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Search results for: PHENOLIC FRACTIONS
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Is participation in music festivals a self-expansion opportunity? Identity, self-perception, and the importance of music’s functions
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New type of repeated Si–C-podand catalysts for solid–liquid phase transfer reactions
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Proton transfer reactions from some diarylcyanomethanes to cis 1,2-bis(diethylaminomethyl)cyclohexane in acetonitrile
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Self-adjusting sub-sample delay estimator based on fractional delaying Hilbert transform filter
PublicationZaprezentowano nowe rozwiązanie samo-nastrajalnego estymatora opóźnienia sygnału sinusoidalnego, działającego w czasie dyskretnym. Zastosowano filtr Hilberta o skończonej odpowiedzi ipulsowej (FIR od ang. finite impulse response) zagregowany z filtrem ułamkowo-opóźniającym. Zilustrowano performancję estymatora, również w obecności szumu. Przeanalizowano jego złożoność numeryczną.
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Single Triglyceride-Rich Meal Destabilizes Barrier Functions and Initiates Inflammatory Processes of Endothelial Cells
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Modelling of First- and Second-order Chemical Reactions on ARUZ – Massively-parallel FPGA-based Machine
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Guidelines regarding ineffective maintenance of organ functions (futile therapy) in paediatric intensive care units
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Facile Deposition of Pd Nanoparticles on Carbon Nanotube Microparticles and Their Catalytic Activity for Suzuki Coupling Reactions
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Fractional-Order PID Controller (FOPID)-Based Iterative Learning Control for a Nonlinear Boiler System
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Comments on various extensions of the Riemann–Liouville fractional derivatives : About the Leibniz and chain rule properties
PublicationStarting from the Riemann–Liouville derivative, many authors have built their own notion of fractional derivative in order to avoid some classical difficulties like a non zero derivative for a constant function or a rather complicated analogue of the Leibniz relation. Discussing in full generality the existence of such operator over continuous functions, we derive some obstruction Lemma which can be used to prove the triviality...
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Modelling of residential sales price with kriging using different distance metrics in different correlation functions
PublicationThe modelling and estimation of sales prices based on economical conditions are important for housing sector especially in developing countries. Analysts are focused on the subject to analyze price movements and estimate the future trend of the sales prices for housing sector. In this study, we tried to generate a robust and efficient model related to the subject. Firstly, we investigated economic variables affecting housing sales...
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Variational principles for bound states of Schrödinger and Dirac equations allowing the use of discontinuous trial functions
PublicationWe present systematic constructions of variational principles for energies of bound states of the Schroedinger and Dirac equations. The principles allow the use of discontinuous trial functions. The method employed is based on a generalized Lagrange procedure. Relationships between our variational principles and those available in the literature are established.
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Influence of chloroform on crystalline products yielded in reactions of 5,10,15,20-tetraphenylporphyrin with HCl and copper(II) salts
PublicationStwierdzono, że chloroform wbudowuje się do sieci krystalicznej dichlorowodorku 5,10,15,20-tetrafenyloporfiryny, oraz że powoduje krystalizację nowej, jednoskośnej odmiany polimorficznej porfirynianu miedzi(II), CuTPP. W pracy opisano strukturę krystaliczną solwatu dichlorowodorku porfiryny z ośmioma cząsteczkami chloroformu, C44H32N42+·2Cl-·8CHCl3, i porównano ją...
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Hybrid super‐twisting fractional‐order terminal sliding mode control for rolling spherical robot
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Reactions of NO2 with chromium(III) complexes with histamine and pyridoxamine ligands studied by the stopped-flow technique
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Airfoil Design Under Uncertainty Using Non-Intrusive Polynomial Chaos Theory and Utility Functions
PublicationFast and accurate airfoil design under uncertainty using non-intrusive polynomial chaos (NIPC) expansions and utility functions is proposed. The NIPC expansions provide a means to efficiently and accurately compute statistical information for a given set of input variables with associated probability distribution. Utility functions provide a way to rigorously formulate the design problem. In this work, these two methods are integrated...
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An investigation on the chemistry of the R2P=P ligand: reactions of a phosphanylphosphinidene complex of tungsten(VI) with electrophilic reagents
PublicationThe nucleophilic properties of the title compound [(2,6-i-Pr2C6H3N)2(Cl)W(η2-t-Bu2PvP)]Li·3DME (1) were investigated in reactions with selected electrophilic reagents such as MeI, M(CO)5THF (M = Cr, Mo, W), AlCl3, and GaCl3. Methylation of 1 by MeI yields phosphanylphosphido complexes [(2,6-i-Pr2C6H3N)2W(X)(1,2-η-t-Bu2PvP–CH3)] (X = Cl, I) (2-Cl/2-I) with the formation of a new P–C bond. Moreover, 1 reacts with electrophilic compounds...
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ORF Approximation in Numerical Analysis of Fractional Point Kinetics and Heat Exchange Model of Nuclear Reactor
PublicationThis paper presents results concerning numerical solutions of the fractional point kinetics (FPK) and heat exchange (HE) model for a nuclear reactor. The model consists of a nonlinear system of fractional and ordinary differential equations. Two methods to solve the model are compared. The first one applies Oustaloup Recursive Filter (ORF) and the second one applies Refined Oustaloup Recursive Filter (RORF). Simulation tests have...
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Linear-scaling calculation of Hartree-Fock exchange energy with Non-orthogonal Generalised Wannier Functions
PublicationWe present a method for the calculation of four-centre two-electron repulsion integrals in terms of localised non-orthogonal generalised Wannier functions (NGWFs). Our method has been imple- mented in the ONETEP program and is used to compute the Hartree-Fock exchange energy component of Hartree-Fock and Density Functional Theory (DFT) calculations with hybrid exchange-correlation functionals. As the NGWFs are optimised in situ...
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ORF Approximation in Numerical Analysis of Fractional Point Kinetics and Heat Exchange Model of Nuclear Reactor
PublicationThis paper presents results concerning numerical solutions of the fractional point kinetics (FPK) and heat exchange (HE) model for a nuclear reactor. The model consists of a nonlinear system of fractional and ordinary differential equations. Two methods to solve the model are compared. The first one applies Oustaloup Recursive Filter (ORF) and the second one applies Refined Oustaloup Recursive Filter (RORF). Simulation tests have...
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MEMORY EFFECT ANALYSIS USING PIECEWISE CUBIC B-SPLINE OF TIME FRACTIONAL DIFFUSION EQUATION
PublicationThe purpose of this work is to study the memory effect analysis of Caputo–Fabrizio time fractional diffusion equation by means of cubic B-spline functions. The Caputo–Fabrizio interpretation of fractional derivative involves a non-singular kernel that permits to describe some class of material heterogeneities and the effect of memory more effectively. The proposed numerical technique relies on finite difference approach and cubic...
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Fractional Calculus Evaluation of Hyaluronic Acid Crosslinking in a Nanoscopic Part of Articular Cartilage Model System
PublicationThis work presents a study of the mechanism of physical crosslinking of hyaluronic acid in the presence of common phospholipids in synovial joint organ systems. Molecular dynamic simulations have been executed to understand the formation of hyaluronan networks at various phospholipid concentrations. The results of the simulations suggest that the mechanisms exhibit subdiffusion characteristics. Transportation quantities derive...
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Reactions of solute species at an electrode modified with titanocene functionalized polypyrrole film: ferrocene and titanocene dichloride
PublicationPo raz pierwszy zbadano możliwość intermediacji ładunku poprzez centra tytanocenowe polimeru modyfikowanego chemicznie związanymi grupami dichloro tytanocenowymido polipirolu. Badano reakcje elektrodowe ferrocenu i dichlorotytanocenu. Wykazano aktywność elektrodową w zakresie potencjałów redoks pary Ti(IV/TiIII)w stosunku do reakcji redoks ferrocenu i reakcji dichlorotytanocenu. Wykazano, że centra TcCl2 polimeru są zadowalająco...
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On designing minimax adjustable wideband fractional delay FIR filters using two-rate approach
PublicationZaprezentowano nowe rozwiązanie problemu projektowania numerycznie oszczędnego, przestrajalnego, szerokopasmowego filtru ułamkowo opóźniającego o skończonej odpowiedzi impulsowej (FIR) w strukturze Farrowa. Innowacja polega na zagregowaniu dwóch podejść. Pierwsze z nich polega na równoczesnej optymalizacji wszystkich podfiltrów struktury Farrowa. Drugie wykorzystuje dwuszybkościową aranżację dwustopniową. Docelowe rozwiązanie jest...
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Valence and lowest Rydberg electronic states of phenol investigated by synchrotron radiation and theoretical methods
PublicationWe present the experimental high-resolution vacuum ultraviolet (VUV) photoabsorption spectra of phenol covering for the first time the full 4.3–10.8 eV energy-range, with absolute cross sections determined. Theoretical calculations on the vertical excitation energies and oscillator strengths were performed using time-dependent density functional theory and the equation-of-motion coupled cluster method restricted to single and double...
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Cross-linking of polymer films using phenol-formaldehyde resins with different functional groups
PublicationWell-know phenol-formaldehyde resins are used in the production of press-materials, glues, protective coating, mastics. They take a special place among known oligomers because the products based on them are characterized by a low cost and a series of positive properties. Aim of the work: to show the possibility to create polymeric films based on epoxy resins and modified phenol-formaldehyde resins, which contain unsaturated double...
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Multivariate statistical comparison of analytical procedures for benzene and phenol determination with respect to their environmental impact
PublicationThe studydescribesthepossibilityofapplicationofself-organizingmapstechniquetoassessthe greenness ofanalyticalmethodologies.Themetrologicaland “environmentalimpact” parametersof proceduresforbenzeneandphenoldeterminationinwatersamplesweresetsofinputdatafor chemometric analysis.Totally47objectsand8variablesformedthedatausedforanalysis.Themajor factors responsiblefornon-greencharacterofthemethodologyaretheamountoforganicsolventand amount...
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Actions of a nitric oxide donor on prostaglandin production and angiogenic activity in the equine endometrium
PublicationNitric oxide (NO) plays an important role in prostaglandin secretion and angiogenesis in the reproductive system. In the present study, the roles of the NO donor spermine NONOate and tumour necrosis factor-alpha (TNF; as a positive control) in prostaglandin production and angiogenic activity of equine endometria during the oestrous cycle were evaluated. In addition, the correlation between NO production...
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Antibody reactivity in patients with IgE-mediated wheat allergy to various subunits and fractions of gluten and non-gluten proteins from ω-gliadin-free wheat genotypes
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Profile and Content of Phenolic Compounds in Leaves, Flowers, Roots, and Stalks of Sanguisorba officinalis L. Determined with the LC-DAD-ESI-QTOF-MS/MS Analysis and Their In Vitro Antioxidant, Antidiabetic, Antiproliferative Potency
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Efficient optimization approaches for microwave assisted extraction of high-quality antioxidant compounds from Salvia officinalis L.: UHPLC-HRMS differential analysis of phenolic profiles obtained by ultrasound and microwave extraction
PublicationThe study aims to optimize MAE of total phenolic compounds (TPC) and antioxidant capacity from Salvia officinalis L. leaves using a definitive screening design (DSD) and I-optimal design. UHPLC-HRMS analysis was used to identify and compare the composition of MAE and UAE optimal extracts. The results showed that DSD and I-optimal design were successfully applied for the optimization of MAE targeting phenolics and other antioxidants...
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First-Phase Left Ventricular Ejection Fraction as an Early Sign of Left Ventricular Dysfunction in Patients with Stable Coronary Artery Disease
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A new method and equipment for the detection of presence and estimation of the content of the petroleum-based fraction in lubricating oils, especially those emitted to the atmosphere
PublicationLubricating oil, used in cutting equipment, works in the so-called open lubrication system and is entirely emitted to the environment. When such an oil contains even a small portion of the crude oil-derived fraction, which is still very common, the oil is a serious environmental pollution. In addition, the oil mist poses a serious threat to the health of employees. Current legal regulations require users of saws and harvesters...
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Hybrid all-cellulose reinforcement in polypropylene matrix biocomposites for injection moulding - influence of particle geometry and volume fraction on hybrid effect
PublicationThe presented study is focused on evaluation of influence of reinforcement volume fraction and geometry on the occurrence of positive hybrid effect by the hybridisation of man-made cellulose fibres (rayon viscose) with cellulose microparticle fillers applied in polypropylene matrix. Four volume fractions of reinforcement were used at 1:1 combination of short man-made cellulose fibres with cellulose microfillers of different aspect...
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The problems of resistance to scuffing of heavily loaded lubricated friction joints with WC/C-coated parts
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Selected aspects of traction transformer diagnosis based on analysis of power looses in windings and the iron core
PublicationW rozdziale przedstawiono metodę diagnostyki detekcji uszkodzeń wewnętrznych uzwojeń transformatora trakcyjnego oparta na analizie strat mocy rozpraszanej wewnątrz transformatora. Straty mocy są powiekszane o szereg czynników świadczacych o uszkodzeniu transformatora takich jak: zwarcia zwojowe, asymetria uzwojeń, relaksacja naprężeń na stykach połaczeń, uszkodzenie izolacji pomiedzy blachami rdzenia itp. Proponowana metoda dokonuje...
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THE EFFECT OF THE FRICTION OF THE REFUSE INSIDE THE REFUSE COLLECTION VEHICLE BODY ON THE WORKING PARAMETERS OF THE COMPACTION MECHANISM
PublicationMechanizm prasujący pojazdu do usuwania odpadów z pojemników (w skrócie PUOP) spełnia dwie funkcje. W pierwszym etapie zagęszcza zebrane z pojemników odpady, a następnie przemieszcza je w głąb skrzyni zbiorczej. Znajo-mość właściwości mechanicznych odpadów znajdujących się wewnątrz skrzyni może w znaczący sposób wpłynąć na poprawę wydajności pojazdu. Celem ba-dań było zwiększenie wydajności PUOP poprzez opracowanie w oparciu...
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Analysis of friction ridge evidence for trace amounts of paracetamol in various pharmaceutical industries by Raman spectroscopy
PublicationThe detection of potentially harmful substances presents a multifaceted challenge. On one hand, it can directly save lives, on the other, it can significantly aid and enhance police work, thereby increasing the effectiveness of investigations. The research conducted in this study primarily aims to identify paracetamol in fingerprints, considering situations involving direct contact of a person with paracetamol either chronically...
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Analysis of Residual Stresses and Dislocation Density of AA6082 Butt Welds Produced by Friction Sir Welding
PublicationThe Friction Stir Welding (FSW) method was employed to join AA6082 sheets. The welds were produced with different tool traverse speed (200 and 250 mm/min), rotational speed (1000 and 1250 RPM) and tool tilt angle (0 and 2 deg). Based on the analysis of XRD patterns, the total precipitation volume fractions in the nugget zones and the base material were calculated. The FSW process resulted in a reduction in the fraction of precipitates...
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Assessment of Corrosive Behaviour and Microstructure Characterization of Hybrid Friction Stir Welded Martensitic Stainless Steel
PublicationThis study examined the effect of induction heating on the microstructure and corrosion characteristics of hybrid friction stir welded AISI 410 stainless steel. Five joints have been produced with different friction stir welding parameters like welding speed, spindle speed, plunge depth, and induction power. Their microstructures were evaluated using a scanning electron microscope, and chemical composition was examined using...
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Results from tests on bolted connection components for evaluation of friction coefficient in various contact conditions
PublicationThe main purpose of the work was the analysis and evaluation of the self-locking quality of a bolted joint covered with Xylan 1070 coating, with comparison to the classic bolts lubricated with Molykote compound during assembly. The second part of the work was the verification of the compliance of the bolts and nuts used in the installation with the ASME B1.1 norm.
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A TPC Detector for Studying Photo-nuclear Reactions at Astrophysical Energies with Gamma-ray Beams at ELI--NP
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Catalytic activity and anion activation in SN2 reactions promoted by complexes of silicon polypodands. Comparison with traditional polyethers
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IL-33 and IL-4 impair barrier functions of human vascular endothelium via different mechanisms
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Medium-sized cyclic bis(anisylphosphonothioyl)- disulfanes and their corresponding cyclic sulfane-structures and most characteristic reactions
PublicationCyclic 8-, 9-, 10-, and 12-membered bis(anisylphosphonothioyl)disulfanes were synthesized. Next, structurally related 7 to 9-membered cis and trans sulfanes were isolated as a result of sulfur atom extrusion from the parent cyclic disulfanes. The results of the desulfurization of the disulfanes were compared to the results obtained for desulfurization of the respective bis(anisylphosphodithioates). Cyclic disulfanes predominantly...
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Advancement of Non-Newtonian Fluid with Hybrid Nanoparticles in a Convective Channel and Prabhakar’s Fractional Derivative—Analytical Solution
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Reactions of the Lithiated DiphosphinetBu2P-P(SiMe3)Li with [(η6-C6H6)RuCl2]2in the Presence of Tertiary Phosphines
PublicationtBu2P–P(SiMe3)Li reacted with [(η6-C6H6)RuCl2]2at–40 °C in the presence of PR3(PR3=PEt3,PEt2Ph, PEtPh2) by the nucleophilic addition of the tBu2P–P(SiMe3) moiety to the benzene ring to yield solely the complexes [(R3P)2Ru(Cl)-{η5-C6H6(Me3SiP–PtBu2)}] (1). These products decomposed slowly at ambient temperature to yield benzene, Ru clusters, and small amounts of the dinuclear ruthenium complexes [{(R3P)2Ru}2(μ,η2:2-P2)2Ru(PR3)2](Ru–Ru)(6)....
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Application of the Fractional Fourier Transform for dispersion compensation in signals from a fiber-based Fabry-Perot interferometer
PublicationOptical methods of measurement do not require contact of a probe and the object under study, and thus have found use in a broad range of applications such as nondestructive testing (NDT), where noninvasive measurement is crucial. Measuring the refractive index of a material can give a valuable insight into its composition. Low‑coherence radiation sources enable measurement of the sample’s properties across a wide spectrum, while...
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Successive Iterative Method for Higher-Order Fractional Differential Equations Involving Stieltjes Integral Boundary Conditions
PublicationIn this paper, the existence of positive solutions to fractional differential equations with delayed arguments and Stieltjes integral boundary conditions is discussed. The convergence of successive iterative method of solving such problems is investigated. This allows us to improve some recent works. Some numerical examples illustrate the results.
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Spectroscopic studies of a ring opening process between epoxy- and aminosilanes and imine formation reactions in aqueous solutions
PublicationNMR and Raman spectroscopy studies were performed for different 3-aminopropyl(trimethoxy)- and 3-glycidoxypropyl (trimethoxy)silane based sol-gel systems containing different ketones. Exceptionally stable imine products were obtained depending on a reaction system at alkaline pH conditions and in the presence of water. These imine formation reactions were carried out without further catalyst. In addition, effect of water for the...