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Search results for: ORGANOMETALLIC CHEMISTRY
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Preparation of soil and sediment samples for the determination of organometallic compounds
PublicationZwiązki metaloorganiczne są szeroko stosowane niemal we wszystkich gałęziach przemysłu. W wyniku ich emisji, zarówno ze źródeł naturalnych jak i antropogenicznych, nastąpiło ich rozprzestrzenienie w środowisku, w którym ulegają szeregowi przemian chemicznych. Niektóre z tych związków charakteryzują się wysoką toksycznością. W oparciu o literaturę naukową dotyczącą procedur oznaczania wybranych związków metaloorganicznych rtęci,...
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Organometallic block copolymers as catalyst precursors for templated carbon nanotube growth.
PublicationArtykuł przedstawia zastosowanie organometalicznych kopolimerów blokowych jako prekursorów katalizatorów dla syntezy nanorurek węglowych. Zjawisko mikroseparacji fazowej kopolimerów blokowych zostało wykorzystane dla przygotowania matrycy aktywnych katalitycznie domen o rozmiarach ~20 nm. Domeny zawierające poli(ferrocenylosilan) (PFS) po utlenienu w plazmie tlenowej oraz redukcji z Fe(III) do Fe(II) oraz Fe(0) z powodzeniem katalizują...
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Green Chemistry Metrics with Special Reference to Green Analytical Chemistry
PublicationThe concept of green chemistry is widely recognized in chemical laboratories. To properly measure an environmental impact of chemical processes, dedicated assessment tools are required. This paper summarizes the current state of knowledge in the field of development of green chemistry and green analytical chemistry metrics. The diverse methods used for evaluation of the greenness of organic synthesis, such as eco-footprint, E-Factor,...
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Analytical chemistry with biosolvents
PublicationOne of the current trends in green analytical chemistry is the introduction of green solvents, some of which are biobased. At the same time, the development of the biorefinery concept has allowed more biochemicals to be obtained with increased efficiency and from a wider range of feedstocks. The first examples of the use of biosolvents in analytical applications included extractions performed with alcohols, esters, and terpenes....
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Green and equitable analytical chemistry
PublicationGreen analytical chemistry introduces the ideas of reduction ofanalytical activities impact on the environment. However, to bemore sustainable, analytical chemistry should include socialaspects in greater manner. In this light‘equitable’analyticalprocedures, which are easily available in terms of price andapplicability by everyday user, are developed. These positivetrends are observed as many procedures, based on commonlyused for...
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Metrics for green analytical chemistry
PublicationGreen analytical chemistry, although not being a new concept, does not have a greenness metrics system. Green chemistry metrics are not suitable for analytical procedure assessment because they often refer to the mass of the product. Some efforts have been made to develop suitable metrics for analytical chemistry. Some are simple to use but do not cover all aspects of analytical methods’ environmental impact. Others are more comprehensive...
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Statistical optimization of the synthesis of plant-derived fatty acid esters of TMP over homogeneous organometallic tin catalyst
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Chemistry Innovations and Ideas from the Classroom to the Real World: The Students’ Perspective on Becoming a Chemistry Entrepreneur
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Green analytical chemistry metrics: A review
PublicationGreen analytical chemistry encourages reducing the use of toxic chemicals/reagents, using energy-efficient equipment, and generating minimal waste. The recent trends in analytical method development focus on the miniaturization of the sample preparation devices, the development of solventless or solvent-minimized extraction techniques, and the utilization of less toxic solvents. The twelve principles of GAC serve as a basic guideline...
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Liquid Crystals in Analytical Chemistry: A Review
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Teaching of Analytical Chemistry in Polisch Universities
PublicationChemia Analityczna zajmuje się poszukiwaniem i opracowywaniem optymalnych strategii (metod i urządzeń) pozwalających na uzyskiwanie miarodajnych informacji dotyczących chemicznej natury różnych obiektów znajdujących się w naszym otoczeniu i przebiegających w nich procesach. Wykorzystanie informacji analitycznej jest bardzo szerokie. Otrzymany wynik jest towarem, tym droższym im jest bardziej miarodajny. Chemik analityk odpowiada...
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Green analytical chemistry : theory and practice
PublicationThis tutorial review summarises the current state of green analytical chemistry with special emphasis on environmentally friendly sample preparation techniques. Green analytical chemistry is a part of the sustainable development concept; its history and origins are described. Miniaturisation of analytical devices and shortening the time elapsing between performing analysis and obtaining reliable analytical results are important...
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Introduction to Green Chemistry, by Albert Matlack
PublicationTemat tzw. ''zielonej chemii'' zyskuje coraz większą uwagę dlatego też wiekszośc uczelni skupia się na jego znaczeniu. Media coraz częściej podejmują ten temat i dzięki temu następuje powolny ale stopniowy wzrost świadomości społeczeństwa dlatego też skomentowana ksiązka wypełnia pustkę w klasycznej literaturze chemicznej.
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History and Milestones of Green Analytical Chemistry
PublicationDue to the increased environmental consciousness, Green Analytical Chemistry (GAC) is an important concept steadily gaining popularity, as its implementation facilitates the decrease the detrimental effect analytical chemistry methodologies may have on the environment. In this chapter, a brief overview of the history of Green Analytical Chemistry (GAC) and its milestones was given. Emphasis has been put on the beginnings of green...
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Greener organic solvents in analytical chemistry
PublicationThe paper presents the most recent advances in analytical applications of greener organic solvents. Substitution of problematic solvents with more benign organic ones is much easier than shifting to technique applying alternative solvents, such as ionic liquids or supercritical fluids. In the area of liquid chromatography greener mobile phases, much attention is given to application ethanol or acetone instead of acetonitrile. Solvent-based...
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The role of analytical chemistry in the study of the Anthropocene
PublicationThe term “Anthropocene” refers to not yet formalized epoch of geologic time during which geologic processes have been dominated by the human impact. This impact takes on many forms. Biological, physical and chemical changes to the Earth System caused by anthropogenic activity are recorded in natural archives either as new fossil assemblages (neobiota), anthropogenic deposits or a wide variety of pollutants emitted to the environment....
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Green Chemistry - current and future issues
PublicationW pracy przedstawiono 12 zasad Zielonej Chemii oraz wybrane przykłady stosowania zasad w życiu codziennym, przemyśle, laboratoriach i edukacji. Pokrótce opisano historię Zielonej Chemii oraz przyszłe wyzwania. ZCH dotyczy nowego podejścia do zagadnienia syntezy, przeróbki i wykorzystania związków chemicznych, związanego ze zmniejszeniem zagrożenia dla zdrowia i środowiska. Istnieje wiele publikacji opisujących metodyki analityczne...
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Green analytical chemistry: Social dimension and teaching
PublicationGreen Analytical Chemistry (GAC) is the idea which every analytical chemist should be familiar of. Due to continuous improvement in the subject both from the aspects of theory and experimentation, the dynamic way analytical chemistry studies are evolving in the frame of chemistry degrees should not be surprising. Recently, many efforts have been made in order to include Green Chemistry principles to Education, also in the field...
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Metal–Organic Frameworks in Green Analytical Chemistry
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Functionalization of graphene: does the organic chemistry matter?
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Hepatoprotective effect of quercetin: From chemistry to medicine
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COLOUR TERMS IN INORGANIC CHEMISTRY: A CORPUS STUDY
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Dew chemistry near a motorway in SW Poland
PublicationW artykule wykazano wpływ bliskości autostrady na wydajność tworzenia się rosy i jej skład chemiczny. Badania przeprowadzono w pobliżu autostrady A4 w Polsce SW. Obszar badań miał charakter lekko pofalowanej równiny intensywnie użytkowanej rolniczo. Do kolekcji osadów wykorzystano płaskie, pasywne kolektory radiacyjne. Dwa z nich (AN i AS) zlokalizowane były w bezpośrednim sąsiedztwie drogi (30 m) po obu jej stronach, natomiast...
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Urban dew formation efficiency and chemistry in Poland
PublicationThe measurements of dew formation efficiency and chemistry were performed in Poland in September 2009, as a part of a longer, two-year sampling campaign. Pairs of sites, representing centers of major Polish cities and rural conditions in three different regions, were compared. With the aim to get more detailed landuse-oriented characteristics of dew, two additional sites were set close to Wroclaw. Collection of dew at each site...
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3-MCPD: A worldwide problem of food chemistry
Publication3-MCPD is a heat-induced food contaminant which has been widely investigated for decades. This paper presents an overview of current knowledge about 3-MCPD including its formation routes, occurrence in various foodstuffs, analytical approach, toxicological aspects and future research perspectives. So far 3-MCPD was determined in its free and bound form in thermally-treated foods, edible oils and fats, and infant foods including...
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Dew Formation and Chemistry Near a Motorway in Poland
PublicationIn this study, the influence of traffic intensity on dewformation efficiency and chemistry is presented. The measurementswere conducted near the A4 motorway in SW Poland in almost flatland relief with intense agricultural activity. The dew/hoarfrost wascollected by means of insulated plain passive radiative condensersat three sites: AN and AS located in the close vicinity of themotorway (30 m) on the opposite sides of the road,...
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Green Analytical Chemistry Approaches in Sample Preparation
PublicationThis chapter presents environmentally friendly solutions for sample preparation. Attention is focused on extraction techniques and the minimization of organic solvent consumption, as the large quantitiesused in analytical laboratories are a pressing environmental problem. Solventless sample preparation techniques, alternative solvents, mediated extractions are discussed. The principle of each technique isbriefly described, together...
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Mussel‐inspired biomaterials: From chemistry to clinic
PublicationAfter several billions of years, nature still makes decisions on its own to identify, develop, and direct the most effective material for phenomena/challenges faced. Likewise, and inspired by the nature, we learned how to take steps in developing new technologies and materials innovations. Wet and strong adhesion by Mytilidae mussels (among which Mytilus edulis—blue mussel and Mytilus californianus—California mussel are the most...
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Metal-Organic Frameworks in Green Analytical Chemistry
PublicationTaking into consideration the rapid expansion of MOFs applications in the analytical chemistry area, it is important to evaluate the existing and future analytical MOF-based methods according to GAC principles. From this point of view, eco-friendly MOFs-based methods should include features such as: green design and synthesis of MOF, evaluation of toxicity issues of MOFs, and incorporation of MOFs in GAC methods. This Chapter will...
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Safe-by-Design Ligand-Coated ZnO Nanocrystals Engineered by an Organometallic Approach: Unique Physicochemical Properties and Low Toxicity toward Lung Cells
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Application of deep eutectic solvents (DES) in analytical chemistry
PublicationRecent years have been associated with efforts to reduce the impact on the natural environment. A greener approach has been introduced in various areas of science, including analytical chemistry. One of the basic procedures for preparing a sample for analysis is its extraction. Traditional methods involve the use of large amounts of organic compounds, often toxic, with an unfavorable impact on the environment. A representative...
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Chemometrics approaches to green analytical chemistry procedure development
PublicationChemometric tools are widely used in analytical chemistry for the reduction of data dimensionality, grouping of variables and processing of analytical signals. They have also the potential to be applied in analytical procedure development with the aim of minimizing the procedure’s environmental impact. The design of experiment gives the possibility to obtain much better information on the system response than in case of “changing...
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Selection of Effective HTRA3 Activators Using Combinatorial Chemistry
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Cyclic Peptidic Furin Inhibitors Developed by Combinatorial Chemistry
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Direct chromatographic methods in the context of green analytical chemistry
PublicationWe review analytical protocols based on gas and liquid chromatography (GC and LC), but involving no sample preparation.Green analytical chemistry seeks to minimize negative impacts of analytical chemistry. Direct analytical methods ideally fulfillthis requirement, as they preclude sample preparation - the most polluting step of the analytical procedure.We describe examples of GC methodologies for environmental and food analysis...
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Surface chemistry aspects of fluorosurfactants as components in AFFF preparation
PublicationZbadano właściwości powierzchniowe fluorowanych surfaktantów anionowych a także roztworów środków pianotwórczych na bazie fluorowanych surfaktantów stosowanych w gaszeniu pożarów substancji ropopochodnych ze szczególnym uwzględnieniem ich zdolności do obniżania napięć międzyfazowych. Wyselekcjonowana para surfaktantów wykazała się wysoką zdolnością obniżania napięć międzyfazowych na granicy faz olej-woda, porównywalną z roztworami...
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Scholarly communication activities in the fields of chemistry and economics. A Polish perspective
PublicationThis study examines the scholarly communication activities in two scientific fields, chemistry and economics, in a Polish context. The dissertation aims at investigating what characterises the publishing choices of researchers and what supplementary forms for the dissemination of research output are used by scholars. In addition, the paper is looking into what are the views and awareness of open access and institutional repositories...
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Green Analytical Chemistry: Summary of Existing Knowledge and Future Trends
PublicationAnalysis of recent publications in green analytical chemistry shows the current trends and future needs in this area. The main issues are related with search for cheaper, more efficient, more accurate, greener and miniaturized alternatives. Miniaturization is perhaps, the most notable current trend in analytical chemistry. Rapid developments and improvements in instrumentation have led to impressive range of benchtop technology...
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Green analytical chemistry as an integral part of sustainable education development
PublicationGreen chemistry is an important way of thinking in the field of chemistry and aims to conduct processes in accordance with the principles of sustainable development. It is the application of a wide range of principles that minimize the impact of both chemical processes and products on the environment. And what about analytical chemistry? Without a doubt, analytical chemistry plays an important role in the sustainable development...
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Chemistry of non-precipitation components of wet deposition with Poland as an example
PublicationW pracy przedstawiono badania dotyczące chemizmu osadów atmosferycznych pobieranych na terenie Polski w okresie od 2004 do 2007 roku. Średni skład jonowy (TIC) dla rosy, szronu i mgły (w stanie ciekłym i stałym) wynosił odpowiednio 2147, 1929 i 1014 µeq/l, gdzie typowy skład jonowy TIC dla opadów atmosferycznych wynosi 318 µeq/l. Dla wszystkich typów osadów atmosferycznych różne jony pełnią ważną rolę: Ca2+ i SO42-...
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Magnetic Covalent Organic Frameworks—Fundamentals and Applications in Analytical Chemistry
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New insights into the application of MSPD in various fields of analytical chemistry
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Green Analytical Chemistry in Determination of Volatile Fatty Acids in Wastewater
PublicationCharakterystyka metodyk oznaczania lotnych kwasów tłuszczowych w próbkach wodnych, opierających się na Zasadach Zielonej Chemii. Opis zastosowania techniki bezpośredniego dozowania próbki wodnej do chromatografu gazowego, techniki analizy fazy nadpowierzchniowej oraz techniki mikroestrakcji do fazy stacjonarnej.
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Remarks on use of the term “deep eutectic solvent” in analytical chemistry
PublicationAbout 20 years ago, Abbott and co-workers researched new solvents that were based on mixtures of choline chloride with urea and carboxylic acids and that were liquid at ambient temperature. The term “deep eutectic solvent” (DES) was later adopted for similar mixtures. As DESs have a number of interesting features, they quickly attracted the attention of researchers and found application in various branches of chemical and materials...
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Dew and hoarfrost frequency, formation efficiency and chemistry in Wroclaw, Poland
PublicationThis article presents the results of a research study concerning a comparison of frequency, formation efficiency and basic physico-chemical properties of dew and hoarfrost in urban conditions. Longer than two-year series of measurements was carried out from 1 February 2008 to 10 March 2010 in Wroclaw, Poland. Sampling of atmospheric deposits was made by means of insulated plain passive radiative condensers, which allowed to collect...
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Environmental Role of Rime Chemistry at Selected Mountain Sites in Poland
PublicationThe results of field experiments on fog pollutantdeposition enhanced by local mountain climate, completed by thedendrochronological analysis of the forest response, are presentedin this paper. In spite of their low absolute altitude (1,000-1,600 ma.s.l), the Sudetes and the Silesian Beskid form a noticeable orographicbarrier for the airflow of the humid Atlantic air masses.This results in the increase of cloudiness and fog frequency...
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Green Chemistry in Higher Education: State of the Art, Challenges, and Future Trends
PublicationNowadays, there is increasing interest in global sustainability, and thus, university students would like to know how human actions affect the health status of our planet. This is mainly due to their basic knowledge of problems such as global warming and greenhouse gases. Students would like to gain knowledge on how to safeguard the earth for future generations. This must involve changes in education programs at interested institutions...
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Chemometrics for Selection, Prediction, and Classification of Sustainable Solutions for Green Chemistry—A Review
PublicationIn this review, we present the applications of chemometric techniques for green and sustainable chemistry. The techniques, such as cluster analysis, principal component analysis, artificial neural networks, and multivariate ranking techniques, are applied for dealing with missing data, grouping or classification purposes, selection of green material, or processes. The areas of application are mainly finding sustainable solutions...
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Rime and hoarfrost chemistry in Poland - an introductory analysis from meteorological perspective
PublicationPróbki szronu i sadzi pobierano odpowiednio w 6 i 3 miejscach, które reprezentują zarówno nizinne jak i górzyste części Polski. Niższe stężenia jonów stwierdzono zarówno w próbkach szronu jak i sadzi pobranych na terenie nizinnym. Wynika to ze stosunkowo wysokiej inwersji temperatury i mniej intensywnego krążenia atmosferycznego w tym regionie. Stwierdzono również różne wartości stosunku Na/Cl w próbkach sadzi i szronu zebranych...
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Green analytical chemistry in sample preparation for determination of trace organic pollutants
PublicationW pracy przedstawiono przyjazne środowisku techniki analityczne, stosowane w celu izolacji i wzbogacania analitów. Ilość używanych rozpuszczalników jest ograniczana przez stosowanie alternatwnych rozpuszczalników, technik bezrozpuszczalnikowych, ekstrakcji wspomaganych czynnikami zewnętrznymi oraz przez wprowadzanie mikrosystemów analitycznych.