Wyniki wyszukiwania dla: multiblock thermoplastic elastomers
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Real-time monitoring of volatiles and particles emitted from thermoplastic filaments during 3D printing
PublikacjaThe proliferation of consumer-grade three-dimensional (3D) printers using fused deposition, also known as fused filament fabrication, has given rise to concerns over the exposure of users to potentially harmful substances. Thermoplastic filaments made of different polymers are extruded through a heated printer nozzle and deposited layer by layer on a build platform to form the printed object. This process leads to the emission...
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A nanostructured carbon-reinforced polyisobutylene-based thermoplastic elastomer
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Pilot study of the influence of thermoplastic starch based polymer packaging material on the growth of diatom population in sea water environment
PublikacjaNovel polymeric packaging materials susceptible to environmentally friendly decomposition appeared on the global market. The paper is devoted to an investigation of the impact of degradable polymer packaging on marine life. The chosen polymer was a commercial packaging based on thermoplastic starch (TPS over 85%). The microorganism chosen was Phaeodactylum tricornutum diatom (identified in many aquatic reservoirs, with a tendency...
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Characteristic of elastomers from the rubber mixtures (NR) containing devulcanizate compounds
PublikacjaW pracy omówiono wyniki badań elastomerów otrzymanych w procesie wulkanizacji mieszanek kauczukowych napełnionych kredą i dodatkowo zawierających różne udziały dewulkanizatu. Dewulkanizaty natomiast otrzymano z pyłu gumowego metodą termomechaniczną. Otrzymane elastomery poddano badaniom w warunkach statycznych i przeprowadzono je na maszynie wytrzymałościowej. Określono wpływ czasu wulkanizacji, ilości napełniacza mineralnego oraz...
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The role of hydrogen bonding on tuning hard-soft segments in bio-based thermoplastic poly(ether-urethane)s
PublikacjaThis work describes the preparation of bio-based thermoplastic poly(ether-urethane)s (TPU) via a prepolymer method and investigates the effect of varying the interphase hydrogen-bonding (H-bonding) on physicochemical, thermal and mechanical properties. This was achieved by varying the glycol type and molar ratio of [NCO]/[OH] groups used during the prepolymer chain extending step. The TPUs’ chemical structure was analyzed by Fourier...
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Ground Tire Rubber Modified by Elastomers via Low-Temperature Extrusion Process: Physico-Mechanical Properties and Volatile Organic Emission Assessment
PublikacjaIn this paper, low-temperature extrusion of ground tire rubber was performed as a proecological waste tires recycling method. During this process, ground tire rubber was modified with constant content of dicumyl peroxide and a variable amount of elastomer (in the range: 2.5–15 phr). During the studies, three types of elastomers were used: styrene-butadiene rubber, styreneethylene/butylene-styrene grafted with maleic anhydride and...
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Properties of PA6/thermoplastic polyurethane and PA6/polyurethane nanocomposite blends
PublikacjaPrzedstawiono wyniki badań właściwości i struktury mieszanin i nanokompozytów układów PA6/termoplastyczny poliuretan. W przypadku nanokompozytów wprowadzano nanonapełniacz w postaci montmorylonitu. Zbadano właściwości termiczne i wytrzymałościowe oraz omówiono wyniki analiz strukturalnych, otrzymanych z dyfrakcji rentgenowskiej i mikroskopii elektronowej.
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Studies on the Combined Impact of Starch Source and Multiple Processing on Selected Properties of Thermoplastic Starch/Ethylene-Vinyl Acetate Blends
PublikacjaThermoplastic starch (TPS)/ethylene vinyl acetate (EVA) blends compatibilized with polyethylene-graft-maleic anhydride (PE-g-MA) were prepared from various native starches (potato, maize and waxy maize) and subjected to multiple extrusion cycles. Source of starch has significant impact on its composition, hence properties of obtained TPS and their blends with EVA. Higher content of amylopectin in waxy maize starch, comparing to...
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Conductive Thermoplastic Polyurethane Nanocomposite Foams Derived from a Cellulose/MWCNTs Aerogel Framework: Simultaneous Enhancement of Piezoresistance, Strength, and Endurance
PublikacjaHigh conductivity and excellent mechanical properties of composite polymers favors their application as piezoresistive strain sensors. Nonetheless, it is difficult to develop composite polymers with desirable piezoresistance, mechanicaland durable properties. Herein, we developed conductive cellulose/MWCNTs aerogel using the freeze-drying technique. Besides, we explored the application of the highly-sensitive piezoresistive polymer...
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PLA–Potato Thermoplastic Starch Filament as a Sustainable Alternative to the Conventional PLA Filament: Processing, Characterization, and FFF 3D Printing
PublikacjaThe growing popularity of the fused filament fabrication (FFF) 3D printing technology in science, industry, and in-home use is associated with an increased demand for high-quality polymer filaments. This study presents an in-depth characterization and analysis of a self-made bio-based polylactide (PLA)/thermoplastic potato starch (TPS) filament dedicated for the FFF 3D printing technology. The obtained results were compared with...
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Dynamic mechanical thermal analysis of polyamide 6/thermoplastic polyurethane blends
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FTIR Study and Mechanical Properties of Cellulose Fiber-Reinforced Thermoplastic Composites
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Properties of polyamide 6 and thermoplastic polyurethane blends containing modified montmorillonites
PublikacjaAnalizie poddano nowy rodzaj mieszanin polimerowych poliamidu 6 z termoplastycznymi elastomerami poliuretanowymi. Mieszaniny wzmocniono poprzez dodatek organicznie modyfikowanych montmorylonitów (Cloisite). Uzyskane układy przebadano metodami termicznymi, dyfrakcyjnymi oraz scharakteryzowano podstawowe właściwości mechaniczne.
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Mitigating Stripping in Asphalt Mixtures: Pretreatment of Aggregate by Thermoplastic Polyethylene Powder Coating
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Effect of molar ratio [NCO]/[OH] groups during prepolymer chains extending step on the morphology and selected mechanical properties of final bio‐based thermoplastic poly(ether‐urethane) materials
PublikacjaThe main aim of this work was to investigate the effect of [NCO]/[OH] molar ratio used during the prepolymer chain extending step (with bio‐based diols) on the chemical structure, and thermomechanical and mechanical properties of thermoplastic poly(ether‐urethane)s. Thermoplastic poly(ether‐urethane)s were obtained from bio‐based polyol (polytrimethylene ether glycol), bio‐based glycol (1,4‐butanediol or 1,3‐propanediol), and 4,4'diphenylmethane...
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Effect of E-Beam Irradiation on Thermal and Mechanical Properties of Ester Elastomers Containing Multifunctional Alcohols
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A novel method of creating thermoplastic chitosan blends to produce cell scaffolds by FDM additive manufacturing
PublikacjaDue to its remarkable and promising biological and structural properties, chitosan has been widely studied in several potential applications in the biomedical sector. Attempts are being made to use this polymer and its properties in thermoplastics dedicated to 3D printing in FDM technology. However, chitosan can be processed only from acid solution, which limits its applications. The paper presents a new path for the production...
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Real-time monitoring of volatiles and particles emitted from thermoplastic filaments during 3D printing
PublikacjaPresentation on the use of instrumental analytical techniques for the assessment of emission of volatiles and particulates during fdm 3d printing.
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Influence of e-Beam Irradiation on the Physicochemical Properties of Poly(polyol Succinate-co-Butylene Succinate) Ester Elastomers
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Medical Plant Extract Purification from Cadmium(II) Using Modified Thermoplastic Starch and Ion Exchangers
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E-Beam Effects on Poly(Xylitol Dicarboxylate-co-diol Dicarboxylate) Elastomers Tailored by Adjusting Monomer Chain Length
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Glass transition temperatures of polyurethane-urea elastomers based on N, N′-ethylenethiourea and N, N′-ethyleneurea as chain extenders
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Wpływ budowy chemicznej na zmiany właściwości mechanicznych i termomechanicznych elastomerów biopoliuretanowych = The influence of chemical structure on mechanical and thermomechanical properties of cast biopolyurethane elastomers
PublikacjaPrzedmiotem niniejszej pracy są elastomery biopoliuretanowe otrzymywane metodą dwuetapową, tzw. prepolimerową, z wykorzystaniem surowców bio-pochodnych. Zbadano wpływ różnych małocząsteczkowych przedłużaczy łańcucha prepolimerowego: 1,2-biopropanodiolu oraz 1,3-biopropanodiolu na strukturę chemiczną i właściwości mechaniczne (warunki statyczne i dynamiczne) elastomerów biopoliuretanowych. Ponadto, wykorzystano również inny surowiec...
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Shape Memory Materials from Rubbers
PublikacjaSmart materials are much discussed in the current research scenario. The shape memory effect is one of the most fascinating occurrences in smart materials, both in terms of the phenomenon and its applications. Many metal alloys and polymers exhibit the shape memory effect (SME). Shape memory properties of elastomers, such as rubbers, polyurethanes, and other elastomers, are discussed in depth in this paper. The theory, factors...
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Nonlinear Viscoelastic Properties of Polyurethane Nanocomposites
PublikacjaIn recent years, the nonlinear viscoelastic behaviors of elastomeric nanocomposites have been examined, especially for a wide range of rubbery composite (including natural rubber) materials. This chapter describes the influence of fillers and nanofillers on the nonlinear viscoelastic properties of elastomeric polyurethane systems. These filled elastomers (similar to the classic natural rubber reinforced elastomers), also exhibit...
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Assessment of dynamic characteristics of thin cylindrical sandwich panels with magnetorheological core
PublikacjaBased on the equivalent single-layer linear theory for laminated shells, free and forced vibrations of thin cylindrical sandwich panels with magnetorheological core are studied. Five variants of available magnetorheological elastomers differing in their composition and physical properties are considered for smart viscoelastic core. Coupled differential equations in terms of displacements based on the generalized kinematic hypotheses...
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Crystallization kinetics study of dynamically vulcanized PA6/NBR/HNTs nanocomposites by nonisothermal differential scanning calorimetry
PublikacjaInvestigation of crystallization behavior and kinetics of thermoplastic elastomer nanocomposites was the subject of limited works because of complexities associated with semiexperimental modeling of such phenomenon in a system containing components having completely different behavior in the molten state. Nonisothermal crystallization kinetics of dynamically vulcanized PA6/NBR/HNTs thermoplastic elastomer nanocomposites was mathematically...
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Investigation of polyurethane elastomer–steel joints using glass lacquer as an adhesive agent
PublikacjaThis article describes an innovative method of coupling polyurethane elastomer (based on polyurethane glycolysate) with constructional steel, by implementation of a Glaspur®—glass lacquer containing latent polyurethanes and monosilane adhesion promoters. The commonly applied coupling agent is Cilbond® 45SF glue or its derivatives. Additionally, glycolysate was synthesised from polyurethane waste and 1,3-propylene glycol in 6:1...
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Chemical modifications of natural oils and examples of their usage for polyurethane synthesis
PublikacjaNatural oils have been used in the production of plastics for a long time. However, the number of studies dedicated to polyurethane research has shown an increase only recently. Usually, petrochemical components are used in polyurethane synthesis. Nowadays, there have been attemptsmade to replace polyols in polyurethanes with the modified oils and other natural raw materials. It is a promising and important scenario because the...
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Porosity and swelling properties of novel polyurethane–ascorbic acid scaffolds prepared by different procedures for potential use in bone tissue engineering
PublikacjaIn this work, a novel polyurethane (PU) system based on poly(ethylene-butylene) adipate diol, 1,6-hexamethylene diisocyanate, 1,4-butanediol, and ascorbic acid was used to prepare scaffolds with potential applications in bone tissue engineering. Two fabrication methods to obtain porous materials were chosen: phase separation (PS)/salt particle leaching (PL) and solvent casting (SC)/salt PL. The calculated porosity demonstrated...
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Thermal properties. DSC analysis of poly(xylitol sebacate-co-butylene sebacate) PXBS.
Dane BadawczeIn this work, a bio-based copolyester with good mechanical properties was synthesized andcharacterized in terms of structure, main properties and biodegradability Determining the chemicalstructure of such materials is important to understand their behavior and properties. Performingan extraction of insoluble cross-linked polymer using di erent solvents...
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Use of response surface methodology in characterization of properties of recycled high density polyethylene/ground tire rubber compositions
PublikacjaSearching for newways to utilize rubber and polymerwaste has been the focus of many studies conducted by research centers and companies worldwide. In this study, the influence of extrusion conditions on the properties of thermoplastic compositions containing post-production recycled high density polyethylene (PE-HD) and ground tire rubber (GTR) at 50:50 mass ratiowas examined. Response Surface Methodology (RSM) was used to determine...
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Polyurethanes as a Potential Medical-Grade Filament for Use in Fused Deposition Modeling 3D Printers – a Brief Review
PublikacjaThe possibility of using 3D printing technology (3DP) in medical field is a kind of revolution in health care. This has contributed to a rapid growth in demand for 3D printers, whose systems and materials are adapted to strict medical requirements. In this paper, we report a brief review of polyurethanes as a potential medical-grade filament for use in Fused Deposition Modeling (FDM) 3D printer technology. The advantages of polyurethanes...
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Interfacial adhesion evaluation in (low-density polyethylene)/elastomer blends
PublikacjaLow-density polyethylene (LDPE) with different elastomers at a ratio of 50/50 wt% blends was prepared by using a co-rotating twin-screw extruder. Three kinds of elastomers were used: ground tire rubber (GTR), partially crosslinked butyl rubber (KalarVR ), and styrenebutadiene- rubber block copolymer (SBS; KratonVR ). For better characterization of interaction between polyethylene and elastomer, influence of the type of elastomer on...
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Effect of Compounding Conditions on Static and Dynamic Mechanical Properties of High Density Polyethylene/Ground Tire Rubber Blends
PublikacjaSearching for new and cost-effective methods of waste rubber recycling is a subject of research in many scientific centers in the world. In this paper there are presented results of the research of the extrusion process of cheap and environmentally friendly thermoplastic compositions containing 50 % wt. of masses of ground tire rubber (GTR). The aim of this study was to determine the relationship between the mixing conditions and...
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Structure and properties comparison of poly(ether-urethane)s based on nonpetrochemical and petrochemical polyols obtained by solvent free two-step method
PublikacjaThe application of thermoplastic polyurethanes (TPU) is becoming more and more extensive, and the decreasing of used petrochemical monomers and reduction of energy for the polymerization and processing processes is getting increasingly important. In this paper, we confirmed the positive influence of high bio-based monomers contents (by replacing petrochemical polyol and glycol by bio-based counterparts) on processing and properties...
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3D printed ABS thermoplastic vs. steel. Dry sliding wear test in constant load & velocity ring on flat configuration. Test parameters: print layer thickness and orientation. Test symbol: 009_v_2
Dane BadawczeData gathered in sliding ring-on-block (flat contact) tribological experiment. Materials: alloy steel (heat treated) vs. ABS plastic.
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3D printed ABS thermoplastic vs. steel. Dry sliding wear test in constant load & velocity ring on flat configuration. Test parameters: print layer thickness and orientation. Test symbol: 009_v_3
Dane BadawczeData gathered in sliding ring-on-block (flat contact) tribological experiment. Materials: alloy steel (heat treated) vs. ABS plastic.
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3D printed ABS thermoplastic vs. steel. Dry sliding wear test in constant load & velocity ring on flat configuration. Test parameters: print layer thickness and orientation. Test symbol: 009_h_3
Dane BadawczeData gathered in sliding ring-on-block (flat contact) tribological experiment. Materials: alloy steel (heat treated) vs. ABS plastic.
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3D printed ABS thermoplastic vs. steel. Dry sliding wear test in constant load & velocity ring on flat configuration. Test parameters: print layer thickness and orientation. Test symbol: 019_v_5
Dane BadawczeData gathered in sliding ring-on-block (flat contact) tribological experiment. Materials: alloy steel (heat treated) vs. ABS plastic.
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3D printed ABS thermoplastic vs. steel. Dry sliding wear test in constant load & velocity ring on flat configuration. Test parameters: print layer thickness and orientation. Test symbol: 009_h_5
Dane BadawczeData gathered in sliding ring-on-block (flat contact) tribological experiment. Materials: alloy steel (heat treated) vs. ABS plastic.
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3D printed ABS thermoplastic vs. steel. Dry sliding wear test in constant load & velocity ring on flat configuration. Test parameters: print layer thickness and orientation. Test symbol: 009_h_4
Dane BadawczeData gathered in sliding ring-on-block (flat contact) tribological experiment. Materials: alloy steel (heat treated) vs. ABS plastic.
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3D printed ABS thermoplastic vs. steel. Dry sliding wear test in constant load & velocity ring on flat configuration. Test parameters: print layer thickness and orientation. Test symbol: 039_h_4
Dane BadawczeData gathered in sliding ring-on-block (flat contact) tribological experiment. Materials: alloy steel (heat treated) vs. ABS plastic.
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3D printed ABS thermoplastic vs. steel. Dry sliding wear test in constant load & velocity ring on flat configuration. Test parameters: print layer thickness and orientation. Test symbol: 019_v_4
Dane BadawczeData gathered in sliding ring-on-block (flat contact) tribological experiment. Materials: alloy steel (heat treated) vs. ABS plastic.
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3D printed ABS thermoplastic vs. steel. Dry sliding wear test in constant load & velocity ring on flat configuration. Test parameters: print layer thickness and orientation. Test symbol: 019_h_5
Dane BadawczeData gathered in sliding ring-on-block (flat contact) tribological experiment. Materials: alloy steel (heat treated) vs. ABS plastic.
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3D printed ABS thermoplastic vs. steel. Dry sliding wear test in constant load & velocity ring on flat configuration. Test parameters: print layer thickness and orientation. Test symbol: 039_v_4
Dane BadawczeData gathered in sliding ring-on-block (flat contact) tribological experiment. Materials: alloy steel (heat treated) vs. ABS plastic.
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3D printed ABS thermoplastic vs. steel. Dry sliding wear test in constant load & velocity ring on flat configuration. Test parameters: print layer thickness and orientation. Test symbol: 009_v_4
Dane BadawczeData gathered in sliding ring-on-block (flat contact) tribological experiment. Materials: alloy steel (heat treated) vs. ABS plastic.
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3D printed ABS thermoplastic vs. steel. Dry sliding wear test in constant load & velocity ring on flat configuration. Test parameters: print layer thickness and orientation. Test symbol: 039_v_3
Dane BadawczeData gathered in sliding ring-on-block (flat contact) tribological experiment. Materials: alloy steel (heat treated) vs. ABS plastic.
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3D printed ABS thermoplastic vs. steel. Dry sliding wear test in constant load & velocity ring on flat configuration. Test parameters: print layer thickness and orientation. Test symbol: 019_v_3
Dane BadawczeData gathered in sliding ring-on-block (flat contact) tribological experiment. Materials: alloy steel (heat treated) vs. ABS plastic.
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3D printed ABS thermoplastic vs. steel. Dry sliding wear test in constant load & velocity ring on flat configuration. Test parameters: print layer thickness and orientation. Test symbol: 019_h_3
Dane BadawczeData gathered in sliding ring-on-block (flat contact) tribological experiment. Materials: alloy steel (heat treated) vs. ABS plastic.