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Wyniki wyszukiwania dla: METAL CATION COMPLEXATION
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A Systematic and Comparative Study of Binary Metal Catalysts for Carbon Nanotube Fabrication Using CVD and Laser Evaporation
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Effect of time on the metal-support (Fe-MgO) interaction in CVD synthesis of single-walled carbon nanotubes
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Graphene hydrogels with embedded metal nanopatricles as efficient catalysts in 4-nitrophenol reduction and methylene blue decolorization
PublikacjaSynthesis and characterization of the graphene hydrogels with three different metallic nanoparticles, that is Au, Ag and Cu, respectively is presented. Synthesized in a one-pot approach graphene hydrogels with embedded metallic nanoparticles were tested as heterogeneous catalysts in a model reaction of 4-nitrophenol reduction. The highest activity was obtained for graphene hydrogel with Cu NPs and additional reaction of methylene...
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Investigations of local/global buckling of cylindrical metal silos with corrugated sheets and open-sectional column profiles
PublikacjaArtykuł zajmuje się problemem lokalnego/globalnego wyboczenia w cylindrycznych metalowych silosach z blachy falistej z otwartymi cienkościennymi profilami słupowymi. Obliczenia wykonano w ramach liniowej teorii bifurkacji stosując metodę elementów skończonych w programie ABAQUS. Zbadano obszernie wpływ różnych parametrów (średnica i wysokość silosów, grubość blachy falistej, wielkość fali blachy, rozstaw słupów, przekrój słupów)...
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New nanoadsorbent based on magnetic iron oxide containing 1,4,7,10-tetraazacyclododecane in outer chain (Fe3O4@SiO2-cyclen) for adsorption and removal of selected heavy metal ions Cd2+, Pb2+, Cu2+
PublikacjaMagnetic Fe3O4@SiO2-cyclen nanoparticles were prepared and used as adsorbent for Cd2+, Pb2+ and Cu2+ from aqueous solution removal process controlled with differential pulse anodic stripping voltammetry (DPASV) and hanging mercury drop electrode (HDME). Nanomaterial was synthesised in three-step process co-precipitation of Fe3O4 core, coating with silane and N-(3-(triethoxysilyl)propyl)-1,4,7,10-tetraazacyclododecane-1-carboxamide...
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Protective Effect of Aronia Melanocarpa Polyphenols on Cadmium Accumulation in the Body: A Study in a Rat Model of Human Exposure to this Metal
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Correlational nutritional relationships and interactions between expansive holoparasite Orobanche laxissima and woody hosts on metal-rich soils
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Study of the selection mechanism of heavy metal (Pb 2+, Cu 2+, Ni 2+ and Cd2+) adsorption on clinoptilite
PublikacjaBadano proces adsorpcji jonów metali ciężkich (w warunkach statycznych) z wodnych roztworów jednoskładnikowych i wieloskładnikowych na klinoptylolicie zarówno surowym jak i po wstępnej obróbce. Proces sorpcji ma charakter procesu jonowymiennego i składa sie z trzech etapów:- adsorpcji na powierzchni mikokryształów,- inwersji,- adsorpcji wewnątrz mikrokryształów.Proces sorpcji może być dobrze opisany zarówno za pomocą modelu Frendlicha...
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O-substituted tetrahydroxamate derivatives of p-tert-butylcalix[4]arene as receptors for transition and heavy metal cations
PublikacjaTetrasubstituted O-hydroxamate derivatives of p-tert-butylcalix[4]arene were applied as active materials in ion-selective membrane electrodes and were tested towards Pb-selectivity. The electrodes gave near-Nernstian characteristics for Pb2+ cations. The selectivity coefficients were determined. The influence of plasticizer on the electrode behaviour was studied. The dependence of the chemical structure on selectivity coefficients...
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Influence of vacuum sublimation deposited metal layer thickness on metrological parameters of the amperometric gas sensor with Nafion membrane
PublikacjaThe paper presents the results of investigation on an influence of vacuum sublimation deposited platinum layer thickness on the signal, sensitivity and response time of a prototype of sulphur dioxide sensor with Nafion membrane. The working electrode was made by vacuum sublimation deposition of platinum on a surface of Nafion membrane. Pt layers deposited changed an initial structure of Nafion membrane and that phenomenon was utilized...
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Application of 3D digital image correlation for development and validation of FEM model of self-supporting metal plates structures
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Correlation between destruction of the metal surface caused by pitting corrosion and intensity of the observed electrochemical noise (Invited Paper)
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Volumes of N,N-dimethylacetamide solvated metal cations. Variation within the manganese(II) to zinc(II) series
PublikacjaDensities and apparent molar volumes for Mn(ClO4)2,Co(ClO4)2 , Ni(ClO4)2,Cu(ClO4)2 , and Zn(ClO4)2 in N, N -dimethylacetamide (DMA) solutions at T = 298.15 K are reported. Densities and apparent molar volumes of tetrabutylammonium tetraphenylborate...
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Solvation of alkaline earth metal ions in N,N-dimethylformamide and N,N-dimethylacetamide – A volumetric and acoustic study
PublikacjaDensities and sound velocities at temperatures (298.15, 303.15, 308.15, 313.15 and 318.15) K of magnesium(II), calcium(II) and strontium(II) rifluoromethanesulfonates (triflates), as well as barium(II) perchloratein N,N-dimethylformamide (dmf) and N,N-dimethylacetamide (dma) have been measured over the composition range studied. From these results, apparent molar volumes and apparent molar isentropic compressibilities at infinite...
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Nitrogen‐Doped Porous Graphene‐Based Aerogels toward Efficient Heavy Metal Ion Adsorption and Supercapacitor Applications
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The importance of evaluating metal exposure and predicting human health risks in urban–periurban environments influenced by emerging industry
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Broad-Range Spectral Analysis for Chiral Metal Coordination Compounds: (Chiro)optical Superspectrum of Cobalt(II) Complexes
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Estimation, optimization and analysis based investigation of the energy consumption in machinability of ceramic-based metal matrix composite materials
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Study on the effect of the metal–support (Fe-MgO and Pt-MgO) interaction in alcohol-CVD synthesis of carbon nanotubes
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A pilot study to assess an in-process inspection method for small diameter holes produced by Direct Metal Laser Sintering
PublikacjaPurpose The purpose of this research is to evaluate the geometric quality of small diameter holes in parts printed by DMLS technology. An in-process optical inspection method is proposed and assessed during a pilot study. The influence of the theoretical hole diameter assumed in a CAD system and the sample thickness (hole length) on the hole clearance was analysed. Design/methodology/approach The samples made of two different...
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Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions
PublikacjaA template synthesis using 2-acetyl-1,3-indandione and ethylenediamine results in formation of octahedral Ni complex, whose crystal structure has been resolved using single crystal X-ray diffraction. The structure indicates that only exocyclic enolic oxygen atom of the triketone takes part in the condensation with ethylenediamine.
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The effects of urban vehicle traffic on heavy metal contamination in road sweeping waste and bottom sediments of retention tanks
PublikacjaDiffuse pollution formed during a surface runoff on paved surfaces is a source of heavy metals (HMs) of various origin. This research study indicates the connection between bottom sediments of retention tanks located on urban streams and road sweeping wastes (RSW) that migrate during surface runoff to the stormwater drainage systems with discharge to the retention tanks. Moreover, we test the primary sources of HMs in RSW by analysing...
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Anion–cation interactions in a series of salts with substituted Hphen, Hbpy and H2bpy cations and [W(CN)8]4− anion: polymer with “super-short” N–H⋯N hydrogen bridges containing exclusively anions and H+
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The reactivity of 1,1-dichloro-2,2-di-tert-butyldiphosphane towards lithiated metal carbonyls: a new entry to phosphanylphosphinidene dimers
PublikacjaReactions of [Cp*(OC)3M]Li (Cp* = C5Me5, M = Mo, W) towards t-Bu2P–PCl2 lead to the formation of phosphanylphosphinidene dimers [Cp*(OC)3M(η2-t-Bu2P–P)]2 in fairly good yields. The formation of a tetraphosphorus ligand proceeds via reductive dimerization of t-Bu2P–P units. NMR, X-ray investigations and DFT calculations show that the resulting tetraphosphorus ligand has a structure of dication t-Bu2P+=P–P=P+t-Bu2.
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Microstructure and nanomechanical properties of single stalks from diatom Didymosphenia geminata and their change due to adsorption of selected metal ions
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Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor
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Geochemical fractionation and spectroscopic fingerprinting for evaluation of the environmental transformation of potentially toxic metal(oid)s in surface–subsurface soils
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Operational control on environmental safety of potentially toxic elements during thermal conversion of metal-accumulator invasive ragweed to biochar
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The river water influence on cationic and anionic dyes collection by nickel foam with carbonized metal-organic frameworks and carbon nanotubes
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Metodologia badania zaworów hamulcowych
PublikacjaArtykuł opisuje metodologię statycznego i dynamicznego badania zaworów hamulcowych. Stanowisko badawcze zaprojektowano i zbudowano na Politechnice Gdańskiej jako część projektu badawczo-rozwojowego pt.: „Zaprojektowanie i zbadanie innowacyjnych podsystemów ładowarek kołowych firmy Hydro-Metal”, dofinansowanego przez PARP w ramach programu „Bon na innowacje”. Ponadto przedstawiono szczegóły konstrukcyjne i funkcje najczęściej spotykanych zaworów...
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Toxic metal pollution of aquatic ecosystems of European Union nature protection areas in a region of intensive agriculture (Lake Gopło, Poland)
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Optimization of a procedure for the simultaneous extraction of polycyclic aromatic hydrocarbons and metal ions by functionalized and non-functionalized carbon nanotubes as effective sorbents
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Estimating the pollution characteristics and health risks of potentially toxic metal(loid)s in urban-industrial soils in the Indus basin, Pakistan
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Characterizing pollution indices and children health risk assessment of potentially toxic metal(oid)s in school dust of Lahore, Pakistan
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Achiral and Chiral Transition Metal Complexes with Modularly Designed Tridentate PNP Pincer-Type Ligands Based on N-Heterocyclic Diamines
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Deformation of thin metal and composite sheets by using anti-buckling fixture for large deformation under tension–compression cyclic loading
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Interaction of Ionomers and Polyelectrolytes with Divalent Transition Metal Cations (Cu2+ and VO2+): A Study by Electron Spin Resonance (ESR) Spectroscopy and Viscosimetry
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Nonlinear harmonic amplitudes in air coils above and below a metal plate as a function of tensile strength via finite element simulation.
PublikacjaOpisano wyniki obliczeń numerycznych (symulacja metodą MES) wpływu naprężeń na amplitudy nieliniowych harmonicznych napięcia indukowanego w cewkach powietrznych umieszczonych nad i pod płytą.
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Thermodynamic properties of inorganic salts in nonaqueous solvents. II. Apparent molar volumes and compressibilities of divalent transition-metal perchlorates in acetonitrile
PublikacjaW oparciu w wyniki pomiarów gęstości wykonanych w temperaturze 15,20,25,30,35,40 i 50 stopni Celsjusza oraz pomiaru szybkości dżwięku w temperaturze 25 stopni Celsjusza, wyznaczono pozorne objętości molowe oraz ściśliwości adiabatyczne roztworów nadchloranów manganu(II), kobaltu(II), niklu(II) i cynku(II). Obliczono odpowiednie wartości standardowe oraz rozszerzalności izobaryczne. Przeanalizowano związki między strukurą elektronową...
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Study on the flammability, thermal stability and diffusivity of polyethylene nanocomposites containing few layered tungsten disulfide (WS2) functionalized with metal oxides
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Thermally induced formation of zinc oxide nanostructures with tailoring morphology during metal organic framework (MOF-5) carbonization process
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Bioactive hybrid metal-organic framework (MOF)-based nanosensors for optical detection of recombinant SARS-CoV-2 spike antigen
PublikacjaFast, efficient, and accurate detection of SARS-CoV-2 spike antigen is pivotal to control the spread and reduce themortality of COVID-19. Nevertheless, the sensitivity of available nanobiosensors to detect recombinant SARS-CoV-2 spike antigen seems insufficient. As a proof-of-concept, MOF-5/CoNi2S4 is developed as a low-cost, safe, and bioactive hybrid nanostructure via the one-pot high-gravity protocol. Then, the porphyrin, H2TMP,...
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Hydrothermal modification of TiO2 nanotubes in water and alkali metal electrolytes (LiNO3, NaNO3, KNO3) – Direct evidence for photocatalytic activity enhancement
PublikacjaThe influence of hydrothermal annealing (HA) of TiO2 nanotubes (TiO2-NTs) in various baths (H2O, LiNO3, NaNO3, KNO3 performed for 4 h, 24 h, 64 h), on their photocatalytic and photoelectrocatalytic properties, was studied. The use of electrolytes was to enable the monitoring of photoactivity changes as a result of the expected impact on the population of hydroxyl groups on the surface. The assumption turned out to be correct and...
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The chemistry of river–lake systems in the context of permafrost occurrence (Mongolia, Valley of the Lakes). Part I. Analysis of ion and trace metal concentrations
PublikacjaThis study provides a description of water chemistry in river–lake systems located in central Mongolia, at the borderline of permafrost occurrence. The analysis involved water samples collected from two river–lake systems: Baydrag River–Böön Tsagaan Lake system, and Shargalyuut/Tuyn Rivers–Orog Lake system. In the water samples, ions and trace elements were detected and quantified. Additionally, the parameters of pH, electrical...
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Biomimetic Metal- and Ammonium-Thiolate Systems: The First Crystalline Imidazolium Thiolate and Cadmium Silanethiolate Complexes with Imidazole and Imidazole-Derived Co-ligands
PublikacjaPrzeprowadzono analizę strukturalną i opisano badania spektroskopowe biomimetycznych tiolanów kadmu oraz tiolanów imidazoliowych.
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Anthropogenic enrichment of the chemical composition of bottom sediments of water bodies in the neighborhood of a non-ferrous metal smelter (Silesian Upland, Southern Poland)
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Determination of nicotine in saliva, urine and wastewater samples using tantalum metal organic framework pipette tip micro-solid phase extraction
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Synthesis of thiol derivatives of azobenzocrown ethers. The preliminary studies on recognition of alkali metal ions by gold nanoparticles functionalized with azobenzocrown and lipoic acid
PublikacjaThe article presents the synthesis of novel 13- and 16-membered azobenzocrown derivatives with peripheral thiol moieties and preliminary studies assessing their possible application in plasmonic sensors based on gold nanoparticles. The effect of the length of the chain connecting the macrocycle with the thiol group and the effect of the presence of the additional functional compound,...
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Multi-step functionalization procedure for fabrication of vertically aligned mesoporous silica thin films with metal-containing molecules localized at the pores bottom
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Thermodynamic properties of inorganic salt in nonaqeous solvents. IV. Apparent molar volumes and compressibilities of divalent transition-metal bromides and chlorides in acetonitrile
PublikacjaWykonano pomiary gęstości roztworów chlorków i bromków w acetonitrylu w temperaturze 288.15, 293.15, 298.15, 303.15, 308.15, 313.15 K oraz pomiar szybkości rozchodzenia się dźwięku w badanych roztworach w temperaturze 298.15 K. Uzyskane wartości pozwoliły wyznaczyć pozorne objętości molowe oraz pozorne adiabatyczne ściśliwości, których wartości oraz zmiany ze stężeniem tłumaczone są obecnością złożonych układów komplesów w roztworze.