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Search results for: copper selenide
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Optimizing the Copper Content in GdBa0.5Sr0.5Co2-XCuxO5+δ Double Perovskites as the High Performance Oxygen Electrodes for Reversible Solid Oxide Cells
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Interactive assessment of lignite and bamboo-biochar for geochemical speciation, modulation and uptake of Cu and other heavy metals in the copper mine tailing
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Dynamic electrochemical impedance spectroscopy and polarization studies to evaluate the inhibition effect of benzotriazole on copper-manganese-aluminium alloy in artificial seawater
PublicationPrzeprowadzono badania wpływu benzotriazolu (BTA) na korozję nowego typ mosiądzu (CMA) w środowisku syntetycznej wody morskiej przy użyciu dynamicznej elektrochemicznej spektroskopii impedancyjnej (DEIS), techniki polaryzacji rezystancyjnej i ekstrapolacji krzywych Tafela. Wyniki pomiarowe otrzymane przy użyciu tych metod wskazują spadek szybkości korozji wraz ze wzrostem stężenia BTA. Wskazuje to na inhibicyjne własności BTA w...
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Molecularly imprinted stir bar sorptive extraction coupled with atomic absorption spectrometry for trace analysis of copper in drinking water samples
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Copper(II) complexes with substituted imidazole and chlorido ligands: X-ray, UV-Vis, magnetic and EPR studies and chemotherapeutic potential
PublicationCrystal structures, UV-Vis and EPR spectra and magnetic properties of four copper(II) complexes with chloride anions and 4-methylimidazole, 2-ethylimidazole, 2-isopropylimidazole or 2-ethyl-4-methylimidazole are described. In the solid state three of the complexes are mononuclear and one complex with 2-ethylimidazole is binuclear with bridging chlorido ions. UV-Vis spectra of the methanolic solutions of the complexes show LMCT...
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Operational loads of diesel engines on trailing suction hopper dredgers in their main service states
PublicationArtykuł przedstawia wyniki badań eksploatacyjnych ośmiu pogłębiarek ssących nasiębiernych. Badania eksploatacyjne obejmowały pomiary parametrów charakteryzujących warunki pracy dwóch podstawowych elementów układów energetycznych pogłębiarek: silników głównych i pomocniczych.
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Analysis of possibility and purposefulness of application of waste-heat boilers to trailing suction hopper dredgers
PublicationThis paper presents an analysis of possibility and purposefulness of application of waste-heat boilers to trailing suction hopper dredgers. Using results of own operational research on dredgers this author determined thermal power demand for six hypothetical trailing suction hopper dredgers of various size, at accounting for a type of power system and kind of fuel combusted by dredger's power plant. By means of basic indices of...
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Doppler estimation method for moving target location
PublicationArtykuł opisuje nowy algorytm lokalizacji obiektów ruchomych bazujących na analizie odchyłek dopplerowskich sygnałów odebranych z sieci hydrofonów rozmieszczonych równomiernie w obserwowanym akwenie. Źródłem analizowanych sygnałów są fale ciągłe o niskim natężeniu odbite od obiektu ruchomego. W artykule została przedstawiona postać algorytmu oraz wyniki symulacji komputerowych.
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Doubly miniaturized rat-race hybrid coupler
PublicationTwo complementary miniaturization techniques have beenapplied to reduce the size of a rat-race hybrid coupler: (i) conventional microstrip sections have been replaced with their diminished lowimpedance counterparts as the first step of size reduction and (ii) novel fractal-shaped compact microstrip resonant cells dedicated to efficiently shorten low-impedance transmission line segments have been implemented as the second step of...
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Secure Quaternion Feistel Cipher for DICOM Images
PublicationAn improved and extended version of a quaternion-based lossless encryption technique for digital image and communication on medicine (DICOM) images is proposed. We highlight and address several security flaws present in the previous version of the algorithm originally proposed by Dzwonkowski et al. (2015). The newly proposed secure quater- nion Feistel cipher (S-QFC) algorithm...
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A 3-dB coupler with UC-PBG structure
PublicationPrzedstawiono nową konstrukcję sprzęgacza z liniami paskowymi sprzężonymi szerokim bokiem oraz zmodyfikowaną warstwą metalizacji masy. Modyfikacja metalizacji polega na periodycznym wytrawieniu dwuwymiarowej struktury szczelin, nazywanej strukturą uniplanarnej zwartej przerwy fotonicznej (UC-PBG: Uniplanar Compact Photonic BandGap). Potwierdzono przewidywane wcześniej zjawisko spowolnienia fali oraz powiększenia wielkości sprzężenia...
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The SEM micrographs of the cavitation erosion-corrosion process of selected copper alloys degradation
Open Research DataThe dataset contains Scanning Electron Micrographs of CuZn40Mn3Fe brass compared with Superston and Novoston bronze after cavitation erosion-corrosion exposure using a vibratory transducer (in accordance with ASTM G32). The micrographs compare the topography of samples subjected cavitation erosion in 3% NaCl at room temperature, leading to the surface...
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Electrochemical, theoretical and surface physicochemical studies of the alkaline copper corrosion inhibition by newly synthesized molecular complexes of benzenediamine and tetraamine with π acceptor
PublicationTwo charge transfer complexes, namely [(BDAH)+(PA−)] CT1 [(BTAH)2+(PA−)2] and CT2 (BDAH = 1,2-benzenediamine, BTAH = 1,2,4,5-benzenetetramine, and PA− = 2,4,6-trinitrophenolate), were synthesized and fully characterized using various spectroscopic techniques. CT1 and CT2 were tested as inhibitors to effectively control the uniform and anodic corrosion processes of copper in an alkaline electrolyte (1.0 M KOH) using various electrochemical...
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Potential of nanocomposites of zero valent copper and magnetite with Eleocharis dulcis biochar for packed column and batch scale removal of Congo red dye
PublicationThe current study is the first attempt to prepare nanocomposites of Eleocharis dulcis biochar (EDB) with nano zero-valent Copper (nZVCu/EDB) and magnetite nanoparticles (MNPs/EDB) for batch and column scale sequestration of Congo Red dye (CR) from synthetic and natural water. The adsorbents were characterized with advanced analytical techniques. The impact of EDB, MNPs/EDB and nZVCu/EDB dosage (1–4 g/L), pH (4–10), initial concentration...
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Contrasting effects of biochar and hydrothermally treated coal gangue on leachability, bioavailability, speciation and accumulation of heavy metals by rapeseed in copper mine tailings
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In Situ Micro-Observation of Surface Roughness and Fracture Mechanism in Metal Microforming of Thin Copper Sheets with Newly Developed Compact Testing Apparatus
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Kinetics and thermodynamics of the reaction of iminodiacetate copper(II) complexes with 1,10-phenanthroline and 2,2′-bipyridine in aqueous, anionic, cationic and nonionic surfactants solutions
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Some Aspects of Measuring Nonlinear Optical Features of Advanced Vertically Aligned Mesoporous Silica Thin Films Activated by Silver and Copper Ions
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Estimation of the Chelating Ability of an Extract from Aronia melanocarpa L. Berries and Its Main Polyphenolic Ingredients Towards Ions of Zinc and Copper
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ANTHROPOGENIC CHANGES OF THE “OLD COPPER BASIN” AREA LANDSCAPE (NORTH-SUDETIC SYNCLINORIUM) IN THE LIGHT OF LIDAR-BASED GEOMORPHOMETRIC ANALYSIS AND ARCHIVAL DATA
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Magnetic Molecularly Imprinted Polymer Nanoparticles for Selective Extraction of Copper from Aqueous Solutions Prior to Its Flame Atomic Absorption Determination
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Magnetic molecularly imprinted polymer nanoparticles for selective extraction of copper from aqueous solutions prior to its flame atomic absorption determination
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Structure and performance properties of environmentally-friendly biocomposites based on poly(ɛ-caprolactone) modified with copper slag and shale drill cuttings wastes
PublicationThe potential application of two types of industrial wastes, drill cuttings (DC) and copper slag (CS), as silica-rich modifiers of poly(ɛ-caprolactone) (PCL) was investigated. Chemical structure and physical properties of DC and CS fillers were characterized using X-ray diffractometer, X-ray fluorescence spectroscopy, particle size and density measurements. PCL/DC and PCL/CS composites with a variable content of filler (5 to 50...
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Copper(II) Complexes with 1-(Isoquinolin-3-yl)heteroalkyl-2-ones: Synthesis, Structure and Evaluation of Anticancer, Antimicrobial and Antioxidant Potential
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EKSPERTYZA TECHNICZNA WOZÓW WYCIĄGOWYCH NA POCHYLNIACH KANAŁU ELBLĄSKIEGO – DLA POCHYLNI BUCZYNIEC I JELENIE
PublicationGłównym celem wykonanej ekspertyzy było wykonanie oceny stanu technicznego wozów wyciągowych znajdujących się na pochylniach Buczyniec i Jelenie, wraz ze wskazaniem przyczyn ich nieprawidłowego funkcjonowania oraz sformułowaniem zaleceń dotyczących dalszej eksploatacji. W ramach wykonanej ekspertyzy przeanalizowano istniejącą dokumentację techniczną i formalną oraz wykonano trzy wizje lokalne na pochylni Buczyniec i dwie wizje...
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Educational Dataset of Handheld Doppler Blood Flow Recordings
PublicationVital signals registration plays a significant role in biomedical engineering and education process. Well acquired data allow future engineers to observe certain physical phenomena as well learn how to correctly process and interpret the data. This dataset was designed for students to learn about Doppler phenomena and to demonstrate correctly and incorrectly acquired signals as well as the basic methods of signal processing. This...
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Magnetization enhancement in magnetite nanoparticles capped with alginic acid
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A quaternion-based modified feistel cipher for multimedia transmission
PublicationIn this paper a quaternion-based modified Feistel Cipher is proposed. The algorithm is based on the scheme proposed by Sastry and Kumar (2012). Our algorithm uses special properties of quaternions to perform rotations of data sequences in 3D space for each of the cipher rounds. The plaintext (image in gray-tone) is divided into two square matrices of equal size which consist of Lipschitz quaternions. A modular arithmetic was implemented...
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The upper critical field in doped MgCNi3
PublicationDyskutowany jest wpływ domieszkowania MgCNi3 na górne pole krytyczne (H_c2). H_c2 monotonicznie maleje wraz ze wzrostem koncentracji domieszki. Silniejszy wpływ widoczny w przypadku domieszkowania Fe może być tłumaczony poprzez efekt rozrywania nadprzewodzących par Coopera poprzez centra magnetyczne tworzone przez domieszki Fe.
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Thermal Energy Development in Magnetohydrodynamic Flow Utilizing Titanium Dioxide, Copper Oxide and Aluminum Oxide Nanoparticles: Thermal Dispersion and Heat Generating Formularization
PublicationThe main aim of this article heat transfer in thermal engineering deals with the production, use, transformation, and transfer of thermal energy. Engineering and industrial fields including food packaging, the production of food additives, electronic cooling, microturbines, etc. heavily rely on heat transmission. Due to its intriguing potential in industries like the production of polymers, paper, crystal glass, etc., scientists...
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Impact of High Pressure on Metallophilic Interactions and Its Consequences for Spectroscopic Properties of a Model Tetranuclear Silver(I)–Copper(I) Complex in the Solid State
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Synthesis and Structure of Novel Copper(II) Complexes with N,O- or N,N-Donors as Radical Scavengers and a Functional Model of the Active Sites in Metalloenzymes
PublicationToevaluatetheantioxidantactivityofpotentialsyntheticenzymemimetics,wepreparednewfivecopper(II)complexesviaaself‐assemblymethodandnamedthem[Cu(2‐(HOCH2)py)3](ClO4)2(1),[Cu(2‐(HOCH2)py)2(H2O)2]SiF6(2),[Cu2(2‐(HOCH2CH2)py)2(2‐(OCH2CH2)py)2](ClO4)2(3),[Cu(pyBIm)3](BF4)2∙1.5H2O(4)and[Cu(py2C(OH)2)2](ClO4)2(5).ThesyntheticprotocolinvolvedN,O‐ orN,N‐donors:2‐(hydroxymethyl)pyridine(2‐(HOCH2)py),2‐(hydroxyethyl)pyridine(2‐(HOCH2CH2)py),2‐(2‐pyridyl)benzimidazole(pyBIm),di(2‐pyridyl)ke‐tone(py2CO).TheobtainedCu(II)complexeswerefullycharacterisedbyelementalanalysis,FTIR,EPR,UV‐Vis,single‐crystalX‐raydiffractionandHirshfeldsurfaceanalysis.Crystallographicandspectroscopicanalysesconfirmedchromophoresofbothmonomeric({CuN3O3}(1),{CuN2O4}(2),{CuN6}(4),{CuN4O2}(5))anddimericcomplex({CuN2O3}(3)).Mostoftheobtainedspeciespos‐sessedadistortedoctahedralenvironment,exceptdimer3,whichconsistedoftwocoppercentreswithsquarepyramidalgeometries.Thewater‐solublecompounds(1,3and5)wereselectedforbiologicaltesting.Theresultsofthestudyrevealedthatcomplex1insolutionsdisplayedbetterradicalscavengingactivitythancomplexes3,5andfreeligands.Therefore,complex1hasbeenselectedforfurtherstudiestotestitsactivityasanenzymemimetic.Thechosencompoundwastestedontheerythrocytelysateoftwogroupsofpatientsafterundergoingchemotherapyandchemoradiotherapy.Theeffectofthetestedcompound(1)onenzymeactivitylevels(TAS,SODandCAT)suggeststhattheselectedcomplexcanbetreatedasafunctionalmimeticoftheenzymes.
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Coordination polymers based on octacyanometalates(iv,v) (M = Mo, W) and aliphatic polyamine copper(ii) tectons with [N3] donor atom sets
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Relationship between copper(ii) complexes with FomA adhesin fragments ofF. nucleatumand colorectal cancer. Coordination pattern and ability to promote ROS production
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Combustion characteristics and retention-emission of selenium during co-firing of torrefied biomass and its blends with high ash coal
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Gamma rays-assisted bacterial synthesis of bimetallic silver-selenium nanoparticles: powerful antimicrobial, antibiofilm, antioxidant, and photocatalytic activities
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Solid-state fermentation for enhanced production of selenium nanoparticles by gamma-irradiated Monascus purpureus and their biological evaluation and photocatalytic activities
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Self-organizing maps classification of epidemiological data and toenail selenium content monitored on cancer and healthy patients from Poland
PublicationW pracy przedstawiono wyniki wielowymiarowej analizy danych pomiarowych (przy wykorzystaniu techniki samoorganizującej sie mapy (SOM))nad oszacowaniem zawartości selenu w próbkach paznokci pobranych od mieszkańców Województwa Pomorskiego ((w tym od grupy osób zdrowych i ze zdiagnozowaną chorobą nowotworową) i Lubuskiego. W wyniku przeprowadzonej analizy uzyskano podział uczestników ze zdiagnozowanym nowotworem na trzy różne grupy:1...
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Ratio of selenium concentrations between soil, forage plants and blood serum of beef cattle studied in organic and conventional farms
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The accessibility, necessity, and significance of certified reference materials for total selenium content and its species to improve food laboratories' performance
PublicationMicronutrients are one of the most important groups of nutrients that our body needs daily in trace amounts to tackle deficiencies. Selenium (Se) is a mineral that occurs naturally in foods and is an essential component of selenoproteins that support the healthy functioning of the human body. Therefore, monitoring dietary Se concentrations must be a higher priority to meet daily intakes. Fulfillment can be addressed through applying...
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Atomic force microscopy images of copper electrical contacts wear under the influence of friction
Open Research DataMeasurement of wear of copper electrical contacts under the influence of friction. Imaging in contact mode in the variant of scanning spreading resistance microscopy. Additionally, there are spectroscopic current-voltage curves showing local changes in electrical conductivity. NTEGRA Prima (NT-MDT) device. Probe NSG 01Pt.
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The comparison of the removal of copper(II) and zinc(II) ions from aqueous solution using 2,6-diaminopyridine in a polymer inclusion membrane and in a classic solvent extraction
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Aiding (opponent) flow of hybrid copper–aluminum oxide nanofluid towards an exponentially extending (lessening) sheet with thermal radiation and heat source (sink) impact
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Copper(II) coordination properties of GxG peptides: Key role of side chains of central residues on coordination of formed systems; combined potentiometric and ITC studies
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Evidence for widespread occurrence of copper in Late Neolithic Poland? A deposit of Funnel Beaker Culture bone products at site 2 in Osłonki (Kuyavia, central Poland)
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Effect of copper and silver modification of NH2-MIL-125(Ti) on the photoreduction of carbon dioxide to formic acid over this framework under visible-light irradiation
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Effect of copper and silver modification of NH2-MIL-125(Ti) on the photoreduction of carbon dioxide to formic acid over this framework under visible-light irradiation
PublicationCu and Ag enhance the photocatalytic activities of metal–organic frameworks (MOFs) toward CO2 conversion because of their CO2 adsorption capacities and effects on the lowest unoccupied molecular orbital (LUMO) overpotentials of MOFs. However, to date, targeted introduction of metals into MOFs to achieve visible (Vis)- light-active photocatalysts for CO2 photoconversion has not been realized. Herein, a series of aminefunctionalized...
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Biogeochemia selenu i jego monitoring w materiałach biologicznych pochodzenia ludzkiego = Selenium biochemistry and its monitoring in biological samples
PublicationNa przestrzeni ostatnich kilkudziesięciu lat selen stał się przedmiotem intensywnych badań naukowych w wielu dyscyplinach nauki. Najczęściej poruszanymi zagadnieniami są aspekty związane z biochemią, geologią, toksykologią, wykorzystaniem przemysłowym selenu oraz jego wpływem na organizmy żywe. Powodem szczególnego zainteresowania tym pierwiastkiem jest niewielka różnica pomiędzy jego poziomem niezbędnym a toksycznym oraz szereg...
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Influence of selenium and/or magnesium on alleviation alcohol induced oxidative stress in rats, normalization function of liver and changes in serum lipid parameters
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Determination of selenium by X-ray fluorescence spectrometry using dispersive solid-phase microextraction with multiwalled carbon nanotubes as solid sorbent
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