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wszystkich: 858
Wyniki wyszukiwania dla: CLAISEN REARRANGEMENT
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The phenylnitrene rearrangment in the inner phase of a hemicarcerand
PublikacjaOpisano przegrupowanie fenylonitrenu wewnątrz kompleksu hemikarceratowego.
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Photochemical Rearrangement of a 19-Membered Azoxybenzocrown: Products and their Properties
PublikacjaThe preparation and characterization of products of the chemical and photochemical rearrangements of a 19-membered o,o'-azoxybenzocrown were presented. In photochemical rearrangement, besides expected product i.e. 19-membered o-hydroxy-o,o'-azobenzocrown (19-o-OH), obtained under defined conditions with 75% yield, also other macrocyclic products were isolated and identified, namely: 19-membered p-hydroxy-o,o'-azobenzocrown (19-p-OH),...
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First recurrent large genomic rearrangement in the BRCA1 gene found in Poland
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Modern Arrangement for Reduction of Voltage Perturbations
PublikacjaThe contents of this chapter encompass general problems and the most important issues of power-supply-quality improvement in AC systems. In the context of the above, consideration is given to evaluation of bilateral interactions of receivers with an electrical power-distribution system and methods of their reduction. Also are discussed the basis of operation of the most important compensation-filtration devices and their applications...
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Otopy classes of equivariant maps
PublikacjaW artykule definiuje się stopień topologiczny niezmienniczych odwzorowań lokalnych w przypadku gradientowym i niegradientowym. Wyniki dotyczą relacji pomiędzy tymi dwoma niezmiennikami topologicznymi.
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Graph classes generated by Mycielskians
PublikacjaIn this paper we use the classical notion of weak Mycielskian M'(G) of a graph G and the following sequence: M'_{0}(G) =G, M'_{1}(G)=M'(G), and M'_{n}(G)=M'(M'_{n−1}(G)), to show that if G is a complete graph oforder p, then the above sequence is a generator of the class of p-colorable graphs. Similarly, using Mycielskian M(G) we show that analogously defined sequence is a generator of the class consisting of graphs for which the...
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Products of Photo- and Thermochemical Rearrangement of 19-Membered di-tert-Butyl-Azoxybenzocrown
PublikacjaThe preparation and characterization of products of the photochemical and thermochemical rearrangements of 19-membered azoxybenzocrowns with two, bulky, tert-butyl substituents in benzene rings in the para positions to oligooxyethylene fragments (meta positions to azoxy group, i.e., t-Bu-19-Azo-O have been presented. In photochemical rearrangement, two colored typical products were expected, i.e., 19-membered o-hydroxy-m,m′-di-tert-butyl-azobenzocrown...
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Rearrangement of azoxybenzocrowns into chromophoric hydroxyazobenzocrowns and the use of hydroxyazobenzocrowns for the synthesis of ionophoric biscrown compounds
PublikacjaThe Wallach rearrangement was used as a method for preparing p-hydroxyazobenzocrown ethers starting from different azoxybenzocrowns as substrates. Synthesis of a series of p-hydroxyazobenzocrowns under modified conditions and characterization of the obtained products are presented. o-Hydroxyazobenzocrowns were identified among the products of the photochemical rearrangement of azoxybenzocrowns. Novel biscrowns were synthesized...
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Enantiopure C1-Cyclotriveratrylene with a Reversed Spatial Arrangement of the Substituents
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Classification of homotopy classes of equivariant gradient maps
PublikacjaNiech V będzie ortogonalną reprezentacją zwartej grupy Liego Gi niech S(V),D(V) oznaczają sferę jednostkową i kulę jednostkową V.Jeżeli F jest G-niezmienniczą funkcją rzeczywistą klasy C^1 na Vto mówimy, że grad F (gradient F) jest dopuszczalny, jeżeli(grad F)(x) jest różny od zera dla x należących do S(V). Pracapoświęcona jest homotopijnej klasyfikacji dopuszczalnychG-niezmienniczych odwzorowań gradientowych.
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A Noether theorem for stochastic operators on Schatten classes
PublikacjaWe prove that a stochastic (Markov) operator S acting on a Schatten class C_1 satisfies the Noether condition S'(A) = A and S'(A^2) = A^2, where A is a Hermitian bounded linear operator on a complex Hilbert space H, if and only if, S(E(G)XE(G)) = E(G)S(X)E(G) holds true for every Borel subset G of the real line R, where E(G) denotes the orthogonal projection coming from the spectral resolution of A. Similar results are obtained...
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Experimental Investigations on the Influence of Coil Arrangement on Melting/Solidification Processes
PublikacjaThe latent heat thermal energy storage units are very popular because of their high energy density and almost close to constant temperature during the charging/discharging. In the present study has been proposed new shell-and-coil geometry with a shifted coil position to enhance the performance of phase change thermal magazine. The experimental investigations have been performed both for the melting and solidification process of...
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Numerical Analysis of Flow in Building Arrangement: Computational Domain Discretization
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Pre-arrangement of solvability, complexity, stability and quality of GPC systems
PublikacjaPraca dotyczy podstawowych problemów strojenia algorytmów dyskretnoczasowego uogólnienia sterowania predykcyjnego (GPC). Optymalne sterowanie predykcyjne, w sensie pewnego kwadratowego funkcjonału kosztów, wyznacza się rozwiązując odpowiednie liniowe zadanie. W pracy podano warunki, przy których macierz tego zadania jest macierzą o pełnym kolumnowym rzędzie - co gwarantuje istnienie optymalnego sterownika. W następnej kolejności...
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Photochemical and thermal reaction of intermediates in the phenylnitrene rearangment inside a hemicarcerand
PublikacjaBroadband irradiation (λ > 320 nm) of hemicarceplex H1 between −74 °C and −84 °C, produces encapsulated didehydroazepine (2), triplet phenylnitrene (3PN), 2-azabicyclo[3.2.0]hepta-1,3,6-triene (6), and 4-azaspiro[2.4]hepta-1,4,6-triene (7). The highly strained anti-Bredt imine 6 is formed from 2 via a photochemical four-electron electrocyclization. Under the irradiation conditions, 6 rearranges further to azaspirene 7. In addition,...
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Rearrangements of the nitrifiers population in an activated sludge system under decreasing solids retention times
PublikacjaDue to the key role of nitrite in novel nitrogen removal systems, nitrite oxidizing bacteria (NOB) have been receiving increasing attention. In this study, the coexistence and interactions of nitrifying bacteria were explored at decreasing solids retention times (SRTs). Four 5-week washout experiments were carried out in laboratory-scale (V=10 L) sequencing batch reactors (SBRs) with mixed liquor from two full-scale activated sludge...
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Two classes of capillary optical fibers: refractive and photonic
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Stathmin reduction and cytoskeleton rearrangement in rat nucleus accumbens in response to clozapine and risperidone treatment – Comparative proteomic study
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Stock price reactions to an arrangement approval in restructuring proceedings – the case of Poland
PublikacjaThe study aims to empirically analyze the reaction of stock prices to the information about the conclusion and acceptance of a debtor–creditor arrangement under restructuring proceedings of companies listed on the stock exchange in Poland. The following main research hypothesis was verified: public disclosure of information about an arrangement conclusion and acceptance in restructuring proceedings...
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Effect of Tube Bundle Arrangement on the Performance of PCM Heat Storage Units
PublikacjaThe results of comprehensive study on charging and discharging of latent heat storage systems (LHSS) are presented. The multi tube shell-and-tube unit with a variable layouts of the tube bundles are examined. Two tube arrangements – in-line and staggered are tested. A variable number of tubes and different tube positions in a bundle are investigated. Moreover, two pitch ratios are studied. Three commercially available substances...