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Wyniki wyszukiwania dla: BINUCLEAR SENSITIZERS
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The importance of anchoring ligands of binuclear sensitizers on electron transfer processes and photovoltaic action in dye-sensitized solar cells
PublikacjaThe relatively low photon-to-current conversion efficiency of dye-sensitized solar cells is their major drawback limiting widespread application. Light harvesting, followed by a series of electron transfer processes, is the critical step in photocurrent generation. An in-depth understanding and fine optimization of those processes are crucial to enhance cell performance. In this work, we synthesize two new bi-ruthenium sensitizers...
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Synthesis of novel dinuclear ruthenium polypyridine dye for dye-sensitized solar cells application
PublikacjaA new dinuclear ruthenium(II) polypyridine complex has been successfully synthesized. The new compound has been characterized by spectroscopic and electrochemical methods. Its potential application as a sensitizing dye in dye-sensitized solar cells has been checked under AM 1.5 G irradiation conditions (100 mW cm−2) and its performance was compared to that of a commercially available mononuclear analogous dye. The overall light-to-electricity...
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Imidazoacridinone Derivatives as Efficient Sensitizers in Photoantimicrobial Chemotherapy
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New Benzo[h]quinolin-10-ol Derivatives as Co-sensitizers for DSSCs
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BODIPY‐Perylene Charge Transfer Compounds; Sensitizers for Triplet‐Triplet Annihilation Up‐conversion
PublikacjaBODIPY heterochromophores, asymmetrically substituted with perylene and/or iodine at the 2 and 6 positions were prepared and investigated as sensitizers for triplet-triplet annihilation up conversion (TTA-UC). Single-crystal X-ray crystallographic analyses show that the torsion angle between BODIPY and perylene units lie between 73.54 and 74.51, though they are not orthogonal. Both compounds show intense, charge transfer absorption...
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Choline Supplementation Sensitizes Legionella dumoffii to Galleria mellonella Apolipophorin III
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Impact of TiO2 Nanostructures on Dye-Sensitized Solar Cells Performance
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Dye-sensitized solar cells, in: Physics of Nanostructured Solar Cells
PublikacjaRozwój nanotechnologii otwiera coraz szersze horyzonty w dziedzinie zastosowania nowych materiałów w istniejących technologiach. Po tranzystorach także inne urządzenia wchodzą w erę nanotechnologii, w tym także te, dla których podstawowym materiałem są półprzewodniki i materiały organiczne. Ogniwa słoneczne nie są w tym zakresie wyjątkiem. W książce przedstawiono różne rodzaje ogniwa fotowoltaicznych i związane z ich eksploatacją...
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Magnetic field effects in dye-sensitized and organic solar cells
PublikacjaThe charge recombination and exciton dissociation are generally recognized as the basic electronic processes limiting the efficiency of photovoltaic devices. The aim of this thesis is to understand the electronic processes limiting the operation of efficient solar cells with particular emphasis on the role of electronic states endowed with magnetic dipole moment. The research work is divided into two parts. The first part deals...
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Descriptors to Predict Dye‐Sensitized Semiconductor Based Photocatalyst for Hydrogen Evolution Reaction
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Examination of the Effect of Selected Factors on the Photovoltaic Response of Dye-Sensitized Solar Cells
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Spray deposited carbon nanotubes counter electrodes for dye-sensitized solar cells
PublikacjaCarbon nanotubes due to their catalytic properties are a promising alternative to platinum counter electrodes (CE) for dye-sensitized solar cells (DSSC). In this study, counter electrodes were made from double-walled carbon nanotube (DWCNT) ink using the spray printing technique and afterwards thermally treated at temperatures ranging from 120 to 300 °C. Morphology and structure was studied using scanning electron microscopy and...
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Spray-deposited carbon-nanotube counter-electrodes for dye-sensitized solar cells
PublikacjaCarbon nanotubes due to their catalytic properties are a promising alternative to platinum counter electrodes (CE) for dye-sensitized solar cells (DSSC). In this study, counter electrodes were made from double-walled carbon nanotube (DWCNT) ink using the spray printing technique and afterwards they were thermally treated at temperatures ranging from 120 to 300 °C. Morphology and structure was studied using scanning electron microscopy...
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The imidazoacridinone C-1311 induces p53-dependent senescence or p53-independent apoptosis and sensitizes cancer cells to radiation
PublikacjaC-1311 is a small molecule, which has shown promise in a number of preclinical and clinical studies. However, the biological response to C-1311 exposure is complicated and has been reported to involve a number of cell fates. Here, we investigated the molecular signaling which determines the response to C-1311 in both cancer and non-cancer cell lines. For the first time we demonstrate that the tumor suppressor, p53 plays a key role...
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Investigations of New Phenothiazine-Based Compounds for Dye-Sensitized Solar Cells with Theoretical Insight
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Effect of thienyl units in cyanoacrylic acid derivatives toward dye-sensitized solar cells
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Magnetic field effects in dye-sensitized solar cells controlled by different cell architecture
PublikacjaThe charge recombination and exciton dissociation are generally recognized as the basic electronic processes limiting the efficiency of photovoltaic devices. In this work, we propose a detailed mechanism of photocurrent generation in dye-sensitized solar cells (DSSCs) examined by magnetic field effect (MFE) technique. Here we demonstrate that the magnitude of the MFE on photocurrent in DSSCs can be controlled by the radius and...
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Effects of dinuclear berenil-platinum(II) complexes on fibroblasts redox status
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The influence of anchoring group position in ruthenium dye molecule on performance of dye-sensitized solar cells
PublikacjaThe effect of anchoring group position and, in consequence, the orientation of the ruthenium dye molecule on titania surface on the performance of dye-sensitized solar cells has been studied intensively. Three model ruthenium sensitizing dyes bearing carboxylic anchoring group in ortho, meta or para position were synthesized and well characterized by spectroscopic, electrochemical, photophysical and photochemical measurements....
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Analysis of a Nuclear Intrinsically Disordered Proteome
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New Dinuclear Macrocyclic Copper(II) Complexes as Potentially Fluorescent and Magnetic Materials
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Inhibition of phthalocyanine-sensitized photohemolysis of human erythrocytes by polyphenolic antioxidants: description of quantitative structure–activity relationships
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Dyes based on the D/A-acetylene linker-phenothiazine system for developing efficient dye-sensitized solar cells
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Comparative analysis of thermodynamic cycles of selected nuclear ship power plants with high-temperature helium-cooled nuclear reactor
PublikacjaThis paper presents a comparative analysis of thermodynamic cycles of two ship power plant systems with a high-temperature helium- cooled nuclear reactor. The first of them is a gas system with recuperator , in which classical gas chamber is substituted for a HTGR reactor (High Temperature Gas-cooled Reactor) . The second of the considered cycles is a combined gas-steam system where working medium flux from gas turbine outlet...
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Current situation in Polish nuclear medicine and Polish example of model Nuclear Medicine Centre meeting European Union requirements
PublikacjaNuclear medicine is currently a well-established part of medicine. It is applied in many fields of clinical medicine and science like endocrinology, oncology, cardiology, molecular medicine and engineering, radiopharmacy, physics and information science. Due to its increasing importance and application, several regulation and supervision bodies have been founded to ensure safe usage of radiation and to improve diagnostic and therapeutic...
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The analysis of turbine propulsion systems in nuclear submarines
PublikacjaThe article systematises submarines, which are presently in service, according to their propulsion types (both conventional and nuclear), power output, and submersion depth. Contemporary types of propulsion systems installed and used in submarines are discussed. Calculations were performed for the PWR (Pressurized Water Reactor) type nuclear propulsion system and the supercritical turbine propulsion system (supercritical reactor...
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Modelling of Nuclear Power Plant Steam Turbine
PublikacjaThe paper describes the approach to a Nuclear Power Plant steam turbine modelling which would enable on-line optimal process control (model based) and diagnosis over wide range of operating conditions caused by changing power demand. Presented model is static, multivariable and nonlinear. Such model enables analyzing the heat cogeneration aspects. Developed model is validated and verified by using archive data gained from researches...
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Modelling of Nuclear Power Plant Steam Turbine
PublikacjaThe paper describes the approach to a Nuclear Power Plant steam turbine modelling which would enable on-line optimal process control (model based) and diagnosis over wide range of operating conditions caused by changing power demand. Presented model is static, multivariable and nonlinear. Such model enables analyzing the heat cogeneration aspects. Developed model is validated and verified by using archive data gained from researches...
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Dynamic model of nuclear power plant turbine
PublikacjaThe paper presents the dynamic multivariable model of Nuclear Power Plant steam turbine. Nature of the processes occurring in a steam turbine causes a task of modeling it very difficult, especially when this model is intended to be used for on-line optimal process control (model based) over wide range of operating conditions caused by changing power demand. Particular property of developed model is that it enables calculations...
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Synthesis of Titanium Dioxide via Surfactant-Assisted Microwave Method for Photocatalytic and Dye-Sensitized Solar Cells Applications
PublikacjaIn this study, titania nanoparticles were obtained using the microwave-assisted technique. Moreover, different surfactants (PEG (Mn = 400), Pluronic P123 and Triton X−100) were used during the synthesis in order to determine their impact on the crystallinity and morphology of the final products. Subsequently, techniques such as XRD, SEM and TEM (performed in high contrast and high-resolution mode), diffuse reflectance spectroscopy...
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The Influence of Titania Electrode Modification with Lanthanide Ions Containing Thin Layer on the Performance of Dye-Sensitized Solar Cells
PublikacjaThe lanthanide and scandium groups ions (except Pm and Ac) have been used as dopants of TiO2 film in dye-sensitized solar cells. The X-ray diffraction spectra show that the modification has no influence on the structure of the electrode; however, the diffuse reflectance UV-Vis measurements exhibit significant changes in the electronic properties of modified electrodes. The appearance of energy barrier preventing photoexcited electron...
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Binuclear Co(II), Zn(II) and Cd(II) tri-tert-butoxysilanethiolates. Synthesis, crystal structure and spectroscopic studies.
PublikacjaA series of Co(II), Zn(II) and Cd(II) complexes have been synthesized in reaction of respective metal tri-tert-butoxysilanethiolates with pyrazine 1 and 2 and 1,2-bis(2-pyridyl)ethylene 3–5. All compounds have been characterized by single-crystal X-ray structure determination, elemental analysis, FT-IR and thermogravimetry. Obtained complexes are bimetallic with the formula of [M{SSi(OtBu)3}2(μ-L)]2 and metal ions bridged by N,N′-spacer....
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Effect of novel dinuclear platinum(II) complexes on redox status of MOLT-4 leukemic cells
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Detection of neutrons with LiF fluorescent nuclear track detectors
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LITHIUM FLUORIDE CRYSTALS AS FLUORESCENT NUCLEAR TRACK DETECTORS
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3D imaging of nuclear reactions using GEM TPC
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Proteomic and bioinformatic analysis of a nuclear intrinsically disordered proteome
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Dynamic model of nuclear power plant steam turbine
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Human factors in nuclear power engineering in Polish conditions
PublikacjaThe paper “Human factors in nuclear power engineering in polish conditions” focuses on analysis of dynamics of preparing polish society to build first nuclear power plant in XXI century in Poland. Authors compare experience from constructing nuclear power plant Sizewell B (Great Britain) and Sizewell C, which is in preparation phase with polish nuclear power program. Paper includes aspects e.g. of creating nuclear safety culture...
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Nuclear power plant as a source of electrical energy and heat
PublikacjaIn this paper certain issues concerning usage of nuclear power plants as sources of not only electric power but also thermal energy will be discussed. For such a solution appeals most of all the need to limit harmful emissions of gases (including CO2) and ashes, which come from the process of burning fossil fuels, as well as the raising demand for network heat and chill. Additionally combined heat and power production brings measurable...
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Profitability criteria of partial cogeneration in nuclear power plant.
PublikacjaIn this paper, profitability criteria and calculation methodology of profitability conditions for partial cogeneration in nuclear power plant (NPP) was presented. Considered NPP supplies electricity to consumers through public power system, whereas heat is expected to be supplied to consumption regions via long-distance heat transport line. First proposed profitability criterion was total annual costs of electricity and heat delivered...
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Human Factors in Nuclear Power Engineering in Polish Conditions
PublikacjaThe paper “Human factors in nuclear power engineering in polish conditions” focuses on analysis of dynamics of preparing polish society to build fi rst nuclear power plant in XXI century in Poland. Authors compare experience from constructing nuclear power plant Sizewell B (Great Britain) and Sizewell C, which is in preparation phase with polish nuclear power program. Paper includes aspects e.g. of creating nuclear safety culture and...
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Self-Sensitized Photocatalytic Degradation of Colorless Organic Pollutants Attached to Rutile Nanorods—Experimental and Theoretical DFT+D Studies
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The Effect of AgInS2, SnS, CuS2, Bi2S3 Quantum Dots on the Surface Properties and Photocatalytic Activity of QDs-Sensitized TiO2 Composite
PublikacjaThe eect of type (AgInS2, SnS, CuS2, Bi2S3) and amount (5, 10, 15 wt%) of quantum dots (QDs) on the surface properties and photocatalytic activity of QDs-sensitized TiO2 composite, was investigated. AgInS2, SnS, CuS2, Bi2S3 QDs were obtained by hot-injection, sonochemical, microwave, and hot-injection method, respectively. To characterize of as-prepared samples high-resolution transmission electron microscopy (HRTEM), scanning...
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Ti/TiO2 nanotubes sensitized PbS quantum dots as photoelectrodes applied for decomposition of anticancer drugs under simulated solar energy
PublikacjaOne of the challenges in research into photoelectrocatalytic (PEC) degradation of pollutants is finding the appropriate photoanode material, which has a significant impact on the process efficiency. Among all others, photoelectrodes based on an ordered TiO2 nanotube arrays are a promising material due to well-developed surface area and efficient charge separation. To increase the PEC activity of this material, the SILAR method was...
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Identification of Mitochondrial DNA (NUMTs) in the Nuclear Genome of Daphnia magna
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Nuclear quantum effects in a HIV/cancer inhibitor: The case of ellipticine
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Novel Nuclear Functions of Arabidopsis ARGONAUTE1: Beyond RNA Interference
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Influence of operation of national experimental nuclear reactor on the natural environment
PublikacjaThis paper presents the impact of experimental nuclear reactor operations on the national environment, based on assessment reports of the radiological protection of active nuclear technology sources. Using the analysis of measurements carried out in the last 15 years, the trends are presented in selected elements of the environment on the Świerk Nuclear Centre site and its surroundings. In addition, the impact of research results...
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Numerical solution of fractional neutron point kinetics in nuclear reactor
PublikacjaThis paper presents results concerning solutions of the fractional neutron point kinetics model for a nuclear reactor. Proposed model consists of a bilinear system of fractional and ordinary differential equations. Three methods to solve the model are presented and compared. The first one entails application of discrete Grünwald-Letnikov definition of the fractional derivative in the model. Second involves building an analog scheme...