Search
Filters
total: 1118
filtered: 1019
-
Catalog
Chosen catalog filters
displaying 1000 best results Help
Search results for: KOMPOZYTY DIAMENT-METAL
-
Effect of the welding environment and storage time of electrodes on the diffusible hydrogen content in deposited metal
PublicationIn the study the glycerin displacement method was used for determination of diffusible hydrogen content in deposited metal. Specimens were welded in the air and in the water with covered rutile electrodes. The first part of the specimens was made immediately after opening the package of the electrodes. The electrodes were then stored in opened packages in laboratory conditions that allowed for contact with the air for three years....
-
Nonlinear FEM analysis of irregular shells composed of fiber metal laminates
PublicationThe paper deals with the analysis of failure initiation in shells made of Fiber Metal Laminates (FML). The elas-tic material law for orthotropic lamina is stated accounting for asymmetric in-plane stress and strain measures. The asymmetry results from the employed general nonlinear 6-field shell theory where the generalized dis-placements involve the translation and the proper rotation field. The novelty of the presented results...
-
Pr-doped TiO2: The effect of metal content on photocatalytic activity
PublicationThe Pr-TiO2 nanoparticles were prepared by using the sol-gel method. As-prepared samples were characterized by BET measurements, X-ray powder diffraction analysis (XRD) and UV-Vis spectra. Visible and ultraviolet light photocatalytic activity of the sample was studied by photodegradation of phenol while considering the influence of the dopant concentration. TiO2 doped with 0.25 mol% of praseodymium showed the highest photocatalytic...
-
The occurrence of heavy metals and metal-resistant bacteria in water and bottom sediments of the Straszyn reservoir (Poland)
PublicationThe aim of this study is investigate the distribution of selected heavy metals (zinc, copper, lead, cadmium) and metal-resistant bacteria in water and bottom sediments of drinking water reservoir for Gdańsk (Poland). The research area - Straszyn Lake is a dam reservoir on Radunia river, of the total volume of 3 mln m3. Sediment and water sampling took place between May and October 2013 (eight series). Regarding metal concentration...
-
A new time-frequency detection method of stray current field interferenceon metal structures.
PublicationA new detection method has been presented of stray current field interference on underground metal structures. The method employs short time Fourier transformation (STFT). This method of analysis allows determination of signal spectral power density changes (e.g., structure potential) in the function of time. In the paper results have been presented of total time–frequency analysis of a pipeline potential in a stray current field...
-
Assessment of metal removal in a surface flow constructed wetland treating landfill leachate
PublicationThe study concerns heavy metal retention and transformation processes in a free water surface constructed wetland treating landfill leachate in a temperate climate. The total effectiveness of heavy metals removal in the analyzed CW was evaluated basing on heavy metals inflow and outflow concentrations. The concentrations of eight heavy metals (Fe, Mn, Zn, Pb, Ni, Cu, Cr, Cd) in landfill leachate (LL) and sediments were measured....
-
Enhancing the Effectiveness of the Diamond Metal Bond Instrument when Grinding High-Strength Materials
Publication -
Electroabsorption study of metal-to-ligand charge transfer in an organic complex of iridium (III).
PublicationW pracy zmierzono i zinterpretowano widmo elektroabsorpcji (EA) próżniowo naparowanych warstw organicznego kompleksu Ir(ppy)3, powszechnie stosowanego jako emiter fosforescencyjny w organicznych diodach elektroluminescencyjnych. Analiza widma EA potwierdziła fakt,że niskoenergetyczne stany elektronowe tego kompleksu związane są z przeniesieniem ładunku metal-ligand.
-
Azomacrocyclic derivatives of imidazole: synthesis, structure, and metal ion complexation properties
PublicationNew azocrown ethers comprising imidazoles in the macrocycle have been synthesized. Imidazole, 2-methyl-, 4-methyl-, and 4-phenylimidazole were incorporated to form macrocyclic units by coupling with the appropriate bis-diazonium salts. The syntheseswere performed under high dilution conditions. The X-ray structure of a water adduct of the 21-membered crown ether derivative of 4-methylimidazole 8 has been solved. Metal...
-
Natural Environments for Nanoparticles Synthesis of Metal, Metal Oxides, Core–Shell and Bimetallic Systems
Publication -
DETERMINATION OF DIFFUSIBLE HYDROGEN CONTENT IN DEPOSITED METAL OF RUTILE ELECTRODES BY GLYCERIN METHOD
PublicationThe presence of diffusible hydrogen in welded joints is one of the causes of formation the welding imperfections. Improvement of weldability can be achieved by reducing the hydrogen amount in welded joints. This requires, among others, the finding of sources of hydrogen. For high hydrogen processes the commonly used method of determining the diffusible hydrogen amount is the glycerin method. This paper concerns issues related to...
-
Calix[4]arene-Thioamides as Ionophores for Transition and Heavy Metal cations
PublicationCalix[4]arene derivatives play an important role as sensing materials in Ion Selective Electrodes(ISEs). Nowadays a high impact is put to control in natural waters the level of toxic heavy metals, like Pb ,Cd, Hg or Cu which may cause the great risk to human health. Our goal was to design and to synthesize ligands possessing ability to bind transition and heavy metal cations. The synthesis, crystal structures,extractive and ionophoric...
-
A novel concept for tissue-metal detection and differentiation using an inductive proximity sensor
PublicationIn this paper a novel application of inductive proximity sensors for detection of living tissue by means of measurements of the coil impedance changes at different frequencies is described. The mathematical analyses utilizing Bessel function estimation include detected object size and its distance from a sensor. The main aim of this study is to prove the possibility of distinguishing between metal objects and living tissues. The...
-
Redox property switching in MOFs with open metal sites for improved catalytic hydrogenation performance
PublicationIn this study, a decompression-thermalization strategy was utilized for a Cu-containing metal-organic framework (MOF) to tune its redox and catalytic hydrogenation properties. Remarkably, at just 120 °C, open metal sites (OMSs) were successfully constructed by removing coordinated solvent molecules to generate the daughter MOF-120. The tailored redox property of MOF-120 is correlated with the presence of OMSs. Compared with the...
-
Preliminary investigations of effect of conditions of FCAW process on diffusible hydrogen content in deposited metal
PublicationOne of the types of hydrogen degradation of steel welded joints is cold cracking. The direct cause of the formation of cold cracks is simultaneous presence of hydrogen, residual stresses and brittle structure. The way of preventing the occurring of degradation is to eliminate at least one of these factors. Practice has shown that the best solution is to control the amount of hydrogen in deposited metal. In this paper the state...
-
Effect of underwater local cavity welding method conditions on diffusible hydrogen content in deposited metal
PublicationOne of the methods with great potential for applications in underwater repairs is local cavity welding. In local cavity method, cooling conditions and diffusible hydrogen amount in weld metal are nearly the same as those existed during welding in the air. This paper presents the results of literature survey and preliminary tests of the effect of local cavity welding conditions on diffusible hydrogen amount in a deposited metal....
-
Transition Metal Oxides influence on phosphate and borate glasses structure
PublicationBorate and phosphate glasses possess many potential luminescence and optical applications. With their low melting point, they are one of the most often studied amorphous materials. In recent years these glasses, doped with transition metal oxides (TMO), gained much attention due to their tunable structural and thermal properties. Review of systems containing TMOs was presented. Additionally synthesis of binary MnO-P2O5 and MnO-B2O3...
-
Microplastics removal from aqueous environment by metal organic frameworks
PublicationThis paper provides an overview of recent research performed on the applications of metal–organic frameworks (MOFs) for microplastics (MPs) removal from aqueous environments. MPs pollution has become a major environmental concern due to its negative impacts on aquatic ecosystems and human health. Therefore, developing effective and sustainable methods for removing them from aqueous environments is crucial. In recent years, MOFs...
-
Effect of water salinity on properties of multipass underwater wet manual metal arc welded joints
PublicationThe weldability of steel under the water is limited due to the influence of the environment. Water causes limited visibility, presence of the residual stresses, increasing the cooling rate, and increasing the diffusible hydrogen content in deposited metal, leading to the formation of brittle microstructures in heat-affected zone (HAZ). The paper presents the results of mechanical properties testing of S420G2+M steel welded joints...
-
Numerical Modeling and Simulation of Vehicular Crashes into Three-Bar Metal Bridge Rail
PublicationAdvanced finite element (FE) modeling and simulations were performed on vehicular crashes into a three-bar metal bridge rail (TMBR). The FE models of a sedan, a pickup truck, and a TMBR section were adopted in the crash simulations subject to Manual for Assessing Safety Hardware (MASH) Test Level 2 (TL-2) and Test Level 3 (TL-3) requirements. The test vehicle models were first validated using full-scale physical crash tests conducted...
-
Fast-SEC coupled to ICP-MS for selected metal determination and its stability over time in polish wine
PublicationMetal ions contribute to the wine browning (as reaction catalysts), turbidity (in complexes), and astringency (due to inter- action with tannins). Being aware that bioavailability and metabolism of metal ions in the human body are strictly related with their concentration and the form they occur it is important to monitor not only the total content of metals but also their speciation. Thus, we can obtain more information about...
-
Signature of Oxide-Ion Conduction in Alkaline-Earth-Metal-Doped Y3GaO6
PublicationWe have studied alkaline-earth-metal-doped Y3GaO6 as a new family of oxide-ion conductor. Solid solutions of Y3GaO6 and 2% −Ca2+-, −Sr2+-, and −Ba2+-doped Y3GaO6, i.e., Y(3−0.06)M0.06GaO6−δ (M = Ca2+, Sr2+, and Ba2+), were prepared via a conventional solid-state reaction route. X-ray Rietveld refined diffractograms of all the compositions showed the formation of an orthorhombic structure having the Cmc21 space group. Scanning electron...
-
Apparent molar volumes and compressibilities of alkaline earth metal ions in methanol and dimethylsulfoxide
PublicationTemperature dependencies of density of magnesium (II), calcium (II), strontium (II), barium (II) perchlorates as well as beryllium (II), and sodium trifluoromethanesulfonates in methanol and dimethylsulfoxide have been determined over the composition range studied. From density data the apparent molar volumes and partial molar volumes of the salts at infinite dilution as well as the expansibilities have been evaluated. The apparent...
-
Metal–metal interactions in bent cyano-bridged trinuclear octacyanomolybdate(IV)–platinum(IV) complexes
Publication -
The effect of metal cluster deposition route on structure and photocatalytic activity of mono- and bimetallic nanoparticles supported on TiO2 by radiolytic method
PublicationTiO2 (P25) was modified with small and relatively monodisperse mono- and bimetallic clusters (Ag, Pd, Pt, Ag/Pd, Ag/Pt and Pd/Pt) induced by radiolysis to improve its photocatalytic activity. The as-prepared samples were characterized by X-ray fluorescence spectrometry (XRF), photoluminescence spectrometry (PL), diffuse reflectance spectroscopy (DRS), X-ray powder diffractometry (XRD), scanning transition electron microscopy (STEM)...
-
Attaching an alkali metal atom to an alkaline earth metal oxide (BeO, MgO, or CaO) yields a triatomic metal oxide with reduced ionization potential and redirected polarity
Publication -
Effect of shielded electrode wet welding conditions on diffusible hydrogen content in deposited metal
PublicationWet welding is the most popular method of joining in water enviroment. During underwater welding, the weldability of steel is limited by the higher cooling rates and hydrogen content in weld metal. Article presents results of preliminary tests on the effects of wet welding conditions on diffusible hydrogen amount. Seven parameters were optimized using a Plackett-Burman plan to get the most relevant variables. These parameters were:...
-
Noble metal modified TiO2 microspheres: Surface properties and photocatalytic activity under UV-vis and visible light
PublicationComposite photocatalysts that consist of TiO2and noble metal nanostructures have been considered tobe the promising and pivotal material for accessible enhancement of the efficiency in the photocatalyticprocess carried out in the aqueous and gas phases. In this work we fabricated porous TiO2microspheresthrough a hydrothermal process followed by photochemical reduction of noble metal nanoparticles atthe TiO2surface. The morphology...
-
Buckling analyses of metal cylindrical silos containing bulk solids during filling
PublicationThe paper presents 3D results on stability of thin-walled cylindrical metal silos made of isotropic rolled and corrugated plates containing bulk solids. The behavior of bulk solids was described using a hypoplastic constitutive model. Nonlinear finite element (FE) analyses with both geometric and material nonlinearity were performed with a perfect and an imperfect silo shell wherein initial geometric imperfections were taken into...
-
Metal-organic frameworks (MOF) based heat transfer: A comprehensive review
PublicationHigher than a standard level, the humidity provides a suitable environment for the pathogenic microorganisms to grow and increases energy consumption for cooling, increasing greenhouse gas emissions. Desiccant air-conditioning (DAC) is an effective method to reduce humidity and energy simultaneously. Conventional desiccants are not suitable for use as a desiccant in building air conditioners, mainly because of high regeneration...
-
Nowe konstrukcje przekładkowe metal-pianka poliuretanowa = New sandwich plate systems metal - PU foam
PublicationWyznaczono statyczne własności mechaniczne przy ściskaniu, rozciąganiu oraz ścinaniu w óżnych kierunkach względem wzrostu piany oraz przy cyklicznych naprężeniach ściskających i ścinających. Stwierdzono różnice własności mechanicznych w zależności od kierunku i formy naprężeń.
-
3-D Printable Metal-Dielectric Metasurface for Risley Prism-Based Beam-Steering Antennas
PublicationA 3-D printable, planar, metal-dielectric metasurface-based, 2-D beam-steering system for aperture-type antennas is presented in this paper. This beam steering system, also known as the near-field meta-steering system, comprises two fully passive phase-gradient metasurfaces placed in the antenna’s nearfield region to steer the radiation beam. To address the non-uniform electric field phase of the aperture antenna, phase correction...
-
Environmental stress cracking in e-glass and aramid/glass epoxy composites
PublicationKompozyty epoksydowe wzmocnione włóknami szklanymi są dość odporne na wpływy środowiskowe w stanie nieobciążonym, jednak po przyłożeniu obciążeń łatwo pękają w środowisku wody i rozcieńczonych kwasów. Charakterystyki propagacji pęknięć środowiskowych w laminatach szklano/epoksydowych były przedmiotem szeregu prac, jednak brak jest danych na temat zachowania laminatów o wzmocnieniu hybrydowym aramidowo-szklanym stosowanych w budowie...
-
Metal dusting in CCR platforming unit
PublicationPrzedstawiono mechanizm pylenia metalu w stali 9Cr-1Mo w instalacji platformingu CCR, na postawie badań rury podgrzewacza wsadu po 10 latach pracy, przy temperaturze metalu koło 600C. W badaniach wykorzystano techniki elektronowej mikroskopii skaningowej, dyfrakcji rentgenowskiej i mikroanalizy rentgenowskiej. Wykazano, że dyfuzji wegla w głąb stali toarzyszy odrdzeniowa dyfuzja pierwiastków węglikotwórczych - chromu i molibdenu....
-
Degradation of metal implants covered with silver
PublicationSilver was known for its antibacterial properties as long ago as in antiquity. The silver ions have ability to join the bacteria surface. Low density of silver ions Ag+ influence the protons through the bacteria surface, which results in total destruction of the cell. Antibacterial activity of silver remains in proportion with the density of silver ions Ag+ in the environment.
-
Metal dusting in CCR platforming unit
PublicationPrzedstawiono mechanizm pylenia metalu w stali 9Cr-1Mo w instalacji platformingu CCR, na postawie badań rury podgrzewacza wsadu po 10 latach pracy, przy temperaturze metalu koło 600C. W badaniach wykorzystano techniki elektronowej mikroskopii skaningowej, dyfrakcji rentgenowskiej i mikroanalizy rentgenowskiej. Wykazano, że dyfuzji wegla w głąb stali toarzyszy odrdzeniowa dyfuzja pierwiastków węglikotwórczych - chromu i molibdenu....
-
Monitoring of metal structures with the dynamic methods
Publication -
Forming of explosively welded metal plates.
PublicationW pracy przedstawiono możliwości kształtowania plastycznego poprzez walcowanie, tłoczenie, gięcie, skręcanie blach wielowarstwowych zgrzewanych wybuchowo.
-
Metal dusting in Platforming CCR furnaces
PublicationPrzedstawiono charakterystykę zjawiska spylania metalu w stali chromowo-molibdenowej 9Cr-1Mo eksploatowanej w piecach instalacji Platformingu CCR w środowisku odsiarczonej benzyny cięzkiej i gazu wodorowego o temperaturze 500C, przy temperaturze metalu 600C.
-
Excitons dissociation on pentacene-metal surface
PublicationBadano proces iniekcji nośników ładunku przez ekscytony z elektrod ITO i Mg do warstwy pentacenu. Stwierdzono, że energia ekscytonów tripletowych nie zawsze wystarcza do pokonania bariery potencjału powstającej na złączu elektroda - pentacen.
-
Prediction of metal deformation due to line heating; an alternative method of mechanical bending, based on artificial neural network approach
PublicationLine heating is one of the alternative methods of forming metals and this kind of forming uses the heating torch as a source of heat input. During the process, many parameters are considered like the size of the substrate, thickness, cooling method, source power intensity, the travel speed of the power source, the sequence of heating, and so on. It is important to analyze the factors affecting the...
-
Hydrogen evolution reaction catalyzed by Co-based metal-organic frameworks and their derivatives
PublicationIn this study, Co-bearing Metal-Organic Frameworks (MOFs) are grown via a facile solvothermal process on the surface of two kinds of conductive substrates – titanium dioxide nanotubes (TiO2NT) and fluorine-doped tin oxide (FTO) glass and tested as electrodes in the electrochemical hydrogen evolution reaction (HER). The materials derived from three organic linkers - terephthalic acid (Co-BDC), 2-aminoterephthalic acid (Co-BDCNH2),...
-
Designate CTOD of Weld Metal of butt weld, No WOiO/II/108/2013
PublicationTypical (normative) testing of materials and/or welded joints do not answer on all questions about material or welded joint properties. In ship building and off-shore sectors, many strucures requires materials and joint with higher than typical fatigue resistance. Imact tests, which are carried out during welding technology qualification, gives answer about ductility, CTOD tests results about material or welded joint ability...
-
Lanthanide co-doped TiO2: the effect of metal type and amount on surface properties and photocatalytic activity
PublicationPreparation of new rare earth metal-containing TiO2 nanocomposites (Nd3+/Er3+, Nd3+/Eu3+, Eu3+/Ho3+-TiO2) using sol–gel route and their photoactivity under visible and ultraviolet light is reported. The obtained photocatalysts were subsequently characterized by Brunauer–Emmett–Teller (BET) method, UV–Vis diffuse-reflectance spectroscopy (DRS), luminescence spectroscopy, X-ray photoelectron spectroscopy (XPS) and X-ray powder diffraction...
-
Palladium versus Platinum: The Metal in the Catalytic Center of a Molecular Photocatalyst Determines the Mechanism of the Hydrogen Production with Visible Light
PublicationTo develop highly efficient molecular photocatalysts for visible light-driven hydrogen production, a thorough understanding of the photophysical and chemical processes in the photocatalyst is of vital importance. In this context, in situ X-ray absorption spectroscopic (XAS) investigations show that the nature of the catalytically active metal center in a (N^N)MCl2 (M=Pd or Pt) coordination sphere has a significant impact on the...
-
Investigation of behaviour of metal structures with polymer dampers under dynamic loads
PublicationA large number of accidents concerning structures subjected to dynamic loads have been recently observed. One of the examples of such a structure is a temporary steel grandstand erected using scaffolding system. Dynamic load that is generated by crowd movement has a significant influence on the behaviour of the structure and may lead to excessive structural vibrations. The aim of the study is to consider the idea of using polymer...
-
Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review
PublicationDry reforming of hydrocarbons (DRH) is a pro-environmental method for syngas production. It owes its pro-environmental character to the use of carbon dioxide, which is one of the main greenhouse gases. Currently used nickel catalysts on oxide supports suffer from rapid deactivation due to sintering of active metal particles or the deposition of carbon deposits blocking the flow of gases through the reaction tube. In this view,...
-
Carbon Nanomaterials From Metal-Organic Frameworks: A New Material Horizon for CO2 Reduction
PublicationThe rise of CO2 in the atmosphere, which results in severe climate change and temperature increase, is known as the major reason for greenhouse effect. Reducing CO2 to value-added products is an attractive solution to this severe problem, along with addressing the energy crisis, to which the catalysts being employed are of vital importance. Due to their high porosity and tunable compositions, Metal-Organic Frameworks (MOFs) show...
-
Influence of alkali metal cations on the photoactivity of crystalline and exfoliated amorphous WO3 – photointercalation phenomenon
PublicationIn order to investigate the effect of photointercalation on photoelectrochemical properties, two types of WO3-based photoanodes, bulk and exfoliated have been prepared and investigated. An aqueous exfoliation method is introduced for the simple fabrication of amorphous and hydrated WO3 nanomaterial using commercial bulk WO3 precursor. The comparison of obtained material with bulk WO3 was performed using Raman, UV–vis, and XPS as...
-
A Review on Metal–Organic Framework as a Promising Catalyst for Biodiesel Production ENERGY & FUELS
PublicationThe rapid depletion of fossil-derived fuels along with rising environmental pollution have motivated academics and manufacturers to pursue more environmentally friendly and sustainable energy options in today’s globe. Biodiesel has developed as an ecologically favorable alternative. However, the mass manufacturing of biodiesel on an industrial scale confronts substantial cost and pricing challenges. To address this issue, high-efficiency...