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Wyniki wyszukiwania dla: GEOLOGICZNE SKŁADOWANIE CO2
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Yields and Time-of-Flight Spectra of Neutral High-Rydberg Fragments at the K Edges of the CO2 Molecule
PublikacjaWe have studied the production of neutral fragments in high-Rydberg (HR) states at the C 1s and O 1s edges of the CO2 molecule by performing two kinds of experiments. First, the yields of neutral HR fragments were measured indirectly by ionizing such fragments in a static electric field and by collecting resulting singly charged positive ions as a function of the photon energy. Such measurements reveal not only excitations below...
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All solid state electrodes taste sensor with modified polymer membranes for discrimination of mineral water with different CO2 content
PublikacjaA potentiometric taste sensor with All Solid State Electrodes containing five all solid state electrodes with appropriate lipophilic compounds (benzyldimethyltetradecylammonium chloride, dodecyltrimethylammonium bromide, palmitic acid, stearic acid, and phytol) embedded in a polymer membrane was applied for discrimination of mineral water samples differed in CO2 content. Samples of still, slightly sparkling, and sparkling Naleczowianka...
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Zr‐Based Metal‐Organic Framework UiO‐66/Ultem® 1000 Membranes for Effective CO2/H2 Separation
PublikacjaMixed-matrix membranes (MMMs) using UiO-66 nanofillers as dispersing inorganic phase and polyetherimide (PEI) as continuous polymeric matrix were synthesized. Different UiO-66 loadings of 10, 20, and 30 wt % were applied. The morphology and UiO-66 dispersion over the prepared MMMs were examined. Gas separation measurements were performed for H2/CO2 gas mixture to evaluate the influence of UiO-66 on the separation yield of resulting...
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Zastosowanie unieruchomionych ciekłych membran z cieczami jonowymi w procesach separacji CO2
PublikacjaPrzedmiotem pracy jest efektywność przenikania CO2 i CH4 przez ciekłe membrany z cieczami jonowymi osadzonymi na nośnika polimerowych. Jako fazę membranową zastosowano imidazoliowe ciecz jonowe będące kombinacją kationu o różnej długości podstawnika alkilowego oraz różnych anionów [Tf2N][, [TfO],[BF4] i [PF6]. Porównano szybkość permeacji obu gazów w układzie laboratoryjnym, gdzie powierzchnia membrany wynosiła 13cm2.
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Surface treatment of C80U steel by long CO2 laser pulses
PublikacjaThe paper presents the results of laser-melted C80U steel. The processed steel was placed between two permanent magnets and laser beam whose scanning velocity was 10 mm/s. CO2 laser beam was working in pulse mode. Pulses were generated at 100% of the average preset power of 700W, with 45 ms irradiation, zero interval between pulses and beginning of pulse repetition upon the achievement of the average laser power. During the operation,...
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Thermodynamic Analysis of Negative CO2 Emission Power Plant Using Aspen Plus, Aspen Hysys, and Ebsilon Software
PublikacjaAbstract: The article presents results of thermodynamic analysis using a zero-dimensional mathematical models of a negative CO2 emission power plant. The developed cycle of a negative CO2 emission power plant allows the production of electricity using gasified sewage sludge as a main fuel. The negative emission can be achieved by the use this type of fuel which is already a “zeroemissive” energy source. Together with carbon capture...
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User-assisted methodology targeted for building structure interpretable QSPR models for boosting CO2 capture with ionic liquids
PublikacjaTask-specific ionic liquid (IL) is an emerging class of compounds that may be environmentally friendly. Properly selected, these compounds may be green alternative to amine solutions and can replace them in post-combustion carbon dioxide (CO2) capture processes on an industrial scale. However, owing to the vast diversity of ions and their possible combinations, laboratory research is time consuming and expensive. Therefore, computational...
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CO2 capture using steam ejector condenser under electro hydrodynamic actuator with non-condensable gas and cyclone separator: A numerical study
PublikacjaThe concept for condensation of steam and CO2 separation in a negative CO2 emission gas power plant involves the utilization of a steam ejector condenser (SEC) for direct-contact condensation of vapor with inert gas (CO2) on a spray of subcooled liquid, integrated with a separator to produce pure CO2. Due to the increasing diffusion resistance and reduced convective heat transfer between the steam and subcooled water phases...
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Emission of CO2 and Fuel Consumption for Automotive Vehicles
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Computational Fluid Dynamics Simulation of Gas–Liquid Multiphase Flow in T-junction for CO2 Separation
PublikacjaThe article presents the results of a computational fluid dynamics (CFD) analysis of gas-liquid multiphase flow. The simulation was conducted using CFD code and the Euler–Euler approach. The presented study relates to the non–reactive, steady-state, turbulent flow of water and carbon dioxide mixture in a 3D pipe. Separation phenomenon between phases is observed. The solution was obtained using a mixture model. Different values...
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Evaluation of the reference fuel consumption and CO2 emission of vehicle with using of the map of operating conditions for selected agglomeration
PublikacjaZaproponowana w pracy metoda tworzenia mapy warunków eksploatacji dla wybranej aglomeracji może zostać przeprowadzona przy wykorzystaniu tanich i prostych w obsłudze urządzeń. Podstawowym urządzeniem badawczym jest pojazd samochodowy wyposażony w system pomiaru położenia GPS z układem korekty wskazań wysokości i rejestracji parametrów jazdy. Zamieszczony w pracy przykład wykorzystania mapy warunków eksploatacji pokazuje możliwości...
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Wymiana i składowanie danych multimedialnych (lato 2021/2022)
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An influence of molecular weight, deacetylation degree of chitosan xerogels on their antimicrobial activity and cytotoxicity. Comparison of chitosan materials obtained using lactic acid and CO2 saturation.
PublikacjaThis paper presents a comparison of the antimicrobial activity and cytotoxicity against L929 cells of chitosan xerogels prepared by dissolving the polymer in a solution of lactic acid (LA) or carbonic acid (CO2) and then freeze-drying. There was no simple relationship between the antimicrobial activity and cytotoxicity of the samples obtained using both techniques (LA and CO2). Chitosan materials obtained by the LA method in a...
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Spatial distribution of CO2, O2, CO, NO and temperature within a biowaste composting pile
Dane BadawczeThe dataset contains the color-coded isophlets illustrating the spatial distribution of gas concentrations (CO, CO2, O2 and NO) and the temperature in biowaste composting pile during 6 weeks of process. Four cross sections and two longitudinal cross sections (the left and right sides of the pile) were made using Surfer 10 software (Golden Software,...
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Hybrid geothermal-fossil power cycle analysis in a Polish setting with a focus on off-design performance and CO2 emissions reductions
PublikacjaGrowing demand for electricity due to economic development contributes to increased greenhouse gas production, especially CO2. However, emissions can be limited by enhancing the efficiency of primary energy conversion, such as integrating geothermal energy into coal-fired power plants. Therefore, this paper proposes replacing conventional feed-water heaters with geothermal preheaters to create a hybridized system. This study was...
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Influence of selected CO2 absorption promoters on the characteristics of calcium carbonate particles produced by carbonation of the post-distillation liquid from the Solvay process
PublikacjaThe aim of this work is to compare the effect of selected process parameters, gas flow rate, CO2 absorption promoter concentration and its pKa, on the precipitation of CaCO3 by the gas-liquid method using a model post-distillation liquid from the Solvay process. To ensure effective capture of CO2, the absorption promoters used were ammonia, triethanolamine and triethylamine. The Box-Behnken Design was applied to plan the experiments....
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Separation of CO2 from biogas using absorption columns
PublikacjaBiogaz zawiera ok. 50-70% metanu, 30-40% di tlenku węgla oraz niewielkie ilości innych związków jak siarkowodór czy amoniaku. Dla uzyskania wysokokalorycznego gazu konieczne jest usunięcie ze strumienia di tlenku węgla. Praca opisuje potencjał użycia do tego celu kolumn absorpcyjnych oraz cieczy jonowych jako absorbenta
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MOF-5 derived carbon as material for CO2 absorption
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Combined operation of 900MW power plant with the ORC through the bleed steam extraction point and CO2 recovery system
PublikacjaThe work presented here is aimed at utylisation of waste heat in the reference supercritical power plant in the manner to produce electricity in ORC installation. The waste heat is available in the form of a stream of hot water at 90 C, recovered from the exhaust gases in the amount of 200MW. Such low enthalpy heat source is rather insufficient to produce a good quality vapour to feed the ORC turbine. Therefore an original approach...
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Reduction of CO2 Emissions from Offshore Combined Cycle Diesel Engine-Steam Turbine Power Plant Powered by Alternative Fuels
PublikacjaDiverse forms of environmental pollution arise with the introduction of materials or energy that exert adverse effects on human health, climate patterns, ecosystems, and beyond. Rigorous emission regulations for gases resulting from fuel combustion are being enforced by the European Union and the International Maritime Organization (IMO), directed at maritime sectors to mitigate emissions of SOx, NOx, and CO2. The IMO envisions...
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High-temperature Co-electrolysis of CO2/H2O and direct methanation over Co-impregnated SOEC. Bimetallic synergy between Co and Ni
PublikacjaTo study the synergy between the transition metals for enhancing the electrochemical and chemical activity, a series of SOECs were modified with a small amount of Co ions, namely 1.8, 3.6, and 5.4 wt% in the reduced state. The addition of βCD into the precursor solution allowed for extremely fine dispersion of Co species across the Ni-YSZ cermet structure. The sample containing 3.6 wt% Co reached an outstanding over 2.5-times-higher...
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Preparation and characterization of genipin cross-linked porous chitosan–collagen–gelatin scaffolds using chitosan–CO2 solution
PublikacjaNovel porous scaffolds composed of chitosan, collagen and gelatin were prepared by the multistep procedure involving final freeze-drying and characterized. To eliminate the need for residual acid removal from the material after drying, carbon dioxide saturation process was used for chitosan blend formulation. The use of CO2 for chitosan dissolution made the scaffold preparation process more reproducible and economically sustainable....
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Analiza procesu rozdrabniania biomateriałów w młynie walcowym z płytą międzywalcową w ujęciu emisji CO2. Część II**. Ocena emisji CO2
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Euilibrium composition of CH4-CO2-CO-H2-H2O-C system under biogas reforming conditions
Dane BadawczeThe equilibrium compositions of CH4, CO2, CO, H2, H2O and C under the biogas mixture reforming were supplied with this dataset
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CO2 Adsorption Study of Potassium-Based Activation of Carbon Spheres
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Correction: MOF-5 derived carbon as material for CO2 adsorption
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O 1s excitation and ionization processes in the CO2 molecule studied via detection of low-energy fluorescence emission
PublikacjaOxygen 1s excitation and ionization processes in the CO2 molecule have been studied with dispersed and non-dispersed fluorescence spectroscopy as well as with the vacuum ultraviolet (VUV) photon-photoion coincidence technique. The intensity of the neutral O emission line at 845 nm shows particular sensitivity to core-to-Rydberg excitations and core-valence double excitations, while shape resonances are suppressed. In contrast,...
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Comparative study of a combined heat and power plant retrofitted by CO2 capture during the combustion of syngas from sewage sludge gasification versus zero-emission combustion of hydrogen produced using renewables
PublikacjaWith ecological requirements aimed at limiting the production of CO2, it is necessary to produce all, or most of the energy from RES. During the transformation process, ecological and highly efficient combustion power plants will be needed. The classic cycle of combined heat and power (CCGT) with green improvements will continue to be one of the most suitable technologies for this task. This article presents the modernization of...
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Exergy analysis of a negative CO2 emission gas power plant based on water oxy-combustion of syngas from sewage sludge gasification and CCS
PublikacjaA power cycle with water-injected oxy-combustion (water cycle) is investigated by exergy analysis. It is fueled with syngas (aka. producer gas) from gasification of sewage sludge. The cycle is equipped with a spray-ejector condenser (SEC). CO2 is separated and compressed for transportation and storage. The net delivered electric power is 31% of the fuel exergy. The task efficiency is 39% when the flue gas bleed to gasification...
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Obtaining and Characterization of the PLA/Chitosan Foams with Antimicrobial Properties Achieved by the Emulsification Combined with the Dissolution of Chitosan by CO2 Saturation
PublikacjaA new method of obtaining functional foam material has been proposed. The materials were created by mixing the poly lactic acid (PLA) solution in chloroform, chitosan (CS) dissolved in water saturated with CO2 and polyethylene glycol (PEG), and freeze-dried for removal of the solvents. The composite foams were characterized for their structural (SEM, FT-IR, density, porosity), thermal (DSC), functional (hardness, elasticity, swelling...
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Obtaining and Characterization of the PLA/Chitosan Foams with Antimicrobial Properties Achieved by the Emulsification Combined with the Dissolution of Chitosan by CO2 Saturation
PublikacjaA new method of obtaining functional foam material has been proposed. The materials were created by mixing the poly lactic acid (PLA) solution in chloroform, chitosan (CS) dissolved in water saturated with CO2 and polyethylene glycol (PEG), and freeze-dried for removal of the solvents. The composite foams were characterized for their structural (SEM, FT-IR, density, porosity), thermal (DSC), functional (hardness, elasticity, swelling...
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Euilibrium composition of CH4-CO2-CO-H2-H2O-C system under various compositions syngas methanation
Dane BadawczeThe equilibrium compositions of CH4, CO2, CO, H2, H2O and C under the methanation reaction of various syngas mixtures (different CO/H2 ratio) were supplied with this dataset
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CO2 adsorption isotherms on PCMCA-X (potassium citrate derived porous carbon materials obtained at various temperatures of carbonization)
Dane BadawczeThis dataset contains static CO2 adsorption isotherms on PCMCA-700 (potassium citrate derived porous carbon material obtained at 700 °C), PCMCA-800 (potassium citrate derived porous carbon material obtained at 800 °C), PCMCA -900 (potassium citrate derived porous carbon material obtained at 900 °C) adsorbents.
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CO2 uptake capacities of PCMCA-900 (potassium citrate-derived porous carbon prepared at 900 °C) adsorbent at various temperatures
Dane BadawczeThese data contain CO2 uptake capacities of PCMCA-900 (potassium citrate-derived porous carbon prepared at 900 °C) adsorbent at various temperatures. Adsorption experiments were carried out at temperatures 0 °C, 25 °C, and 50 °C at 1 bar.
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Preparation of Activated Carbon from the Biodegradable film for Co2 Capture Applications
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Surface characteristics of KOH-treated commercial carbons applied for CO2 adsorption
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ELECTROCHEMOTHERAPY COMBINED WITH STANDARD AND CO2 LASER SURGERIES IN CANINE ORAL MELANOMA
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Conductivity and viscosity changes of imidazolium ionic liquids induced by H2O and CO2
PublikacjaSeveral solutions of ionic liquids based on 1-ethyl-3-methylimidazolium cation saturated and unsaturated with carbon dioxide were prepared and characterized by electrochemical impedance spectroscopy. The in fluence of ILs saturation on its electrical conductivity was determined. Additionally, the in fluence of the water presence and variations of temperature on electrical properties of ionic liquids were investigated. Changes of...
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Amine-Based Ionic Liquid for CO2 Capture and Electrochemical or Thermal Regeneration
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The Effect of CO2 Gas Emissions on the Market Value, Price and Shares Returns
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Assessment, optimisation and working fluid comparison of organic rankine cycle combined with negative CO2 gas power plant system
PublikacjaThis study aims to investigate the application of the Organic Rankine Cycle (ORC) as an alternative to low-pressure expansion in the negative CO2 power plant (nCO2PP). The reason for this study is that a detailed analysis of nCO2PP indicates a certain amount of waste heat present in the exhaust gas from the high-to-intermediate pressure gas turbine. Some of this energy can be used by the application of the expansion in a low-pressure...
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Direct-contact condensation from vapour- gas mixture in a spray ejector condenser for negative CO2 power plant
PublikacjaDirect-contact condensation of vapour containing the inert gas on a spray of subcooled liquid exists in a number of technical applications. For example, it may be found in the nuclear industry (e.g. pressurized jet under normal operating conditions, in safety analyses) or in the chemical industry (e.g. mixing-type heat exchanger, degasser, sea water desalting). The problem is also essential to modelling and analysis of some...
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Ru/Al2O3 on Polymer-Derived SiC Foams as Structured Catalysts for CO2 Methanation
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Conventional and Alternative Sources of Thermal Energy in the Production of Cement—An Impact on CO2 Emission
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Euilibrium composition of CH4-CO2-CO-H2-H2O-C system under various compositions syngas methanation with 10% water vapour introduced
Dane BadawczeThe equilibrium compositions of CH4, CO2, CO, H2, H2O and C under the methanation reaction of various syngas mixtures (different CO/H2 ratio) were supplied with this dataset
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Euilibrium composition of CH4-CO2-CO-H2-H2O-C system under various compositions syngas methanation with 30vol.% water vapour introduced
Dane BadawczeThe equilibrium compositions of CH4, CO2, CO, H2, H2O and C under the methanation reaction of various syngas mixtures (different CO/H2 ratio) were supplied with this dataset
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Strącanie węglanu wapnia w kolumnowym reaktorze barbotażowym z CO2 jako reagentem
PublikacjaBadano przebieg procesu precypitacji węglanu wapnia z roztworu wodorotlenku wapnia za pomocą dwutlenku węgla w reaktorze typu airlift. Zbadano wpływ czasu nagazowania, prędkości przepływu dwultenku węgla i przepływu mieszaniny dwutlenku węgla i powietrza na wielkość otrzymywanych cząstek. W czasie procesu mierzono pH mieszaniny reakcyjnej oraz stopień zatrzymania gazu.
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Direct conversion of biomass to nanoporous activated biocarbons for high CO2 adsorption and supercapacitor applications
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Euilibrium composition of CH4-CO2-CO-H2-H2O-C system under various compositions syngas methanation with 20vol.% water vapour introduced
Dane BadawczeThe equilibrium compositions of CH4, CO2, CO, H2, H2O and C under the methanation reaction of various syngas mixtures (different CO/H2 ratio) were supplied with this dataset
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Effect of selected ammonia escape inhibitors on carbon dioxide capture and utilization via calcium carbonate precipitation
PublikacjaCarbon dioxide was used to precipitate CaCO3 with CaCl2 solution in the presence of NH3 as a CO2 absorption promoter. Compounds that were previously indicated as inhibitors of ammonia escape during CO2 absorption were also added to the reaction mixture. Inorganic salts, i.e. ZnCl2, CuCl2, CoCl2, and organic substances, i.e. glycerol, ethylene glycol and triethanolamine were tested inhibitors in this work. A model post-distillation...