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Wyniki wyszukiwania dla: functionalized polypropylene
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Unprecedented Adhesive Performance of Propylene-Based Hydroxyl Functionalized Terpolymers
PublikacjaThe synthesis of hydroxyl functionalized propylene-based terpolymers and their performance as hot melt adhesives were investigated. The products comprise uniformly distributed butyl and 4-hydroxyl-butyl branches along the polypropylene backbone. Despite the low hydroxyl-functionality level of ≤ 0.5 mol%, hydroxyl functionalized terpolymers show formidable adhesion to aluminum and steel providing an adhesive strength exceeding 16...
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Functionalized Peptide Fibrils as a Scaffold for Active Substances in Wound Healing
PublikacjaTechnological developments in the field of biologically active peptide applications in medicine have increased the need for new methods for peptide delivery. The disadvantage of peptides as drugs is their low biological stability. Recently, great attention has been paid to self-assembling peptides that can form fibrils. Such a formulation makes bioactive peptides more resistant to enzymatic degradation and druggable. Peptide fibrils...
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The protective properties of graphene oxide coatings functionalized with phosphorus atoms.
PublikacjaRecently, electrophoretically deposited graphene oxide coatings are commonly applied as an anti-corrosion layer. However, improper adjustment of electrophoretic deposition (EPD) parameters as well as the hydrophilic nature of graphene oxide contribute to the formation of defects in the coatings and the increase in the wetting properties, respectively, and thus lead to a reduction of protective properties. The growth of wetting...
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Convenient and Efficient Diastereoselective Preparation of Functionalized Z -Alkenyl Sulfides
PublikacjaWe have developed an efficient and convenient regio‐ and stereoselective reduction of the alkynyl sulfides with pinacolborane in the presence of copper(I) chloride to produce (Z)‐alkenyl sulfides in good and very good yields. The functionalized alkynyl sulfides are readily available based on the reaction of lithium acetylides with thiotosylates under mild conditions.
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Synergistic effect of activated carbon and Ni2O3 in promoting the thermal stability and flame retardancy of polypropylene
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Effect of treating method on the physicochemical properties of amine-functionalized carbon nanotubes
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Functionalized mesoporous silica thin films as a tunable nonlinear optical material
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Functionalized Magnetic Bacterial Cellulose Beads as Carrier for Lecitase® Ultra Immobilization
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Recent developments in the synthesis and applications of graphene-family materials functionalized with cyclodextrins
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Biomass-Derived Nitrogen Functionalized Carbon Nanodots and Their Anti-Biofouling Properties
PublikacjaThe prevalence of the antibiotic resistant bacteria remains a global issue. Cheap, sustainable and multifunctional antibacterial membranes are at the forefront of filtrating materials capable of treating multiple flow streams, such as water cleansing treatments. Carbon nanomaterials are particularly interesting objects shown to enhance antibacterial properties of composite materials. In this article, amino-functionalized, photoluminescent...
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Enzymatic electrodes nanostructured with functionalized carbon nanotubes for biofuel cell applications
PublikacjaNanostructured bioelectrodes were designed and assembled into a biofuel cell with no separating membrane.
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Synthesis and structural characterization of new cyclic siloxane with functionalized organic substituents
PublikacjaOcta(2-pyridyloxy)cyclotetrasiloxane was isolated as the product of the reaction between silicon disulfide and 2-hydroxypyridine. The new compound has been characterised by single crystal X-ray analysis, revealing a planar eight-membered ring with functionalized organic substituents on the silicon atoms.
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A convenient method for the preparation of functionalized N-acylsulfenamides from primary amides.
PublikacjaWe have developed a convenient method for the synthesis of functionalized N-acylsulfenamides under mild conditions and in moderate to good yields. The designed method is based on the reaction of (5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)-disulfanyl derivatives with nitrogen nucleophiles generated from primary amides or imides and sodium hydride. The developed method allows for the preparation of N-acylsulfenamides bearing...
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Functionalized azobenzocrown ethers as sensor materials—The synthesis and ion binding properties
PublikacjaNew 13- and 16-membered azobenzocrown ethers with aromatic amino, amide, ether–ester or ether–amide residue in para position to an azo moiety were obtained. Acid–base properties and ion binding ability of the colored compounds were studied by spectroscopic methods: UV–vis, fluorimetry and 1H NMR spectroscopy. Selected azobenzocrowns were tested as ionophores in ion-selective membrane electrodes (ISEs) – classic and miniature all...
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Potential of Functionalized Polyolefins in a Sustainable Polymer Economy: Synthetic Strategies and Applications
PublikacjaPolymers play a crucial role in our modern life as no other material exists that is so versatile, moldable, and lightweight. Consequently, the demand for polymers will continue to grow with the human population, modernization, and technological developments. However, depleted fossil resources, increasing plastic waste production, ocean pollution, and related growing emission of greenhouse gases has led to a change in the way we...
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Hyperbranched polyethylenimine functionalized silica/polysulfone nanocomposite membranes for water purification
PublikacjaHyperbranched polyethyleneimine functionalized silica (PEI-SiO2) nanoparticles with considerable hydrophilicity were synthesized and incorporated into a polysulfone (PSF)/dimethylacetamide (DMA)/polyvinylpyrrolidone (PVP) membrane casting solution in five different ratios to fabricate PEI-SiO2/PSF nanocomposite membranes using nonsolvent-induced phase separation. The hydrophilic PEI-SiO2 nanoparticles were characterized by TEM,...
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Effect of nanosized carbon black on thermal stability and flame retardancy of polypropylene/carbon nanotubes nanocomposites
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Catalytic carbonization of polypropylene by the combined catalysis of activated carbon with Ni2O3 into carbon nanotubes and its mechanism
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Modulation of dielectric properties in low-loss polypropylene-based composites at GHz frequencies: theory and experiment
PublikacjaPolymer composites with high dielectric constant and low loss tangent are highly regarded as substrates for modern high-speed electronics. In this work, we analyze the high-frequency dielectric properties of two types of composites based on polypropylene infused with high-dielectric-constant microparticles. Two types of fillers are used: commercial ceramics or titanium oxide ( TiO2) with different concentrations. The key observation...
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Badania wpływu nieorganicznych napełniaczy proszkowych na właściwości polipropylenu
PublikacjaOmówiono sposób wytwarzania tworzyw polimerowych zawierających nieorganiczne napełniacze proszkowe. Podczas badań jako matrycę polimerową zastosowano polipropylen, który napełniano talkiem, kredą oraz ich mieszaniną. Próbki kompozytów na bazie polipropylenu otrzymywano stosując wytłaczarkę dwuślimakową współbieżną. Temperatura stref grzewczo-chłodzących cylindra wytłaczarki oraz temperatura głowicy wynosiła 195°C. Scharakteryzowano...
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Synthesis and characterization of periphery-functionalized porphyrazines containing mixed pyrrolyl and pyridylmethylamino groups
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Gallic Acid-Functionalized, TiO2-Based Nanomaterial—Preparation, Physicochemical and Biological Properties
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Synthesis, characterization, photochemical properties and cytotoxicity of the novel porphyrazine functionalized with nitroimidazolylbutylsulfanyl groups
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Polyurethane/Silane-Functionalized ZrO2 Nanocomposite Powder Coatings: Thermal Degradation Kinetics
PublikacjaA polyurethane (PU)-based powder coating reinforced with vinyltrimethoxysilane (VTMS)-functionalized ZrO2 nanoparticles (V-ZrO2) for thermal stability was developed. Chemical structure, microstructure and thermal degradation kinetics of the prepared coatings were investigated. The peak of aliphatic C–H vibrating bond in the Fourier transform infrared (FTIR) spectrum of V-ZrO2 was a signature of VTMS attachment. Scanning electron...
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Graphene oxide functionalized with methylene blue and its performance in singlet oxygen generation
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Hexagonal Boron Nitride Functionalized with Au Nanoparticles—Properties and Potential Biological Applications
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Structurally well-defined functionalized polyolefins and graft copolymers thereof as bitumen modifiers
PublikacjaHere we demonstrate the application of hydroxyl-functionalized propylene-based copolymers, poly(propylene-co-1-hexene-co-10-undecen-1-ol) (FPP) and poly(styrene-co-maleic anhydride) (SMA) graft copolymers derived thereof, poly(propylene-co-1- hexene-graft-styrene-co-maleic anhydride) (FPP-g-SMA) as bitumen modifiers. The FPP samples were synthesized via solution copolymerization, while FPP-g-SMA products were obtained via transesterification...
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Functionalized nanodiamonds as a perspective green carbo-catalyst for removal of emerging organic pollutants
PublikacjaRapid industrial and urban development jointly with rising global population strongly affect the large-scale issues with drinking, groundwater, and surface water pollution. Concerns are not limited to environmental issues but also human health impact becoming serious global aspect. Organic pollution becomes a primarily serious hazard, therefore, the novel sophisticated approaches to treat them are thoroughly investigated. Among...
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Synthesis and ionophoric properties of functionalized p-tert-butyl-calix[4]arenes
PublikacjaProjektowanie struktury związków o właściwościach jonoforowych stanowi ważny element chemii supramolekularnej. W pracy przedstawiono wyniki badań nad funkcjonalizacją makrocyklicznych kaliks[4]arenów prowadzacą do nowych związków o zróżnicowanych właściwościach kompleksujących. Syntezowane przez nas jonofory badane były w membranowych elektrodach jonoselektywnych. Wyznaczono potencjometryczne współczynniki selektywności oraz stałe...
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Striking influence of NiO catalyst diameter on the carbonization of polypropylene into carbon nanomaterials and their high performance in the adsorption of oils
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New insights into the role of lattice oxygen in the catalytic carbonization of polypropylene into high value-added carbon nanomaterials
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Effect of the added amount of organically-modified montmorillonite on the catalytic carbonization of polypropylene into cup-stacked carbon nanotubes
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Amine-functionalized magnetite-silica nanoparticles as effective adsorbent for removal of uranium(VI) ions
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Porphyrazines Peripherally Functionalized with Hybrid Ligands as Molecular Scaffolds for Bimetallic Metal-Ion Coordination
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Photosensitizing potential of tailored magnetite hybrid nanoparticles functionalized with levan and zinc (II) phthalocyanine
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Kinetics of Cross-Linking Reaction of Epoxy Resin with Hydroxyapatite-Functionalized Layered Double Hydroxides
PublikacjaThe cure kinetics analysis of thermoset polymer composites gives useful information about their properties. In this work, two types of layered double hydroxide (LDH) consisting of Mg2+ and Zn2+ as divalent metal ions and CO32− as an anion intercalating agent were synthesized and functionalized with hydroxyapatite (HA) to make a potential thermal resistant nanocomposite. The curing potential of the synthesized nanoplatelets in the...
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The Antibacterial and Antifungal Textile Properties Functionalized by Bimetallic Nanoparticles of Ag/Cu with Different Structures
PublikacjaWe reported a preparation and characterization of five kinds of impregnation solutions, containing Ag/Cu in the formof bimetallic nanoparticles (alloy and core-shell) as well as ionic species. The cotton-polyester textiles were successfully impregnated during the washing and ironing process by as-prepared solutions to have antibacterial and antifungal properties against to Escherichia coli, Staphylococcus aureus, and Candida albicans....
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Synthesis of functionalized new conjugates of batracylin with tuftsin/ retro-tuftsin derivatives and their biological evaluation
PublikacjaNew batracylin conjugates with tuftsin/retro-tuftsin derivatives were designed and synthesized using T3P as a coupling agent. The conjugates possess an amide bond formed between the carboxyl group of heterocyclic molecule and the N-termini of the tuftsin/retro-tuftsin chain. The in vitro cytotoxic activity of the new analogues and their precursors was evaluated using a series of human and murine tumor cells. BAT conjugates containing...
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Electrochemical synthesis and characterization of nanocomposites based on poly(3,4-ethylenedioxythiophene) and functionalized carbon nanotubes
PublikacjaThis work is focused on new composite materials consisting of poly(3,4-ethylenedioxythiophene) (pEDOT) and functionalized multi-walled carbon nanotubes synthesized electrochemically. Three types of composites were synthesized: the first one containing carbon nanotubes with carboxyl groups (covalent functionalization), the second one containing oxidized carbon nanotubes ox-MWCNTs (with different oxygen-rich polar groups) (covalent...
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Correction: New insights into the role of lattice oxygen in the catalytic carbonization of polypropylene into high value-added carbon nanomaterials
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The Impact of Operational Parameters on Polypropylene Membrane Performance during the Separation of Oily Saline Wastewaters by the Membrane Distillation Process
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Striking Influence about HZSM-5 Content and Nickel Catalyst on Catalytic Carbonization of Polypropylene and Polyethylene into Carbon Nanomaterials
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Comparative Analysis of Carbon, Ecological, and Water Footprints of Polypropylene-Based Composites Filled with Cotton, Jute and Kenaf Fibers
PublikacjaComposites containing natural fibers are considered environmentally friendly materials which is related to the reduced use of fossil fuels and the emission of carbon dioxide compared to petroleum-based polymers. Nevertheless, a complete evaluation of their environmental impact requires a broader view. This paper presents a carbon, ecological, and water footprints assessment of polypropylene-based composites filled with cotton,...
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Separation of surfactant functionalized single-walled carbon nanotubes via free solution electrophoresis method
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Determination of carbamazepine in urine and water samples using amino-functionalized metal–organic framework as sorbent
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Boronate-appended polymers with diol-functionalized ferrocene: an effective and selective method for voltammetric glucose sensing
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Novel and effective synthesis protocol of AgNPs functionalized using L-cysteine as a potential drug carrier
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Curing epoxy with ethylenediaminetetraacetic acid (EDTA) surface-functionalized Co Fe3-O4 magnetic nanoparticles
PublikacjaIn this work, the bulk and surface composition of Fe3O4 supermagnetic nanoparticles were modified for efficient epoxy curing. The bare, ethylenediaminetetraacetic acid (EDTA) capped, and cobalt (Co)-doped EDTA capped Fe3O4 nanoparticles were synthesized electrochemically. The crystalline structure and phase information, surface capping, morphology and magnetization behavior of nanoparticles were studied by X-Ray diffraction (XRD),...
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Photosensitive and pH-dependent activity of pyrazine-functionalized carbazole derivative as promising antifungal and imaging agent
PublikacjaCarbazole skeleton plays a significant role as a structural scaffold of many pharmacologically active compounds. Pyrazine-functionalized carbazole derivative was constructed by coupling 2-amino-5-bromo-3-methylaminepyrazine (ABMAP) into 3 and 6 positions of the carbazole ring. Multi-experimental methods were used, e.g., potentiometric, spectroscopic (ATR, UV, XRD powder,1H and13C NMR), electrochemical (cyclic voltammetry), and...
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Folic Acid/Methotrexate Functionalized Mesoporous Silica Nanoflakes from Different Supports: Comparative Study
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