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Search results for: biological nutrient removal
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A mechanistic model for fate and removal of estrogens in biological nutrient removal activated sludge systems
PublicationTwo estrogen fate and transformation models were integrated with a comprehensive activated sludge model (ASM) to predict estrogen removal based on biomass and solids production. Model predictions were evaluated against published full-scale plant data as well as results from a laboratory-scale sequencing batch reactor (SBR) fed synthetic wastewater. The estrogen fate model relating the rate of total estrogen degradation to soluble...
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Impact of enhanced pretreatment on biological nutrient removal in municipal wastewater treatment plants
PublicationThe aim of this study was to determine the effect of enhanced primary treatment on: increasing primary sludge production for increased biogas production; reducing the organic load on downstream biological treatment processes and thereby reducing energy consumption for aeration; denitrification and enhanced biological phosphorus removal (EBPR) rates in the activated sludge system. For this purpose, three commercial organic polymers...
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The role of particulate and colloidal substrate in biological nutrient removal activated sludge systems
PublicationThe authors investigated COD fractionation according to the physical state (soluble/colloidal/particulate) in four wastewater treatment plants (WWTPs) in northern Poland. It was found that particulate and colloidal organic compounds constituted up to 70% of total COD. On the other hand, according to literature data, municipal wastewater contains readily and slowly biodegradable substrates in the amount of approximately 10-30% and...
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Characteristics and fate of organic nitrogen in municipal biological nutrient removal wastewater treatment plants
PublicationThe aim of this study was to investigate the occurrence and fate of colloidal and dissolved organic nitrogen (CON and DON) across biological nutrient removal (BNR) activated sludge bioreactors. Primary and secondary effluent total nitrogen (TN) measurements and component fractionation, CON and DON concentration profiles across BNR bioreactors, and laboratory batch experiments with the process mixed liquor were carried out at several...
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Comparison of two model concepts for simulation of nitrogen removal at a full-scale biological nutrient removal pilot plant
PublicationCelem badań było porównanie zdolności predykcyjnych dwóch mechanistycznych modeli procesu osadu czynnego (ASM1 i ASM3). W tym celu wykorzystano bazę danych empirycznych z pilotowej oczyszczalni ścieków Gummerwald w Hanowerze (Niemcy). Oba badane modele prognozowały szczytowe stężenia azotu amonowego na poziomie >8 gN/m3 w ciągu, którego obciążenie hydrauliczne wzrastało czterokrotnie w porównaniu do okresu bezdeszczowego. Prognozowany...
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The role of slowly biodegradable substrate in a full-scale biological nutrient removal activated sludge systems
PublicationThis paper contains futher results obtained at ''Wschod'' WWTP in Gdańsk under transient conditions (spring season) and comparation of similar experiments carried out at a recently upgraded ''Debogorze'' WWTP in Gdynia. The removal of colloidal and particulate fractions resulted in similar effects (reduced process rates) at both plants. For example, the initial denitrification rates (NUR1) were up to 30% lower during the ''conventional''...
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Modeling hydrolysis of slowly biodegradable organic compounds in biological nutrient removal activated sludge systems
PublicationHydrolysis is an important process in biological wastewater treatment and is known to be the ratelimiting step in organic carbon removal from municipal or industrial wastewater. The influence of the readily biodegradable chemical oxygen demand fraction in biological wastewater treatment systems has been extensively investigated, but little is known about the effects of slowly biodegradable substrate (XS) on denitrification and...
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The role of biodegradable particulate and colloidal organic compounds in biological nutrient removal activated sludge systems
PublicationThe efficiency of denitrification and enhanced biological phosphorus removal in biological nutrient removal activated sludge systems is strongly dependent on the availability of appropriate carbon sources. Due to high costs of commercial compounds (such as methanol, ethanol, acetic acid, etc.) and acclimation periods (usually) required, the effective use of internal substrates is preferred. The aim of this study was to determine...
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Modeling hydrolysis of slowly biodegradable organic compounds in biological nutrient removal activated sludge systems
PublicationHydrolysis is an important process in biological wastewater treatment and has been known as the rate limiting step in organic carbon removal from municipal or industrial wastewater. The biodegradation of XS is initiated by hydrolysis which is an integral part of activated sludge models, such as the Activated Sludge Model no. 2d (ASM2d). The aim of this study was to evaluate different concepts of modeling the hydrolysis process...
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The role of slowly biodegradable organic compounds in a full-scale biological nutrient removal activated sludge systems
PublicationThe aim of this study was to determine the immediate effects of slowly biodegradable substrates on the denitrification capability and phosphate release/uptake interactions for a full-scale biomass process from two large wastewater treatment plants (WWTPs) located in the cities of Gdansk and Gdynia (northern Poland). Since it is hard to distinguish the slowly biodegradable substrate in a direct way, a novel procedure based on batch...
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Strategies for achieving energy neutrality in biological nutrient removal systems - a case study of the Slupsk WWTP (northern Poland)
PublicationThe paper presents a model-based evaluation of technological upgrades on the energy and cost balance in a large biological nutrient removal wastewater treatment plant (WWTP) in the city of Slupsk (northern Poland). The proposed upgrades include chemically enhanced primary sludge removal and reduction of the nitrogen load in the deammonification process employed for reject water treatment. Simulations enabled to estimate the increased...
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Strategies for Achieving Energy Neutrality in Biological Nutrient Removal Systems – a Case Study of the Slupsk WWTP (northern Poland)
PublicationThe paper presents a model-based evaluation of technological upgrades on the energy and cost balance in a large biological nutrient removal wastewater treatment plant (WWTP) in the city of Slupsk (northern Poland). The proposed upgrades include chemically enhanced primary sludge removal and reduction of the nitrogen load in the deammonification process employed for reject water treatment. Simulations enabled to estimate the increased...
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The impact of precipitation and external carbon source addition on biological nutrient removal in activated sludge systems - experimentalinvestigation and mathematical modeling
PublicationThe aim of this study was to determine the effects of chemical precipitation and addition of external carbonsources on the denitrification capability and enhanced biological phosphorus removal (EBPR) interactions atthe 'Wschod' WWTP (600,000 PE) in Gdansk (northern Poland). For this purpose, different kinds of batch experimentswere carried out with the settled wastewater (without pretreatment and after coagulation-flocculation)and...
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The impact of precipitation and external carbon source addition on biological nutrient removal in activated sludge systems – experimental investigation and mathematical modeling
PublicationThe aim of this study was to determine the effects of chemical precipitation and addition of external carbonsources on the denitrification capability and enhanced biological phosphorus removal (EBPR) interactions atthe ‘Wschod’ WWTP (600,000 PE) in Gdansk (northern Poland). For this purpose, different kinds of batch experimentswere carried out with the settled wastewater (without pretreatment and after coagulation-flocculation)and...
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Modeling the Effect of External Carbon Source Addition under Different Electron Acceptor Conditions in Biological Nutrient Removal Activated Sludge Systems
Publicationhe aim of this study was to expand the International Water Association Activated Sludge Model No. 2d (ASM2d) to predict the aerobic/anoxic behavior of polyphosphate accumulating organisms (PAOs) and “ordinary” heterotrophs in the presence of different external carbon sources and electron acceptors. The following new aspects were considered: (1) a new type of the readily biodegradable substrate, not available for the anaerobic activity...
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Modelization of Nutrient Removal Processes at a Large WWTP Using a Modified ASM2d Model
PublicationThe biodegradation of particulate substrates starts by a hydrolytic stage. Hydrolysis is a slow reaction and usually becomes the rate limiting step of the organic substrates biodegradation. The objective of this work was to evaluate a novel hydrolysis concept based on a modification of the activated sludge model (ASM2d) and to compare it with the original ASM2d model. The hydrolysis concept was developed in order to accurately...
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Modeling nutrient removal and energy consumption in an advanced activated sludge system under uncertainty
PublicationActivated sludge models are widely used to simulate, optimize and control performance of wastewater treatment plants (WWTP). For simulation of nutrient removal and energy consumption, kinetic parameters would need to be estimated, which requires an extensive measurement campaign. In this study, a novel methodology is proposed for modeling the performance and energy consumption of a biological nutrient removal activated sludge system...
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Disturbances of biological N-removal processes in the presence of sulphonamides
PublicationBadano podatność na biodegradację oraz wpływ na efektywność nitryfikacji wybranych sulfonamidów (sulfanilamidu SA, sulfacetamidu SCM oraz p-toluenosulfonamidu p-TSA). Podatnośc na biodegradację badano przy użyciu testu OECD 301D (test zamkniętej butelki). Efektywność nitryfikacji miarzono zgodnie z ISO 9509:1989. Stwierdzono, że wszystkie badane związki wykazują bardzo słabą podatność na biodegradację oraz mają wyraźny wpływ na...
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The Occurrence and Role of Tetrasphaera in Enhanced Biological Phosphorus Removal Systems
PublicationThe application of enhanced biological phosphorus removal (EBPR) in wastewater treatment plants (WWTPs) has commonly been utilized worldwide. However, the optimum efficiency has not been realized over the past decades, prompting many studies and publications. The limitations, especially comprehension of the abundance and actual potential of polyphosphate-accumulating organisms (PAOs), are not fully understood. Recently identified...
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The efficiency of biological nutrients removal in WWTP`s "Wschód" in Gdańsk (Poland)
PublicationRozbudowana w latach 1997-99 oczyszczalnia ścieków Wschód w Gdańsku zapewnia wysokoefektywne oczyszczanie ścieków odprowadzanych do wód Zatoki Gdańskiej Morza Bałtyckiego. Zrealizowany układ technologiczny biologicznego oczyszczania ścieków o przepustowości 180 tys. m3 na dobę jest złożony z sześciu reaktorów MUCT, z których każdy współpracuje z dwoma osadnikami wtórnymi. W artykule podsumowano okres pierwszych trzech lat eksploatacji...
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The effect of aeration mode (intermittent vs. continuous) on nutrient removal and greenhouse gas emissions in the wastewater treatment plant of Corleone (Italy)
PublicationThe paper reports the results of an experimental study aimed at comparing two configurations of a full-scale wastewater treatment plant (WWTP): conventional activated sludge (CAS) and oxic-settling-anaerobic process (OSA) with intermittent aeration (IA). A comprehensive monitoring campaign was carried out to assess multiple parameters for comparing the two configurations: carbon and nutrient removal, greenhouse gas emissions, respirometric...
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Impact of aeration conditions on the removal of low concentrations of nitrogen in a tertiary partially aerated biological filter
PublicationA submerged biological aerated filter (BAF) partially aerated was used to study the removal of low concentrations of ammonia nitrogen (0.3 g N/m3 to 30.5 g N/m3) typically found in nutrient enriched river and lake waters, and treated effluents. Four series of experiments were performed with a synthetic wastewater at ammonia loading rates between 6 g N/m3 d and 903 g N/m3 d and C/N ratios from 2 to 20. The results showed that ammonia...
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Comparative Evaluation of Selected Biological Methods for the Removal of Hydrophilic and Hydrophobic Odorous VOCs from Air
PublicationDue to increasingly stringent legal regulations as well as increasing social awareness, the removal of odorous volatile organic compounds (VOCs) from air is gaining importance. This paper presents the strategy to compare selected biological methods intended for the removal of different air pollutants, especially of odorous character. Biofiltration, biotrickling filtration and bioscrubbing technologies are evaluated in terms of...
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The influence of phosphorus fractions in bottom sediments on phosphate removal in semi-natural systems as the 3rd stage of biological wastewater treatment
PublicationThe research was carried out in two semi-natural systems (the polishing ponds in Swarzewo and the free water surface constructed wetland in Zarnowiec) in Poland. They were built as the 3rd stage of a conventional mechanical–biological wastewater treatment plant. These systems were built to improve the quality of the effluent of treated wastewater. In the polishing ponds and FWS wetland system, suspended solids, organic matter as...
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Influence of the boron doping level on the electrochemical oxidation of raw landfill leachates: advanced pre-treatment prior to the biological nitrogen removal
PublicationThe electrochemical oxidative treatment of landfill leachates (LLs) containing high amounts of ammonia nitrogen and organic matter was used as a promising method, prior to biological processes, to achieve the final effluent quality that would be acceptable by current regulations. The deposited boron-doped diamond electrodes (BDDs) with different boron doping concentrations (10000, 5000 and 500 ppm of B) were applied as anodes....
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Heavy metals removal in the mechanical - biological wastewater treatment plant ''Wschod'' in Gdańsk. Usuwanie metali ciężkich w mechaniczno-biologicznej oczyszczalni ścieków Gdańsk ''Wschód''.
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Nutrient removal in municipal wastewater treatment
e-Learning CoursesThis series of lectures and interactive teaching sessions will cover all the important aspects of nutrient removal in municipal wastewater treatment. There will be five sessions. The topics of the sessions are: 1) Nutrient removal – why, how and what has been achieved?; 2) Biological treatment processes and conventional nitrogen removal; 3) Shortcut nitrogen removal processes and climate implication of nitrogen removal; 4) Biological...
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Jacek Mąkinia prof. dr hab. inż.
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The occurrence and role of Nitrospira in nitrogen removal systems
PublicationApplication of the modern microbial techniques changed the paradigm about the microorganisms performing nitrification. Numerous investigations recognized representatives of the genus Nitrospira as a key and predominant nitrite-oxidizing bacteria in biological nutrient removal systems, especially under low dissolved oxygen and substrate conditions. The recent discovery of Nitrospira capable of performing complete ammonia oxidation...
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Wastewater Engineering 2020/21 (Environmental Engineering, II stopnia, stacjonarne, II semestr))
e-Learning CoursesWastewater sources and flows Wastewater characterization based on physical and biodegradation criteria Preliminary treatment unit operations (screens, grit chambers, primary clarifiers) Biological processes (suspended growth vs. attached growth, hybrid systems, granular sludge) for wastewater treatment. Principles of biological nutrient removal (nitrification, denitrification, enhanced biological P removal, anammox). Implementation...
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Wastewater Engineering 2021/22 (Environmental Engineering, II stopnia, stacjonarne, II semestr))
e-Learning CoursesWastewater sources and flows Wastewater characterization based on physical and biodegradation criteria Preliminary treatment unit operations (screens, grit chambers, primary clarifiers) Biological processes (suspended growth vs. attached growth, hybrid systems, granular sludge) for wastewater treatment Principles of biological nutrient removal (nitrification, denitrification, enhanced biological P removal, anammox) Implementation...
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Wastewater Engineering 2022/23 (Environmental Engineering, II stopnia, stacjonarne, II semestr))
e-Learning CoursesWastewater sources and flows Wastewater characterization based on physical and biodegradation criteria Preliminary treatment unit operations (screens, grit chambers, primary clarifiers) Biological processes (suspended growth vs. attached growth, hybrid systems, granular sludge) for wastewater treatment Principles of biological nutrient removal (nitrification, denitrification, enhanced biological P removal, anammox) Implementation...
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Wastewater Engineering 2023/24 (Environmental Engineering, II stopnia, stacjonarne, II semestr)
e-Learning CoursesWastewater sources and flows Wastewater characterization based on physical and biodegradation criteria Preliminary treatment unit operations (screens, grit chambers, primary clarifiers) Biological processes (suspended growth vs. attached growth, hybrid systems, granular sludge) for wastewater treatment Principles of biological nutrient removal (nitrification, denitrification, enhanced biological P removal, anammox) Implementation...
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Porównanie efektywności biologicznego usuwania związków biogennych w procesach MUCT i A2/O na przykładzie oczyszczalni w Gdańsku
PublicationThis paper presents a comparison of the efficiency of nutrient removal in two different technological systems functioning in WWTP in Gdansk. The upgrade was necessary in order to adjust the parameters of wastewater treatment to more stringent requirements for Total Nitrogen removal (Total Nitrogen concentration < 10 mg/L). Since 2012 the biological treatment line has operated based on modified A2/O process instead of MUCT process....
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Dissolved and colloidal organic nitrogen removal from WWTP effluents and reject waters using physical-chemical processes
PublicationFour physical-chemical processes were compared in terms of the efficiencies of dissolved and colloidal organic nitrogen (DON and CON) removal from the secondary effluents (SE) and reject water from full-scale biological nutrient removal activated sludge systems. Adsorption on activated carbon was most efficient and allowed to remove from the SE up to 80% and 100% of DON and CON, respectively. High efficiencies of DON removal from...
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Effects of different external carbon sources and electron acceptors on interactions between denitrification and phosphorus removal in BNR processes
PublicationThe effects of two different external carbon sources (acetate, ethanol) and electron acceptors (dissolved oxygen, nitrate and nitrite) were investigated under aerobic and anoxic conditions with non-acclimated process biomass from a full-scale biological nutrient removal activated sludge system. When acetate was added as an external carbon source, phosphate release was observed even in the presence of electron acceptors. The release...
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Strategies for mitigating nitrous oxide production and decreasing the carbon footprint of a full-scale combined nitrogen and phosphorus removal activated sludge system
PublicationNitrous oxide (N2O) emitted from biological nutrient removal activated sludge systems contributes significantly to the total carbon footprint of modern wastewater treatment plants. In the present study, N2O production and emissions were experimentally determined in a large-scale plant (220,000 PE) employing combined nitrogen (N) and phosphorus (P) removal. As a modelling tool, the Activated Sludge Model 2d (ASM2d) was extended...
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Modeling nitrous oxide production by a denitrifying-enhancedbiologically phosphorus removing (EBPR) activated sludge in thepresence of different carbon sources and electron acceptors
PublicationIn this study, the IWA Activated Sludge Model No. 2d (ASM2d) was expanded to identify the most important mechanisms leading to the anoxic nitrous oxide (N2O) production in the combined nitrogen (N) and phosphorus (P) removal activated sludge systems. The new model adopted a three-stage denitrification concept and was evaluated against the measured data from one/two-phase batch experiments carried out with activated sludge withdrawn...
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The Hydrolysis of Slowly Biodegradable Substrate in Activated Sludge
PublicationIn a present work a novel procedure, based on the standard batch tests and pretreatment of wastewater sample with coagulation-flocculation method, was proposed to evaluate the effects of hydrolysis of slowly biodegradable substrate (Xs) on biological nutrient removal (BNR) processes in activated sludge systems. The study was conducted at two large BNR wastewater treatment plants (WWTPs) in northern Poland: "Wschod" in Gdansk and...
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The experimental evaluation and modeling of SBR removing nutrients under varied aeration conditions
PublicationSequencing batch reactors (SBR) are mainly characterized by sequential process phases of fill, react, settle, decant and idle periods that allow considerable flexibility in the design and operation in different conditions. This flexibility and the unique features of SBRs used to wastewater treatment by activated sludge systems operated in laboratory scale, allow not only conducting experiments for the standard conditions but also...
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The Use of Organic Coagulants in the Primary Precipitation Process at Wastewater Treatment Plants
PublicationMeasurements for determining the effect of chemically enhanced primary treatment (CEPT) on the efficiency of pollutant removal from wastewater were carried out using conventional inorganic coagulants PIX113 with polymer A110 (Kemipol, Police, Poland) and unconventional cationic organic coagulants Cofloc (Attana, Coalville, UK) C29510 (Kemipol, Police, Poland) and Sedifloc 575 (3F Chimica, Sandrigo, Italy). The average removal efficiency...
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Mathematical modelling and computer simulation of activated sludge systems.Second edition
PublicationMathematical Modelling and Computer Simulation of Activated Sludge Systems – Second Edition, provides, from the process engineering perspective, a comprehensive and up-to-date overview regarding various aspects of the mechanistic (“white box”) modelling and simulation of advanced activated sludge systems performing biological nutrient removal. In the new edition of the book, a special focus is given to nitrogen removal and an overview...
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Fractionation and origin of dissolved and colloidal organic nitrogen in BNR plant effluent
PublicationThe characteristics of effluent dissolved and colloidal organic nitrogen (DON and CON) as well as their origin, fate and biodegradability in wastewater treatment plants and receiving waters were identified as the major issues that limit the ability to achieve low total N in the effluent. This study presents the results of a comprehensive survey, which was conducted in eight biological nutrient removal (BNR) WWTPs in northern Poland....
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Spatial distribution of pharmaceuticals in conventional wastewater treatment plant with Sludge Treatment Reed Beds technology
PublicationPharmaceutical residues are an emerging environmental problem. It is strongly confirmed that pharmaceuticals are present in soils and environmental waters (surface, marine and even groundwater), and that wastewater treatment plant (WWTP) effluents are the main source of pharmaceuticals in the watershed. The aim of this studywas to recognize the spatial distribution and seasonal changes of selected pharmaceuticals in conventional WWTP...
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The impact of slowly biodegradable organic compounds on the oxygen uptake rate in activated sludge systems
PublicationThe hydrolysis process of slowly biodegradable substrate (Xs) have impact on the efficiencies of nutrient removal in activated sludge systems. Measurement of OUR and corresponding COD is accepted as a very useful tool to reflect the consumption of biodegradable substrates. The influence of the readily biodegradable substrate (Ss) in biological wastewater treatment systems has been extensively investigated, but little is known about...
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The impact of slowly biodegradable organic compounds on the oxygen uptake rate in activated sludge systems
PublicationThe hydrolysis process of slowly biodegradable substrate (Xs) have impact on the efficiencies of nutrient removal in activated sludge systems. Measurement of OUR and corresponding COD is accepted as a very useful tool to reflect the consumption of biodegradable substrates. The influence of the readily biodegradable substrate (Ss) in biological wastewater treatment systems has been extensively investigated, but little is known about...
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The Simulation of Activated Sludge System for Optimization of Predictive Aeration at Large WWTP
PublicationEffective use of biodegradable substrates as an internal carbon sources (ICS) for denitrification and EBPR and predicting performance of aeration systems during nitrification in activated sludge bioreactors, may be useful in realization the sustainable development by potentially saving energy consumption at WWTPs. A large number of WWTPs use activated sludge systems with an integrated removal of carbon, nitrogen and phosphorus...
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Estimation and modeling hydrolysis of slowly biodegradable substrate based on the batch respirometric tests in activated sludge systems
PublicationNowadays, appropriate determination of chemical oxygen demand (COD) fractionation together with degradation kinetics of organic compounds have a prime importance on the design and operation of activated sludge systems. Batch respirometric tests based on the oxygen uptake rates (OUR) and corresponding COD is accepted method to reflect the consumption of biodegradable substrates. The influence of the readily biodegradable (Ss) fraction...
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Modeling sequencing batch reactor operational conditions depending on oxygen concentration
PublicationSequencing batch reactors (SBR) can be used as a fill-and draw activated sludge system for wastewater treatment with considerable operating flexibility and the possibility to conduct experiments under standard conditions and extreme case scenarios. Mathematical modeling and computer simulations provide an opportunity to implement existing wastewater processes in modeling software and evaluate different modifications at low costs...
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The potential of enhancing denitrification in the activated sludge process with by-products from the alcohol production
PublicationIn this study, by-products from the alcohol production were examined in terms of their potential application as external carbon sources for enhancing denitrification in biological nutrient removal systems. Three kinds of experimental assays were used to compare the effects of the by-products with other external carbon sources (ethanol and acetic acid) and the settled wastewater. Based on the results obtained, it appears that one...