Wyniki wyszukiwania dla: TOTAL ORGANIC CARBON (TOC)
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Application of chemometric approach in studies of dew chemistry (on the basis of samples collected in Poland)
PublikacjaPrzedstawiono wyniki badań wybranych związków chemicznych (aniony, kationy, formaldehyd, nadtlenek wodoru, suma fenoli, TC, TIC, TOC) oznaczonych w próbkach rosy zebranych z różnych obszarów na terenie Polski (Gdynia, Gdańsk, Sopot, Mława, Kraków). Zastosowano analizę funkcji dyskryminacyjnej aby dokonać klasyfikacji poszczególnych próbek w zależności od miejsca pobierania oraz wykryć podstawowe zależności pomiędzy poszczególnymi...
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Heterojunction of (P, S) co-doped g-C3N4 and 2D TiO2 for improved carbamazepine and acetaminophen photocatalytic degradation
PublikacjaNovel photocatalysts of phosphorus and sulfur co-doped graphitic carbon nitride incorporated in 2D TiO2 structure were successfully fabricated and applied for solar-driven degradation of emerging pollutants from the group of pharmaceuticals not susceptible to biodegradation. The hybrid photocatalysts with different loadings of (P, S)-doped g-C3N4 were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR),...
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Studies on the Presence and Spatial Distribution of Anthropogenic Pollution in the Glacial Basin of Scott Glacier in the Face of Climate Change (Fiord Bellsund, Spitsbergen)
PublikacjaThe study area covered the NW part of the Wedel Jarlsberg Land (SW part of the Svalbard Archipelago). The primary study object was the catchment of the Scott Glacier in the vicinity of the Research Station of of Maria Curie-Skłodowska University in Lublin – Calypsobyen. The Scott River catchment (of glacial hydrological regime) has an area of approximately 10 km2, 40% of which is occupied by the valley Scott Glacier in the phase...
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Metodyka Logicznego Wnioskowania w procesie realizacji zmiany.
PublikacjaRozdział ten jest poświecony problematyce możliwości wykorzystania metodyki i narzędzi Wnioskowania Logicznego w celu planowania i realizacji efektywnej zmiany. Przedstawiono w nim trzyetapowy model procesu Logicznego Wnioskowania i scharakteryzowano funkcje poszczególnych narzędzi. Zaprezentowano również przykłady budowy wybranych narzędzi TOC TP. W rozdziale przedstawiono ponadto miejsce poszczególnych narzędzi Logicznego Wnioskowania...
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AlP compound and P-doping for promotion of electrocatalytic activity of N-doped carbon derived from metal-organic framework
PublikacjaWater splitting plays a key role in future fuels, where two processes occur - the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). Nitrogen-doped carbon derived from...
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Elemental and water-insoluble organic carbon in Svalbard snow: a synthesis of observations during 2007–2018
PublikacjaLight-absorbing carbonaceous aerosols emitted by biomass or fossil fuel combustion can contribute to amplifying Arctic climate warming by lowering the albedo of snow. The Svalbard archipelago, being near to Europe and Russia, is particularly affected by these pollutants, and improved knowledge of their distribution in snow is needed to assess their impact. Here we present and synthesize new data obtained on Svalbard between 2007...
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Planowanie realizacji projektów w środowisku wieloprojektowym z wykorzystaniem metody łańcucha krytycznego
PublikacjaMetoda CCMPM (Critical Chain Multi Project Management) pozwala zarządzać projektami w środowisku wieloprojektowym zgodnie z zasadami teorii ograniczeń TOC. Poprzez zsynchronizowanie projektów względem terminów zadań wykorzystujących zasób ograniczający pozwala na maksymalne jego wyeksploatowanie. Bufor ograniczenia chroni termin wykonania zadania przez zasób ograniczający w kolejnym projekcie. W artykule przedstawiono...
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Numerical modeling of PFAS movement through the vadose zone: Influence of plant water uptake and soil organic carbon distribution
PublikacjaIn this study, we investigated the effects of soil organic carbon (SOC) distribution and water uptake by plant roots on PFAS movement in the vadose zone with a deep groundwater table under temperate, humid climate conditions. Two series of numerical simulations were performed with the HYDRUS computer code, representing the leaching of historical PFOS contamination and the infiltration of water contaminated with PFOA, respectively. We...
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Selected aspects of performance of organic Rankine cycles incorporated into bioenergy with carbon capture and storage using gasification of sewage sludge
PublikacjaThe study aims to investigate the application of the Organic Rankine Cycle (ORC) in the bioenergy with carbon capture and storage (BECCS) using gasification of sewage sludge. The tool used in the investigation is the Aspen Plus software with REFPROP property methods for calculating fluid properties. The reason for this study is that a detailed analysis of the proposed BECCS process flow diagram indicates that a certain amount of...
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Wykorzystanie metody planowania i sterowania produkcją zgodnej z Teorią Ograniczeń do optymalizacji procesu produkcyjnego
PublikacjaOptymalizacja procesu produkcyjnego nie jest mozliwa bez zastosowania odpowiedniej metody planowania i sterowania produkcją, dostosowanej do cech systemu produkcji i wymagań rynku. W artykule scharakteryzowano metodę werbel-bufor-linia zgodną z Teorią Ograniczeń i jej wpływ na parametry systemu produkcji. Przedstawiono algorytmy, któe umożliwiaja planować i sterować produkcją zgodnie z wymogami TOC i dostarczają informacji pozwalających...
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Wykorzystanie metody planowania i sterowania produkcją zgodnej z teorią ograniczeń do optymalizacji procesu produkcyjnego
PublikacjaOptymalizacja procesu produkcyjnego nie jest możliwa bez zastosowania odpowiedniej metody planowania i sterowania produkcją, dostosowanej do cech systemu produkcji i wymagań rynku. W artykule scharakteryzowano metodę werbel-bufor-lina zgodną z Teorią Ograniczeń i jej wpływ na parametry systemu produkcji. Przedstawiono algorytmy, które umożliwiają planować i sterować produkcją zgodnie z wymogami TOC i dostarczają informacji pozwalających...
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Plant–soil interactions in soil organic carbon sequestration as a restoration tool
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Particulate organic carbon in the southern Baltic Sea: numerical simulations and experimental data
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Stratification of particulate organic carbon and nitrogen in the Gdańsk Deep (Southern Baltic Sea)
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Do we need a catalyst in the determination of dissolved organic carbon in environmental samples?
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Wykorzystanie teorii ograniczeń do realizacji zasad koncepcji Lean
PublikacjaZłożone i dynamiczne otoczenie wymaga nieustannych zmian i doskonalenia działalności organizacji oraz rekonfiguracji procesów realizowanych w sieciach organizacji. Przed organizacjami stawiane są liczne wyzwania. Wymagania rynku powodują, że za pożądane metacechy organizacji można uznać elastyczność, jakość oraz innowacyjność. Ponadto wewnętrzne naciski na poprawę efektywności funkcjonowania organizacji wymagają ograniczania kosztów...
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A magnetic stir bar sorbent of metal organic frameworks, carbon foam decorated zinc oxide and cryogel to enrich and extract parabens and bisphenols from food samples
PublikacjaA porous composite magnetic stir bar adsorbent was fabricated for the extraction and enrichment of parabens and bisphenols from selected beverage samples. The adsorbent comprised a metal organic framework, carbon foam decorated zinc oxide and magnetic nanoparticles embedded in polyvinyl alcohol cryogel. The porous composite stir bar adsorbent could adsorb parabens and bisphenols via hydrogen bonding, π-π and hydrophobic interactions....
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Correlation between chemical composition and the presence of selected groups of bacteria in freshwater samples collected from Isfjorden and Billefjorde
PublikacjaThe average concentrations of pollutants in the arctic water, snow and the atmosphere are much lower than those observed in the temperate climate. Specific conditions occurring in the polar regions have apotential to accumulate the pollutants transported from other parts of the world. In this study, attempts were made to find a correlation between selected chemical components and the bacterial population. The analysis involved...
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Reducing Carbon Footprint of Agriculture—Can Organic Farming Help to Mitigate Climate Change?
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Photocatalytic Carboxylation of Organic Substrates with Carbon Dioxide at Zinc Sulfide with Deposited Ruthenium Nanoparticles
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The Role of Organic and Inorganic Amendments in Carbon Sequestration and Immobilization of Heavy Metals in Degraded Soils
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Elemental and organic carbon in aerosols over urbanized coastal region (southern Baltic Sea, Gdynia)
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Seashore sediment and water chemistry at the Admiralty Bay (King George Island, Maritime Antarctica) – geochemical analysis and correlations between the concentrations of chemical species
PublikacjaThis study covers water and sediment chemical characteristics by the western shore of Admiralty Bay (King George Island, Antarctica) in 2016. Chemical processes between sediment and water have been described based on the determination of ions, metals, non-metals, and TOC concentrations. Rock weathering is an important source of Fe, Ni, Co, Al in the seashore area. The PCA shows the impact of acidification in the release metals...
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Soil organic carbon, macro- and micronutrient changes in soil fractions with different lability in response to crop intensification
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Hierarchical porous carbon materials from nanosized metal-organic complex for high-performance symmetrical supercapacitor
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Large-scale converting waste coffee grounds into functional carbon materials as high-efficient adsorbent for organic dyes
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Porewater dissolved organic and inorganic carbon in relation to methane occurrence in sediments of the Gdańsk Basin (southern Baltic Sea)
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The effect of land use in the catchment and meteorological conditions on the riverine transport of dissolved organic carbon into the Puck Lagoon (southern Baltic)
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Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor
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Catalytic carbonization of polypropylene into cup-stacked carbon nanotubes with high performances in adsorption of heavy metallic ions and organic dyes
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The river water influence on cationic and anionic dyes collection by nickel foam with carbonized metal-organic frameworks and carbon nanotubes
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Converting real-world mixed waste plastics into porous carbon nanosheets with excellent performance in the adsorption of an organic dye from wastewater
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Direct QSPR: the most efficient way of predicting organic carbon/water partition coefficient (log K OC) for polyhalogenated POPs
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Electrical and noise responses of carbon nanotube networks enhanced by UV light for detection of organic gases (ethanol, acetone)
Dane BadawczeCarbon nanotube networks of different optical transparencies were investigated via resistance and 1/f noise measurements for detection of ethanol and acetone. The sensor resistive and noise responses were collected for dark and UV-assisted conditions, revealing the improvement in sensor sensitivity and limit of detection after applying UV light (275...
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Toxicity and chemical analyses of airport runoff waters in Poland
PublikacjaThe aim of this study was to assess the ecotoxicological effects of various compounds in complex airport effluents using a chemical and ecotoxicological integrated strategy. The present work deals with the determination of sum of PCBs, PAHs, pesticides, cations, anions, phenols, anionic, cationic, non-ionic detergents, formaldehyde and metals – as well as TOC and conductivity – in runoff water samples collected from 2009 to 2011...
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Enhanced photocatalytic, electrochemical and photoelectrochemical properties of TiO2 nanotubes arrays modified with Cu, AgCu and Bi nanoparticles obtained via radiolytic reduction
PublikacjaTiO2 nanotubes arrays (NTs), obtained via electrochemical anodization of Ti foil, were modified with monometallic (Cu, Bi) and bimetallic (AgCu) nanoparticles. Different amounts of metals’ precursors were deposited on the surface of NTs by the spin-coating technique, and the reduction of metals was performed via gamma radiolysis. Surface modification of titania was studied by EDS and XPS analysis. The results show that AgCu nanoparticles...
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Kazimierz Darowicki prof. dr hab. inż.
OsobyStudia wyższe ukończyłem w czerwcu 1981 roku po zdaniu egzaminu dyplomowego i obronie pracy magisterskiej. Opiekunem pracy magisterskiej był dr hab. inż. Tadeusz Szauer. W roku 1991, 27 listopada uzyskałem stopień naukowy broniąc pracę doktorską zatytułowaną „Symulacyjna i korelacyjna analiza widm immitancyjnych inhibitowanej reakcji elektrodowej”. Promotorem pracy był prof. dr hab. inż. Józef Kubicki (Wydział Chemiczny...
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Environmentally Friendly Fabrication of High-Efficient Fe-ZnO/Citric Acid-Modified Cellulose Composite and the Enhancement of Photocatalytic Activity in the Presence of H2O2
PublikacjaIn the present study, a novel Fe-ZnO/citric acid-modified cellulose composite (x%Fe-ZnOy% CAC) was synthesized using an environmentally friendly hydrothermal method. The obtained samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), UV−vis diffuse reflectance spectroscopy (DRS), Fourier transform infrared spectroscopy (FTIR), nitrogen physisorption, and electrochemical and photocurrent density...
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Effect of synthesis method parameters on properties and photoelectrocatalytic activity under solar irradiation of TiO2 nanotubes decorated with CdS quantum dots
PublikacjaThe growing research interest on photoelectrocatalysis has encouraged the search for new materials with high activity and the development of methods for their synthesis. The successive ionic layer adsorption and reaction (SILAR) method is an effective way to synthesize materials with photoelectrocatalytic (PEC) properties that are active under visible radiation. Therefore, studies on the impact of the parameters of the SILAR method...
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Contamination of runoff waters from roads with high traffic intensity in the urban region of Gdańsk, Poland
PublikacjaW ramach pracy prowadzone były badania zanieczyszczeń w próbkach wód spływnych z arterii komunikacyjnych. Próbki pobierano z sześciu stałych punktów zlokalizowanych wzdłuż szlaku komunikacyjnego prowadzącego z Redy do Gdańska (z miejsc o dużym natężeniu ruchu pojazdów) oraz z ulicy M. Buczka w Redzie (o mniejszym natężeniu ruchu). Próbki pobierane były przez okres dwóch miesięcy (okres deszczów jesiennych: 24.10 - 18.12.2000) oraz...
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Fine-Tuning the Photocatalytic Activity of the Anatase {1 0 1} Facet through Dopant-Controlled Reduction of the Spontaneously Present Donor State Density
PublikacjaThe present study highlights the importance of the net density of charge carriers at the ground state on photocatalytic activity of the faceted particles, which can be seen as a highly underexplored problem. To investigate it in detail, we have systematically doped {1 0 1} enclosed anatase nanoparticles with Gd3+ ions to manipulate the charge carrier concentration. Furthermore, control experiments using an analogical Nb5+ doped...
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Sequential treatment of landfill leachate by electrocoagulation/aeration, PMS/ZVI/UV and electro-Fenton: Performance, biodegradability and toxicity studies
PublikacjaThis study presents a systematic study on sequential treatment of highly resistant landfill leachate by electrocoagulation (EC)/aeration, sulfate radical advanced oxidation process (SR-AOP) and electro-Fenton (EF). In case of SR-AOP, peroxymonosulfate (PMS) catalyzed by zero valent iron (ZVI) and ultraviolet irradiation (UV) system was developed. Treatment process was optimized in respect to COD removal. Analysis of results revealed...
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Environmental characteristics of a tundra river system in Svalbard. Part 1: Bacterial abundance, community structure and nutrient levels
PublikacjaThe Arctic hosts a set of unique ecosystems, characterised by extreme environmental conditions and undergoing a rapid change resulting from the average temperature rising. We present a study on an aquatic ecosystem of the Revelva catchment (Spitsbergen), based on samples collected from the lake, river and their tributaries, in the summer of 2016. The landscape variety of the study site and the seasonal change in the hydrological...
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Improved degradation of etodolac in the presence of core-shell ZnFe2O4/SiO2/TiO2 magnetic photocatalyst
PublikacjaIn the present study, susceptibility to photocatalytic degradation of etodolac, 1,8-diethyl-1,3,4,9 – tetrahydro pyran - [3,4-b] indole-1-acetic acid, which is a non-steroidal anti-inflammatory drug frequently detected in an aqueous environment, was for the first time investigated. The obtained p-type TiO2-based photocatalyst coupled with zinc ferrite nanoparticles in a core-shell structure improves the separation and recovery...
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An Overview of Treatment Approaches for Octahydro-1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetrazocine (HMX) Explosive in Soil, Groundwater, and Wastewater
PublikacjaOctahydro-1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetrazocine (HMX) is extensively exploited in the manufacturing of explosives; therefore, a significant level of HMX contamination can be encountered near explosive production plants. For instance, up to 12 ppm HMX concentrations have been observed in the wastewater effluent of a munitions manufacturing facility, while up to 45,000 mg/kg of HMX has been found in a soil sample taken from...
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Determination of selected chemical parameters in surface water samples collected from the Revelva catchment (Hornsund fjord, Svalbard)
PublikacjaSurface water samples (river and lake) were collected from the Revelva catchment every summer from 2010 to 2013. This study concerns importance of the use of some analytical techniques for pollutants and parameters deter- mination in Arctic environmental samples based on the example of total organic carbon, phenols, and formaldehyde determination and measurement of pH and electrical conductivity parameters. Significant...
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Non-toxic fluorine-doped TiO2 nanocrystals from TiOF2 for facet-dependent naproxen degradation
PublikacjaIn the present study, the photocatalytic degradation of naproxen (NPX), which is a nonsteroidal anti-inflammatory drug (NSAID), frequently detected in drinking water, was investigated. The F-doped TiO2 with defined morphology was successfully obtained from TiOF2 and applied for photocatalytic degradation under UV-vis and visible light. All samples were characterised by X-ray diffraction, scanning electron microscopy, X-ray photoelectron...
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Mono- and bimetallic (Pt/Cu) titanium(IV) oxide core–shell photocatalysts with UV/Vis light activity and magnetic separability
PublikacjaTitanium(IV) oxide is one of the most widely investigated photocatalysts. However, separation of nano-sized particulate titania might result in profitless technologies for commercial applications. Additionally, bare titania is almost inactive under the Vis range of solar spectrum due to its wide bandgap. Therefore, the present study aims to prepare novel coreinterlayer- shell TiO2 magnetic photocatalysts modified with metal nanoparticles...
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Fluorine ions in photocatalysts’ synthesis: an obstacle or an ally? The investigation of photocatalysts in Ti-O-F system
PublikacjaTitanium(IV) oxide (TiO2) is one of the most promising photocatalysts, which is expected to be applied in the photocatalytic degradation of xenobiotics. For sustainable development and green chemistry approach recently, much effort has been paid to enhance TiO2 photocatalytic activity in UV-vis light by modifying its structure. The photocatalytic process’s complexity cannot be simply described as electron-hole pairs generations...
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The use of selected analytical techniques for pollutants determination in the environmental samples collected from the Arctic regions
PublikacjaThe paper concern importance of the use of analytical techniques for pollutants determination in the Arctic based on the example of total organic carbon, phenolsandformaldehyde determinationandmeasurementofpHand electrical conductivity parameters in surfacewater samples collected fromthe Revelva catchment.