb0.1O3-δ
Dane BadawczeThe dataset consists of two main catalogs consisting of measurement data: of the electrical conductivity of the BaCe0.6Zr0.2Y0.1Tb0.1O3-δ (BCZYTb) sample as a function of temperature and of the electrical conductivity as a function of oxygen partial pressure (pO2). Measurements as a function of temperature were carried out in dry and wet air (pH2O ~...
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Influence of sintering temperature of porous SrTi0.30Fe0.70O3-d oxygen electrode on electrochemical impedance spectroscopy spectra measured at 800 °C
Dane BadawczeThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at different temperatures (800 °C; 900 °C and 1000 °C). Measure temperature was 800 °C (syntetic air, 40 ml min-1). Results converted to electrode surfaces area and dived by two electrodes.
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Influence of sintering temperature of porous SrTi0.50Fe0.50O3-d oxygen electrode on electrochemical impedance spectroscopy spectra measured at 800 °C
Dane BadawczeThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.50Fe0.50O3-d oxygen electrodes sintered at different temperatures (800 °C; 900 °C and 1000 °C). Measure temperature was 800 °C (syntetic air, 40 ml min-1). Results converted to electrode surfaces area and dived by two electrodes.
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Influence of sintering temperature of porous SrTi0.65Fe0.35O3-d oxygen electrode on electrochemical impedance spectroscopy spectra measured at 800 °C
Dane BadawczeThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.65Fe0.35O3-d oxygen electrodes sintered at different temperatures (800 °C; 900 °C and 1000 °C). Measure temperature was 800 °C (syntetic air, 40 ml min-1). Results converted to electrode surfaces area and dived by two electrodes.
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Electrochemical impedance spectroscopy spectra measured at 700 °C on porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at different temperatures
Dane BadawczeThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at different temperaturs (800 °C, 900 °C and 1000 °C). EIS spectra were measured at 700 °C with synthetic air flow (21% O2, 40 ml min-1). Results converted to electrode surfaces area and dived by two...
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Electrochemical impedance spectroscopy spectra measured at 700 °C on porous SrTi0.65Fe0.35O3-d oxygen electrodes sintered at different temperatures
Dane BadawczeThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.65Fe0.35O3-d oxygen electrodes sintered at different temperaturs (800 °C, 900 °C and 1000 °C). EIS spectra were measured at 700 °C with synthetic air flow (21% O2, 40 ml min-1). Results converted to electrode surfaces area and dived by two...
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Electrochemical impedance spectroscopy spectra measured at 700 °C on porous SrTi0.50Fe0.50O3-d oxygen electrodes sintered at different temperatures
Dane BadawczeThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.50Fe0.50O3-d oxygen electrodes sintered at different temperaturs (800 °C, 900 °C and 1000 °C). EIS spectra were measured at 700 °C with synthetic air flow (21% O2, 40 ml min-1). Results converted to electrode surfaces area and dived by two...
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Electrochemical impedance spectroscopy spectra measured at 800 °C, 750 °C and 700 °C on porous SrTi0.50Fe0.50O3-d oxygen electrode sintered at 800 °C
Dane BadawczeThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.50Fe0.50O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 800 °C; 750°C and 700 °C (synthetic air). Results converted to electrode surfaces area and dived by two electrodes.
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Electrochemical impedance spectroscopy spectra measured at 800 °C, 750 °C and 700 °C on porous SrTi0.65Fe0.35O3-d oxygen electrode sintered at 800 °C
Dane BadawczeThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.65Fe0.35O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 800 °C; 750°C and 700 °C (synthetic air). Results converted to electrode surfaces area and dived by two electrodes.
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Electrochemical impedance spectroscopy spectra measured at 800 °C, 750 °C and 700 °C on porous SrTi0.30Fe0.70O3-d oxygen electrode sintered at 800 °C
Dane BadawczeThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 800 °C; 750°C and 700 °C (synthetic air). Results converted to electrode surfaces area and dived by two electrodes.
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Electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for porous SrTi0.30Fe0.70O3-d oxygen electrode measured at 800 °C and 15% oxygen partial pressure
Dane BadawczeThis dataset contains electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for symmetrical cell with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 800 °C and 15% of oxygen partial pressure. Spectra of two RCPE elements from equivalent circuit , are also included....
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Electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for porous SrTi0.30Fe0.70O3-d oxygen electrode measured at 600 °C and 15% oxygen partial pressure
Dane BadawczeThis dataset contains electrochemical impedance spectroscopy and Distribution of Relaxation Times results for symmetrical cell with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 600 °C and 15% of oxygen partial pressure. Spectra of two RCPE elements from equivalent circuit , are also included. Results converted...
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Electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for porous SrTi0.30Fe0.70O3-d oxygen electrode measured at 700 °C and 15% oxygen partial pressure
Dane BadawczeThis dataset contains electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for symmetrical cell with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 700 °C and 15% of oxygen partial pressure. Spectra of two RCPE elements from equivalent circuit , are also included....
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Electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for porous SrTi0.30Fe0.70O3-d oxygen electrode measured at 700 °C and 100% oxygen partial pressure
Dane BadawczeThis dataset contains electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for symmetrical cell with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 700 °C and 100% of oxygen partial pressure. Spectra of two RCPE elements from equivalent circuit , are also included....
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Electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for porous SrTi0.30Fe0.70O3-d oxygen electrode measured at 700 °C and 20% oxygen partial pressure
Dane BadawczeThis dataset contains electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for symmetrical cell with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 700 °C and 20% of oxygen partial pressure. Spectra of two RCPE elements from equivalent circuit , are also included....
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Electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for porous SrTi0.30Fe0.70O3-d oxygen electrode measured at 700 °C and 5% oxygen partial pressure
Dane BadawczeThis dataset contains electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for symmetrical cell with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 700 °C and 5% of oxygen partial pressure. Spectra of two RCPE elements from equivalent circuit , are also included. Results...
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Kazimierz Darowicki prof. dr hab. inż.
OsobyStudia wyższe ukończyłem w czerwcu 1981 roku po zdaniu egzaminu dyplomowego i obronie pracy magisterskiej. Opiekunem pracy magisterskiej był dr hab. inż. Tadeusz Szauer. W roku 1991, 27 listopada uzyskałem stopień naukowy broniąc pracę doktorską zatytułowaną „Symulacyjna i korelacyjna analiza widm immitancyjnych inhibitowanej reakcji elektrodowej”. Promotorem pracy był prof. dr hab. inż. Józef Kubicki (Wydział Chemiczny...
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Multivariate analysis of impedance data obtained for coating systems of varying thickness applied on steel
PublikacjaElectrochemical impedance spectroscopy (EIS) has proven to be a valuable test method for the electrochemical characterization of protective coatings on metals. The common way of analysis in impedance spectroscopy is to model the impedance spectrum by means of an equivalent circuit and to extract the quantity of interest using optimization techniques. A model, corresponding to the behavior of the sample under testing, is important...
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Degradation of protective coatings in steel chimneys of flue gas desulfurisation system
PublikacjaThis paper presents problems associated with corrosion of steel stacks and changes in philosophy of corrosion protection when implemented into flue gas desulphurization systems. In-situ tests were taken by means of electrochemical impedance spectroscopy at the stack which discharges flue gas before wet lime/limestone desulphurization. A very quick electrolyte absorption by the spherical infill vinylester coating was found using...
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Underwater Electrochemical Offshore Tests of a Paint Coating Applied in Water on the Legs of an Oil Production Platform
PublikacjaThis paper presents the methodology developed for underwater measurements using electrochemical impedance spectroscopy (EIS) technique, aimed at determining the resistance of an epoxy coating applied in seawater to the legs of an oil production platform. Performing such underwater tests in an offshore environment was technically challenging. The results of measurements obtained on the platform were confronted with comparative results...
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Impedance evaluation of coatings from biobased material
PublikacjaThe authors propose a modification of sodium caseinate edible coating for foodstuff protection. The aim was to improve the film’s barrier properties. It was achieved by the addition of propolis, which is a natural, environmentally friendly product known from its intrinsic sealing action. In the next step, propolis-admixed sodium caseinate films were exposed to elevated temperature for 10 min. This approach was meant to improve...
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PROBLEMS WITH CORROSION PROTECTION STEEL STACKS IN FGD SYSTEMS
PublikacjaThis paper presents problems associated with corrosion of steel stacks and changes in philosophy of corrosion protection when implemented into flue gas desulphurization systems. In-situ tests were taken by means of electrochemical impedance spectroscopy at a stack which discharges flue gas before wet lime/limestone desulphurization. A very rapid soaking of spherical infill vinylester coating with electrolyte has been observed....
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Jacek Ryl dr hab. inż.
OsobyStopień doktora nauk technicznych uzyskał w roku 2010. W tym samym roku podjął pracę w Katedrze Elektrochemii, Korozji i Inżynierii Materiałowej na Wydziale Chemicznym. W 2018 roku uzyskał stopień doktora habilitowanego nauk technicznych w dyscyplinie technologia chemiczna. Od 2021 roku zatrudniony w Instytucie Nanotechnologii i Inżynierii Materiałowej Wydziału Fizyki Technicznej i Matematyki Stosowanej PG. W pracy naukowej skupia...
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Tailoring the electrochemical degradation of iron protected with polypyrrole films for biodegradable cardiovascular stents
PublikacjaThe degradation of polypyrrole (PPy) coated iron is studied in phosphate buffer saline solution at 37 °C by odd random phase multisine electrochemical impedance spectroscopy (ORP-EIS). PPy is electropolymerized with anti-inflammatory salicylates incorporated in the film, as a drug release system. The modelling of EIS over time provides the quantitative description of the corrosion behaviour of the material. Thus, the reliable...
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Performance of zinc-rich coatings evaluated using AFM-based electrical properties imaging
PublikacjaThe paper presents the results of investigation of polyvinyl zinc-rich coating exposed to 97% relativehumidity atmosphere for 40 days. Condition of the coating and evolution of its protective properties weredetermined with the novel AFM-based approach capable of providing surface profiles, local dc currentmaps as well as local impedance spectra. The proposed technique allowed insight into the local changesof coating topography...
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Performance of organic coatings upon cyclic mechanical load
PublikacjaA number of engineering structures fail due to the fatigue damage resulting from cyclic mechanical stress. However, as far as organic coatings are concerned this degradation factor remains underestimated. In the paper the authors propose a methodology combining global electrochemical impedance spectroscopy and local atomic force microscopy measurements for evaluation of coating resistance to an impact of repetitive mechanical stress. Typical...
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Insightful Analysis of Phenomena Arising at the Metal|Polymer Interphase of Au-Ti Based Non-Enzymatic Glucose Sensitive Electrodes Covered by Nafion
PublikacjaThis paper focuses on the examination of glucose oxidation processes at an electrode material composed of gold nanoparticles embedded in a titanium template. Three dierent conditions were investigated: the chloride content in the electrolyte, its ionic conductivity and the presence of a Nafion coating. The impact of the provided environment on the oxidation reaction was evaluated by cyclic voltammetry (CV) and electrochemical impedance...
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Nickel-nanodiamond coatings electrodeposited from tartrate electrolyte at ambient temperature
PublikacjaIn this study, nanocrystalline Ni and Ni-diamond coatings were obtained by electrodeposition from tartrate electrolyte at ambient temperature aiming at improving corrosion and wear properties of the material. The created surfaces were investigated with regard to microhardness, adhesion, wear- and corrosion-resistance. The various methods such as atomic force microscopy, scanning electron microscopy, electrochemical impedance spectroscopy...
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Highly Oriented Zirconium Nitride and Oxynitride Coatings Deposited via High‐Power Impulse Magnetron Sputtering: Crystal‐Facet‐Driven Corrosion Behavior in Domestic Wastewater
PublikacjaHerein, highly crystalline ZrxNy and ZrxNyOz coatings are achieved by the deposition via high‐power impulse magnetron sputtering. Various N2 and N2/O2 gas mixtures with argon are investigated. The chemical composition and, as a result, mechanical properties of the deposited layer can be tailored along with morphological and crystallographic structural changes. The corrosion resistance behavior is studied by potentiodynamic measurements...
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Strontium-based nanosized phosphates as anticorrosive fi llers of epoxy and polyurethane coating compositions
PublikacjaAnticorrosive epoxy and polyurethane coatings were compounded using zinc-free nanosized phosphates of strontium (SP) or strontium and aluminum (SAP). For comparison, a nanosized calcium aluminum ammonium phosphate (CAP) and a microsized zinc phosphate (ZP) were tested. Results of salts spray and cyclic corrosion tests revealed better anticorrosive properties of the SAP-based coatings...
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Conducting polymers for biodegradable metallic implants
PublikacjaNowadays permanent metallic cardiovascular stents are long-term implants. The long-time presence of such an implant in human body can cause overgrowth of tissue within the treated portion of the vessel, blockage of the circulatory system and many other clinical complications, such as thrombosis, prolonged physical irritations or chronic inflammation. Therefore, in recent years, there is an interest to create biodegradable metallic...
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Enhanced electrochemical performance of partially amorphous La0.6Sr0.4CoO3-δ oxygen electrode materials for low-temperature solid oxide cells operating at 400 °C
PublikacjaThis work evaluates partially amorphous La0.6Sr0.4CoO3-δ (LSC) as a potential oxygen electrode for lowtemperature solid oxide cells. LSC was deposited using the spin-coating technique onto Ce0.8Gd0.2O2-δ (CGO) substrates. The optimal oxygen electrode thickness was determined as 500 nm. The electrochemical impedance spectroscopy (EIS) study showed a significant improvement in oxygen reduction/oxidation reaction kinetics when annealing...
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A Comprehensive Analysis of Impedance of the Electrochemical Cell
PublikacjaA comprehensive impedance characteristics of two electrodes electrochemical cell has been pre sented. In this method a multisinusoidal current excitation signal is used. The change of potential of both the electrodes are all registered as a function of time. The proposed method gives the possibility of determining the impedance of both electrodes individually as well as the impedance of a twoelectrode system. Additional application...
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Validation of dynamic electrochemical impedance spectrograms using autocorrelation function
PublikacjaValidation of impedance data is essential for checking the reliability of experimental data. Kramers – Kronig transformation is used to verify data obtained from classical Electrochemical Impedance Spectroscopy (EIS) measurements. Data obtained from Dynamic Electrochemical Impedance Spectroscopy (DEIS) could be validated in the same way, but in this case, there is no information about internal consistency between every single spectrum...
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Water uptake in protective organic coatings and its reflection in measured coating impedance
PublikacjaWater uptake in commercially available epoxy coating on mild steel using impedance spectroscopy and gravimetry was studied. The water content in the coating was determined using the Brasher-Kingsbury equation and various methods of coating capacitance calculation used in the literature. The obtained results were compared with reference gravimetric data. An overestimation of values obtained from impedance data in relation to gravimetric...
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Application of quartz crystal microbalance and dynamic impedance spectroscopy to the study of copper corrosion inhibitors
PublikacjaThe study investigates the application of Dynamic Electrochemical Impedance Spectroscopy (DEIS) and Electrochemical Quartz Crystal Microbalance (EQCM) techniques to examine the corrosion inhibition of copper by Benzotriazole and Sodium Folate in a 0.1 M NaCl solution. DEIS, an advanced version of Electrochemical Impedance Spectroscopy (EIS), allows for real-time monitoring of non-stationary electrochemical systems,...
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Selection of excitation signals for high-impedance spectroscopy
PublikacjaA method of fast impedance spectroscopy of technical objects with high impedance (|Zx| > 1 GOhm) is evaluated in this paper. An object is excited with a signal generated by a digital-to-analog converter (DAC) located on the U2531A DAQ module. Response signals proportional to current flowing through and voltage across the measured object are sampled by analog-to-digital converters (ADC) in the DAQ module. The object impedance spectrum...
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Assessment of organic coating degradation via local impedance imaging
PublikacjaThe paper presents a new approach to organic coating condition evaluation at micrometer scale using localized impedance measurements. It is based on atomic force microscopy (AFM) in contact mode. Impedance is measured between conductive AFM tip and metal substrate covered with organic coating. A single-frequency voltage perturbation signal is applied between the electrodes and current response signal is registered. As the tip is...
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Time evolution of Electrochemical Impedance spectra of cathodically protected steel in artificial seawater
PublikacjaUsability of Electrochemical Impedance Spectroscopy data for better cathodic protection control was investigated. Carbon steel – S235JR2 grade specimen were exposed in artificial seawater environment. Samples were polarized and their potentials corresponded to four different cathodic protection degrees. Time evolution of Electrochemical Impedance spectra was investigated. Goodness of fit function (X2) was analysed in terms of proper...
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Impedance spectroscopy of the lithium titanate doped by copper thin films
Dane BadawczeLithium titanate doped by copper thin films were derived by sol-gel method. Prepared gel was deposited by spin-coating technique. Samples with various content of Cu were measured by impedance spectroscopy method in a wide range of temperature, from -120 up to 150 deg.
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Application of galvanodynamic impedance spectroscopy for studying passive film cracking under mechanical strain
PublikacjaThe paper reports the results of simultaneous mechanical and electrochemical investigations on austenitic (18/8) stainless steel in a 2 % solution of sulphuric acid. The measurements were performed using Galvanodynamic Electrochemical Impedance Spectroscopy (GDEIS). Electrochemical analysis of mechanical passive layer cracking and repassivation conditions during a tensile test was carried out. Application of this methodology allowed...
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The influence of chitosan hydrogel coating on different redox probes kinetics
Dane BadawczeThis dataset contains cyclic voltammetry studies of three redox probes: 1 mM K3[Fe(CN)6], [K4Fe(CN)6], C12H14FeO2, and [Ru(NH3)6]Cl2 dissolved in 0.1 M KCl or PBS as the primary electrolyte. The studies are made for glassy carbon electrode (GC) and glassy carbon electrode covered with thin chitosan hydrogel membrane (C2A2). Cyclic voltammograms were...