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Search results for: IRON-OXIDE GLASS
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Recent anode advances in Solid Oxide Fuel Cells
PublicationW pracy podsumowano bieżące doniesienia na temat potencjalnych materiałów anodowych dla wysokotemperaturowych tlenkowych ogniw paliwowych z uwzględnieniem wyników otrzymanych przez autora pracy.
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Exhaled nitric oxide in pediatric patients with respiratory disease
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Micro solid oxide fuel cells and their fabrication methods
PublicationW pracy przedstawiono obecny stan badań związany z tlenkowymi microogniwami paliwowymi oraz metodami ich wytwarzania.
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Quantum chemical modeling of electrochromism of tungsten oxide films
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Micro solid oxide fuel cells and their fabrication methods
PublicationW pracy przedstawiono obecny stan badań i tendencje w rozwoju tlenkowych ogniw paliwowych.
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A novel technology of solid oxide fuel cell fabrication
PublicationW pracy przedstawiono metodę wytwarzania wartstw i materiałów elektroceramicznych. Metoda jest kombinacją metod nanoszenia szkieletu z proszków ceramicznych i prekursorów polimerowych. Umożliwia ona otrzymanie zarówno gęstych jak i porowatych warstw i materiałów jednorodnych oraz kompozytowych. W pracy przedstawiono przykłady struktur dla tlenkowych ogniw paliwowych.
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Cellular uptake of biotransformed graphene oxide into lung cells
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The interference between electrode and poly(ethylene oxide) electrolytes
PublicationSpektroskopia impedancyjna zastosowana została do scharakteryzowania granicy faz elektroda-elektrolit poli(oksyetylenowy) zawierający sole litu. Udział rozpuszczalnika w pojemności wewnętrznej warstwy, Cs(σ), dla CH3(OCH2CH2 )nOCH3 DLA N=4,8,10 oraz dla PMEO [(CH2CH2O)mCH2O]m m=5-10 został wyznaczony z wartości pojemności warstwy sztywnej pomniejszonej o udział metalu CM. Wyznaczono wartość pojemności dipolowej Ci(dip) dla PEO...
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Solid oxide fuel cells for distributed energy generation
PublicationW pracy przedstawiono zasadę działania tlenkowego ogniwa paliwowego. Zaprezentowano wybrane problemy oraz rozwiązania technologiczne.
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Oxide Layers Fabricated by Spray Pyrolysis on Metallic Surfaces
Publicationw pracy przedstawiono wyniki badań nad opracowaniem optymalnych warunków przygotowania warstwy stabilizowanego itrem cyrkonu jako prekursora na stali 316L jako podłoża za pomocą pirolizy aerozolowej.
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Antibacterial properties of laser-encapsulated titanium oxide nanotubes decorated with nanosilver and covered with chitosan/Eudragit polymers
PublicationTo provide antibacterial properties, the titanium samples were subjected to electrochemical oxidation in the fluoride-containing diethylene glycol-based electrolyte to create a titanium oxide nanotubular surface. Afterward, the surface was covered by sputtering with silver 5 nm film, and the tops of the nanotubes were capped using laser treatment, resulting in an appearance of silver nanoparticles (AgNPs) of around 30 nm in diameter...
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Study on Combined Optical and Electrochemical Analysis Using Indium-tin-oxide-coated Optical Fiber Sensor
PublicationThe growing needs for fast and reliable sensing devices stimulate development of new technological solutions. In this work a new multi-domain sensing method is demonstrated where optical sensing device has been applied to enhance amount of data received during electrochemical analysis. Thin, optically transparent, high-refractive-index, and electrically conductive indium tin oxide (ITO) film was deposited using magnetron sputtering...
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Optical investigations of electrochemical processes using a long-period fiber grating functionalized by indium tin oxide
Publicationhe growing needs for fast and reliable sensing devices stimulate development of new technological solutions. In this work a new multi-domain sensing method is demonstrated where optical sensing device has been applied to enhance amount of data received during electrochemical analysis. Thin, optically transparent, high-refractive-index, and electrically conductive indium tin oxide (ITO) film was deposited using magnetron sputtering...
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Wpływ procesu redukcji na właściwości strukturalne i mechaniczne szkieł tlenkowych z grupy (Pb,Bi)-(Si,Ge)-O = Influence of reduction process on the structural and mechanical properties of (Pb,Bi)-(Si,Ge)-O oxide glasses
PublicationThe effect of the reduction process in H2 at 380 °C on the microstructure and elemental composition of a glass Bi0.4Pb0.2Si0.4Ox has been investigated. It has been shown that after reduction a clearly separated top layer with a thickness of approx. 50 µm was formed on the surface of the sample. This layer is depleted of oxygen and has higher electrical conductivity than the interior of the glass. It has also been found that some...
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Design and characterization of apatite La9.8Si5.7Mg0.3O26±δ-based micro-tubular solid oxide fuel cells
PublicationIn this study, electrolyte-supported (Cell A) and anode-supported (Cell B) micro-tubular solid oxide fuel cells (SOFCs) based on the La9.8Si5.7Mg0.3O26±δ (LSMO) electrolyte is built through an extrusion and dip-coating processes. The formulations and process conditions for these cells are established and optimized. Both cell configurations show no visible delamination or cracking, and reaction zones and inter-diffusion of any species...
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Low temperature processed MnCo2O4 and MnCo1.8Fe0.2O4 as effective protective coatings for solid oxide fuel cell interconnects at 750 °C
PublicationIn this study two materials, MnCo2O4 and MnCo1.8Fe0.2O4 are studied as potential protective coatings for Solid Oxide Fuel Cell interconnects working at 750 °C. First powder fabrication by a modified Pechini method is described followed by a description of the coating procedure. The protective action of the coating applied on Crofer 22 APU is evaluated by following the area specific resistance (ASR) of the scale/coating for 5500...
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Gas‐Phase Removal of Indoor Volatile Organic Compounds and Airborne Microorganisms Over Mono‐ and Bimetal‐Modified (Pt, Cu, Ag) Titanium(IV) Oxide Nanocomposites
PublicationThe photocatalytic deactivation of volatile organic compounds and mold fungi using TiO2 modified with mono‐ and bimetallic (Pt, Cu, Ag) particles is reported in this study. The mono‐ and bimetal‐modified (Pt, Cu, Ag) titanium(IV) oxide photocatalysts were prepared by chemical reduction method and characterized using XRD, XPS, DR/UV‐Vis, BET and TEM analysis. The effect of incident light, type and content of mono‐ and bimetallic...
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Anti-cancer effect of Rumex obtusifolius in combination with arginase/nitric oxide synthase inhibitors via downregulation of oxidative stress, inflammation, and polyamine synthesis
PublicationCancer continues to be a leading cause of death worldwide, making the development of new treatment methods crucial in the fight against it. With cancer incidence rates increasing worldwide, ongoing research must focus on identifying new and effective ways to prevent and treat the disease. The combination of herbal extracts with chemotherapeutic agents has gained much interest as a novel strategy to combat cancer. Rumex obtusifolius...
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Evolution of the optical properties of chromium doped calcium tetraborate glass under high pressure
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The anisotropic photorefractive effect in lithium sulfo-phosphate glass system doped with nickel ions
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(Bi,Pb)-Sr-Ca-Cu-O glass-ceramics - superconductor and granular metal
PublicationW materiale o składzie (Bi,Pb)-Sr-Ca-Cu-O wskutek stosowania różnych warunków wytwarzania można otrzymać materiały o różnorodnych właściwościach. W efekcie wygrzewania materiał amorficzny częściowo krystalizuje. To powoduje wzrost rozmiaru i zawartości przewodzących i nadprzewodzących granul oraz zmniejszenie szerokości izolujących barier pomiędzy granulami. Zależność temperaturowa oporu słabo skrystalizowanego materiału jest funkcją...
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Graffiti saves birds: A year-round pattern of bird collisions with glass bus shelters
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Computer study of the lead-germanium alloy formation in over-reduced lead-germanate glass
PublicationPraca poświęcona jest badaniom dynamiczno-molekularnym struktury zredukowanego szkła ołowiowo-germanianowego o składzie 1Pb 1Ge 1GeO2. Analizie poddano strukturę matrycy szkła, GeO2 i osadzonej w niej fazy metalicznej, którą formują neutralne atomy Pb i Ge.
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The effect of low energy impact on the tensile strength of coated and uncoated glass particulate composites.
PublicationPrzedstawiono model teoretyczny pozwalający przewidywać poudarową wytrzymałość na rozciąganie w funkcji parametrów materiałowych i budowy kompozytu. Określono eksperymentalnie poudarową wytrzymałość na ściskanie kompozytów zbrojonych ciągłym włóknem szklanym w osnowie żywicy epoksydowej napełnianej mikrokulkami szklanymi w celu obniżenia skłonności do powstawania dużych zniszczeń przy udarze o niskiej energii. Wyniki eksperymentalnie...
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Characterization of Mechanical and Bactericidal Properties of Cement Mortars Containing Waste Glass Aggregate and Nanomaterials
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Electro-optical transducer based on indium-tin-oxide-coated optical fiber for analysis of ionized media
PublicationThe paper introduces a concept of an optical fiber based electro-optical transducer for monitoring of ionized media, such as low-temperature plasma. It utilizes optical fiber with a section of a core coated with tailored indium tin oxide (ITO) thin film and thus combines the optical phenomena of lossy-mode resonance (LMR) with the electrostatic probe. ITO is an optically transparent and electrically conductive material and if its...
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Electrochemical performance of indium-tin-oxide-coated lossy-mode resonance optical fiber sensor
PublicationAnalysis of liquids performed in multiple domain, e.g., optical and electrochemical (EC), has recently focus significant attention. Our previous works have shown that a simple device based on indium-tin-oxide (ITO) coated optical fiber core may be used for optical monitoring of EC processes. At satisfying optical properties and thickness of ITO a lossy-mode resonance (LMR) effect can be obtained and used for monitoring of optical...
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Processing of Ce0.8Gd0.2O2-δ barrier layers for solid oxide cells: The effect of preparation method and thickness on the interdiffusion and electrochemical performance
PublicationCe0.8Gd0.2O1.9 (CGO) barrier layers are required to mitigate the chemical reactions between Sr-containing oxygen electrode materials and Zr-based oxygen ion conductors in high-temperature solid oxide cells. Barrier layers produced by different methods were studied in this work. As a reference, a cell with no barrier layer was measured. The application of the powder-processed barrier layers, considerably increases the performance....
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Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad
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Application of TOF-SIMS Method in the Study of Wetting the Iron (111) Surface with Promoter Oxides
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Modeling of effect of plastic deformation on Barkhausen noise and magnetoacoustic emission in iron with 2% silicon
PublicationW modelowaniu zaadaptowano model Alessandro-Beatrice-Bertotti-Montorsi dla opisu ruchu granic nie-180 stopniowych oraz model Jiles-Atherton dla opisu wpływu plastycznej deformacji na natężenie efektu Barkhausena oraz emisji magnetoakustcznej.
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Iron-based catalysts under solar and visible radiation for contaminants of emerging concern removal
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Liver steatosis correlates with iron overload but not with HFE gene mutations in chronic hepatitis C
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The role of MR imaging in detection of hepatic iron overload in patients with cirrhosis of different origins
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Fulminant hepatic failure in woman with iron and non-steroidal anti-inflammatory drug intoxication
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Covalent mechanochemical functionalization of carbon-encapsulated iron nanoparticles towards the improvement of their colloidal stability
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Graphene-encapsulated iron nanoparticles as a non-viral vector for gene delivery into melanoma cells
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Impact of methane occurrence on iron speciation in the sediments of the Gdansk Basin (Southern Baltic Sea)
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A tribological research on a reciprocating sliding contact of aluminum-ferrous composite against cast-iron.
PublicationOpisano badania kompozytów: silumin AlSi11-żelazo albo silumin AlSi11-stal narzędziowa N9 (otrzymanych in situ), a także samego siluminu AlSi11 w skojarzeniu z żeliwem 350, przy tarciu ślizgowym w ruchu posuwisto-zwrotnym. Stwierdzono wpływ sposobu otrzymywania materiału kompozytowego na zużycie i opory ruchu skojarzenia badawczego, w szczególności materiały te zużywały się wolniej, niż silumin AlSi11.
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Comparative study on homogeneity, filling ratio and purity of iron filled multiwalled carbon nanostructures
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Electroactive heterojunctions of iron-based compounds in oxygen evolution reaction—Insight into synergy and mechanism
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Evaluation of Barkhausen Noise and Magnetoacoustic Emission Signals Properties for Plastically Deformed Armco Iron
PublicationArtykuł prezentuje wyniki badania wpływu różnych rodzajów deformacji plastycznej na właściwości magnetoakustyczne żelaza Armco. Badane były dwie serie próbek - pierwsza składała się ze wstępnie wyżarzonych próbek, które następnie były walcowane na zimno, w skład drugiej wchodziły natomiast próbki wycięte z komercyjnie dostępnej blachy wykonanej z żelaza Armco a następnie poddane obciążeniom rozciągającym. Walcowanie na zimno prowadzi...
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Investigation of thin perovskite layers between cathode and doped ceria used as buffer layer in solid oxide fuel cells
PublicationIn this paper, thin perovskite layers between cathode material of solid oxide fuel cells and gadolinia-doped ceria buffer layer are investigated. Thin layers made of LaNi0.6Fe0.4O3-δ (LNF), La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF), or SrTi0.65Fe0.35O3-δ (STF) were symmetrically deposited by spin coating method from metallo-organic polymer precursors on a Ce0.8Gd0.2O2-δ (CGO) substrate. Porous and about 40-μm-thick LNF cathodes were deposited...
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Tuning Electrochemical Performance by Microstructural Optimization of the Nanocrystalline Functional Oxygen Electrode Layer for Solid Oxide Cells
PublicationFurther development of solid oxide fuel cell (SOFC) oxygen electrodes can be achieved through improvements in oxygen electrode design by microstructure miniaturisation alongside nanomaterials implementation. In this work, improved electrochemical performance of an La0.6Sr0.4Co0.2Fe0.8O3-d (LSCF) cathode was achieved by the controlled modification of the La0.6Sr0.4CoO3-d (LSC) nanocrystalline interlayer introduced between a porous...
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An algorithm for selecting a machine learning method for predicting nitrous oxide emissions in municipal wastewater treatment plants
PublicationThis study presents an advanced algorithm for selecting machine learning (ML) models for nitrous oxide (N2O) emission prediction in wastewater treatment plants (WWTPs) employing the activated sludge process. The examined ML models comprised multivariate adaptive regression spline (MARS), support vector machines (SVM), and extreme gradient boosting (XGboost). The study explores the concept that involves new criteria to select the...
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Improvement of Oxygen Electrode Performance of Intermediate Temperature Solid Oxide Cells by Spray Pyrolysis Deposited Active Layers
PublicationIntermediate temperature solid oxide fuel cells oxygen electrodes are modified by active interfacial layers. Spray pyrolysis is used to produce thin (≈500 nm) layers of mixed ionic and electronic conductors: Sm0.5Sr0.5CoO3−δ (SSC), La0.6Sr0.4CoO3−δ (LSC), La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF), and Pr6O11 (PrOx) on the electrode–electrolyte interface. The influence of the annealing temperature on the electrode polarization (area specific...
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Electrophoretic co-deposition of Fe2O3 and Mn1,5Co1,5O4: Processing and oxidation performance of Fe-doped Mn-Co coatings for solid oxide cell interconnects
PublicationThe “in-situ” Fe-doping of the manganese cobalt spinel was achieved by electrophoretic co-deposition of Mn1,5Co1,5O4 and Fe2O3 powders followed by a two-step reactive sintering treatment. The effects on the coating properties of two different Fe-doping levels (5 and 10 wt.% respectively) and two different temperatures of the reducing treatment (900 and 1000 °C) are discussed. Samples with Fe-doped coatings demonstrated a lower...
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Effects of La0.8Sr0.2MnO3 and Ag electrodes on bismuth-oxide-based low-temperature solid electrolyte oxygen generators
PublicationIn this study, La0.8Sr0.2MnO3 (LSM) was used as the ceramic electrode in a (Bi1.50Y0.50)0.98Zr0.04O3+δ (BYO)-based solid electrolyte oxygen generator (SEOG) and its performance was compared with that of a previously studied high-fire Ag electrode. Among La0.6Sr0.4Co0.2Fe0.8O3, LaNi0.6Fe0.4O3, Cu1.4Mn1.6O4, and LSM materials, only LSM materials did not trigger any chemical reaction or interdiffusion with BYO at temperatures up to...
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Hydration phase diagram for sodium cobalt oxide Na0.3CoO2·yH2O
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Electron scattering by trimethylene oxide, c-(CH2)3O, molecules
PublicationZmierzono całkowity przekrój czynny na rozproszenie elektronów na drobinach c-(CH2)3O w zakresie energii 1 - 400 eV. Wyniki porównano z elastycznymi i jonizacyjnymi przekrojami czynnymi obliczonymi dla tej drobiny. Przedyskutowano energetyczną zależność całkowitego przekroju czynnego na rozproszenie dla rodziny eterów cyklicznych (CH2)nO, n=2-4.