Wyniki wyszukiwania dla: RUTHENIUM HALF-SANDWICH
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In situ spectroelectrochemical and theoretical study on the oxidation of a 4H-imidazole-ruthenium dye adsorbed on nanocrystalline TiO2thin film electrodes
PublikacjaTerpyridine 4H-imidazole-ruthenium(ii) complexes are considered promising candidates for use as sensitizers in dye sensitized solar cells (DSSCs) by displaying broad absorption in the visible range, where the dominant absorption features are due to metal-to-ligand charge transfer (MLCT) transitions. The ruthenium(iii) intermediates resulting from photoinduced MLCT transitions are essential intermediates in the photoredox-cycle...
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Anti-plane shear waves in an elastic strip rigidly attached to an elastic half-space
PublikacjaWe consider the anti-plane shear waves in a domain consisting of an infinite layer with a thin coating lying on an elastic half-space. The elastic properties of the coating, layer, and half-space are assumed to be different. On the free upper surface we assume the compatibility condition within the Gurtin–Murdoch surface elasticity, whereas at the plane interface we consider perfect contact. For this problem there exist two possible...
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Billiard in a rotating half-plane
PublikacjaThe main objective of this research is to study the properties of a billiard system in an unbounded domain with moving boundary. We consider a system consisting of an infinite rod (a straight line) and a ball (a massless point) on the plane. The rod rotates uniformly around one of its points and experiences elastic collisions with the ball. We define a mathematical model for the dynamics of such a system and write down asymptotic...
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Synthesis and characterization of ruthenium and rhenium dyes with phosphonate anchoring groups
PublikacjaRe(L1)–Re(L3), a series of rhenium(I) tricarbonyl chloride complexes with bpy-R2 derivatives L1–L3 (bpy = 2,2′-bipyridine, R represents the substitution at the 4- and 4′-positions), and their corresponding trishomoleptic Ru(L1)3–Ru(L3)3 as well as heteroleptic ruthenium(II) complexes Ru(tbbpy)2(L1) and Ru(tbbpy)2(L2) have been synthesized and characterized. Their applicability as immobilizable metal–organic chromophores in solar...
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On Wrinkling in Sandwich Panels with an Orthotropic Core
PublikacjaThis paper deals with the local loss of stability (wrinkling) problem of a thin facing of a sandwich panel. Classical solutions to the problem of facing instability resting on a homogeneous and isotropic substructure (a core) are compared. The relations between strain energy components associated with different forms of core deformations are discussed. Next, a new solution for the orthotropic core is presented in detail, which...
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Photophysics of a Ruthenium 4H-Imidazole Panchromatic Dye in Interaction with Titanium Dioxide
PublikacjaThe photophysics of bis(4,4′-di-tert-butyl-2,2′-bipyridine-κ2N,N′)[2-(4-carboxyphenyl)-4,5-bis(p-tolylimino-κN)imidazolato]ruthenium(II) hexafluorophosphate is investigated, both in solution and attached to a nanocrystalline TiO2 film. The studied substitution pattern of the 4H-imidazole ligand is observed to block a photoinduced structural reorganization pathway within the 4H-imidazole ligand that has been previously investigated....
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The influence of core material on strength properties of hybrid sandwich panels
PublikacjaAlong with high prices of fuels and more restrictive safety and environmental regulations (including environment protection) increased interest in sandwich structures is being observed. One of the solution having growing application potential is steel sandwich panel. The construction consist of very thin steel plates (about 2mm) and stiffeners between them. The main advantage of using such solution is very high strength to weight...
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Synthesis, structure, DNA binding and anticancer activity of mixed ligand ruthenium(II) complex
PublikacjaIn order to obtain a potential chemotherapeutic which is not affected on the normal BALB/3T3 cell line, a new arene ruthenium(II) complex {[RuCl(L1)(η6-p-cymene)]PF6}2 · H2O has been synthesized by a direct reaction of precursor, [{(η6-p-cymene)Ru(μ-Cl)}2Cl2], with N,N-chelating ligand (L1 - 2,2′-bis(4,5-dimethylimidazole). The compound has been fully characterized by elemental analysis, X-ray diffraction, IR, UV–Vis and 1H, 13C...
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Fatigue properties of laser welded steel sandwich panel.
PublikacjaPrzedstawiono wyniki badań laboratoryjnych paneli SANDWICH, prowadzonych w Kat. TOiOO Wydz. OiO na konstrukcjach w skali rzeczywistej. Przedstawiono program badań, omówiono założenia procedur badawczych i konstrukcję stanowisk testowych. Dokonano porównania uzyskanych rezultatów z wynikami prezentowanymi w literaturze. Przedstawiono propozycję algorytmu szacowania trwałości zmęczeniowej konstrukcji spawanych laserowo.
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Tests of local strains in steel laser - welded sandwich structure
PublikacjaW publikacji zaprezentowano rezultaty badań odkształceń w strefie spoiny laserowej konstrukcji sandwich. Pokazano obiekt badań, metodykę i oprzyrządowanie oraz proces rejestracji. Przedstawiono uzyskane wyniki i wnioski z nich wypływające.
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Synthesis of novel dinuclear ruthenium polypyridine dye for dye-sensitized solar cells application
PublikacjaA new dinuclear ruthenium(II) polypyridine complex has been successfully synthesized. The new compound has been characterized by spectroscopic and electrochemical methods. Its potential application as a sensitizing dye in dye-sensitized solar cells has been checked under AM 1.5 G irradiation conditions (100 mW cm−2) and its performance was compared to that of a commercially available mononuclear analogous dye. The overall light-to-electricity...
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Problemy modelowania własności wytrzymałościowych stalowych konstrukcji typu ''sandwich''
PublikacjaW pracy omówiono wyniki badań zmęczeniowych stalowych, laserowo spawanych konstrukcji typu sandwich. Na ich tle uogólniono mechanizmy niszczenia takich konstrukcji. Dla wybranego modelu niszczenia przedstawiono wyniki badań elementarnego połączenia spawanego laserowo.
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Numerical simulations of novel GFRP sandwich footbridge
PublikacjaIn the following paper some aspects of numerical analysis and designing stages of a footbridge made of composite materials are elucidated. Because of the used materials the design process in this case is not ordinary and requires the development of concepts, material selections, identification of material properties, numerical simulations, strength calculations, serviceability and durability analyses. This contribution presents...
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Dynamic Tests and Technical Monitoring of a Novel Sandwich Footbridge
PublikacjaA novel sandwich composite footbridge is described in this paper, for the first time after it has been put into operation over the Radunia River in the Pruszcz Gdański municipality. This paper presents results of dynamic tests and describes technical monitoring of the footbridge. The dynamic tests were conducted to estimate pedestrian comfort and were compared with the ones from numerical simulations made in the environment of...
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Poli-optimization of selected variants of steel sandwich panels connections
PublikacjaPanele kompozytowe odgrywają coraz większą role w różnorodnych zastosowaniach inżynierskich. Jednym z zagadnień kluczowych dla możliwości aplikacyjnych są połączenia między cienkościennymi formami w układzie wzdłużnym i poprzecznym. Praca prezentuje wyniki polioptymalizacji numerycznej wybranych połączeń stalowych paneli typu sandwich.
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Numerical and experimental investigation of rotational stiffness of zed-purlins connection with sandwich panels
PublikacjaA rotational resistant stiffness of the zed-purlins connection with sandwich panels is investigated. A simple finite element method model of the connection is proposed. The numerical analysis of the model performed by ABAQUS software, in physically linear and geometrically nonlinear ranges, leads to the rotational resistant stiffness sought. The numerical solution obtained is verified experimentally. Two variants of distribution...
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Composite sandwich footbridge - measured dynamic response vs. FEA
PublikacjaThe paper describes a process of in situ dynamic tests of a composite sandwich footbridge before its accepta-tion for exploitation in real traffic conditions. It is only a part of a big research task that includes design, manufacture and introduce practical application of the bridge. The in situ measured natural modes and fre-quencies are compared with numerically determined ones. Finite element analysis is established to estimate...
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Anticancer and antimicrobial properties of novel η6-p-cymene ruthenium(ii) complexes containing a N,S-type ligand, their structural and theoretical characterization
PublikacjaRuthenium(II) complexes are lately of great scientific interest due to their chemotherapeutic potential asanticancer and antimicrobial agents. Here we present the synthesis of new pyrazole carbothioamidederivatives and their four arene–ruthenium complexes. The title compounds were characterized with theapplication of IR, NMR, mass spectrometry, elemental analysis and X-ray diffraction. Additionally, for newcomplexes DFT calculations...
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JOURNAL OF SANDWICH STRUCTURES & MATERIALS
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Experimental Tests Of Sandwich Beams In The Design Process Of GFRP Shell Footbridge Structure
PublikacjaThe paper includes selected aspects of the study to elaborate architectural, material and construction design of pedestrian footbridge spans made of composite materials. The considered footbridge is a sandwich-type shell structure. The cooperation of PET foam core with outer lining surfaces is crucial for its load bearing capacity. The paper is aimed to experimental investigation of sandwich beams subjected to bending loading....