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Search results for: isotherm
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Galvanostatic impedance measurements for the efficient adsorption isotherm construction in corrosion inhibitor studies
PublicationWe present an approach towards an accurate and time-efficient adsorption isotherm determination to evaluate the corrosion inhibitor interaction in electrolytic environments. The approach is based on dynamic impedance spectroscopy measurements in galvanostatic mode (g-DEIS). The studied corrosion inhibitor is continuously injected between the secondary cell and the corrosion cell. The efficiency corresponding to instantaneous inhibitor...
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Titanium(IV) Oxide Modified with Activated Carbon and Ultrasounds for Caffeine Photodegradation: Adsorption Isotherm and Kinetics Study
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The Finite Pore Volume GAB Adsorption Isotherm Model as a Simple Tool to Estimate a Diameter of Cylindrical Nanopores
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Development, characterization and evaluation of composite adsorbent for the adsorption of crystal violet from aqueous solution: Isotherm, kinetics, and thermodynamic studies
PublicationThe purpose of this work focuses on the production and investigations of a new composite material as alternative low-cost adsorbent for the removal of crystal violet (CV) dye from waste solution. The production method was performed by in-situ thermal activation technology via extrusion process of polymer wastes containing tire rubber (50 wt%) and polyurethane foam (50 wt%) using single-screw extruder under processing temperature...
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Nitrogen sorption isotherm for V2CTx
Open Research DataData of points for nitrogen sorption isotherm for sample V2CTx (only sorption branch). The V2CTx was prepared via selective etching of aluminium from MAX matrice V2AlC using 50% HF for 96 h at room temperature.
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BET adsorption-desorption isotherm of nano-CeO2
Open Research DataThe dataset includes the isotherms of adortion and desorption of N2 at LN2 temperature. The sorption isotherms were obtained using Quatachrome NovaTouch LX1 equippment. The catalyts powder composed of nanoCeO2 (AlfaAesar)
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BET adsorption-desorption isotherm of nano-MgO
Open Research DataThe dataset includes the isotherms of adortion and desorption of N2 at LN2 temperature. The sorption isotherms were obtained using Quatachrome NovaTouch LX1 equippment. The ceramic measured powder was composed of nanometric MgO (CA-assisted method of synthesis)
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BET adsorption-desorption isotherm of nano-ZrO2
Open Research DataThe dataset includes the isotherms of adortion and desorption of N2 at LN2 temperature. The sorption isotherms were obtained using Quatachrome NovaTouch LX1 equippment. The ceramic measured powder was composed of nanometric ZrO2 (CA-assisted method of synthesis)
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BET adsorption-desorption isotherm of CeO2 pure
Open Research DataThe dataset includes the isotherms of adortion and desorption of N2 at LN2 temperature. The sorption isotherms were obtained using Quatachrome NovaTouch LX1 equippment. The ceramic measured powder was composed of nanometric pure CeO2 (CA-assisted method of synthesis)
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BET adsorption-desorption isotherm of nano-SrTiO3
Open Research DataThe dataset includes the isotherms of adortion and desorption of N2 at LN2 temperature. The sorption isotherms were obtained using Quatachrome NovaTouch LX1 equippment. The ceramic measured powder was composed of nanometric SrTiO3 (CA-assisted method of synthesis)
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BET adsorption-desorption isotherm of nano-CeO2 impregnated with Cu
Open Research DataThe dataset includes the isotherms of adortion and desorption of N2 at LN2 temperature. The sorption isotherms were obtained using Quatachrome NovaTouch LX1 equippment. The catalyts powder composed of nanoCeO2 impreganted with Cu oxide nanoparticles with the usage of BCD (Beta-cyclodextrins) and without addition.
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BET adsorption-desorption isotherm of nano-CeO2 impregnated with Co
Open Research DataThe dataset includes the isotherms of adortion and desorption of N2 at LN2 temperature. The sorption isotherms were obtained using Quatachrome NovaTouch LX1 equippment. The catalyts powder composed of nanoCeO2 impreganted with Co oxide nanoparticles with the usage of BCD (Beta-cyclodextrins) and without addition.
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BET adsorption-desorption isotherm of nano-CeO2 impregnated with Mn
Open Research DataThe dataset includes the isotherms of adortion and desorption of N2 at LN2 temperature. The sorption isotherms were obtained using Quatachrome NovaTouch LX1 equippment. The catalyts powder composed of nanoCeO2 impreganted with Mn oxide nanoparticles with the usage of BCD (Beta-cyclodextrins) and without addition.
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BET adsorption-desorption isotherm of nano-CeO2 impregnated with Ni
Open Research DataThe dataset includes the isotherms of adortion and desorption of N2 at LN2 temperature. The sorption isotherms were obtained using Quatachrome NovaTouch LX1 equippment. The catalyts powder composed of nanoCeO2 impreganted with Ni oxide nanoparticles with the usage of BCD (Beta-cyclodextrins) and without addition.
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BET adsorption-desorption isotherm of nano-CeO2 impregnated with Fe
Open Research DataThe dataset includes the isotherms of adortion and desorption of N2 at LN2 temperature. The sorption isotherms were obtained using Quatachrome NovaTouch LX1 equippment. The catalyts powder composed of nanoCeO2 impreganted with Fe oxide nanoparticles with the usage of BCD (Beta-cyclodextrins) and without addition.
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BET adsorption-desorption isotherm of CeO2 prepared using Pechini method
Open Research DataThe dataset includes the isotherms of adortion and desorption of N2 at LN2 temperature. The sorption isotherms were obtained using Quatachrome NovaTouch LX1 equippment. The ceramic measured powder was composed of nanometric pure CeO2 prepared using modified Pechini method - citric acid and propylene glycol (2:1)
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Natural convective heat transfer from isothermalconic
PublicationTheoretical considerations on convective heat transfer from isothermal upward conicalsurfaces have been presented. The physical model of this phenomenon consists of an isothermalcone of inclination angle (φ) between the cone generating line (X) and the radius (R) of the cone base. The angle is a parameter of conical surface which varied from (φ = 0−circular horizontal plate) to (φ = π/2—vertical cylinder) . Onthe basis of Navier–Stokes...
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Mathematical Description of Sorption Isotherms of Autoclaved Aerated Concrete
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Isothermal turbines − New challenges. Numerical and experimental investigations into isothermal expansion in turbine power plants
PublicationThe efficiency of power plants with steam or gas turbines depends on the efficiencies of a thermodynamic cycle and devices implementing this cycle. In the case of high power outputs, we cannot expect a significant increase in the efficiency of individual devices. Therefore, what remains is to increase the efficiency of the implemented thermodynamic cycle - the complex Rankine cycle in the case of steam turbines or the extended...
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Isothermal Vulcanization and Non-Isothermal Degradation Kinetics of XNBR/Epoxy/XNBR-g-Halloysite Nanotubes (HNT) Nanocomposites
PublicationThe effect of several concentrations of carboxylated nitrile butadiene rubber (XNBR) functionalized halloysite nanotubes (XHNTs) on the vulcanization and degradation kinetics of XNBR/epoxy compounds were evaluated using experimental and theoretical methods. The isothermal vulcanization kinetics were studied at various temperatures by rheometry and differential scanning calorimetry (DSC). The results obtained indicated that the...
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Isotherms, Isosteres, and Enthalpy of Adsorption of 1,2-Dichloroethane from Aqueous Solution onto Activated Carbons
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DSC isothermal and non-isothermal assessment of thermo-oxidative stability of different cultivars of Camelina sativa L. seed oils
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Evaluation of Langmuir and Freundlich Isotherms for Removal of Cephalexin and Tetracycline Antibiotics By Sistan Sand from Water and Wastewater Samples
PublicationIn this research, Sistan sand was used as a natural and inexpensive sorbent for removal of cephalexin and tetracycline antibiotics from water and wastewater samples. For a concentration 60.0 mg L-1 of cephalexin, optimum removal conditions were: pH of the sample 3.0, adsorbent amount 1.0 g, contact time 20.0 min, added amount of sodium chloride to adjust the ionic strength of the solution 7.0 g L-1. Langmuir isotherm was the best...
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Non-isothermal effects in condensation inside tubes
PublicationWrzenie i kondensacja w przepływie są zjawiskami symetrycznymi, aczkolwiek ich opis za pomocą jednej korelacji w konfrontacji z eksperymentem nie dawał dobrych rezultatów. W pracy zmodyfikowano naprężenia styczne na granicy rozdziału faz w ten sposób, że uwzględniono wymianę pędu na granicy rozdziału faz i możliwym stała się adaptacja wcześniej zaproponowanego przez autorów modelu wrzenia w przepływie do obliczeń wymiany ciepła...
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Organic Supercritical Thermodynamic Cycles with Isothermal Turbine
PublicationOrganic Rankine cycles (ORC) are quite popular, but the overall efficiencies of these plants are rather very low. Numerous studies have been conducted in many scientific centers and research centers to improve the efficiency of such cycles. The research concerns both the modification of the cycle and the increase in the parameters of the medium at the inlet to the turbine. However, the efficiency of even these modified cycles rarely...
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Natural convective heat transfer from isothermal cuboids
PublicationThe paper presents results of theoretical and experimental investigations of the convective heat transfer from isothermal cuboid. The analytical solution was performed taking into account complete boundary layer length and the manner of its propagation around isothermal cuboid. It arises at horizontal bottom surface and grows on vertical lateral surface of the block. After changing its direction, the boundary layer occurs above...
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Natural convective heat transfer from isothermal cuboids
PublicationPrzestawiono rozważania teoretyczne i wyniki badań eksperymentalnych konwekcyjnej wymiany ciepła od powierzchni izotermicznego prostopadłościanu. W rozwiązaniu analitycznym uwzględniono pełną długość warstwy przyściennej i sposób jej rozchodzenia się wzdłuż powierzchni prostopadłościanu. W celu zweryfikowania otrzymanego rozwiązania przeprowadzono badania eksperymentalne w trzech możliwych położeniach bryły. Zaproponowano uniwersalną...
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Subcritical Thermodynamic Cycles with Organic Medium and Isothermal Expansion
PublicationThe efffciencies of the Organic Rankine Cycle (ORC) are not very high and only very seldom do they exceed 20%. The increase and optimization of initial parameters and certain modifications of the thermodynamic cycle make it possible to overcome these drawbacks. A new modified cycle has been described and analyzed in detail in the paper. Similarly to the Ericsson cycle for gas turbines, isothermal expansion in the turbine is suggested...
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Estimation of microbiological contamination of maize seeds using isothermal calorimetry
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A theoretical consideration of a free convective boundary layer on an isothermal horizontal conic.
PublicationPrzedstawiono rozwiązanie analityczne naturalnej konwekcji swobodnej od izotermicznego, poziomego stożka o kącie przy podstawie alfa. Rozwiązanie przeprowadzono w oparciu o typowe dla konwekcji swobodnej założenia upraszczające. Rozwiązania dla przypadków granicznych (poziomy walec i pionowa płyta kołowa) wykazują dobrą zgodność z danymi literaturowymi.
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Natural convective heat-transfers from an isothermal horizontal hemispherical cavity
PublicationPrzedstawiono rozwiązanie analityczne oraz wyniki badań eksperymentalnych i numerycznych konwekcyjnej wymiany ciepła od poziomej izotermicznej kulistej wklęsłej powierzchni.
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Cure kinetics of epoxy/MWCNTs nanocomposites: Isothermal calorimetric and rheological analyses
PublicationA combinatorial route has been applied in cure kinetics study of epoxy nanocomposites containing multi-walled carbon nanotubes (MWCNTs) based on differential scanning calorimetry and rheokinetic analyses under isothermal conditions. Pristine and amine-modified MWCNTs bearing primary and secondary amines were used at very low concentrations (0.1 and 0.3 wt.% based on epoxy weight). Model-free and model-fitting methods were applied...
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Experimental verification of natural convective heat transfer phenomenon from isothermal cuboids
PublicationArtykuł przedstawia wyniki badań eksperymentalnych konwekcyjnej wymiany ciepła od powierzchni izotermicznego prostopadłościanu o stosunkowo dużych rozmiarach (t.j. 1.5 m x1 m x 0.5 m). Celem tych badań było otrzymanie wyników, które można by porównać z otrzymanymi dla obiektu w mniejszej skali i prezentowano we wcześniejszych doniesieniach (Int. J. Heat Mass Transfer 46 (2003) 2169-2178). Rozwiązanie eksperymentalne przeprowadzono...
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Loop-mediated isothermal amplification (LAMP) as a diagnostic tool in detection of infectious diseases
PublicationLoop-mediated isothermal amplification (LAMP) is a gene amplification method which amplifies DNA with high specificity and efficiency under isothermal conditions. Because of its rapidity and simplicity, it is a valuable diagnostic tool in the early detection and identification of infectious diseases. LAMP method is based on the use of a set of four to six specially designed primers spanning six to eight distinct sequences on the...
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Decomposition of Acoustic and Entropy Modes in a Non-Isothermal Gas Affected by a Mass Force
PublicationDiagnostics and decomposition of atmospheric disturbances in a planar flow are considered in this work. The study examines a situation in which the stationary equilibrium temperature of a gas may depend on the vertical coordinate due to external forces. The relations connecting perturbations are analytically established. These perturbations specify acoustic and entropy modes in an arbitrary stratified gas affected by a constant...
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Study of free convective boundary layer of isothermal lateral surface of axisymmetrical horizontal body
PublicationPrzedstawiono rozwiązanie równań Naviera-Stokesa i Fouriera-Kirchhoffa we współrzędnych tau i sigma. Pierwsza jest styczną a druga normalną do konwekcyjnych linii prądu, wzdłuż jakich porusza się ogrzany od powierzchni płyn. Wynik w postaci równania na grubość warstwy przyściennej zweryfikowano dla granicznych przypadków ciała obrotowego o poziomej osi symetrii (stożka poziomego i kołowej pionowej płyty).
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Natural convective heat transfer from isothermal horizontal, vertical and inclined plates - a review
PublicationW artykule przedstawiono przegląd otrzymanych przez różnych badaczy korelacji eksperymentalych, teoretycznych i numerycznych, opisujących wymianę ciepła od izotermicznych płyt o różnym kącie pochylenia. Przedstawiono model matematyczny zjawiska. Opisano stosowane metody badawcze i wskazano przyczyny rozbieżności pomiędzy przedstawionymi przez wielu autorów wynikami.
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Method to determine the critical concentration Rayleigh number in isothermal passive membrane transport processes
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Free convective heat transfer structures as a function of the width of isothermal horizontal rectangular plates
PublicationZaprezentowano rezultaty badań eksperymentalnych konwekcyjnej wymiany ciepła od izotermicznych płyt prostokątnych skierowanych ku górze. Na podstawie przeprowadzonych wizualizacji zaproponowano dwa modele struktur przepływu. Rozwiązania analityczne dla tych modeli przedstawiono w postaci zależności liczb Nusselta Rayleigh'a. Stwierdzono, że przepływ koncentryczny występuje dla małych wartości liczb Ra, szczególnie w przypadku płyt...
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Isothermal Calorimetry and Compressive Strength Tests of Mortar Specimens for Determination of Apparent Activation Energy
PublicationThe hydration process of cementitious materials involves a thermally activated reaction that depends on the composition of the mixture and the curing temperature. The main parameter affecting the temperature variation of cast-in-place concrete is the apparent activation energy, which can be used for the efficient prediction of the temperature evolution and maturity index of hardening concrete. This paper discusses two methods to...
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Real-time isothermal DNA amplification monitoring in picoliter volumes using an optical fiber sensor
PublicationRolling circle amplification (RCA) of DNA can be considered as a great alternative to the gold standard polymerase chain reaction (PCR), especially during this pandemic period, where rapid, sensitive, and reliable test results for hundreds of thousands of samples are required daily. This work presents the first research to date on direct, real-time and label-free isothermal DNA amplification monitoring using a microcavity in-line...
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Possibility of thermal imaging use in studies of natural convection heat transfer on the example of an isothermal vertical plate
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Buffer contribution to formation enthalpy of copper(II)–bicine complex determined by isothermal titration calorimetry method
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Crystal structure and isothermal titration calorimetry studies of new cobalt(II) complex with 2-methylnitrilotriacetate ion
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Green`s function methods for Mathematical modeling of unidirectional diffusion process in isothermal metals bonding process
PublicationPodano wykorzystanie funkcji Greena w rozwiązaniu matematycznego modelu dyfuzji jednowymiarowej podczas izotermicznego łączenia metali.
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Possibility of thermal imaging use in studies of natural convection heat transfer on the example of an isothermal vertical plate.
PublicationA new method of infrared (IR) camera use in convective heat transfer studies has been presented. Until now, IR cameras were utilized for temperature field visualizations of flat heated surfaces of solid objects only. Because liquids and gasses do not emit radiation in the infrared range of wave lengths, detection of temperature field in the air was conducted with the use of plastic mesh, which, after heating by hot air, emits infrared...
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Standing Waves in One-Dimensional Resonator Contaning an Ideal Isothermal Gas Affected by the Constant Mass Force
PublicationThe study is devoted to standing acoustic waves in one-dimensional planar resonator which containing an ideal gas. A gas is affected by the constant mass force. Two types of physically justified boundary conditions are considered: zero velocity or zero excess pressure at both boundaries. The variety of nodal and antinodal points is determined. The conclusion is that the nodes of pressure and antinodes of velocity do not longer...
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Study of Slip Effects in Reverse Roll Coating Process Using Non-Isothermal Couple Stress Fluid
PublicationThe non-isothermal couple stress fluid inside a reverse roll coating geometry is considered. The slip condition is considered at the surfaces of the rolls. To develop the flow equations, the mathematical modelling is performed using conservation of momentum, mass, and energy. The LAT (lubrication approximation theory) is employed to simplify the equations. The closed form solution for velocity, temperature, and pressure gradient...
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Using isothermal calorimetry and FT-Raman spectroscopy for step-by-step monitoring of maize seed germination: case study
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Non-isothermal effects in a common method for calculation of heat transfer coefficient in flow boiling and flow condensation in minichannels
PublicationW pracy przestawiono efekty nieizotermiczne w metodzie wyznaczania współczynnika przejmowania ciepła podczas wrzenia w przepływie oraz kondensacji w przepływie w minikanałach. Wyniki obliczeń porównano z badaniami eksperymentalnymi z literatury, uzyskując dobrą zgodność.