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Wyniki wyszukiwania dla: sofc anodes
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SOFT MATERIALS
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CGO FILMS ON YSZ ELECTROLYTE FABRICATED BY SPRAY PYROLYSIS FOR SOFC
PublikacjaINTRODUCTION Solid oxide fuel cells are one of the fastest developing energy converters. The advancement introduced by research community provides steady state progress is stability and performance of the fuel cells. Significant influence on the cell’s performance and stability is related to cell design. The simplest design just consists of an anode, a solid electrolyte and a cathode. However, in order to improve the properties,...
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Exsolution of Ni nanoparticles on the surface of cerium and nickel co-doped lanthanum strontium titanate as a new anodic layer for DIR-SOFC. Anti-coking potential and H2S poisoning resistance of the prepared material
PublikacjaThe aim of this study was to evaluate a new catalytic material for biogas fueled DIR-SOFC. This material was a perovskite-type SrTiO3 doped with La, Ce and Ni of a general formula La0.27Sr0.54Ce0.09Ni0.1Ti0.9O3-σ (LSCNT). Additional preparation steps were undertaken to promote a nickel exsolution process. Heat post-treatment of powders in a humidified H2 resulted in an intensive growth of nickel nanoparticles (NPs) while the temperature...
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Andes Pediatrica
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The Symmetry of GPS Orbit Ascending Nodes
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The outline of percolation theory in reference to Solid Oxide Fuel Cell composite anodes
PublikacjaPrzedstawiono podstawy teoretyczne dotyczące zjawiska perkolacji w układach nieuporządkowanych. Zaprezentowano obecny stan wiedzy na temat wykorzystania teorii perkolacji w materiałach elektrodowych dla tlenkowych ogniw paliwowych.
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The Effect of Increasing the Amount of Indium Alloying Material on the Efficiency of Sacrificial Aluminium Anodes
PublikacjaAl-Zn-In alloys having 4.2% zinc content and various indium content in the range of 0.02–0.2% were tested with respect to the most important electrochemical properties of sacrificial anodes in a cathodic protection, i.e., the current capacity and potential of the operating anode. The distribution of In and Zn in the tested alloys was mapped by means of the EDX technique, which demonstrated that these elements dissolve well in the...
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Diatoms Biomass as a Joint Source of Biosilica and Carbon for Lithium-Ion Battery Anodes
PublikacjaThe biomass of one type cultivated diatoms (Pseudostaurosira trainorii), being a source of 3D-stuctured biosilica and organic matter—the source of carbon, was thermally processed to become an electroactive material in a potential range adequate to become an anode in lithium ion batteries. Carbonized material was characterized by means of selected solid-state physics techniques (XRD, Raman, TGA). It was shown that the pyrolysis...
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Electrochemical investigations of conductive coatings applied as anodes in cathodic protection of reinforced concrete
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Hollow carbon sphere/metal oxide nanocomposites anodes for lithium-ion batteries
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A review on the critical challenges and progress of SiOx-based anodes for lithium-ion batteries
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Electrochemical investigations of conductive coatings applied as anodes in cathodic protection of reinforced concrete.
PublikacjaW pracy przedstawiono rezultaty badań elektrochemicznych polimerów przewodzących z pigmentem grafitowym. Wyznaczono parametry elektrochemiczne badanych powłok w trakcie długotrwałej polaryzacji zbrojonego betonu. W oparciu o pomiary impedancyjne wyznaczono parametry elektrochemiczne powłok przewodzących. Wykazano, że badane powłoki mogą być stosowane w ochronie katodowej żelbetu. Badania wykazały, że optymalne stężenie grafitu...
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Tailoring of SiOC composition as a way to better performing anodes for Li-ion batteries
PublikacjaPolymer derived silicon oxycarbide (SiOC) ceramics are investigated as potential anodes for lithiumion batteries. Different SiOC ceramics are prepared by pyrolysis (1000 °C and 1400 °C under controlled argon atmosphere) of polysiloxanes ceramic precursors. Preceramic polymers are synthesized using the sol–gel method. Phenyltriethoxysilane (PhTES) and methyltriethoxysilane (MTES) have been used as starting precursors and mixed with...
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A facile strategy for reclaiming discarded graphite and harnessing the rate capabilities of graphite anodes
PublikacjaGraphite negative electrodes are unbeaten hitherto in lithium-ion batteries (LiBs) due to their unique chemical and physical properties. Thus, the increasing scarcity of graphite resources makes smart recycling or repurposing of discarded graphite particularly imperative. However, the current recycling techniques still need to be improved upon with urgency. Herein a facile and efficient hydrometallurgical process is reported to...
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Application of wet powder spraying for anode supported solid oxide fuel cell with a perowskite SrTi0.98Nb0.02O3-d anode
PublikacjaAnode-supported solid oxide fuel cell with SrTi0.98Nb0.02O3–d anode, yttria-stabilized zirconia electrolyte and La(Ni0.6Fe0.4) O3d cathode has been successfully fabricated and evaluated. Process of anode support fabrication has been presented. Wet powder spraying and high temperature sintering method have been studied and applied to deposit the thin electrolyte layer.In order to improve catalytic properties of the anode, it has...
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Design and Thermodynamic Analysis of an SOFC System for Naval Surface Ship Application
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Characterization of novel GdBa0.5Sr0.5Co2−xFexO5+δ perovskites for application in IT-SOFC cells
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Badania tytanianu strontu - materiału anodowego dla ogniw paliwowych SOFC
PublikacjaW artykule opisano wyniki badan nad kompozytami Sr(Ti,Nb)O3-YSZ przygotowywane metoda mieszania proszkow w mozdzierzu agatowym. Scharakteryzowano ich wlasciwosci strukturalne, elektryczne i mechaniczne.
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Evaluation of porous 430L stainless steel for SOFC operation at intermediate temperatures
PublikacjaW pracy przedstawiono badania porowatej stali nierdzewnej typu 430L do zastosowań w tlenkowych ogniwach paliwowych jako podłoża. Podłoża były poddawane utlenianiu w powietrzu oraz w wodorze i analizowane z wykorzystaniem mikroskopu elektronowego, dyfrakcji rentgenowskiej i termograwimetrii cyklicznej.
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Przegląd materiałów stosowanych w tlenkowych ogniwach paliwowych typu sofc
PublikacjaArtykuł przeglądowy opisujący nano i mikrokrystaliczne materiały elektrodowe i elektrolitowe stosowane obecnie do budowy ogniw paliwowych ze stałym elektrolitem tlenkowym (SOFC).
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Investigation of functional layers of solid oxide fuel cell anodes for synthetic biogas reforming
PublikacjaSolid oxide fuel cells (SOFCs) are one of the most promising energy conversion devices due to their high efficiency, low pollution and fuel flexibility. Unfortunately, when hydrocarbons are used as a fuel, for example in the form of a biogas, solid carbon can deposit on the anode surface. This process leads to the degradation of the fuel cell performance. A possible solution to this problem is to apply an additional catalytic material,...
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New fast photomultipliers with a screening grid at the anode
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Remote DHCPv6 autoconfiguration for mobile IPv6 nodes
PublikacjaPrzedstawiono ideę przełączania międzydomenowego węzłów wspierających protokół IPv6, z wykorzystaniem procedur stanowej (statefull) z użyciem serwerów autokonfiguracji DHCPv6. Dokonano analizy czasu trwania procesów przełączania w warstwach: drugiej i trzeciej. Zaproponowano zmodyfikowaną metodę autokonfiguracji węzła, pozwalającą na wyeliminowanie przerwy w transmisji związanej z wykrywaniem zduplikowanych adresów (Duplicate Address...
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Self-Organizing Wireless Nodes Monitoring Network
PublikacjaThe concept of data monitoring system and self-organizing network of multipurpose data transfer nodes are presented. Two practical applications of this system are also presented. The first of these is the wireless monitoring system for containers, and the second is the mobile monitoring system for gas air pollution measurements.
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Fabrication and structural properties of Y and Fe co-doped SrTiO3 nanoceramics for SOFC
PublikacjaYttria and iron co-doped strontium titanate perovskites, (Y0,07Sr0,93Ti1-xFexO3-δx=0,1; 0,2) samples were fabricated by two methods: solid-state synthesis (SS) and the Pechinisol-gel modified method. The morphology of samples were measured by SEM and X-raydiffraction. Results were compared and discussed. The strong relationship between fabricationprocedure and microstructure has been proven. It was also observed, that the nanoceramicsobtained...
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Rhythm and Colours of the Angles
PublikacjaABSTRACT The game of space was and still is a crucial aspect of visual arts. The aim of this study is to examine how the arrangement of hues, rhythms and angles of various polygons can create an impression of depth and movement on a flat surface. The so-called Penrose tiling and Ulam's spiral are mathematical models that have been applied for the painting experiment. There is a vast amount of evidence gathered over the ages that...
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Performance comparison of SiC Schottky diodes and silicon ultra fast recovery diodes
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Systems and Soft Computing
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Recent anode advances in Solid Oxide Fuel Cells
PublikacjaW pracy podsumowano bieżące doniesienia na temat potencjalnych materiałów anodowych dla wysokotemperaturowych tlenkowych ogniw paliwowych z uwzględnieniem wyników otrzymanych przez autora pracy.
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The Influence of Iron Doping on Performance of SrTi1-XFexO3-δ Perovskite Oxygen Electrode for SOFC
PublikacjaSolid Oxide Fuel Cells (SOFC) are based on electrolytes and mixed ionic and electronic conductivity (MIEC) materials. The need to reduce costs causes an increase in interest of new compounds suitable for operating temperatures between 600 °C and 800 °C. The SrTi1-xFexO3 (STF) perovskite material is a perspective material that could be used for the oxygen electrodes. In this work STF materials with different content of iron (x =...
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Structural and electrical properties of Sr(Ti,Fe)O3-δ materials for SOFC cathodes
PublikacjaW niniejszym artykule, dwa związki SrTiO3 domieszkowanego Fe przebadano pod względem przydatności na katody w tlenkowych ogniwach paliwowych. SrTi0.65Fe0.35O3 i SrTi0.5Fe0.5O3 zostały przebadane pod względem reaktywności chemicznej z elektrolitem YSZ. Stwierdzono, że przewodnictwo elektryczne tych związków jest stosunkowo niskie: 0,4 S/cm i 2 S/cm odpowiednio dla STF35 i STF50.
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Soft modelling support for information management
PublikacjaW artykule zaproponowano trzystopniowy proces modelowania przepływów informacji. Zaproponowane stopnie obejmują dekompozycje, reprezentacje i integracje. Przedyskutowano możliwości wspomagania każdego z powyższych stopni przypomocy systemów opartych na bazie wiedzy, głównie inteligentnego przeszuki-wania, systemów ekspertowych i sieci neuronowych.
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Applications of soft modelling and intelligent techniques
PublikacjaW edytorialu omówiono szeroko obecne praktyczne zastosowania modelowania miękkiego oraz technik inteligentnych, rozumianych jako takie techniki, które potrafią wspomagać podejmowanie decyzji w zmiennych warunkach otoczenia.
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Kinetics of the Organic Compounds and Ammonium Nitrogen Electrochemical Oxidation in Landfill Leachates at Boron-Doped Diamond Anodes
PublikacjaElectrochemical oxidation (EO) of organic compounds and ammonium in the complex matrix of landfill leachates (LLs) was investigated using three different boron-doped diamond electrodes produced on silicon substrate (BDD/Si)(levels of boron doping [B]/[C] = 500, 10,000, and 15,000 ppm—0.5 k; 10 k, and 15 k, respectively) during 8-h tests. The LLs were collected from an old landfill in the Pomerania region (Northern Poland) and were...
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Silicon oxycarbide ceramics as anodes for lithium ion batteries: influence of carbon content on lithium storage capacity
PublikacjaWe report here on the synthesis and characterization of silicon oxycarbide (SiOC) in view of its application as a potential anode material for Li-ion batteries. SiOC ceramics are obtained by pyrolysis of various polysiloxanes synthesized by sol–gel methods. The polysiloxanes contain different organic groups attached to silicon, which influence the chemical composition and the microstructure of the final ceramic product. The structure...
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Influence of pyrolysis atmosphere on the lithium storage properties of carbon-rich polymer derived SiOC ceramic anodes
PublikacjaPolymer derived carbon-rich SiOC ceramics are prepared from polysiloxane precursors through a pyrolysis process at 1000 °C using pure argon and argon/hydrogen mixture as pyrolysis atmosphere. The precursor is synthesized from a linear (Si–H)-containing polysiloxane cross-linked with divinylbenzene using hydrosilylation reaction in the presence of a platinum catalyst. Pyrolysis in Ar/H2 mixtures, compared to the treatment under...
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Notes
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InGaN trapered laser diodes
PublikacjaW pracy zaprezentowano rezultaty badan nad diodami laserowymi InGaN ze zwężającym się kanałem. Kąty kanałów zmieniane były w zakresie 2 -5 stopni, jak również zmieniana była długość kanału. Wykazano, że w przypadku optymalnych parametrów, parametr M2 (M kwadrat) opisujący odtępstwa wiązki od krzywej Gaussa, wynosił 2.1 przy mocy optycznej 200 mW.
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High temperature oxidation behavior of SUS430 SOFC interconnects with Mn-Co spinel coating in air
PublikacjaIn this study, SUS430 alloy is evaluated for its high temperature corrosion properties as a possible material for interconnects of solid oxide fuel cells (SOFCs). Samples are coated with Mn-Co by commercial physical vapor deposition (PVD) process and oxidized in air for 1250 h at 800 °C. A dense cubic Mn-Co-Fe spinel layer is formed on the surface, showing great effect on corrosion reduction compared with the samples without coating....
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Fabrication and characterization of anode supported solid oxide fuel cells
PublikacjaW tej pracy, napylanie aerozolowe zawiesiny proszków jest oceniane jako metoda osadzania cienkich elektrolitów tlenkowych ogniw paliwowych. Metoda ta jest tania, prosta i mam zalety w stosunku do szeroko stosowanej metody sitodruku. Wpływ parametrów osadzania: stężenie zawiesiny, ciśnienie robocze są w artykule omawiane.
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Filled Carbon Nanotubes as Anode Materials for Lithium-Ion Batteries
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Pemphigus foliaceus in a patient with skin cancer with metastases to lymph nodes
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Solid oxide fuel cells with Ni-infiltrated perovskite anode
PublikacjaWytworzono próbki na bazie tytanianu strontu domieszkowanego niobem i przebadano wpływ nasączania niklem na właściwości tych materiałów.
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Sandwich Biobattery with Enzymatic Cathode and Zinc Anode Integrated with Sensor
PublikacjaCarbon paper covered with side-naphthylated multi walled carbon nanotubes was used as the conducting support for the construction of a biocathode in a hybrid biofuel cell. Laccase Carrena unicolor enzyme was employed as the catalyst for the 4e reduction of oxygen and a zinc disc covered with hopeite was used as the anode. Derivatized carbon nanotubes increase the working surface of the electrode and provide direct contact with...
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Dynamic host configuration protocol for IPv6 improvements for mobile nodes
PublikacjaIn wireless networks mobile clients change their physical location, which results in changing point of attachment to the network. Such handovers introduce unwanted periods, when node does not have communication capabilities. Depending on many conditions, such events may require reconfiguration of layer 2 (e.g. IEEE 802.16) or both 2 and 3 layers (IPv6). This paper investigates delays introduced in the latter type of handover. IPv6...
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Distributed state estimation using a network of asynchronous processing nodes
PublikacjaWe consider the problem of distributed state estimation of continuous-time stochastic processes using a~network of processing nodes. Each node performs measurement and estimation using the Kalman filtering technique, communicates its results to other nodes in the network, and utilizes similar results from the other nodes in its own computations. We assume that the connection graph of the network is not complete, i.e. not all nodes...
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Solid Oxide Fuel Cells with Ni infiltrated perovskite anode
PublikacjaNiobium-doped strontium titanate was used as the anode for a solid oxide fuel cell. Electrolyte-supported cells were prepared with pure perovskite and composite perovskite–yttria–stabilized-zirconia (YSZ) anodes. Fuel cell tests demonstrated significant improvement in power density after infiltration with a small amount of Ni. The obtained values of power densities are comparable with conventional Ni/YSZ cermet anode. In addition,...
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Low-temperature processed anode for Solid Oxide Fuel Cells
PublikacjaPrzygotowano i przebadano kompozytową anode Ni/YSZ, która została przygotowana z wykorzystaniem technologii net shape. Wyniki potwierdziły, że kompozyt może być wykorzystany jako potencjalna anoda w tlenkowych ogniwach paliwowych.
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Method of sacrificial anode transistor-driving in cathodic protection system
PublikacjaA magnesium anode driving system has been proposed. A PNP driving transistor has been used. Electrochemical testing in 3%NaCl, results and comparison of the driving system and classic direct anode to cathode connection are presented. The driving system reduced the protection current and stabilized the working conditions of the anode. Higher anode efficiency was achieved. Overprotection and hydrogen embrittlement threats were prevented...
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Distributed state estimation using a network of asynchronous processing nodes
PublikacjaWe consider the problem of distributed state estimation of continuous-time stochastic processes using a~network of processing nodes. Each node performs measurement and estimation using the Kalman filtering technique, communicates its results to other nodes in the network, and utilizes similar results from the other nodes in its own computations. We assume that the connection graph of the network is not complete, i.e. not all nodes...