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Search results for: IRREVERSIBLE THERMODYNAMICS
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Influence of Antimony Substitution on Spontaneous Strain and Thermodynamic Stability of Lanthanum Orthoniobate
PublicationThe analysis of the antimony substitution influence on temperature dependence of unit cell distortion has been done. The values of spontaneous strain and Landau order parameter for three different antimony contents varied had been calculated. The phase transition occurring for antimony substituted lanthanum orthoniobate was found to be second order. The high temperature solution calorimetry method has been used to investigate...
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THERMODYNAMIC ANALYSIS OF A GENERATION IV SCWR NUCLEAR POWER PLANT CYCLE
PublicationThis article presents a flow and thermodynamic analysis of a Generation IV nuclear cycle. An SCWR (Supercritical water reactor) is a high temperature and high pressure reactor that uses water at a temperature above its thermodynamic critical point as the working fluid. The cycle used for the calculations consists of one interstage superheater and 7 regenerative heat exchangers. Division pressure was optimized in view of the cycle efficiency,...
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Thermodynamic Cycles of Air Microturbine Power Plants Working on Biomass Fuels
PublicationThe gas turbine engine is modified to work as an air turbine set which consists, in the simplest arrangement, of a compressor, a heat exchanger and a turbine. Air is a working medium for both: the compressor and the turbine. This kind of air turbine set can be applied in power plants working on biomass fuels. In this solution we can burn fuels of varying parameters in the external combustion chamber without any harmful effects...
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Thermodynamics, size, and dynamics of zwitterionic dodecylphosphocholine and anionic sodium dodecyl sulfate mixed micelles
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Thermodynamics and kinetics of amphotericin B self-association in aqueous solution characterized in molecular detail
PublicationAmphotericin B (AmB) is a potent but toxic drug commonly used to treat systemic mycoses. Its efficiency as a therapeutic agent depends on its ability to discriminate between mammalian and fungal cell membranes. The association of AmB monomers in an aqueous environment plays an important role in drug selectivity, as oligomers formed prior to membrane insertion – presumably dimers – are believed to act differently on fungal (ergosterol-rich)...
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Arterial stiffness, central hemodynamics, and cardiovascular risk in hypertension
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UNRES server for physics-based coarse-grained simulations and prediction of protein structure, dynamics and thermodynamics
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Reversible data hiding in encrypted DICOM images using sorted binary sequences of pixels
PublicationIn this paper, a novel reversible data hiding method for encrypted DICOM images is proposed. The method utilizes binary decomposition of the input data paired with a sorting process of the obtained binary sequences to ensure efficient data embedding in each predefined data block for specific most significant bit (MSB) planes while exploiting the properties of run-length encoding. The proposed scheme is lossless, and based on the...
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Reversible Video Stream Anonymization for Video Surveillance Systems Based on Pixels Relocation and Watermarking
PublicationA method of reversible video image regions of interest anonymization for applications in video surveillance systems is described. A short introduction to theanonymization procedures is presented together with the explanation of its relation to visual surveillance. A short review of state of the art of sensitive data protection in media is included. An approach to reversible Region of Interest (ROI) hiding in video is presented,...
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The thermodynamic critical field and specific heat of superconducting state in phosphorene under strain
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Theoretical Organic Rankine Cycle efficiency depending on different thermodynamic work variables.
PublicationOne of promising technologies of utilizing low- temperature waste heat is through ORC (Organic Rankine Cycle) system implementation. A primary objective in designing in-stallations based on such systems is to maximize the installation's work efficiency. On the other hand, ecological factors are commonly considered a natural barrier in introducing new, often very expensive technologies. Ecological effect of a potential modernization...
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Nonlocalized thermal behavior of rotating micromachined beams under dynamic and thermodynamic loads
PublicationRotating micromachined beams are one of the most practical devices with several applications from power generation to aerospace industries. Moreover, recent advances in micromachining technology have led to huge interests in fabricating miniature turbines, gyroscopes and microsensors thanks to their high quality/reliability performances. To this end, this article is organized to examine the axial dynamic reaction of a rotating...
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THE THERMODYNAMIC ANALYSIS OF THE SZEWALSKI HIERARCHIC VAPOUR CYCLE COOPERATED WITH THE SYSTEM OF HEAT RECOVERY
PublicationIn this paper, thermodynamic analysis of the Szewalski hierarchic vapour cycle cooperated with the system of heat recovery from exhaust gases are presented. According to that purpose, the CFM (Computation Flow Mechanics [1,3]) approach has correctly been used. The whole system consists of the first traditional steam cycle, the second organic Rankine cycle (ORC) and system of heat recovery with use of water with temperature 90...
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Application of the tetraphenylphosphonium tetraphenylborate (TPTB) assumption to the thermodynamic properties of solvated ions in dimethylsulfoxide
PublicationW niniejszej pracy za pomocą spektroskopii ATR FTIR sprawdzano możliwość zastosowania tetrafenyloboranu tetrafenylofosfoniowego w metodzie elektrolitu wzorcowego, służącej do podziału wielkości termodynamicznych elektrolitów w dimetylosulfotlenku na udziały jonowe. Jednoznacznie stwierdzono, że poza termodynamiczne założenie o identycznych oddziaływaniach jonów w elektrolicie wzorcowym z cząsteczkami DMSO jest nieprawdziwe. Uzyskane...
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Power augmentation of PGE Gorzow's gas turbine by steam injection - thermodynamic overview
PublicationThe impact of steam injection upon a gas turbine and a combined power plant performance has been investigated. This article describes and summarizes possibilities of modification for current gas turbine in PGE Gorzow power plant into the Cheng cycle. Our modification deals with a thermal cycle, in which steam produced in a heat recovery steam generator is injected into the gas turbine's combustion chamber. It has been proved that...
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A thermodynamic criterion for selection of working fluid for subcritical and supercritical domestic micro CHP
PublicationW pracy przedstawiono kryterium termodynamiczne doboru czynnika roboczego dla mikrosiłowni pracującej w warunkach podkrytycznych i nadkrytycznych. Przeanalizowano 20 płynów możliwych do wykorzystania w mikrosiłowni ORC. Z analizy wynika, że najlepszym płynem roboczym jest etanol, R123 oraz R141b.
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Thermodynamic analysis of the double Brayton cycle with the use of oxy combustion and capture of CO2
PublicationIn this paper, thermodynamic analysis of a proposed innovative double Brayton cycle with the use of oxy combustion and capture of CO2, is presented. For that purpose, the computation flow mechanics (CFM) approach has been developed. The double Brayton cycle (DBC) consists of primary Brayton and secondary inverse Brayton cycle. Inversion means that the role of the compressor and the gas turbine is changed and firstly we have expansion...
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Comparison of soil models in the thermodynamic analysis of a submarine pipeline buried in seabed sediments
PublicationThis paper deals with mathematical modelling of a seabed layer in the thermodynamic analysis of a submarine pipeline buried in seabed sediments. The existing seabed soil models: a “soil ring” and a semi-infinite soil layer are discussed in a comparative analysis of the shape factor of a surrounding soil layer. The meaning of differences in the heat transfer coefficient of a soil layer is illustrated based on a computational example...
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Left Ventricular Mass: Correlation with Fatness, Hemodynamics and Renal Morphology
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Adsorption of cationic dyes onto Fe@graphite core–shell magnetic nanocomposite: Equilibrium, kinetics and thermodynamics
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Scale-consistent approach to the derivation of coarse-grained force fields for simulating structure, dynamics, and thermodynamics of biopolymers
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Reversible energy transfer between monomers and fluorescent dimers of rhodamine S in polyvinyl alcohol films
PublicationBezpromienisty transfer energii i jej pułapkowanie jest analizowane dla rodaminy S domieszkowanej w foliach PVA. Z analizy wynika że fluoryzujące dimery rodaminy S grają rolę niedoskonałych pułapek energii wzbudzenia. Dla najwyższych koncentracji barwnika wyniki doświadczalne wydajności kwantowej i anizotropii emisji nie mogą być wyjaśnione przy pomocy modelu pomijającego transfer powrotny energii do monomerów. Uwzględnienie transferu...
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Metrological characteristics of the flat voltammetric electrode in time domain with a reversible electrochemical reaction running on the surface
PublicationW artykule przedstawiono właściwości metrologiczne płaskich elektrod woltamperometrycznych. Omówiono wpływ napięcia polaryzującego na wartości parametrów charakteryzujących te elektrody.
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Heat transfer enhancement of modular thermal energy storage unit for reversible heat pump cooperation
PublicationThe following article presents experimental comparison research on a hexagonal shelland-tube latent thermal energy storage (TES). Such shape of a shell was deliberately chosen instead of a cylindrical one due to its high modularity and with intent for future applications in automobiles (EV and PHEV) air conditioning systems (HVAC). Two geometries of helical coils, acting as tubes, were studied in this article. One was a simple...
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Nonequilibrium thermodynamic model of diffusion processes in the steel - carbon thin film tribological system
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Thermodynamic Characteristics of Phenacetin in Solid State and Saturated Solutions in Several Neat and Binary Solvents
PublicationThe thermodynamic properties of phenacetin in solid state and in saturated conditions in neat and binary solvents were characterized based on differential scanning calorimetry and spectroscopic solubility measurements. The temperature-related heat capacity values measured for both the solid and melt states were provided and used for precise determination of the values for ideal solubility, fusion thermodynamic functions, and...
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Design and thermodynamic and thermoeconomic analysis of an organic Rankine cycle for naval surface ship applications
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Design and thermodynamic analysis of an H2O–LiBr AHP system for naval surface ship application
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A concept of zero-dimensional and three-dimensional thermodynamic modelling of steam storage in a steam cycle
PublicationThis work presents the thermodynamic model of steam storage in a steam cycle. The innovative steam storage is an integral part of the unit and thus responds quickly to changes in load. This enhances the primary control reserve while maintaining high efficiency of energy conversion. With regard to power plants, it improves the operational safety of generation units, as it prevents boiler and turbines overload in the case of steep...
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Review of hydrogen production technologies for automotive sector – thermodynamic analysis of energy and exergy losses
PublicationFew recent years has shown that hydrogen technology has a good chance to replace petroleum technology in automotive sector. However, hydrogen in pure form practically does not occur on Earth. That is why H2 form is used only as an energy carrier and it must be produced using another source of energy form water or hydrocarbon fuels. In this paper short overview of hydrogen production technology has been presented, with energy and...
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Thermodynamic, Anticoagulant, and Antiproliferative Properties of Thrombin Binding Aptamer Containing Novel UNA Derivative
PublicationThrombin is a serine protease that plays a crucial role in hemostasis, fibrinolysis, cell proliferation, and migration. Thrombin binding aptamer (TBA) is able to inhibit the activity of thrombin molecule via binding to its exosite I. This 15-nt DNA oligonucleotide forms an intramolecular, antiparallel G-quadruplex structure with a chair-like conformation. In this paper, we report on our investigations on the influence of certain...
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Non-dimensional thermodynamic criterion for selection of dry working fluid for organic Rankine cycle
PublicationW pracy przedstawiono bezwymiarowe kryterium termodynamiczne do selekcji suchych czynników roboczych dla organicznego obiegu Rankina, które umożliwia wstępną selekcję potencjalnych czynników.
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Podstawowe pojęcia w termodynamice technicznej: energia, praca i ciepło
PublicationPrzypomniano podstawowe pojęcia z zakresu termodynasmiki technicznej. Zwrócono szczególną uwagę, że praca i ciepło są sposobem przekazywania energii. Omówiono również pojęcie energii wewnętrznej oraz entalpii. Zwrócono uwagę, że praca i ciepło różnią się przydatnością energetyczną, którą określamy przy pomocy przypomnianego pojęcia egzergii.
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Podstawowe pojęcia w termodynamice technicznej: energia a praca i ciepło
PublicationPrzypomniano podstawowe pojęcia energii i wielkości z nią związanych. Omówiono takie pojęcia, jak praca i ciepło, ale również energia wewnętrzna, entalpia i egzergia, kładąc nacisk na ich stosowanie w problematyce chłodniczej.
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Reactive metabolites of acridinone antitumor agents, C-1311 and C-1305, are trapped within the active site of CYP1A2 and CYP3A4, causing irreversible enzymes inactivation
PublicationZwiązki C-1305 i C-1311, zsyntetyzowane w Katedrze Technologii Leków i Biochemii, wykazują najsilniejsze właściwości przeciwnowotworowe wśród pochodnych, odpowiednio, triazolo- i imidazoakrydonu. Obecnie prowadzone są badania mające na celu określenie biochemicznego mechanizmu działania, jak również potencjalnych szlaków biotransformacji C-1305 i C-1311.W bieżącym etapie podjęto próbę określenia mechanizmu obserwowanej inhibicji...
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A chemo-mechano-thermodynamical contact theory for adhesion, friction, and (de)bonding reactions
PublicationThis work presents a self-contained continuum formulation for coupled chemical, mechanical, and thermal contact interactions. The formulation is very general and, hence, admits arbitrary geometry, deformation, and material behavior. All model equations are derived rigorously from the balance laws of mass, momentum, energy, and entropy in the framework of irreversible thermodynamics, thus exposing all the coupling present in the...
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Gradient theories of ductile and brittle damage: a thermodynamical consistent framework and computational issues
PublicationPrzedstawiono termodynamicznie zgodny opis gradientowych teorii plastycznego i kruchego zniszczenia. Przyjęto, że propagujące mikro-zniszczenia posiadają bezwładność i ich ruch jest wywołany przez mikro-siły, które spełniają ich własne dynamiczne równania równowagi. Poza równaniami równowagi makro- i mikro-sił sformułowano pierwsze i drugie prawo termodynamiki na poziomie mikro i mezo. Zakładając ogólną formę równań konstytutywnych...
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Reversible Data Hiding in Encrypted DICOM Images Using Cyclic Binary Golay (23, 12) Code
PublicationIn this paper, a novel reversible data hiding method for encrypted images (RDHEI) is proposed. An efficient coding scheme based on cyclic binary Golay (23, 12) code is designed to embed additional data into the least significant bits (LSBs) of the encrypted image. The most significant bits (MSBs) are used to ensure the reversibility of the embedding process. The proposed scheme is lossless, and based on the receiver’s privileges,...
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Description of the thermodynamic properties of BiH 5 and BiH 6 superconductors beyond the mean-field approximation
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Thermodynamic Analysis of a Closed-Cycle Ocean Thermal Energy Conversion Power Plant for Offshore Platforms
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Thermodynamic interpretation and prediction of CO2 solubility in imidazolium ionic liquids based on regular solution theory
PublicationRegular solution theory (RST) is the most popular model for the interpretation of the interaction between CO2 and ionic liquids. In the present work, the parameters of this model were determined for the CO2 absorption in eleven imidazolium ionic liquids. The y-intercept (A) of the RST model for the investigated imidazolium liquids increases with increasing temperature whereas the slope (B) remains constant. The values of RST parameters...
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Thermodynamic analysis of the Compressed Air Energy Storage system coupled with the Underground Thermal Energy Storage
PublicationImprovement of flexibility is one of the key challenges for the transformation of the Polish Power System aiming at a high share of renewable energy in electricity generation. Flexible and dispatchable power plants will contribute to this ongoing transformation process as they compensate for fluctuations in electricity generation from renewable energy sources such as wind and photovoltaics. In this context, CAES storage tanks are...
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Thermodynamic Cycle Concepts for High-Efficiency Power Plans. Part A: Public Power Plants 60+
PublicationAn analysis was carried out for different thermodynamic cycles of power plants with air turbines. Variants with regeneration and different cogeneration systems were considered. In the paper, we propose a new modification of a gas turbine cycle with the combustion chamber at the turbine outlet. A special air by-pass system of the combustor was applied and, in this way, the efficiency of the turbine cycle was increased by a few points....
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On the production of electricity in Poland using a geothermal binary power plant - A thermodynamic overview - Part I
PublicationPoland has a significant potential of geothermal energy. However, the high-temperature sources that are needed to drive power plants are found in relatively few places. Therefore, the objective of this paper is to consider any location in the northern part of Poland as a possible place to build a binary power plant. A scientific research was confirmed the existence of an elevated temperature gradient in this region. The hot rocks...
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Quantitative study of free convective heat losses from thermodynamic partitions using Thermal Imaging
PublicationThe following paper presents a simple method of determining the presence, distribution and values of heat losses from external building walls as thermodynamic partitions using a Thermal Imaging Camera (TIC). According to Fourier's equation, the value of heat loss is proportional to the temperature gradient ∂t/∂y|y=0 in air in the y direction perpendicular to the heated surface. Unfortunately, air temperature cannot be measured...
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Association of muscular strength with pulsatile and steady hemodynamics in patients with acute myocardial infarction
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Thermodynamics and Intermolecular Interactions of Nicotinamide in Neat and Binary Solutions: Experimental Measurements and COSMO-RS Concentration Dependent Reactions Investigations
PublicationIn this study, the temperature-dependent solubility of nicotinamide (niacin) was measured in six neat solvents and five aqueous-organic binary mixtures (methanol, 1,4-dioxane, acetonitrile, DMSO and DMF). It was discovered that the selected set of organic solvents offer all sorts of solvent effects, including co-solvent, synergistic, and anti-solvent features, enabling flexible tuning of niacin solubility. In addition, differential...
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Influence of the Square Wave Voltage on Dynamical Properties of a Flat Voltammetric Electrode in the Time Domain by the Electrochemical Reversible Reaction
PublicationIn this article there is a presentation of the analysis of the polarizing voltage shape influencing dynamic properties of voltammetric electrodes when on their surface reversible reaction takes place in the time domain. The electrode polarization with linearly increasing voltage and with a square component, was analyzed. The analysis that were conducted showed that the voltammetric electrode behaves like a first order transducer....
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Alkali-activated slag supplemented with waste glass powder: Laboratory characterization, thermodynamic modelling and sustainability analysis
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Design and Thermodynamic Analysis of a Steam Ejector Refrigeration/Heat Pump System for Naval Surface Ship Applications
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