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Search results for: ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY
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Enhanced capacitance of composite TiO2 nanotube / boron-doped diamond electrodes studied by impedance spectroscopy
PublicationWe report on the novel composite nanostructures based on boron-doped diamond thin film grown on top of TiO2 nanotubes. The nanostructures made of BDD-modified titania nanotubes showed an increase in activity and performance when used as electrodes in electrochemical environments. The BDD thin films (~200-500 nm) were deposited using microwave plasma assisted chemical vapor deposition (MW PA CVD) onto anodically fabricated TiO2...
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Influence of sintering temperature of porous SrTi0.30Fe0.70O3-d oxygen electrode on electrochemical impedance spectroscopy spectra measured at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at different temperatures (800 °C; 900 °C and 1000 °C). Measure temperature was 800 °C (syntetic air, 40 ml min-1). Results converted to electrode surfaces area and dived by two electrodes.
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Influence of sintering temperature of porous SrTi0.50Fe0.50O3-d oxygen electrode on electrochemical impedance spectroscopy spectra measured at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.50Fe0.50O3-d oxygen electrodes sintered at different temperatures (800 °C; 900 °C and 1000 °C). Measure temperature was 800 °C (syntetic air, 40 ml min-1). Results converted to electrode surfaces area and dived by two electrodes.
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Influence of sintering temperature of porous SrTi0.65Fe0.35O3-d oxygen electrode on electrochemical impedance spectroscopy spectra measured at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.65Fe0.35O3-d oxygen electrodes sintered at different temperatures (800 °C; 900 °C and 1000 °C). Measure temperature was 800 °C (syntetic air, 40 ml min-1). Results converted to electrode surfaces area and dived by two electrodes.
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Electrochemical impedance spectroscopy spectra measured at 700 °C on porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at different temperatures
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at different temperaturs (800 °C, 900 °C and 1000 °C). EIS spectra were measured at 700 °C with synthetic air flow (21% O2, 40 ml min-1). Results converted to electrode surfaces area and dived by two...
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Electrochemical impedance spectroscopy spectra measured at 700 °C on porous SrTi0.65Fe0.35O3-d oxygen electrodes sintered at different temperatures
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.65Fe0.35O3-d oxygen electrodes sintered at different temperaturs (800 °C, 900 °C and 1000 °C). EIS spectra were measured at 700 °C with synthetic air flow (21% O2, 40 ml min-1). Results converted to electrode surfaces area and dived by two...
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Electrochemical impedance spectroscopy spectra measured at 700 °C on porous SrTi0.50Fe0.50O3-d oxygen electrodes sintered at different temperatures
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.50Fe0.50O3-d oxygen electrodes sintered at different temperaturs (800 °C, 900 °C and 1000 °C). EIS spectra were measured at 700 °C with synthetic air flow (21% O2, 40 ml min-1). Results converted to electrode surfaces area and dived by two...
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Carbon nanotube based dielectric spectroscopy of tumor secretion; electrochemical lipidomics for cancer diagnosis
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Impedance spectroscopy of BaTiO3 cubes suspended in lossy liquids as a physical model of two-phase system
PublicationTechniki spektroskopii impedancyjnej zostały wykorzystane do analizy modelu fizycznego w układzie dwufazowym w celu wyznaczanie stałej dielektrycznej dielektryka umieszczonego w cieczy. Badania eksperymentalne przeprowadzono z użyciem BaTiO3 jako materiału dielektrycznego, który został przygotowany jako kostki o jednakowej wielkości 2x2x1 mm3.
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Dynamic elektrochemical impedance spectroscopy measurements of passive layer cracking under static tensile stresses.
PublicationDynamiczna elektrochemiczna spektroskopia impedancyjna umożliwia badanie podatności i odporności korozyjnej różnych materiałów konstrukcyjnych, a w szczególności określenie właściwości elektrochemicznych warstw pasywnych występujących na ich powierzchni. W wielu przypadkach pęknięcie warstwy pasywnej pod wpływem działania naprężeń rozciągających prowadzi do korozji naprężeniowej. Z tego względu badania pękania warstw pasywnych...
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Enhanced capacitance of composite TiO2 nanotube/boron-doped diamond electrodes studied by impedance spectroscopy
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Determination of pseudocapacitance chan ges of nickel oxide NiO electrode with use of dynamic electrochemical impedancje spectroscopy
PublicationThe electrochemical capacitors (ECs) are attractive energy storage devices which can be applied in many electronic products (e.g., cameras, laptops, cell phones) or hybrid electric vehicles (HEV). The energy storage in ECs is based on capacitive (the electrical double layer charging/discharging) and pseudocapacitive (additional charge provided by faradic reaction) phenomena. Considering the electrodes exhibiting pseudocapacitance,...
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Electrochemical properties of porous Sr0.86Ti0.65Fe0.35O3 oxygen electrodes in solid oxide cells: Impedance study of symmetrical electrodes
PublicationThis work evaluates porous Sr0.86Ti0.65Fe0.35O3 (STF35) as a possible oxygen electrode material for Solid Oxide Cells. The powder synthesis was performed by solid state method. Characterization included DC electrical conductivity study of sintered bulk samples and impedance spectroscopy study of symmetrical electrodes deposited on gadolinium doped ceria substrates. Measurements were carried out in atmospheres with different pO2...
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Impedance spectroscopy studies on hybrid materials consisting of poly(3,4-ethylenedioxythiophene) and iron, cobalt and nickel hexacyanoferrate
PublicationBadania warstw polimeru pEDOT modyfikowanego heksacyjanożelazianami żelaza, kobaltu i niklu przeprowadzono za pomocą spektroskopii impedancyjnej (SI). Wykazano, że materiały hybrydowe charakteryzują się dobrą stabilnością. Warstwy testowano w zakresie temperatur od 283 do 313K. w kontakcie z wodnym roztworem KCl. Wysokie współczynniki dyfuzji wskazują na możliwości wykorzystania układów jako przewodników jonowych.
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Evaluation of cavitation erosion–corrosion degradation of mild steel by means of dynamic impedance spectroscopy in galvanostatic mode
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Evaluation of cavitation erosion-corrosion degradation of mild steel by means of Dynamic Impedance Spectroscopy in galvanostatic mode
PublicationPrzedstawiono wyniki badań degradacji stali węglowych na skutek oddziaływania erozji-korozji kawitacyjnej. Do analizy wykorzystano technikę Dynamicznej Elektrochemicznej Spektroskopii Impedancyjnej w trybie galwanostatycznym, bliżej odwzrorowującym warunki naturalne. Do oceny stopnia degradacji posłużyły również funkcja ubytku masy MDPR oraz obrazy mikroskopowe SEM. Potwierdzono wpływ łączonej degradacji erozyjno-korozyjnej na...
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Electrical and mechanical characterization of two-phase alloys by means of scanning probe microscopy in dynamic impedance spectroscopy mode
PublicationDynamic impedance spectroscopy, evaluated for measuring non-stationary systems, was used in combination with scanning probe microscope. Using this approach, localized impedance measurements in the AFM contact mode could be carried out. Additionally, impedance–force curves were made at each phase of investigated materials to illustrate the relation between impedance and the force applied to a probe. Therefore, correlation of electrical...
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Unique agreement of experimental and computational infrared spectroscopy: a case study of lithium bromide solvation in an important electrochemical solvent
PublicationInfrared (IR) spectroscopy is a widely used and invaluable tool in the studies of solvation phenomena in electrolyte solutions. Using state-of-the-art chemometric analysis of a spectral series measured in a concentration-dependent manner, the spectrum of the solute-affected solvent can be extracted, providing a detailed view of the structural and energetic states of the solvent molecules influenced by the solute. Concurrently,...
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Electrochemical impedance spectroscopy spectra measured at 800 °C, 750 °C and 700 °C on porous SrTi0.50Fe0.50O3-d oxygen electrode sintered at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.50Fe0.50O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 800 °C; 750°C and 700 °C (synthetic air). Results converted to electrode surfaces area and dived by two electrodes.
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Electrochemical impedance spectroscopy spectra measured at 800 °C, 750 °C and 700 °C on porous SrTi0.65Fe0.35O3-d oxygen electrode sintered at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.65Fe0.35O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 800 °C; 750°C and 700 °C (synthetic air). Results converted to electrode surfaces area and dived by two electrodes.
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Electrochemical impedance spectroscopy spectra measured at 800 °C, 750 °C and 700 °C on porous SrTi0.30Fe0.70O3-d oxygen electrode sintered at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 800 °C; 750°C and 700 °C (synthetic air). Results converted to electrode surfaces area and dived by two electrodes.
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Solid State Conductivity of Optimized Polypyrrole Coatings on Iron Obtained from Aqueous Sodium Salicylate Solution Determined by Impedance Spectroscopy
PublicationIn this work the optimization procedure for corrosion resistance, surface analysis and electrical properties of PPy-Fe electrodes have been examined. Polypyrrole (PPy) film was electrochemically synthesized in a one step process from an aqueous solution of sodium salicylate and pyrrole with certain concentrations, different parameters and type of polymerization...
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Electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for porous SrTi0.30Fe0.70O3-d oxygen electrode measured at 800 °C and 15% oxygen partial pressure
Open Research DataThis dataset contains electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for symmetrical cell with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 800 °C and 15% of oxygen partial pressure. Spectra of two RCPE elements from equivalent circuit , are also included....
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Electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for porous SrTi0.30Fe0.70O3-d oxygen electrode measured at 600 °C and 15% oxygen partial pressure
Open Research DataThis dataset contains electrochemical impedance spectroscopy and Distribution of Relaxation Times results for symmetrical cell with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 600 °C and 15% of oxygen partial pressure. Spectra of two RCPE elements from equivalent circuit , are also included. Results converted...
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Electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for porous SrTi0.30Fe0.70O3-d oxygen electrode measured at 700 °C and 15% oxygen partial pressure
Open Research DataThis dataset contains electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for symmetrical cell with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 700 °C and 15% of oxygen partial pressure. Spectra of two RCPE elements from equivalent circuit , are also included....
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Electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for porous SrTi0.30Fe0.70O3-d oxygen electrode measured at 700 °C and 100% oxygen partial pressure
Open Research DataThis dataset contains electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for symmetrical cell with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 700 °C and 100% of oxygen partial pressure. Spectra of two RCPE elements from equivalent circuit , are also included....
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Electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for porous SrTi0.30Fe0.70O3-d oxygen electrode measured at 700 °C and 20% oxygen partial pressure
Open Research DataThis dataset contains electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for symmetrical cell with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 700 °C and 20% of oxygen partial pressure. Spectra of two RCPE elements from equivalent circuit , are also included....
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Electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for porous SrTi0.30Fe0.70O3-d oxygen electrode measured at 700 °C and 5% oxygen partial pressure
Open Research DataThis dataset contains electrochemical impedance spectroscopy and Distribution of Relaxation Times analysis results for symmetrical cell with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 700 °C and 5% of oxygen partial pressure. Spectra of two RCPE elements from equivalent circuit , are also included. Results...
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Impedance spectroscopy as a diagnostic tool of degradation of Solid Oxide Fuel Cells = Spektroskopia impedancyjna jako narzędzie diagnostyczne degradacji tlenkowych ogniw paliwowych
PublicationTlenkowe ogniwa paliwowe SOFC sa obecnie bliskie komercjalizacji. Wiedza na temat mechanizmów degradacji ogniw paliwowych jest niezbędna do dalszej poprawy ich działania. Spektroskopia impedancyjna jest skutecznym narzędziem diagnostycznym. Pozwala ona na wskazanie który element ogniwa SOFC ulega pogorszeniu oraz pozwala poznać dokładniej naturę procesu degradacji. W tej pracy degradacja ogniwa SOFC została zbadana przy użyciu...
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Electrochemical cell impedance spectra at Eoc
Open Research DataThe dataset presents impedance spectrum of electrochemical cell filled with 3% NaCl solution presented in the figure below. This cell was used measured using Atlas-Sollich 0531 impedance analyser with built-in potentiostat. When changing the DC polarisation of the cell the non-linear phenomena could be observed. The impedance spectrum frequency range...
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Impedance Evaluation of the Effect of Ru[sub 0.3]Ti[sub 0.7]O[sub 2] on Electrochemical Properties of Polymeric Conducting Electrodes Used in Cathodic Protection
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Electrochemical cell impedance spectra at Eoc+100mV
Open Research DataThe dataset presents impedance spectrum of electrochemical cell filled with 3% NaCl solution presented in the figure below. This cell was used measured using Atlas-Sollich 0531 impedance analyser with built-in potentiostat. When changing the DC polarisation of the cell the non-linear phenomena could be observed. The impedance spectrum frequency range...
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Electrochemical cell impedance spectra at Eoc+200mV
Open Research DataThe dataset presents impedance spectrum of electrochemical cell filled with 3% NaCl solution presented in the figure below. This cell was used measured using Atlas-Sollich 0531 impedance analyser with built-in potentiostat. When changing the DC polarisation of the cell the non-linear phenomena could be observed. The impedance spectrum frequency range...
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Electrochemical cell impedance spectra at Eoc-100mV
Open Research DataThe dataset presents impedance spectrum of electrochemical cell filled with 3% NaCl solution presented in the figure below. This cell was used measured using Atlas-Sollich 0531 impedance analyser with built-in potentiostat. When changing the DC polarisation of the cell the non-linear phenomena could be observed. The impedance spectrum frequency range...
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Electrochemical cell impedance spectra at Eoc-200mV
Open Research DataThe dataset presents impedance spectrum of electrochemical cell filled with 3% NaCl solution presented in the figure below. This cell was used measured using Atlas-Sollich 0531 impedance analyser with built-in potentiostat. When changing the DC polarisation of the cell the non-linear phenomena could be observed. The impedance spectrum frequency range...
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Adsorption behavior and corrosion inhibitive characteristics of newly synthesized cyano-benzylidene xanthenes on copper/sodium hydroxide interface: Electrochemical, X-ray photoelectron spectroscopy and theoretical studies
PublicationElegant process for synthesis of 3-(7H-dibenzo[c,h]xanthen-7-yl)benzaldehyde (3), as new starting material to create a set of novel xanthene analogues, 2-(3-(7H-dibenzo[c,h]xanthen-7-yl)benzylidene)malononitrile (4), 3-(3-(7H-dibenzo[c,h]xanthen-7-yl)phenyl)-2-cyanoacrylic acid (5), and Ethyl-3-(3-(7H-dibenzo[c,h]xanthen-7-yl)phenyl)-2-cyanoacrylate (6), was achieved starting with available materials under mild conditions. Various...
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Electrochemical impedance spectra and CV curves of V2O5 nanocrystals
Open Research DataThe DataSet contains the EIS spectra for coin-cells and CV curves with the V2O5 nanocrystals obtained by the sol-gel method. Cyclic voltammetry and electrochemical impedance spectroscopy (EIS) were measured using the AUTOLAB 302N potentiostat-galvanostat under Nova software. The EIS measurements were recorded in the frequency range 100 kHz to 10 mHz...
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Electrochemical impedance spectra and CV curves of V2O5 nanorods
Open Research DataThe DataSet contains the EIS spectra for coin-cells and CV curves with the V2O5 nanorods obtained by the sol-gel method. Cyclic voltammetry and electrochemical impedance spectroscopy (EIS) were measured using the AUTOLAB 302N potentiostat-galvanostat under Nova software. The EIS measurements were recorded in the frequency range 100 kHz to 10 mHz for...
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Linear impedance of Bi2VO5.5 glass-ceramic measured with impedance spectroscopy method at low temperature region
Open Research DataThe linear electrical properties of Bi2VO5.5 glass-ceramic prepared by traditional melt quenching technique was measured by impedance spectroscopy method.
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Linear impedance of strontium–borate glass measured with impedance spectroscopy method at low temperature region
Open Research DataThe linear electrcial properties of strontium–borate glass was measured by impedance spectroscopy method.
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Linear impedance of strontium–borate glass measured with impedance spectroscopy method at high temperature region
Open Research DataThe linear electrcial properties of strontium–borate glass was measured by impedance spectroscopy method.
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Linear impedance of 50Bi2VO5.5-50SrB4O7 glass measured with impedance spectroscopy method at low temperature region
Open Research DataThe linear electrcial properties of 50Bi2VO5.5-50SrB4O7 glass was measured by impedance spectroscopy method.
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Nonlinear impedance of 50Bi2VO5.5-50SrB4O7 glass measured with impedance spectroscopy method at low temperature region
Open Research DataThe nonlinear electrcial properties of 50(Bi2VO5.5)-50SrB4O7 glass was measured by impedance spectroscopy method.
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Nonlinear impedance of 35Bi2VO5.5-65SrB4O7 glass measured with impedance spectroscopy method at high temperature region
Open Research DataThe nonlinear electrcial properties of 35Bi2VO5.5-65SrB4O7 glass was measured by impedance spectroscopy method.
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Nonlinear impedance of 30Bi2VO5.5-70SrB4O7 glass measured with impedance spectroscopy method at high temperature region
Open Research DataThe nonlinear electrcial properties of 30Bi2VO5.5-70SrB4O7 glass was measured by impedance spectroscopy method.
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Nonlinear impedance of 50Bi2VO5.5-50SrB4O7 glass measured with impedance spectroscopy method at high temperature region
Open Research DataThe nonlinear electrcial properties of 50(Bi2VO5.5)-50SrB4O7 glass was measured by impedance spectroscopy method.
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Nonlinear impedance of 45Bi2VO5.5-55SrB4O7 glass measured with impedance spectroscopy method at high temperature region
Open Research DataThe nonlinear electrcial properties of 45Bi2VO5.5-55SrB4O7 glass was measured by impedance spectroscopy method.
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Impedance spectroscopy of the lithium titanate doped by copper thin films
Open Research DataLithium titanate doped by copper thin films were derived by sol-gel method. Prepared gel was deposited by spin-coating technique. Samples with various content of Cu were measured by impedance spectroscopy method in a wide range of temperature, from -120 up to 150 deg.
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Linear impedance of 40Na2O-20CaO-40P2O5 glass measured with impedance spectroscopy method at low temperature region
Open Research DataThe linear electrical properties of 40Na2O-20CaO-40P2O5 glass was measured by impedance spectroscopy method.
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Nonlinear impedance of as-quenched Bi2VO5.5 glass-ceramic was measured with impedance spectroscopy method at low temperature region
Open Research DataThe nonlinear electrical properties of as-quenched Bi2VO5.5 glass-ceramic was measured by impedance spectroscopy method.