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Search results for: RARE EARTH IONS
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Processing of Satellite Data in the Cloud
PublicationThe dynamic development of digital technologies, especially those dedicated to devices generating large data streams, such as all kinds of measurement equipment (temperature and humidity sensors, cameras, radio-telescopes and satellites – Internet of Things) enables more in-depth analysis of the surrounding reality, including better understanding of various natural phenomenon, starting from atomic level reactions, through macroscopic...
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Acoustic emission studies of the 7075 aluminium alloy pitting corrosion process
Open Research DataThe dataset contains the cyclic polarization studies and corresponding acoustic emission measurements, revealing the pitting corrosion process of the passive layer at the surface of the 7075 aluminum alloy in the borate buffer with different chloride ions concentrations, in the range between 0.05 and 25 mM.
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DETERMINATION OF VERTICAL DISPLACEMENTS IN RELATIVE MONITORING NETWORKS
PublicationThe problem of determining displacements of objects is an important and current issue, in particular in terms of operational safety. This is a requirement that covers geodetic, periodic control measurements in order to determine horizontal and vertical displacements. The paper is focused on the analysis of vertical displacements. Geodetic measurements and their interpretation allow to reduce the risk of possible structural catastrophes....
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Assessing the Effects of the Road Surface and Weather Conditions on Road Safety
PublicationWhen transport is analysed for its safe delivery the focus is mainly on assessing the safety of roads and the risk of undesired events. These include road accidents, an occurrence which is relatively rare and random. Randomness means that accidents depend on several factors which are partly deterministic (can be controlled) and partly stochastic (random and unpredictable). The set of crash contributing factors can be classified...
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Structural changes of a simple peptide—Trpzip-1—in aqueous solutions and the corresponding hydration phenomena under the influence of temperature
PublicationTrpzip-1, a simple β-hairpin, is a rare example of peptide with stable secondary structure and can be a convenient model to study temperature-related processes that potential prion or amyloid proteins undergo. Although its sequence is simple, the exact processes which the peptide undergoes in aqueous solutions are quite complex and not well understood. The selection of well-established experimental (DSC, FTIR) and theoretical methods...
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Structural, magnetic and spectral properties of tetrahedral cobalt(II) silanethiolates: a variety of structures and manifestation of field-induced slow magnetic relaxation
PublicationBlue crystals of five heteroleptic cobalt(II) silanethiolates 1–5 have been obtained by the reaction of [Co{SSi (tBuO)3}2(NH3)]2 with aminopyridines and aminomethylpyridines at an appropriate molar ratio and their structural, spectral, thermal and magnetic properties have been established and described. All complexes 1–5 contain Co(II) ions in a tetrahedral CoN2S2 environment formed by (tBuO)3SiS− residues and pyridines and present...
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Self-assembly, stability and conductance of amphotericin B channels: bridging the gap between structure and function
PublicationAmphotericin B (AmB), one of the most powerful but also toxic drugs used to treat systemic mycoses, is believed to selectively permeabilize fungal cell membranes to ions in a sterol-dependent manner. Unfortunately, the structure of the biologically active AmB channels has long eluded researchers, obstructing the design of safer alternatives. Here, we investigate the structural and thermodynamic aspects of channel formation, stability,...
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Synthesis, Structure, and Spectroscopic Properties of Calcium Thiophenecarboxylate Polymers. Structural Comparison with Analogous Lead Complexes
PublicationThree novel calcium coordination polymers [Ca(2tpCOO)2(2mpa)(H2O)]n (1), [Ca(3tpCOO)2(2mpa)(H2O)]n (2), and {[Ca(3tpacCOO)2(H2O)2]⋅⋅⋅H2O}n (3) (2tpCOO− or 3tpCOO− – thiophene-2- or thiophene-3-carboxylate, 3tpacCOO− – thiophene-3-acetate, 2mpa – 2-methylpropanal), were synthesised using a self-assembly method. The obtained polymers were characterised using SC-XRD, FTIR, UV-Vis DRS, thermogravimetric and luminescence analyses. The...
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Synthesis and physical properties of the 10.6 K ferromagnet NdIr3
PublicationThe magnetic, transport, and thermodynamic properties of NdIr3 are reported. Its PuNi3-type crystal structure (space group R−3m), with lattice parameters a= 5.3262(1)Å and c=26.2218(3)Å, was confirmed by powder x-ray diffraction. Our measurements indicate that NdIr3 exhibits a previously unreported paramagnetic to ferromagnetic phase transition below TC=10.6 K(determined by using the Arrott plot). The magnetic susceptibility obeys...
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Treatment of bitumen post oxidative effluents by sulfate radicals based advanced oxidation processes (S-AOPs) under alkaline pH conditions
PublicationSulfate radicals based Advanced Oxidation Processes (S-AOPs), namely Persulfate and peroxymonosulfate, were used for the treatment of post oxidative effluents from a production of petroleum bitumens under alkaline pH. Studies on the identification and monitoring of the volatile organic compounds (VOCs) along with COD, BOD and sulfide ions reduction were performed. Persulfate with a ratio between the oxygen from the oxidant and...
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Modeling the application of steel slag in stabilizing expansive soil
PublicationThe objective of this study was to evaluate the suitability of steel slag as an additive to the engineering properties of weak clay soil. Different geotechnical laboratory tests were conducted on both stabilized and natural soils. Steel slag (SS) was added at a rate of 0, 5, 10, 15, 20, and 25% to the soil. Specific gravity, grain size analysis, Atterberg limit test, compaction test, free swell, California bearing ratio (CBR),...
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Evaluation of Eucalyptus leaves as an adsorbent for decolorization of Methyl Violet (2B) dye in contaminated waters: Thermodynamic and Kinetics model
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Hydraulic Conditions of Flood Wave Propagation in the Valley of the Narew River after the Siemianówka Dam Overtopping Failure
PublicationW pracy przedstawiono prognozę propagacji fali powodziowej w dolinie rzeki Narwi wywołanej potencjalną przelaniem się wody przez koronę zapory Siemianówka. Do modelowania hydrodynamiki przepływu powodziowego wykorzystano model jednowymiarowy w formie równań de Saint-Venanta. Opisano również mechanizm powstawania rozmycia w ziemnej zaporze zbiornika i przedstawiono model tworzenia się wyrwy w korpusie zapory. Wykonane obliczenia...
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Advanced sensitivity analysis of the impact of the temporal distribution and intensity of rainfall on hydrograph parameters in urban catchments
PublicationKnowledge of the variability of the hydrograph of outflow from urban catchments is highly important for measurements and evaluation of the operation of sewer networks. Currently, hydrodynamic models are most frequently used for hydrograph modeling. Since a large number of their parameters have to be identified, there may be problems at the calibration stage. Hence, sensitivity analysis is used to limit the number of parameters....
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Shallow Water Equations as a Mathematical Model of Whitewater Course Hydrodynamics
PublicationPredicting the positions of local hydraulic phenomena, as well as accurately esti-mating the depth and velocity of the water flow are necessary to correctly config-ure a whitewater canoeing course. Currently, a laboratory and full 3D CFD model-ing are typically used in the design process to meet these needs. The article points to another possibility which can be useful at the preliminary stage of the design. The authors show that...
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An advanced tool integrating failure and sensitivity analysis into novel modeling of the stormwater flood volume
PublicationAn innovative tool for modeling the specific flood volume was presented that can be applied to assess the need for stormwater network modernization as well as for advanced flood risk assessment. Field measurements for a catchment area in Kielce, Poland, were used to apply the model and demonstrate its usefulness. This model extends the capability of recently developed statistical and machine learning hydrodynamic models developed...
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Modeling of Ice Passage Through Reservoirs System on the Vistula River
PublicationNumerical model was used to assess ice passage through proposed reservoir on the lower Vistula River. Model results were compared with observation on the Vistula River, but because the dam is not constructed yet, the direct comparison was not possible. The study focused on ice movement and accumulation in the reservoir for variety of low flow condition with and without wind effect. Bridge’s piers in the upper part of the reservoir...
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Earthquake-Induced Structural Pounding
PublicationEarthquake-induced structural pounding between insufficiently separated build-ings, or bridge segments, has been repeatedly observed during ground motions. The reports after earthquakes indicate that it may lead to some local damage in the case of moderate seismic events or may result in considerable destruction or even collapse of colliding structures during severe ground motions. Pounding in build-ings is usually caused by the...
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Microbiological Survey in Two Arctic Fjords: Total Bacterial Number and Biomass Comparison of Hornsund and Kongsfjorden
PublicationTwo microbiological parameters: total bacterial number (TBN) and biomass (BBM) were studied in two Arctic fjords: Hornsund and Kongsfjorden. Samples were collected from three sampling points in each fjord, from various water depth layers: from the surface to 75 m depth. Total bacterial number and biomass were examined using the DAPI staining and direct count method. The greater amount of bacteria, as well as highest bacterial biomass...
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Organic carbon fluxes of a glacier surface: a case study of Foxfonna, a small Arctic glacier
PublicationArctic glaciers are rapidly responding to global warming by releasing organic carbon (OC) to downstream ecosystems. The glacier surface is arguably the most biologically active and biodiverse glacial habitat and therefore the site of important OC transformation and storage, although rates and magnitudes are poorly constrained. In this paper, we present measurements of OC fluxes associated with atmospheric deposition, ice melt,...
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Numerical Modeling of Water and Ice Dynamics for Analysis of Flow Around the Kiezmark Bridge Piers
PublicationThis paper presents the results of a numerical model study on the effect of ice on the proposed bridge piers in the Vistula River outlet and its effect on flow conditions in the river. The model DynaRICE is used in this study, which is a two-dimensional hydro-ice dynamic numerical model developed for dynamic ice transport and jamming in rivers. To simulate river hydrodynamics in the vicinity of the bridge piers, 2-dimensional numerical...
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An Experimental Investigation of Pressure Wave Celerity During the Transient Slurry Flow
PublicationTransportation of slurries in pressure pipelines is an example of a complex flow due to specific parameters of transported medium. For practitioners, the economy of designing and maintenance is usually the most important factor. For this reason, most of hydrotransport installations are fairly simple; however, they become more vulnerable to negative effects of the transient flow which can occur in pressure pipelines. As the consequence,...
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Types of Treatment Wetlands
PublicationThe removal of pollutants in treatment wetland systems is the result of the sorption of biochemical pollutants, redox reactions, and a biological activity of microorganisms as well as hydrophytes plants.
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Characteristics of the Hydrophytes Method
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Storm Water Treatment in TWs
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Domestic Wastewater Treatment
PublicationSSF systems are usually applied at the 2nd stage of domestic wastewater treatment, after mechanical treatment. The number of such installations working at the moment in Europe is estimated to be 100,000. In Germany about 10,000 systems are in operation.
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Landfill Leachate Treatment in Treatment Wetlands
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Dewatering of Sewage Sludge Dewatering in Reed Systems
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Poly(hydroxybutyrate-co-hydroxyvalerate) as a biodegradable binder in a negative electrode material for lithium-ion batteries
PublicationIn this work, graphite-based negative electrode for lithium-ion battery consisting a novel and biodegradable binder poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV) is compared with standard graphite electrode with polyvinylidene fluoride (PVDF) as a binder. The rate and cycling performance of lithium ion insertion/extraction of electrodes with PHBV in a half-cell configuration are evaluated. Moreover, on the basis of the electrochemical...
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The profiles and spectrum of aqua solution of tannic acid by HPLC-DAD-MS analysis.
Open Research DataThe profiling of tannic acid is determined by examining the content and proportion / ratio of gallotannins [Aras et al. 2016, Clifford et al. 2007, Gauri et al. 2012, Nishizawa et al. 1982]. In order to check the ion mass distribution (TIC) in an aqueous solution of commercial tannic acid, a direct sample injection (TA) was performed into the mass spectrometer....
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Investigation of poly(3,4-ethylenedioxythiophene) deposition method influence on properties of ion-selective electrodes based on bis(benzo-15-crown-5) derivatives
PublicationGlassy carbon electrodes modified by conductive polymers and membrane with derivatives of bis(benzo-15-crown-5) were tested as solid contact ion selective electrodes for K+ ions concentration determination. PEDOT with PSS, Cl- and ClO4- counter ions was electrochemically deposited onto glassy carbon substrates using four different electrochemical approaches (potentiostatic, galvanostatic, potentiodynamic and potentiostatic pulses)....
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Centrally Pivoted Tilting Pad Thrust Bearing with Carbon-Based Coated Collar—Experimental Results of Low- and Medium-Speed Operation
PublicationExperimental results of the research on a tilting pad thrust bearing with symmetrical pad support in the conditions of high loads and low speeds are presented in the paper. As described in the literature review, experimental results of tilting pad bearings at low speed/high load regime and transient conditions are rare. Unusual material selection - steel pad against a DLC-type coating on the collar was utilized. Such material combination...
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Nano-engineered diamond-based materials for supercapacitor electrodes: A review
PublicationOwing to the popularity of carbon-based supercapacitors, diamond has also been examined as a potential candidate with unique advantages such as a wide electrochemical potential window and stable capacitive behavior in both aqueous and non-aqueous electrolytes. Moreover, its chemical stability in harsh environments at extreme applied potential and current provides rare opportunities for designing new supercapacitors. Owing to the...
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Global Competitiveness and Economic Growth: A One-Way or Two-Way Relationship?
PublicationThe Global Competitiveness Index is treated as a standard to measure the competitiveness of countries. Leaders look at it to make policy and resource allocation decisions because global competitiveness is expected to be related to economic growth. However, studies which analyze the empirical relationship between these two economic categories are very rare. It is still an open question in the literature whether economic growth can...
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A Preliminary Study and Analysis of Tidal Stream Generators
PublicationFor a sustainable future, tidal energy can play a vital role. Tidal energy relies on the gravitational pull of the Moon and the Sun along with the centrifugal forces created by the Earth. Tidal barrage uses the potential energy from the tide and has been very successful in electricity production. With the help of a turbine, kinetic energy can also be harnessed from tidal currents to generate electricity. However, it is not economically...
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Experimental study of the effect of vertical acceleration component on the slope stability
PublicationThe paper deals with the stability of earth dams subjected to seismic and paraseismic excitations occurring in the close distance to the dam. The Newmark’s stability approach, classified as a simplified dynamic method, has been extended for two directional dynamic loading case and the evolution of the friction coefficient. The paper is focused on the experimental verification of the proposed method for harmonic and cyclic excitations...
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Green Chemistry in Higher Education: State of the Art, Challenges, and Future Trends
PublicationNowadays, there is increasing interest in global sustainability, and thus, university students would like to know how human actions affect the health status of our planet. This is mainly due to their basic knowledge of problems such as global warming and greenhouse gases. Students would like to gain knowledge on how to safeguard the earth for future generations. This must involve changes in education programs at interested institutions...
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The role of analytical chemistry in the study of the Anthropocene
PublicationThe term “Anthropocene” refers to not yet formalized epoch of geologic time during which geologic processes have been dominated by the human impact. This impact takes on many forms. Biological, physical and chemical changes to the Earth System caused by anthropogenic activity are recorded in natural archives either as new fossil assemblages (neobiota), anthropogenic deposits or a wide variety of pollutants emitted to the environment....
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The changes of groundwater quality of the ''Czarny Dwór'' intake as a result of the aquifer vulnerability
PublicationThe "Czarny Dwór" groundwater intake is one of the main sources of water for Gdańsk. It is situated on the Marine Terrace and exploits mainly Quaternary aquifer, but also Tertiary and Cretaceous. The water is generally of good quality although some undesirable changes were observed in the Quaternary aquifer during almost 40 years of exploitation. The changes are caused by developing urbanization, former high pumping rates and...
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A new B-D-galactosidase with a low temperature optimum isolated from the Antarctic Arthrobacter sp. 20B: gene cloning, purification and characterization.
PublicationA psychrotrophic bacterium producing a coldadaptedB-galactosidase upon growth at low temperatureswas classiWed as Arthrobacter sp. 20B. A genomic DNAlibrary of strain 20B introduced into Escherichia coliTOP10F' and screening on X-Gal (5-bromo-4-chloro-3-indolyl-B-D-galactopyranoside)-containing agar plates ledto the isolation of B-galactosidase gene. The B-galactosidasegene (bgaS) encoding a protein of 1,053 amino acids,with a...
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Organic-inorganic composites consisted of poly(3,4-ethylenedioxythiophene)and Prussian Blue analogues
PublicationThe organic-inorganic material consisted of poly(3,4-ethylenedioxythiophene) (pEDOT) and copper hexacyanoferrate (Cuhcf) was synthesized. The pEDOT film with Fe(CN)63−/4− as counter-ions potentiodynamically polarized in aqueous CuCl2 electrolyte brings about stable hybrid material (pEDOT/Cuhcf) performing single redox activity of FeII/III at a formal potential Ef = 0.61 V (vs. Ag/AgCl/0.1 M KCl) and less clearly shaped two redox...
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High-performance activation of ozone by sonocavitation for BTEX degradation in water
PublicationThis work presents a novel advanced oxidation process (AOP) for degradation of emerging organic pollutants – benzene, toluene, ethylbenzene and xylenes (BTEXs) in water. A comparative study was performed for sonocavitation assisted ozonation under 40–120 kHz and 80–200 kHz dual frequency ultrasounds (DFUS). Based on the obtained results, the combination of 40–120 kHz i.e., low-frequency US (LFDUS) with O3 exhibited excellent oxidation...
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Corncob-supported calcium oxide nanoparticles from hen eggshells for cadmium (Cd-II) removal from aqueous solutions; Synthesis and characterization
PublicationThis study investigated the efficient removal of cadmium ions from aqueous solutions using calcium oxide nanoparticles (CaO NPs) synthesized from waste hen eggshells using a Sol-gel method and supported on corncob bio-adsorbent. The synthesized CaO NPs were characterized using FT-IR, XRD, specific surface area, and TGA. Batch adsorption experiments were conducted to examine the influence of process parameters such as adsorbent...
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Artificial neural network prophecy of ion exchange process for Cu (II) eradication from acid mine drainage
PublicationThe removal of heavy metal ions from wastewater was found to be significant when the cation exchange procedure was used effectively. The model of the cation exchange process was built using an artificial neural network (ANN). The acid mine drainage waste’s Cu(II) ion was removed using Indion 730 cation exchange resin. Experimental data from 252 cycles were recorded. In a column study, 252 experimental observations validated the...
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Progressing Pollutant Elution from Snowpack and Evolution of its Physicochemical Properties During Melting Period— a Case Study From the Sudetes, Poland
PublicationMain aim of the work assumed recognition of physicochemical changes in snowpack occurring during the melting period. Properties of snow cover had been identified at two sites in Western Sudetes mountains (860 and 1228 m asl) in SW Poland since the end of January, and monitored until the disappearance of snow in late Spring. Snow pit measurements and sample collection at both sites were made followed by chemical analyses with the...
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Do morphometric parameters and geological conditions determine chemistry of glacier surface ice? Spatial distribution of contaminants present in the surface ice of Spitsbergen glaciers (European Arctic)
PublicationAbstract The chemism of the glaciers is strongly determined by long-distance transport of chemical substances, and their wet and dry deposition on the glacier surface. This paper concerns spatial distribution of metals, ions, and dissolved organic carbon, as well as the differentiation of physicochemical parameters (pH, electrical conductivity) determined in ice surface samples collected from four Arctic glaciers during the summer...
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Austenitic stainless steel sensitization
Open Research DataHigh-alloy steels, thanks to their composition and content of appropriate alloying additives, are characterized by increased resistance to many corrosive environments. However, this is due to the increased sensitivity of the described construction materials to specific environmental conditions during their use. An example may be the increased susceptibility...
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The luminescence study of Ga1.98–xAlxO3:0.02Cr3+ coumpounds.
Open Research DataA chemical and mechanical pressure-induced photoluminescence tuning method was developed through structural evolution and hydrostatic pressure involving phase transition. A series of Ga1.98−xAlxO3:0.02Cr3+ phosphors were synthesized by collaborators from National Taiwan University. Structural evolution reveals a crystal phase change with the incorporation...
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Lower rim substituted p-tert-butyl-calix[4]arene. Part 17. synthesis, extractive and ionophoric properties of p-tert-butylcalix[4]arene appended with hydroxamix acid moieties
PublicationThe synthesis and characterization of four p-tert-butylcalix[4]arene-hydroxamic acidc are reported. The dependence of the metal ion binding, assessed by liquid extraction of the metal nitrates from water into dichloromethane in individual and competitive experiments, on the ligand structure, is presented. The results showed that those ligands could be successfully used in separation process of trnasition and heavy metals often...
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Conductivity and viscosity changes of imidazolium ionic liquids induced by H2O and CO2
PublicationSeveral solutions of ionic liquids based on 1-ethyl-3-methylimidazolium cation saturated and unsaturated with carbon dioxide were prepared and characterized by electrochemical impedance spectroscopy. The in fluence of ILs saturation on its electrical conductivity was determined. Additionally, the in fluence of the water presence and variations of temperature on electrical properties of ionic liquids were investigated. Changes of...