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Search results for: DEVULCANIZED CRUMB TIRE RUBBER
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Ground Tire Rubber Modified by Elastomers via Low-Temperature Extrusion Process: Physico-Mechanical Properties and Volatile Organic Emission Assessment
PublicationIn this paper, low-temperature extrusion of ground tire rubber was performed as a proecological waste tires recycling method. During this process, ground tire rubber was modified with constant content of dicumyl peroxide and a variable amount of elastomer (in the range: 2.5–15 phr). During the studies, three types of elastomers were used: styrene-butadiene rubber, styreneethylene/butylene-styrene grafted with maleic anhydride and...
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Characterization and properties of LDPE/(ground tire rubber)/crosslinked butyl rubber blends
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Investigating the combined impact of plasticizer and shear force on the efficiency of low temperature reclaiming of ground tire rubber (GTR)
PublicationIn the present work, ground tire rubber (GTR) was mechano-chemically reclaimed at ambient temperature using two-roll mills. Road bitumen and styrene-butadiene-styrene (SBS)-modified bitumen at variable content (in range: 2.5–20 phr) were applied as reactive plasticizers to enhance reclaiming of GTR. For better understanding the plasticizing effect of bitumen on the quality of obtained reclaimed rubber, mechano-chemically reclaimed...
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Insights into Stoichiometry Adjustments Governing the Performance of Flexible Foamed Polyurethane/Ground Tire Rubber Composites
PublicationPolyurethanes (PU) are widely applied in the industry due to their tunable performance adjusted by changes in the isocyanate index—stoichiometric balance between isocyanate and hydroxyl groups. This balance is affected by the incorporation of modifiers of fillers into the PU matrix and is especially crucial for PU foams due to the additional role of isocyanates—foaming of the material. Despite the awareness of the issue underlined...
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The Impact of Hybrid Flame Retardant Compositions on the Performance of Foamed Flexible Polyurethane/Ground Tire Rubber Composites
PublicationCurrent sustainability-oriented trends affect polyurethane (PU) materials and stimulate the incorporation of recycled or waste-based materials as fillers. Ground tire rubber (GTR) poses as an auspicious candidate due to the excellent performance of car tires. Despite the benefits related to the mechanical performance, it contributes to the increasing flammability of the resulting composites. Herein, presented work assessed the...
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Reactive Extrusion of Waste Plastics with Compatibilizer and Lightly Pyrolyzed Crumb Rubber for Asphalt Modification
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Ground Tire Rubber Modified by Ethylene-Vinyl Acetate Copolymer: Processing, Physico-Mechanical Properties, Volatile Organic Compounds Emission and Recycling Possibility
PublicationGround tire rubber (GTR) was reclaimed and modified with 10 phr of ethylene-vinyl acetate copolymer via low-temperature extrusion process. Processing, physico-mechanical properties, volatile organic compounds emission, and recycling possibility were investigated. In order to better understand the impact of used modifiers, their efficiency was compared with transpolyoctenamer, which is an additive that is commercially dedicated...
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Structural Changes and Their Implications in Foamed Flexible Polyurethane Composites Filled with Rapeseed Oil-Treated Ground Tire Rubber
PublicationThe utilization of post-consumer car tires is an essential issue from an ecological andeconomic point of view. One of the simplest and the least harmful methods is their material recyclingresulting in ground tire rubber (GTR), which can be further applied as fillers for polymer-basedcomposites. Nevertheless, insufficient interfacial interactions implicate the necessity of GTR modi-fication before introduction into polymer matrices....
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Fire-Retardant Flexible Foamed Polyurethane (PU)-Based Composites: Armed and Charmed Ground Tire Rubber (GTR) Particles
PublicationInadequate fire resistance of polymers raises questions about their advanced applications. Flexible polyurethane (PU) foams have myriad applications but inherently suffer from very high flammability. Because of the dependency of the ultimate properties (mechanical and damping performance) of PU foams on their cellular structure, reinforcement of PU with additives brings about further concerns. Though they are highly flammable and...
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Recycled polyethylene and crumb rubber composites modified asphalt with improved aging resistance and thermal stability
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The Impact of Isocyanate Index and Filler Functionalities on the Performance of Flexible Foamed Polyurethane/Ground Tire Rubber Composites
PublicationThe structure and performance of polyurethane (PU) foams are strongly driven by the stoichiometry of the polyaddition reaction, quantitatively described by the isocyanate index. It determines the balance between isocyanate and hydroxyl groups in the reacting system and is affected by the introduction of additional functionalities originated, e.g., from applied fillers. Nevertheless, this issue is hardly taken into account in research...
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Reclaiming ground tire rubber at low temperatures: benefits and limitations
PublicationLower extrusion temperatures during rubber reclamation lead to a reduction in toxic degradation products and improve the mechanical properties of vulcanizates, at the expense of reduced processability.
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Modification of Ground Tire Rubber—Promising Approach for Development of Green Composites
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Structural, thermal and physico-mechanical properties of polyurethane/brewers’ spent grain composite foams modified with ground tire rubber
PublicationIn this work, brewers’ spent grain (BSG) and ground tire rubber (GTR) waste fillers were applied as low-cost reinforcement phase in rigid polyurethane foam (PUR). PUR/BSG/GTR composites were prepared by a single step method, using polyglycerol as partial substitute of commercially available petrochemical polyols. Foaming parameters, chemical structure, dynamic mechanical properties, thermal stability, physico-mechanical properties...
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Alkali-activated slag (AAS) and OPC-based composites containing crumb rubber aggregate: Physico-mechanical properties, durability and oxidation of rubber upon NaOH treatment
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Investigating the Impact of Curing System on Structure-Property Relationship of Natural Rubber Modified with Brewery By-Product and Ground Tire Rubber
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Comprehensive Enhancement of Prepolymer-Based Flexible Polyurethane Foams’ Performance by Introduction of Cost-Effective Waste-Based Ground Tire Rubber Particles
PublicationMaterial innovations in polyurethane (PU) foams should ideally combine performance enhancement, environmental impact limitation, and cost reduction. These goals can be achieved by applying recycled or waste-based materials without broader industrial applications, implicating their low price. Herein, from 5 to 20 parts by weight of ground tire rubber (GTR) particles originated from the recycling of postconsumer car tires were incorporated...
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The impact of filler thermomechanical modifications on static and dynamic mechanical performance of flexible foamed polyurethane/ground tire rubber/zinc borate composites
PublicationThe rapid development of the automotive industry is very beneficial to many aspects of human life, but it is also a very significant environmental burden. The most straightforward impact is related to the generation of exhaust, but the management of post-consumer car parts is also a major challenge. Among them, waste tires are very burdensome due to their enormous numbers. Therefore, it is essential to develop novel, environmentally...
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Waste tire rubber as low-cost and environmentally-friendly modifier in thermoset polymers – A review
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Thermomechanical reclaiming of ground tire rubber via extrusion at low temperature: Efficiency and limits
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The influence of feed rate and shear forces on the devulcanization process of ground tire rubber (GTR) conducted in a co-rotating twin screw extruder
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Evaluation and rationale of the performance of several elastomeric composites incorporating devulcanized EPDM
Publicationthylene Propylene Diene rubber (EPDM), is present in many applications. However, its crosslinked structure makes difficult its recycling. The use of devulcanized EPDM, (dEPDM) as a component of elastomeric composites, is a real possibility to reuse EPDM scraps. In this study, three matrices (natural rubber (NR), styrene butadiene rubber (SBR) and EPDM rubber) have been tested including devulcanized EPDM as a recycled component....
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Evaluation of Low Temperature Properties of Rubberized Asphalt Mixtures
PublicationThe paper presents low-temperature test results of asphalt mixtures designed with use of bitumen modified by crumb rubber and also SBS polymer. Laboratory tests were conducted on two types of asphalt mixtures for wearing course – stone matrix asphalt (SMA 8) and porous asphalt (PA 8). This paper presents results of the following laboratory tests at low temperatures: TSRST test, three point bending creep test, fracture toughness...
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The influence of rubber recyclate morphology on the properties of rubber-asphalt composite
PublicationIn the paper wastes, mostly in the form of used tires, were analyzed. One of the methods of waste tires application use them as a modifier of asphalt. However, the properties of rubber-asphalt composites depend on the morphology of waste tiregranulate and kind of tire recycled (car/truck). In this chapter, the influence of grinding methods of waste tire on the prop¬erties of rubber-asphalt composites were studied. SEM analysis...
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Recycling of Waste Rubber by Thermo-Mechanical Treatment in a Twin-Screw Extruder
PublicationRecycling of waste tires is a significant issue considering both environmental and economic aspects. One of the leading recycling routes is the shredding of tires resulting in the generation of ground tire rubber. This material can be easily introduced into various polymer matrices as a filler, reducing the use of conventionally applied petroleum-based materials. In such cases, it is essential to ensure sufficient interfacial compatibility,...
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Vegetable derived-oil facilitating carbon black migration from waste tire rubbers and its reinforcement effect
PublicationThree dimensional chemically cross-linked polymer networks present a great challenge for recycling and reutilization of waste tire rubber. In this work, the covalently cross-linked networks of ground tire rubber (GTR) were degraded heterogeneously under 150 °C due to the synergistic effects of the soybean oil and controlled oxidation. The degradation mechanism was discussed using Horikx theory and Fourier transformation infrared...
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Recycling of Waste Rubber by the Manufacturing of Foamed Polyurethane-Based Composites—Current State and Perspectives
PublicationWorn car tires are disruptive waste, and the issue of their management is crucial for the natural environment. In many countries, the primary method of end-of-life tires utilization is energy recovery. However, more effective and beneficial for the environment is material recycling. Using them for the production of polymer-rubber composites seems to be an auspicious direction of research. Incorporation of ground tire rubber into...
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Study on polymer modified road asphalt mixture
PublicationThe formulation of ternary asphalt-additives blend composed of crumb rubber : low-density polyethylene (CR : LDPE) and crumb rubber : textile fiber (CR : TF) couples, and quaternary asphalt additives-blend composed of (CR : LDPE : TF) triplets on the virgin asphalt to optimize the asphalt basic and rheological properties and to use the extrusion process of two or three additives to obtain composite materials of them, as well as...
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Reclaimed rubber in-situ grafted with soybean oil as a novel green reactive plasticizer in SBR/silica compounds
PublicationPolymer recycling and biodegradable polymeric materials are two major routes towards the sustainable development of polymer materials which contributes to the management of waste. In this regard, an eco-friendly approach is presented wherein high reclaiming degree of ground tire rubber (GTR) was achieved by low-temperature oxidation under swollen action of soybean oil. In-situ reclaimed GTR with soybean oil was cured into reactive...
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Low Noise Poroelastic Road Pavements Based On Bituminous Binder
PublicationTire/road noise is the dominant source of traffic noise. It depends both on the tire design and on the characteristics of road pavements as well as on the vehicles’ operating conditions. Due to the fact that conventional (pneumatic) car tires have almost reached the limits of their ability to further reduce their noisiness, it is widely believed that the additional reduction of tire noise will be possible mainly through modifications...
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Charakterystyka procesu ciągłej dewulkanizacji termomechanicznej z zastosowaniem metod doświadczalnych
PublicationBadano proces termomechanicznej dewulkanizacji rozdrobnionych odpadów gumowych prowadzono przy użyciu wytłaczarki dwuślimakowej współbieżnej o specjalnej konfiguracji układu uplastyczniającej, umożliwiającego wywieranie znacznych sił ścinających na miał gumowy. W badaniach doświadczalnych zastosowano metodę powierzchni odpowiedzi RSM (response surface methodology). Wyznaczono modele matematyczne wyrażające zmienność właściwości...
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Wpływ termoplastycznych kompozycji napełnianych miałem gumowym na wybrane właściwości asfaltu drogowego
PublicationDynamiczny rozwój transportu samochodowego zmusza do wykonywania nawierzchni drogowych z materiałów o wysokiej wytrzymałości oraz odporności na odkształcenia trwałe, co znacznie wydłuża żywotność nawierzchni. Polskie przedsiębiorstwo BISEK Sp. z o.o. z Wrocławia we współpracy z Politechniką Wrocławską, jako pierwsze wykorzystało miał gumowy do modyfikacji asfaltów metodą mokrą. W chwili obecnej firma Lotos Asfalt Sp. z o.o. wprowadziła...
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Processing, physico-mechanical and thermal properties of reclaimed GTR and NBR/reclaimed GTR blends as function of various additives
PublicationIn this work, ground tire rubber (GTR) was mechano-chemically reclaimed in the presence of bitumen and various additives. During studies three types of processing and curing additives: (i) peptizer P300; (ii) vulcanization accelerator tetramethylthiuram disulfide (TMTD) and (iii) organic peroxide di(2-tert-butyl-peroxyisopropyl)benzene (BIB1) were applied to enhance reclaiming of GTR. Reclaiming process was evaluated by oscillating...
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Rolling resistance and tyre/road noise on rubberised asphalt pavement in Poland
PublicationThe paper presents results of tyre/road noise and rolling resistance measurements performed on stone mastics asphalt (SMA) that contains rubberised asphalt, developed and produced by a refinery in Poland. Bituminous binder was modified with polymer and addition of crumb rubber. The first observations of asphalt mixture with the new kind of modified bitumen used on the field section are presented. Rolling resistance of passenger...
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Wpływ polietylenu szczepionego bezwodnikiem maleinowym oraz sił ścinających na właściwości mieszanin polietylen wysokiej gęstości-miał gumowy
PublicationScharakteryzowano wpływ kompatybilizatora w postaci polietylenu szczepionego bezwodnikiem maleinowym na właściwości mieszanin PE-HD–miał gumowy. Kompozycje termoplastyczne zawierające 50 cz. mas. rozdrobnionych odpadów gumowych, otrzymano przy użyciu współbieżnej wytłaczarki dwuślimakowej. Poziom sił ścinających generowanych podczas mieszania, regulowano za pomocą zmian prędkości obrotowych ślimaków. Przeprowadzono charakterystykę...
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Assessment of the devulcanization process of EPDM waste from roofing systems by combined thermomechanical/microwave procedures
PublicationEthylene-propylene-diene rubber (EPDM) is a elastomer widely used in common industrial applications. EPDM can be shaped into sheets and employed as isolating material for roofing systems. In this study, scraps of EPDM from commercial, industrial and residential roofing systems were treated by combined thermo-mechanical and microwave devulcanization processes including peroxide of benzoyl (BPO). The devulcanized EPDM (Dev-EPDM)...
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Influence of microwave treatment conditions of GTR on physico-mechanical and structural properties of NBR/NR/GTR composites
PublicationThe increasing amount of tires used in the industry induces the researchers to find alternatives to the recycling of the end-of-life tires. Several alternatives in order to application of ground tire rubber GTR include their incorporation as a filler in composites. The main issue in this approach is the lack of compatibility between GTR and polymer matrix. In order to solve this problem the devulcanization by microwaves has been...
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Influence of cooling rate and additives on low-temperature properties of asphalt mixtures in the TSRST
PublicationThe paper presents the results and analysis of low-temperature properties of asphalt mixtures according to Thermal Stress Restrained Specimen Test (TSRST) and Indirect Tensile Test methods. Different groups of bitumen were investigated: neat, SBS-modified and highly SBS-modified. Influence of cooling rates (1 C/h, 3 C/h, 5 C/h and 10 C/h) and additives (aramid fibres and crumb rubber) was identified as well. Moreover, for each...
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Thermoplastic Elastomers Filled With GTR
PublicationIn recent years, searching for new and cost-effective methods of recycling waste tires has been a subject of research in many laboratories worldwide. This is due to regulations in the law and environmental factors, which have both stimulated industry to re-use high quality rubber found in ground tire rubber (GTR). One of the most promising solutions in this area seems to be thermoplastic elastomers (TPEs) filled with GTR, which...
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Interfacial adhesion evaluation in (low-density polyethylene)/elastomer blends
PublicationLow-density polyethylene (LDPE) with different elastomers at a ratio of 50/50 wt% blends was prepared by using a co-rotating twin-screw extruder. Three kinds of elastomers were used: ground tire rubber (GTR), partially crosslinked butyl rubber (KalarVR ), and styrenebutadiene- rubber block copolymer (SBS; KratonVR ). For better characterization of interaction between polyethylene and elastomer, influence of the type of elastomer on...
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Eco-friendly modification of bitumen: The effects of rubber wastes and castor oil on the microstructure, processability and properties
PublicationThe bitumen industry in the European Union is facing several difficulties, including rising demand, unstable oil supply, rising prices for synthetic polymer modifiers, and a focus on lowering carbon footprint. Bitumen modification with crumb rubber (CR) is one of the most promising solution to these challenges. However, CR-modified bitumen have poor processability and low storage stability. To overcome these flaws we are introducing...
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Pyrolysis Process of Whole Waste Tires as a Biomass Energy Recycling
PublicationThe article is devoted to the description of material recycling of whole waste tires, including a new method of pyrolysis process, resulting in the final products: technically oil fractions (rubber plasticizer of rubber compounds) or diesel fuels (light, medium and heavy), activated carbon, gas fuel and steel scrap. Operational and performance tests of the first version of the pilot plant, consisting of three contributions cooperating...
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Enhanced interfacial and mechanical performance of styrene-butadiene rubber/silica composites compatibilized by soybean oil derived silanized plasticization
PublicationSilanized plasticizer (SP) was chemically derived and synthesized from soybean oil (SBO) co-vulcanized with bis-(3-(triethoxysilyl)-propyl) tetrasulfide (TESPT) by using the sulfur-accelerated curing system. SP extended styrene-butadiene rubber (SBR)/silica composites have been studied for their improved filler dispersion through coupling interaction at the SBR/silica interface. The effect of SP on cross-link density, thermal,...
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A recent developments in polyurethane foams containing a low-cost and pro-ecological modifiers
PublicationDiversity of the polyurethane (PU) foams applications cause that investigation of the relationships between their structure and properties is currently very popular topic among the many research institutions and companies. At the turn of the last years many scientific papers about PU foams and their composites were published. The one of the main research trends in this field is related to the reduction of production costs of...
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Ultra Low Noise Poroelastic Road Surfaces
PublicationNoise is one of the most important environmental problems related to road traffic. During the last decades, the noise emitted by the engines and powertrains of vehicles was greatly reduced and tires became a clearly dominant noise source. The article describes the concept of low noise poroelastic road surfaces that are composed of mineral and rubber aggregate bound by polyurethane resin. Those surfaces have a porous structure and...
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Recycling of waste tires in the light of binding law in Poland
PublicationA risings of large quantities of used rubber products, especially used tires has been increasing every year in Poland, in 2006 it was 160 thousand. The waste management and recycling of used tires become a major environmental problem. Well known methods of utilization of used tires are presented in this article. The main problem is ignorance of the law by tyre manufactures and users. In Poland first act on waste introduces ban...
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Rubber wastes recycling for developing advanced polymer composites: A warm handshake with sustainability
PublicationRecycling and management of rubber wastes experiences an early-stage maturity in the quest for sustainable and circular materials. Up to now, solutions proposed for sustainable development of rubber wastes are limited, so that properties and performance features of recycled products are inadequate for practical applications. Herein, an experimental protocol is introduced for manufacturing semi-sustainable polymer composites based...
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Interfacially modified LDPE/GTR composites with non-polar elastomers: From microstructure to macro-behavior
PublicationThis paper provides some new insights into the mechanism of interaction and modifications in thermoplastic composites based on low density polyethylene (LDPE), ground tire rubber (GTR) and non-polar elastomer. The composites were prepared using a co-rotating twin-screw extruder at variable LDPE/GTR ratio and constant elastomer content. Two types of commercial elastomer were applied: styrene-butadiene-styrene (SBS) block copolymers (Kraton®)...
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Poroelastic Road Surfaces - State of The Art
PublicationPoroelastic Road Surfaces (PERS) constitute a specific group of pavements containing a great amount of crumbled rubber. In most cases rubber aggregate constitutes about 20% of the mixture (by weight) and a polyurethane resin is used as a binder. As a result, PERS is characterized by a much higher elasticity than asphalt and a high porosity typical for drainage pavements. Due to this, tire/road noise is greatly reduced and on top...
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Oxygen concentration regulated the efficient liquefaction of vulcanized natural rubber
PublicationOxidative liquefaction represents a promising avenue for the homogeneous and high-value utilization of waste tire rubber. Given that truck tires predominantly comprise natural rubber (NR), this study investigated the efficient liquefaction of vulcanized NR regulated by oxygen concentration. Remarkably, the liquefaction of vulcanized NR was realized with an oxygen concentration of 75 % at 200 °C within 3 min. FTIR spectroscopy showed...