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Search results for: HOMOGENEOUS CATALYSIS
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Catalysts
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Comparison of the Efficiency of Hetero- and Homogeneous Catalysts in Cellulose Liquefaction
PublicationBiomass liquefaction is a well-known and extensively described process. Hydrothermal processes are well understood and can be used in the fuel industry. The use of organic solvents can result in full-fledged products for use in the synthesis of polyurethanes. The plastics industry, including polyurethanes, is targeting new, more environmentally friendly solutions. One of these is the replacement of petrochemical polyols with compounds...
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A review on homogeneous and heterogeneous catalytic microalgal lipid extraction and transesterification for biofuel production
PublicationExtracting lipids from microalgal biomass presents significant potential as a cost-effective approach for clean energy generation. This can be achieved through the chemical conversion of lipids to produce fatty acid methyl esters via transesterification. The extraction mainly involves free fatty acids, phospholipids, and triglycerides, and requires less energy, making it an attractive option for satisfying the growing demand for...
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Synthesis of Fatty Acid Esters of Selected Higher Polyols Over Homogeneous Metallic Catalysts
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Local variance factors in deformation analysis of non-homogenous monitoring networks
PublicationThis paper proposes a modification of the classical deformation analysis algorithm for non-homogeneous (e.g. linear-angular) monitoring networks. The basis for the proposed solution is the idea of local variance factors. The theoretical discussion was complemented with an example of its application on a simulated horizontal monitoring network. The obtained results confirm the usefulness of the proposed solution.
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Conventional and advanced bending strength analysis of common and castellated, homogeneous and hybrid I-beams
PublicationAnaliza wytrzymałości na zginanie belek dwuteowych
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Valorisation of bioplastics synthesised by liquefaction of celluloseusing hetero- and homogeneous catalysts
Open Research DataThe purpose of the present study was to test the effectiveness of a heterogeneous catalyst such as Nafion ion-exchange resin on the cellulose liquefaction process. The results obtained were compared with the bio-polyols obtained in a conventional way, using a homogeneous catalyst (sulfuric acid (VI)). Depending on the catalyst used and the temperature...
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Rigorous Modal Analysis of Structures Containing Inhomogeneous Dielectric Cylinders.
PublicationW pracy wykorzystano zmodyfikowaną procedurę iteracyjną i metodę dopasowania rodzajów w celu analizy struktur zawierających asymetrycznie umieszczone, niepełnej wysokości lub wielowarstwowe, niejednorodne, cylindryczne rezonatory dielektryczne. Analiza bazuje na nowatorskiej koncepcji zwanej hybrydową macierzą impedancyjną (HIM - hybryd impedancje matrix), która opisuje relacje pomiędzy całkowitym polem elektrycznym i magnetycznym...
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Measurements of fundamental properties of homogeneous tissue phantoms
PublicationWe present the optical measurement techniques used in human skin phantom studies. Their accuracy and the sources of errors in microscopic parameters’ estimation of the produced phantoms are described. We have produced optical phantoms for the purpose of simulating human skin tissue at the wavelength of 930 nm. Optical coherence tomography was used to measure the thickness and surface roughness and to detect the internal inhomogeneities....
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APPLIED CATALYSIS B-ENVIRONMENTAL
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CATALYSIS TODAY
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Modeling of the acoustic waves propagation in non-homogeneous medium
PublicationRozważano zagadnienie propagacji fal w ośrodku niejednorodnym. Przedstawiono model matematyczny i przykładowe wyniki badań numerycznych. Model matematyczny zbudowano w oparciu o równanie KZK. Do rozwiązania zagadnienia zastosowano metodę różnic skończonych. Badano zmiany ciśnienia i zmiany widma odpowiednio w ośrodku jednorodnym i niejednorodnym.
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Vibration based damage localization in non-homogeneous structures
PublicationPrzedmiotem badań jest identyfikacja lokalnych uszkodzeń w konstrukcjach budowlanych. Przedstawione są trzy metody bazujące na teorii drgań. Są to metody badające: częstości własne, podatność i krzywizny postaci drgań układu. Skuteczność metod pokazana jest na przykładach symulacji komputerowych, wykonanych dla belki swobodnie podpartej, wspornikowej oraz podwieszonej kładki dla pieszych. Dodatkowo zaprezentowane są wyniki badań...
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Statistical optimization of the synthesis of plant-derived fatty acid esters of TMP over homogeneous organometallic tin catalyst
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SMOTE-Based Homogeneous Ensemble Methods for Software Defect Prediction
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Secondary emission influenced fluorescence decay of a homogeneous fluorophore solution
PublicationAn analytical expression is found allowing the calculation of the secondary emission influenced fluorescence decay of a homogeneous fluorophore solution. Before starting the calculation one has to know the shape of the primary fluorescence decay of the fluorophore and the value of the parameter kappa denoting the ratio of the secondary to primary steady-state fluorescence intensities. The method elaborated by Budo and Ketskemety...
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Inhomogeneous broadening ofCr3+luminescence in dopedLiTaO3
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Tree-based homogeneous ensemble model with feature selection for diabetic retinopathy prediction
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Understanding homogenous nucleation: the recent phenomenological and molecular dynamic approaches
PublicationPraca przedstawia dwa podejścia do problemu homogenicznej nukleacji. Pierwsze jest podejściem fenomenologicznym. Nukleacja jest tu rozumiana jako wzrost kropel krytycznych, które po przejściu określonego wymiaru, warunku równowagi termodynamicznej, mają tendencje do wzrostu. W tym podejściu problem wzrostu kropel oraz problem populacji kropel jest określany poprzez parametry makroskopowe. Przedstawiono nowe rozwiązania uzyskane...
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Inhomogeneous broadening of the dominant Cr3+sites in LiTaO3 system
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Canonical perturbation theory for inhomogeneous systems of interacting fermions
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Homogeneous nucleation rate of methane hydrate formation under experimental conditions from seeding simulations
PublicationIn this work, we shall estimate via computer simulations the homogeneous nucleation rate for the methane hydrate at 400 bars for a supercooling of about 35 K. The TIP4P/ICE model and a Lennard-Jones center were used for water and methane, respectively. To estimate the nucleation rate, the seeding technique was employed. Clusters of the methane hydrate of different sizes were inserted into the aqueous phase of a two-phase gas–liquid...
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CATALYSIS LETTERS
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Identification of Shear Modulus Parameters of Half-space Inhomogeneous by Depth
PublicationThe paper propose a method for determining of the parameters of the exponential shear modulus of a functionally graded half-space based on the solution of the problem of a pure shear of an elastic functionally graded half-space by a strip punch. The solution of the integral equation of the contact problem is constructed by asymptotic methods with respect to the dimensionless parameter. The dependence of contact stresses on the...
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Kinetics of the photosensitized degradation of benzyl 4-hydroxybenzoate in homogeneous aqueous solution under visible-light irradiation
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Combination of homogeneous liquid–liquid extraction and vortex assisted dispersive liquid–liquid microextraction for the extraction and analysis of ochratoxin A in dried fruit samples: Central composite design optimization
PublicationThis paper presents a new analytical procedure based on combination of homogeneous liquid–liquid extraction (HLLE) and vortex-assisted dispersive liquid–liquid microextraction (VA-DLLME) for the accurate and reliable determination of ochratoxin A (OTA) in dried fruit samples. To enable selective extraction of the OTA, six hydrophobic deep eutectic solvents (hDESs) were prepared and tested as extraction solvents. Optimization of...
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ENGINEERING FAILURE ANALYSIS
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ACS Catalysis
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JOURNAL OF CATALYSIS
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APPLIED CATALYSIS A-GENERAL
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Are Radiosensitive and Regular Response Cells Homogeneous in Their Correlations Between Copy Number State and Surviving Fraction After Irradiation?
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Physical properties of homogeneous TiO2films prepared by high power impulse magnetron sputtering as a function of crystallographic phase and nanostructure
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Physical properties of homogeneous TiO2 films prepared by high power impulse magnetron sputtering as a function of crystallographic phase and nanostructure
PublicationOptical, photo-electrochemical, crystallographic and morphological properties of TiO2 thin films prepared by high power impulse magnetron sputtering at low substrate temperatures (<65 ◦C) without post-deposition thermal annealing are studied. The film composition-anatase, rutile or amorphous TiO2-is adjusted by the pressure (p ∼ 0.75-15 Pa) in the deposition chamber. The different crystallographic phases were determined with grazing...
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Piecewise continuous distribution function method in the theory of wave disturbances of inhomogeneous gas
PublicationUkład równań typu hydrodynamicznego dla warstwowych gazów w polu grawitacyjnym pochodzi od równania BGK metodą częściowej ciągłej funkcji dystrybucji. Otrzymany system równań uogólnia układ Naviera-Stokesa w dowolnych liczbach Knudsena.
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CATALYSIS COMMUNICATIONS
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Phyloproteomic study by MALDI-TOF MS in view of intraspecies variation in a significant homogenous phytopathogen Dickeya solani
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Noise level arrangement in determined zones of homogenous development of green areas on the example of the spa park in Inowrocław
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Effect of grain roughness on strength, volume changes, elastic and dissipated energies during quasi-static homogeneous triaxial compression using DEM
PublicationArtykuł omawia wpływ szorstkości ziaren na wytrzymałość, zmiany objętościowe, sprężyste i dysypywane energie podczas jednorodnego quasi-statycznego trójosiowego ściskania. Obliczenia wykonano stosując metodę elementów dyskretnych. W obliczeniach zastosowano różne szorstkości ziaren.
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Advances in Catalysis
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Catalysis in Industry
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KINETICS AND CATALYSIS
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Accuracy of parameter identification using the dispersion of surface waves and the role of data quality for inhomogeneous concrete
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Sweeping of hydrophobic amines under inhomogeneous electric field and low surfactant concentration in micellar electrokinetic chromatography
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On nonlinear 3D electro-elastic numerical modeling of two-phase inhomogeneous FG piezocomposites reinforced with GNPs
PublicationThe novelty here comes from not only the perfect nonlinear three-dimensional (3D) electro-elasticity investigation but also the mixed material itself. The literature widely showed mechanical assessments on the piezoelectric structures; however, a lack of nonlinear three-dimensional elasticity studies has been witnessed on these kinds of smart materials. Therefore, a nonlinear 3D elasticity-piezoelectricity coupling is considered...
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Catalysis Science & Technology
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Diffraction of a Gaussian beam in a three-dimensional smoothly inhomogeneous medium: an eikonal-based complex geometrical-optics approach
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Molecular Catalysis
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Reaction Kinetics Mechanisms and Catalysis
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Particle swarm optimization–artificial neural network modeling and optimization of leachable zinc from flour samples by miniaturized homogenous liquid–liquid microextraction
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Catalysis Structure & Reactivity
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