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- Publikacje 1626 wyników po odfiltrowaniu
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Wyniki wyszukiwania dla: COOPER SULPHIDES
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On Design Optimization of Miniaturized Microscrip Dual-Band Rat-Race Coupler with Enhanced Bandwidth
PublikacjaIn the paper, a novel topology of a miniaturized wideband dual-band rat-race coupler has been presented. Small size of the circuit has been obtained by meandering transmission lines of the conventional circuit. At the same time, the number of independent geometry parameters has been increased in order to secure sufficient circuit flexibility in the context of its design optimization for dual-band operation. Optimum dimensions of...
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Novel structure and size-reduction-oriented design of microstrip compact rat-race coupler
PublikacjaIn this paper, a novel structure of a miniaturized microstrip rat-race coupler has been proposed. Surrogate-based optimization procedures are applied to explicitly reduce the coupler size while maintaining equal power split at the operating frequency of 1 GHz and sufficient bandwidth for return loss and isolation characteristics. The optimization is performed using the objective function with four penalty components. The footprint...
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Impact of High Pressure on Metallophilic Interactions and Its Consequences for Spectroscopic Properties of a Model Tetranuclear Silver(I)–Copper(I) Complex in the Solid State
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Relationship between copper(ii) complexes with FomA adhesin fragments ofF. nucleatumand colorectal cancer. Coordination pattern and ability to promote ROS production
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Coordination polymers based on octacyanometalates(iv,v) (M = Mo, W) and aliphatic polyamine copper(ii) tectons with [N3] donor atom sets
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Thermal Energy Development in Magnetohydrodynamic Flow Utilizing Titanium Dioxide, Copper Oxide and Aluminum Oxide Nanoparticles: Thermal Dispersion and Heat Generating Formularization
PublikacjaThe main aim of this article heat transfer in thermal engineering deals with the production, use, transformation, and transfer of thermal energy. Engineering and industrial fields including food packaging, the production of food additives, electronic cooling, microturbines, etc. heavily rely on heat transmission. Due to its intriguing potential in industries like the production of polymers, paper, crystal glass, etc., scientists...
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Synthesis and Structure of Novel Copper(II) Complexes with N,O- or N,N-Donors as Radical Scavengers and a Functional Model of the Active Sites in Metalloenzymes
PublikacjaToevaluatetheantioxidantactivityofpotentialsyntheticenzymemimetics,wepreparednewfivecopper(II)complexesviaaself‐assemblymethodandnamedthem[Cu(2‐(HOCH2)py)3](ClO4)2(1),[Cu(2‐(HOCH2)py)2(H2O)2]SiF6(2),[Cu2(2‐(HOCH2CH2)py)2(2‐(OCH2CH2)py)2](ClO4)2(3),[Cu(pyBIm)3](BF4)2∙1.5H2O(4)and[Cu(py2C(OH)2)2](ClO4)2(5).ThesyntheticprotocolinvolvedN,O‐ orN,N‐donors:2‐(hydroxymethyl)pyridine(2‐(HOCH2)py),2‐(hydroxyethyl)pyridine(2‐(HOCH2CH2)py),2‐(2‐pyridyl)benzimidazole(pyBIm),di(2‐pyridyl)ke‐tone(py2CO).TheobtainedCu(II)complexeswerefullycharacterisedbyelementalanalysis,FTIR,EPR,UV‐Vis,single‐crystalX‐raydiffractionandHirshfeldsurfaceanalysis.Crystallographicandspectroscopicanalysesconfirmedchromophoresofbothmonomeric({CuN3O3}(1),{CuN2O4}(2),{CuN6}(4),{CuN4O2}(5))anddimericcomplex({CuN2O3}(3)).Mostoftheobtainedspeciespos‐sessedadistortedoctahedralenvironment,exceptdimer3,whichconsistedoftwocoppercentreswithsquarepyramidalgeometries.Thewater‐solublecompounds(1,3and5)wereselectedforbiologicaltesting.Theresultsofthestudyrevealedthatcomplex1insolutionsdisplayedbetterradicalscavengingactivitythancomplexes3,5andfreeligands.Therefore,complex1hasbeenselectedforfurtherstudiestotestitsactivityasanenzymemimetic.Thechosencompoundwastestedontheerythrocytelysateoftwogroupsofpatientsafterundergoingchemotherapyandchemoradiotherapy.Theeffectofthetestedcompound(1)onenzymeactivitylevels(TAS,SODandCAT)suggeststhattheselectedcomplexcanbetreatedasafunctionalmimeticoftheenzymes.
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Conditions of spatiotemporal variability of the thickness of the ice cover on lakes in the Tatra Mountains
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Snow cover and its variability in the Polish Sudetes Mts. and the Sudetic Foreland
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REINFORCED CONCRETE SUPPORTING CONSTRUCTION OF THE STADIUM COVER FOR EURO 2012 IN GDAŃSK
PublikacjaIn the article structural issues that connected with the reinforced concrete supporting construction of the stadium roofing for EURO 2012 in Gdańsk were described. In the first part of the article the concept of stadium foundation were described. In the second the static - strength analysis for two variants fastening together individual foundation elements were made. The two assumed geometrically different concept of foundation...
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Improved selectivity compact band-stop filter with gosper fractal-shaped defected ground structures
PublikacjaA novel band-stop filter using Gosper fractal-shaped defected ground structures has been designed and manufactured. The improvement in the filter selectivity has been achieved by introducing a multiresonance fractal-shaped defect leading to a higher filter order, simultaneously maintaining its compact size. The experimental results prove the validity of proposed solution and its utility in novel miniaturized and severe requirement...
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Occurrence of cyanobacteria and cyanotoxin in the Southern Baltic Proper. Filamentous cyanobacteria versus single-celled picocyanobacteria
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Effect of Attractants and Micronutrient Biofortification on the Yield and Quality of Red Clover (Trifolium pratense L.) Seeds
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Hyponastic Leaves 1 Interacts with RNA Pol II to Ensure Proper Transcription of MicroRNA Genes
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Structural and Magnetic Properties of Co‒Mn Codoped ZnO Nanoparticles Obtained by Microwave Solvothermal Synthesis
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Closer look into the structures of tetrabutylammonium bromide–glycerol-based deep eutectic solvents and their mixtures with water
PublikacjaIn recent years, deep eutectic solvents (DES) and it’s mixture with water have become more and more attention as green solvents used in chemistry. However, there are only a few theoretical studies on the mechanisms of pure DES and DES-water complex formation. Therefore, the structural properties of tetrabutylammonium bromide–glycerol-based deep eutectic solvents and their mixtures with water have been investigated by means of Molecular...
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Engineering boron and nitrogen codoped carbon nanoarchitectures to tailor molecularly imprinted polymers for PFOS determination
PublikacjaPer- and polyfluoroalkyl substances (PFAS) have gained significant attention as emerging contaminants due to their persistence, abundance, and adverse health effects. Consequently, the urgent need for ubiquitous and effective sensors capable of detecting and quantifying PFAS in complex environmental samples has become a priority. In this study, we present the development of an ultrasensitive molecularly imprinted polymer (MIP)...
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Evidence for widespread occurrence of copper in Late Neolithic Poland? A deposit of Funnel Beaker Culture bone products at site 2 in Osłonki (Kuyavia, central Poland)
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Effect of copper and silver modification of NH2-MIL-125(Ti) on the photoreduction of carbon dioxide to formic acid over this framework under visible-light irradiation
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The comparison of the removal of copper(II) and zinc(II) ions from aqueous solution using 2,6-diaminopyridine in a polymer inclusion membrane and in a classic solvent extraction
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Aiding (opponent) flow of hybrid copper–aluminum oxide nanofluid towards an exponentially extending (lessening) sheet with thermal radiation and heat source (sink) impact
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Copper(II) coordination properties of GxG peptides: Key role of side chains of central residues on coordination of formed systems; combined potentiometric and ITC studies
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Effect of copper and silver modification of NH2-MIL-125(Ti) on the photoreduction of carbon dioxide to formic acid over this framework under visible-light irradiation
PublikacjaCu and Ag enhance the photocatalytic activities of metal–organic frameworks (MOFs) toward CO2 conversion because of their CO2 adsorption capacities and effects on the lowest unoccupied molecular orbital (LUMO) overpotentials of MOFs. However, to date, targeted introduction of metals into MOFs to achieve visible (Vis)- light-active photocatalysts for CO2 photoconversion has not been realized. Herein, a series of aminefunctionalized...
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Durability of snow cover and its long-term variability in the Western Sudetes Mountains
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Duration of snow cover and its variability in the Polish part of the Sudetes Mts. and their foreland
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Monitoring Trends of Land Use and Land Cover Changes in Rajang River Basin
PublikacjaIn this study, the spatiotemporal changes in land use and land cover (LULC) were evaluated from 1992 to 2015 for the Rajang River Basin (RRB) located in the Sarawak State of Malaysia. The changes in water bodies cropped lands, and forests were assessed based on the available remotely sensed satellite data. Supervised classification with the Maximum-Likelihood-Algorithm technique was adopted for monitoring the LULC changes using...
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Industry 4.0—Supporting Industry in Design Solutions—All-in-One Computer Cover
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Seasonal and spatial differences in metal and metalloid concentrations in the snow cover of Hansbreen, Svalbard
PublikacjaMetals and metalloids in snow on glaciers, depending on the season of deposition, may come from various sources: local rock dust (erosion of the geological substratum), marine aerosol, local human activity (e.g. fuel combustion, waste incineration) and long-range atmospheric transport. Hansbreen glacier, located close to the Polish Polar Station in Svalbard, is a perfect site to study metals and metalloids: it has complex geological...
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THE METHOD OF MEASURING THE MEMBRANE COVER GEOMETRY USING LASER SCANNING AND SYNCHRONOUS PHOTOGRAMMETRY
PublikacjaThe authors present the experience and results of field studies carried out at the technical acceptance of Forest Opera (name in Polish: Opera Leśna) in Sopot (Poland). An unusual design of covering made in the form of “Sheerfill I” technical fabric membrane required spanned in the form of sails, required the use of terrestrial laser scanning. Such approach allowed for the fast and accurate record of the surface of individual panels...
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Hydrological responses to large-scale changes in land cover of river watershed: Review
PublikacjaDespite many studies on the hydrological responses to forest cover changes in micro and mesoscale watersheds, the hydrological responses to forest cover alterations and associated mechanisms through the large spatial scale of the river watershed have not been comprehensively perceived. This paper thus reviews a wide range of available scientific evidence concerning the impacts exerted by the forest removal on precipitation, water...
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Assessment of the impact of jet impingement technique on the energy efficiency of air-cooled BIPV/T roof tile
PublikacjaThe paper concerns a numerical analysis of cooling of the hybrid photovoltaic (PV) modules dedicated to Building-Integrated Photovoltaic/Thermal (BIPV/T) systems. Attention was focused on the photovoltaic roof tiles, using a jet impingement technique, in which the intensification of heat transfer is ensured by streams of air hitting the heat exchange partition. A series of numerical simulations were carried out to assess an influence...
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Tailoring Defects in B, N-Codoped Carbon Nanowalls for Direct Electrochemical Oxidation of Glyphosate and its Metabolites
PublikacjaTailoring the defects in graphene and its related carbon allotropes has great potential to exploit their enhanced electrochemical properties for energy applications, environmental remediation, and sensing. Vertical graphene, also known as carbon nanowalls (CNWs), exhibits a large surface area, enhanced charge transfer capability, and high defect density, making it suitable for a wide range of emerging applications. However, precise...
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Air-cooled photovoltaic roof tile as an example of the BIPVT system – An experimental study on the energy and exergy performance
PublikacjaThe air-cooled photovoltaic tile is a subject of presented investigations, which focused on improving the overall system efficiency of PV tiles with heat recovery. The operational efficiency of a PV roof tile, together with the construction optimising the air cooling efficiency, were the main points of plans realized at this research stage. The article describes the experimental research consisting of the assessment of electrical,...
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A structure and design optimization of novel compact microscrip dual-band rat-race coupler with enhanced bandwidth
PublikacjaIn the letter, a topology of a novel compact wideband dual-band rat-race coupler has been presented along with its computationally efficient design optimization procedure. Reduction of the circuit size has been achieved by meandering transmission lines of the conventional circuit. At the same time, the number of independent geometry parameters has been increased so as to secure sufficient flexibility of the circuit, necessary in...
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Finite element analysis on failure of reinforced concrete corner in sewage tank under opening bending moment
PublikacjaW artykule omówiono mechanizm uszkodzenia żelbetowego zbiornika ściekowego w narożniku ściany, który uległ uszkodzeniu podczas próby wypełnienia na skutek nadmiernych przemieszczeń poziomych ścian pod wpływem otwierającego momentu zginającego. Aby wyjaśnić przyczyny awarii, przeprowadzono kompleksowe obliczenia metodą elementów skończonych (MES) żelbetowego zbiornika w warunkach odkształcenia płaskiego. Beton zamodelowano za pomocą...
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Crystal structure, DFT-study and NLO properties of the novel copper(I) nitrate π,σ-coordination compound based on 1-allyl-3-norbornan-thiourea
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Optical measurements of LTO:Cu sol-gel derived thin films
Dane BadawczeLithium titanate doped by copper thin films were manufactured by chemical, sol-gel method. Flms were deposited on a Corning glass substrated by spin coater. To calculated optical band gap and other optcal parameters, UV-VIS spectroscopy measurements were performed. For measurements selected samples with various content of Cu.
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Linking the diversity of native flora to land cover heterogeneity and plant invasions in a river valley
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Biological and Agrotechnical Aspects of Weed Control in the Cultivation of Early Potato Cultivars under Cover
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Reasons for shortening snow cover duration in the Western Sudetes in light of global climate change
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Land cover transitions and changing climate conditions in the Polish Carpathians: Assessment and management implications
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Similarities and Differences Between the Vertex Cover Number and the Weakly Connected Domination Number of a Graph
PublikacjaA vertex cover of a graph G = (V, E) is a set X ⊂ V such that each edge of G is incident to at least one vertex of X. The ve cardinality of a vertex cover of G. A dominating set D ⊆ V is a weakly connected dominating set of G if the subgraph G[D]w = (N[D], Ew) weakly induced by D, is connected, where Ew is the set of all edges having at least one vertex in D. The weakly connected domination number γw(G) of G is the minimum cardinality...
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The X-ray crystallographic structures, spectral and magnetic properties of nickel(II), copper(II) and cobalt(II) complexes with tetra(3-iso-propylpyrazol-1-yl)borate
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Interference-Free Determination of Trace Copper in Freshly Ripened Honeys by Flame Atomic Absorption Spectrometry Following a Preconcentration by Solid-Phase Extraction and a Two-Step Elution Process
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Adsorption behavior and corrosion inhibitive characteristics of newly synthesized cyano-benzylidene xanthenes on copper/sodium hydroxide interface: Electrochemical, X-ray photoelectron spectroscopy and theoretical studies
PublikacjaElegant process for synthesis of 3-(7H-dibenzo[c,h]xanthen-7-yl)benzaldehyde (3), as new starting material to create a set of novel xanthene analogues, 2-(3-(7H-dibenzo[c,h]xanthen-7-yl)benzylidene)malononitrile (4), 3-(3-(7H-dibenzo[c,h]xanthen-7-yl)phenyl)-2-cyanoacrylic acid (5), and Ethyl-3-(3-(7H-dibenzo[c,h]xanthen-7-yl)phenyl)-2-cyanoacrylate (6), was achieved starting with available materials under mild conditions. Various...
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White Clover (Trifolium repens L.) Cultivation as a Means of Soil Regeneration and Pursuit of a Sustainable Food System Model
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Implementations of Nosé–Hoover and Nosé–Poincaré thermostats in mesoscopic dynamic simulations with the united-residue model of a polypeptide chain
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Reforms of Polish Antitrust Law: Closer to, or Further From, the European Model? Journal of European Competition Law and Practice
PublikacjaThe Polish Act on the Protection of Competition and Consumers has been recently amended. Changes include the introduction of a two-phase based merger control, a more efficient leniency program, and the administrative liability of individuals involved in antitrust agreements.
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Comparison analysis of selected nuclear power plants supplied with helium from high-temperature gas-cooled reactor
PublikacjaThe article presents results of efficiency calculations for two 560 MW nuclear cycles with high-temperature gas-cooled reactor (HTGR). An assumption was made that systems of this type can be used in so-called marine nuclear power plants. The first analysed system is the nuclear steam power plant. For the steam cycle, the efficiency calculations were performed with the code DIAGAR, which is dedicated for analysing this type of systems....
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bio-based polyester polyols - chemical structure of Miniatura 4 proper samples
Dane BadawczePresented results are related with project MINIATURA 4 realization. At the document, the chemical structure of bio-based polyester polyols (poly(propylene-co-propan-1,2,3-triol succinate)s) are presented as analysis of FTIR and H NMR spectroscopy.